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Adaptable "bubble particles" prepared by green aqueous phase reshaping for completely removing odor

Nano Research 2024年第3期17卷 2172-2180页

作者： Jiajia Ma yichang Xia Tienan Zhao Wenfeng Hu Weifeng Zhang Qinfei Ke Yi Zhao Shanghai Frontiers Science Center of Advanced Textiles Donghua UniversityShanghai 201620China Engineering Research Center of Technical Textiles Ministry of EducationDonghua UniversityShanghai 201620China School of Fashion Engineering Central Laboratory Shanghai University of Engineering ScienceShanghai 201620China Department of Materials Science and Engineering National University of SingaporeSingapore 117575Singapore School of Perfume and Aroma Technology Shanghai Institute of TechnologyShanghai 201418China

Facile and ecofriendly loading of micro/nano function-specific substances to create functional materials is a trend being pursued by ***,current micro/nano particles loading approaches are often hindered by issues such as uneven distribution,unsatisfactory stability and complicate *** this work,we present an aqueous phase reshaping method that only utilizes the moisture to fabricate the"bubble particles",which could perfectly cater to the topography of the *** green preparation of bubble particles adopts an absolutely zero-pollution method,realizing the firm loading of particles on the *** the preparation and loading of particles overcomes the traditional complicate process,while the aqueous phase reshaping ensures uniform and firm loading of the"bubble particles"onto the *** mechanism demonstrates a significant enhancement in the interface relation after aqueous phase reshaping,with a 12.-fold increase in contact surface area achieved by reducing the height by 1μ***,we explore for the first time the influence of the nature of the receiving substrate on the interface morphology of particles during electrostatic spraying,which has important guiding significance for the interface relationship of electrostatic spraying and even electrostatic spinning *** also screen out the natural antibacterial essential oil linalool as the effective specialized antibacterial agent,which can specifically inhibit the odor-producing Proteus in urine,with an antibacterial rate of up to 100%.Taken together,this simple,ecofriendly method for fabricating functional materials with optimal interface stability appears highly promising for use in various products formed by electrostatic spraying/spinning.

关键词： bubble particle electrostatic spraying aqueous phase reshaping interface bonding remove odor nano spraying

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Identification of Hercynian shoshonitic intrusive rocks in central Hainan Island and its geotectonic implications

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Science Bulletin 2006年第20期51卷 2507-2519页

作者： XIE Caifu1, 2. ZHU Jinchu1, DING Shijiang3. ZHANG Yeming2. FU Tai’an2.& LI Zhihong2.1. State Key Laboratory for mineral Deposits Research and Department of Earth Sciences, Nanjing University, Nanjing 2.0093. china 2. {2. institute of geology and mineral Resources, yichang 443.03. china 3. Hainan Bureau of geology and mineral Resources, Haikou 5702.6, china Department of Otolaryngology University Hospital VU P.O. Box 7057 1007 MB Amsterdam The Netherlands State Key Laboratory for mineral Deposits Research and Department of Earth Sciences Nanjing University Nanjing 210093 China

An identification has been made of some shoshonitic intrusive rocks in central Hainan Island recently. These rocks are K-rich (K2.=2.9%―5.1%, K2./Na2.=0.95―2.12., distinctly enriched in LILE and LREE, strongly depleted in Nb, Ta, and moder- ately depleted in Sr and Ti, with (87Sr/86Sr)i = 0.70859―0.7142. and ε Nd(t) = (?2.77―?7.49). They were derived from an EMⅡ-type mantle source. The enrichment process is related to metasomatism of depleted mantle caused by a great amount of fluid-melt released from oceanic crust and terri- genous sediments at great depth (eclogite facies) during the subduction of the South china plate under the Indochina-South china Sea plate in the Carbon- iferous–Early Permian. A SHRIMP U-Pb zircon dating yields a crystallization age of 2.2.7 Ma for the sho- shonitic intrusions, which is coeval with the strongly peraluminous granites found in central Hainan Island. These two kinds of rocks generally possess syn-intrusion ductile deformation structures. Thus they are considered to have been generated during the early stage (syn-thrust phase) of a post-collisional event. The primary magma of shoshonitic rocks was produced at a depth > 80 km by decompression- dehydration melting of previously enriched litho- spheric mantle wedge, phlogopite-bearing garnet peridotite, which was in turn caused by the break-off of a descendent slab and upwelling of a hot as- thenosphere. The rising of melts was accompaniedby crustal contamination and crystallization fractiona- tion (AFC). Combining with other related data, it is proposed that the southwards subduction and amal- gamation of the South china plate with the Indo- china-South china Sea plate took place at ca. 2.7- 2.8 Ma, which was a part of the convergence proc- ess of the Pangea supercontinent. The suture zone was probably located along the line of Song Ma-Beibu Gulf-north margin of the Yunkai Moun- tains-Wuyi Mountains.

关键词： SHRIMP U-Pb dating Hercynian shoshonitic intrusive rocks post-collisional event enriched mantle Hainan Island.

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Changes of infrared absorption wave number of aromatic-ring C=C bond of vitrinite and their significance

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Chinese Science Bulletin 1998年第12期43卷 1048-1050页

作者： XIAO Jianxin 1 and CHEN Shanqing 2.1. china University of Geosciences, Beijing 100083. china 2. {2. institute of geology and mineral Resources, yichang 443.03. china china University of Geosciences Beijing China yichang institute of {2. and {3. Resources Yichang China

The humilith series of lignite, longflame coal, gas coal, fat coal, coking coal, lean coal, meagre coal and anthracite are measured by FIR1600 infrared spectrophotometer. The variation curve between the infrared absorption wave number of aromaticring C--C bond of vitrinite and its reflectance values are gained, which shows the shift of infrared absorption wave number of aromaticring C--C bond of humic coals towards lower wave number with the increase of coalification. It is believed that the coal rank of humilith series can be determined and more evolutional information about coal composition and structure can be obtained by the infrared spectroscopic method.

关键词： aromatic_nucleus C--C bond infrared absorption wave number vitrinite humic coal.

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Aoyitake plagiogranite in western Tarim Block, NW china: Age, geochemistry, petrogenesis and its tectonic implications

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Science china Earth Sciences 2006年第11期49卷 1121-1134页

作者： ZHANG Chuanlin1,2. YU Haifeng3. YE Haimin2. ZHAO Yu2.& ZHANG Dongsheng4 1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou {3. of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, china 2. Nanjing {3. of geology and mineral Resources, Nanjing 2.0016, china 3. Tianjin {3. of geology and mineral Resources, Tianjin 3.0170, china 4. The 2.d Regional Geological Investigation Party, Xinjiang Bureau of geology and mineral Resources, Changji 83.100, china 1. Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 2. Nanjing institute of geology and {2. Resources Nanjing 210016 China 3. Tianjin institute of geology and {2. Resources Tianjin 300170 China 4. The 2.d Regional Geological Investigation Party Xinjiang Bureau of Geology and Mineral Resources Changji 831100 China

SHRIMPP U-Pb zircon age and geochemical and Nd isotopic data are reported for the Aoyitake plagiogranite in western Tarim Block, NW china. The plagiogranite intruded the Middle Pro- terozoic and Lower Carboniferous with an exposure area of ca. 60 km2.and crystallized at 3.0.7±4.8 Ma. Rock types mainly include tonalite, trondhjemite and minor amounts of diorite and quartz-diorite. Feldspars in the rocks are dominated by oligoclase-andesine, and minor perthite observed locally. The granites are sodic with Na/K ratios (molar) between 4 and 87. Total REE (50-2.0 ppm) show a clear positive correlation with SiO2. There is no LRRE/HREE fractionation (LaN/YbN=0.5-1.5), me- dium negative Eu anomalies (δ Eu=0.3.0.6), high Y content and low Sr/Y ratio (~1.0). These granites exhibit relatively juvenile Nd T2.M model ages of 470 to 580 Ma and positive εNd(3.1 Ma) values of 6.2. to 7.65. The aforementioned characteristics are similar to those of ocean island or ocean ridge plagiogranites. However, the regional geology, especially its scale, precludes that the plagiogranite pluton was derived directly from fractionational crystallization of mantle-derived basaltic magma. We interpreted that the primary magma of the pluton might be tonalitic in composition generated by ca. 50% partial melting of the juvenile basaltic crust. The primary magma experienced intensive frac- tionational crystallization, and intruded into the middle to upper crusts to form the granite pluton. In combination with the previous regional geological data, it is concluded that the plagiogranite pluton was emplaced within the Tarim Block in respond to the Carboniferous continental rifting along the Tianshan orogenic belt.

关键词： western Tarim, Aoyitake plagiogranite, age, geochemistry, tectonic implications.

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Hydrogen and Oxygen Isotope Fractionation Mechanism in the Hydrothermal System and Its Geologic Significance

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Acta Geologica Sinica(English Edition) 1992年第4期66卷 397-409页

作者： Chen Zhensheng Zhang Ligang yichang institute of {2. and {3. Resources, Chinese Academy of Geological Sciences, yichang, Hubei Jiang Minxi yichang institute of {2. and {3. Resources Chinese Academy of Geological Sciences Yichang Hubei

The geochemical behaviors of hydrogen and oxygen isotopes in the hydrothermal system and their inher-ent relationship with the water / rock exchange are discussed in this paper In addition to the temperature con-ditions, the effective W / R ratio is another factor controlling the changes in H and O isotope compositions ofthe altered rock and hydrothermal water. Besides, the application and geological significance of the water-rockexchange theory are also discussed in the light of the H and O isotope compositions and their variation charac-teristics of the mineralizing hydrothermal water and altered rocks from several mineral deposits. Finally, abrief evolutional model of H and O istotope compositions of meteoric and magmatic hydrothermal waters in ahydrothermal system is given.

关键词： hydrothermal system isotope fractionation mechanism water/rock exchnage effective W/R ratio evolutional model

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The Genetic Types of Some Granite Intrusions Associated with Tin Polymetallic Deposits in the Nanling Region

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Acta Geologica Sinica(English Edition) 1988年第3期1卷 307-324页

作者： Liu Houqun Yang Shiyi yichang institute of {2. and {3. Resources, CAGS, yichang, Hubei yichang institute of {2. and {3. Resources CAGS Yichang Hubei

Tin polymetallic deposits are the most important type of tin deposit in the Nanling region. Manyresearchers both at home and abroad consider this type of tin deposit to be the product of differentiation andevolution of granite magmas resulting from anatexis of continental crust and to be genetically related to thetransformation-type (S-type) granitoids. In this paper, on the basis of the geological settings, petrology, REEgeochemistry and strontium and oxygen isotopic compositions of 6 granite intrusions associaied with tinpolymetallic deposits in the Nanling region, the authors suggest that the ore-bearing granites of this type areprobably the products of differentiation and evolution of acid magmas resulting from 40-50‰ fractionalcrystallization of magmas formed by partial melting of the pre-existing intermediate-basic volcanic rocks ofmantle origin in the lower crust and a small amount of sialic material and belong to crust-mantle-derivedgranitoids (approaching I-type of B. W. Chappell and A.J.R. White, but being evidently different from theS-type granitoid related to W, Sn, Nb, Ta and REE deposits).

关键词： The Genetic Types of Some Granite Intrusions Associated with Tin Polymetallic Deposits in the Nanling Region

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Characteristics of fluid inclusion planes and dynamical mechanism of structure-fluid-ore-forming processes in Yindongpo gold deposit, Henan Province, china

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Chinese Science Bulletin 1999年第S2期44卷 150-152页

作者： WEI Changshan~1, ZHAI Yusheng~2.and GHI Sanchuan~2.1. yichang {3. of {2. and mineral Resources, Chinese Academy of Geoscience, yichang 443.03. china 2. china University of Geosciences, Beijing 100083. china yichang institute of {2. and {3. Resources Chinese Academy of Geoscience Yichang 443003 China china University of Geosciences Beijing 100083 China

THE Yindongpo gold deposit, situated in northern Tongbei County, northern Qinling orogenic belt, is alarge-scale one controlled by the Heqianzhuang anticline that plunges northwestwards and dips northeastwards. The ore-bodies locates in the carbon layers belonging to the Neoproterozoic Waitoushan *** ore-forming periods can be distinguished: the pre-Mesozoic epithermal mineralization in primary sediment with metamorphic superposition and the Mesozoic epithermal-mesothermal mineralization related totectonomagmatic activities. The principal ore-forming period can be divided into four stages. The ore bodies consist of networked and brecciated quartz veins. Gold is mainly rich in the veinlet-type quartz veinsthat formed during the diagentic-metamorphism or syn-metamorphic hydrothermal period, but a little inthe coarse veins related to later tectonomagmatic activities. The phenomenon that the fracturing degree

关键词： fluid inclusion planes dynamical mechanism structure-fluid-ore-forming processes gold deposit Yindongpo Henan.

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The species diversity of fusulinaceans and high-frequency sea-level changes in the Carboniferous-Permian boundary section at Xikou, Zhen'an County,Shaanxi Province, china

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Science china Earth Sciences 2006年第7期49卷 673-683页

作者： ZHANG Haijun1, WANG Xunlian2. DING Lin1, XIA Guoying3.& WANG Lei2.1. institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100085, {3. 2. Faculty of Earth Sciences and {2. Resources, {3. University of Geosciences, Beijing 100083. {3. 3. Tianjin institute of geology and {2. Resources, Tianjin 3.0170, {3. 1. institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China 2. Faculty of Earth Sciences and mineral Resources China University of Geosciences Beijing 100083 China 3. Tianjin institute of geology and {2. Resources Tianjin 300170 China

The study on the interrelation between sea-level changes and biodiversity with its evolu-tion has great significance for understanding the impact of global changes on organic evolution and exploring the inherent laws of life-environment coevolution in geological history. In this paper, the stratigraphic distribution of fusulinacean fauna in the Carboniferous-Permian boundary section at Xikou, Zhen’an County, Shaanxi Province, is analyzed quantitatively, and the relationship between the species diversity of fusulinaceans and relative sea-level changes is discussed. As a whole, the spe-cies numbers of fusulinacean fauna experience a rapid increase and an obvious decline in Xikou, Zhen’an County, from the Late Carboniferous to the Early Permian. There is a significant increase in species diversity around the Carboniferous-Permian boundary, which is one of the biggest bio-events of the fusulinacean fauna, and represents the radiation of Pseudoschwagerininae subfamily in the studied area. Integrated fusulinacean species diversity into sequence stratigraphic framework, de-tailed study suggests that the species diversity of the fusulinaceans is closely related to its relative stratigraphic location, and is essentially controlled by the sea-level changes, especially by the high-frequency sea-level changes. Generally, the species diversity of fusulinaceans is low, and the number of first and last appearance datum is small in the lower unit of high-frequency depositional cycle formed during the quick rise of the sea level; whereas the species diversity of fusulinaceans is high, and the number of first and last appearance datum is large in the upper unit of high-frequency cycle formed during the slow fall of the sea level. Within the third-order depositional sequence, the species diversity of the fusulinaceans at the first flooding surfaces and the maximum flooding surfaces is low, and it increases upward. The fusulinacean species diversity is low within the transgressive syst

关键词： fusulinaceans, species diversity, high-frequency cyclothem, sequence stratigraphy, sea-level changes, Carboniferous-Permian boundary, Zhen'an, Shaanxi.

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^(2.7)Pb/^(2.6)Pb Zircon Dating of the Huangtuling Hypersthene-Garnet-Biotite Gneiss from the Dabie Mountains, Luotian County, Hubei Province, china: New Evidence for Early Precambrian Evolution

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Acta Geologica Sinica(English Edition) 1999年第1期73卷 78-83,127-128页

作者： JIAN Ping YANG Weiran and ZHANG Zichao institute of geology,CAGS,2. Baiwanzhuang Rd, Beijing 10003. {2. University of Geosciences, Wuhan, Hubei 43.074 yichang institute of geology and mineral Resources, CAGS, yichang, Hubei 443.03 institute of geology CAGS 26 Baiwanzhuang Rd Beijing 100037 china University of Geosciences Wuhan Hubei 430074 yichang institute of {2. and {3. Resources CAGS Yichang Hubei 443003

The Huangtuling hypersthene-garnet-biotite gneiss at Luotian County, Hubei Provine, is a typicalgranulite-facies rock of the Dabie Group Complex in the Dabie orogenic belt. Investigations on the morphology andoccurrence of zircons and their internal structures shown in the thin sections lead to the recognition of three types ofzircons, which are in good agreement with the types identified on the basis of morphology, colour and external fea-tures from the related zircon concentrates. The observation of zircons in the rock reveals that part of type 1 zirconsshow signs of a double-layered structure. The interval part existed in the protolith prior to the granulite-facies meta-morphism. Type 2. the prismatic zircons which mainly occur in garnet and hypersthene are metamorphic minerals ofthe granulite-facies metamorphism. Type 3. the round multifaceted zircons in felsic minerals and biotite, are proba-bly attributed to a later geological event related to migmatization. The ^(2.7)Pb/^(2.6)Pb zircon dating by direct evaporationon (thermal evaporation ion mass spectrometer) yields ages ranging from 2.14 Ma to 1992.Ma. The age discrepancyamong these different zircon types is conspicuous. The yellow-brown(type 1) zircons give ages of 2.14±2. Ma to2.2.±6 Ma, the prismatic euhedral zircons (type 2., 2.56±7 Ma to 2.54±4 Ma, and the round multifaceted zircons(type 3., 1992.10 Ma. The results are geologically interpreted in consideration of the complicated behaviours of zir-cons during Precambrian geological evolution of the Dabie area. (1) If the protolith of the gneiss is a sedimentaryrock, then type 1 zircons are clastic ones and the ages 2.14±2. Ma and 2.11±2. Ma may reflect the minimum age ofthe rocks of its source region. also the first geological event in the area. Sedimentation of the protolith occurred be-tween 2.14 Ma and 2.2. Ma, probably close to 2.14 Ma. If the protolith is a volcanic rock, then the formation age ofthe supracrustal rocks of the Dabie Group Complex is

关键词： Dabie Mountains granulite facies Archaean multistage evolution zircon 2.7~Pb/2.6~Pb

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On the siltation of the middle Yangtze River

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Science china Earth Sciences 2004年第5期47卷 463-480页

作者： YIN Hongfu1, CHEN Guojin2. LI Chang抋n1 & WEI Yuan3.1. School of Earth Sciences, china University of Geosciences, Wuhan 43.074, china 2. Hydrogeological Team, Hubei Bureau of {2. and mineral Resources, Jingzhou 43.100, china 3. Geological Survey of Jiangxi Province, Nanchang 3.02.1, china china Univ Geosci Sch Earth Sci Wuhan 430074 Peoples R China Hubei Bur Geol & mineral Resources Hydrogeol Team Jinzhou 434100 Peoples R China Geol Survey Jiangxi Province Nanchang 3300201 Peoples R China

About 5.2.108 t/a of silts from the upper reach of the Yangtze River are transported through yichang into the middle Yangtze River. The middle Yangtze itself and its tributaries yield ca. 0.8×108 t silts annually. Of this total 6×108 t/a input of silts, ca. 1.2.108 t/a are deposited within the river artery and lakes, while ca 4.83.108 t/a are at first transported into the lower reach through Datong, and then either deposited along the river and the Yangtze Delta, or output into the sea. Along the middle Yangtze River silting generally exceeds scouring, but the spatial and temporal distributions of scour-and-fill, as well as its distribution in the river valley transections, are uneven. Along the yichang-Chenglingji and Jiujiang-Datong Segments of the middle Yangtze, scouring exceeds or equals silting. Silting mainly occurs along the Luoshan-Wuhan-Huangshi Segments with Wuhan as the pivotal point, as well as in the Dongting and Poyang Lakes. Even in these silting-dominated areas, there are times and parts of segments that scouring prevails. As to the transections, generally the river channel of main stream is scouring-dominated, forming V-shaped sections to a depth of 2.3. m or more, whereas the floodplains and bar islands are silting-dominated, forming wide and relatively high flats, which are often artificially transformed into protected embankments. Because the Jingjiang Levee separates the Jianghan Plain from Yangtze to the south, little has been deposited in that plain except a few sediments from the Han River—a tributary of the middle Yangtze. This factor plus the tectonic sag of that plain has made the altitude of plain surface several meters lower than that of the levee in most of the areas. Sil-tation along the Luoshan-Wuhan-Huangshi Segments has resulted in the elevation of flood level in this and upstream segments. River channel scouring plus floodplain silting have caused the transections of the middle Yangtze valley typically with deep channel and height

关键词： the middle Yangtze, scour-and-fill, siltation, silt utilization.

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