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Photogeneration of the free radicals and singlet oxygen by chrysophanol from rheum

science china Chemistry 2004年第5期47卷 381-387页

作者： RAO Jing1,2. XIE Jie1, ZHAO Jingquan1 & ZHU Teng2.1. Key Laboratory of Photochemistry, Center for Molecular science, Institute of Chemistry, The Chinese Academy of sciences, {2. 100080, china 2. university of science and technology beijing, beijing 10083, china Key Laboratory of Photochemistry Center for Molecular Science Institute of Chemistry The Chinese Academy of Sciences Beijing China university of science and {2. beijing Beijing China

In the current work, chryosphanol (MHAQ) was isolated and purified from rheum, and the photosensitization activities were studied. In nitrogen-saturated DMSO solution, irradia- tion of chryosphanol (MHAQ) with visible light (>430 nm) produced the semiquinone radical anions (MHAQ??), which was intensified significantly by an electron donor NADH, suggesting electron transfer between the excited and ground state photosensitizer molecules. In an air-saturated DMSO solution, superoxide radical anions (O2.), trapped by DMPO, were detected. ?? It was proved that O2.was not originated from the singlet oxygen (1O2. but dependent on DMPO, ?? chrysophanol, oxygen and the irradiation time. The singlet oxygen and OH could also be pro- ? duced by the photosensitization of the photosensitizer. These suggest that chrysophanol pos- sesses the photosensitization activity via Type I mechanism and Type II mechanism. To evaluate the photosensitization activities of MHAQ, emodin and mixed anthraquinone derivatives ex- tracted from rheum, the relative productivities of O2.were estimated to be 1.8, 1.1 and 1.0 re- ?? spectively and the quantum yields for singlet oxygen to be 0.36, 0.53 and 0.14 respectively. Therefore, these low-cost pigments may be potentially used as phototherapeutic medicine for some kind of vascular diseases or photo-activated pesticides.

关键词： chrysophanol, ESR, semiquinone radical anions, superoxide radical anions, hydroxyl radical, singlet oxygen.

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CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,university of science and {2. beijing,beijing 100083,china

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Acta Metallurgica Sinica(English Letters) 1992年第9期5卷 178-182页

作者： QIAO Lijie LIU Rui XIAO Jimei university of science and {2. beijing,beijing,china

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词： stress corrosion cracking stress compoonent brass ammonia solution

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Characteristics of Water Absorption and the Loss of Dust-Sticking Agent

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International Journal of Minerals,Metallurgy and Materials 1999年第1期13卷 1-3页

作者： Longzhe Jin Thongan Jiang Auiying Jin (Resources Engineering School, university of science and {2. beijing, beijing 10083, china) Resources Engineering School University of Science and Technology Beijing Beijing 10083 China

The development of NCZ-1 dust-sticking agent was first intreduced in china. The speed of water absorption of dust-stick-ing agent was measured and studied on mining site and in laboratory, and then the law of water absorption of dust-sticking agent was analyzed. In addition, the mathematical model of the loss rate of dust-sticking agent was established by the application of fluid mechanics theory, and the method of determining the sprinkle parameters of dust-sticking agent was obtained. Through practical verifi-cation, it is found that the error of this mathematical model is less than 10%. So it can be used in the field.

关键词： dust-sticking, water absorption loss rate mathematical model

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Role of science and technology in environmentally sound urbanization in{2.

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Journal of Environmental sciences 1999年第3期11卷 298-302页

作者： Qin Da\|he, Liu Jian Bureau of science and technology for Resources and Environment, Chinese Academy of sciences, beijing\ 100864, china Bur. Sci. Technol. Rsrc. Environ. Chinese Academy of Sciences Beijing 100864 China

In the process of accelerating industrialization, urbanization is inevitable and important to chinas modernization drive. While people are cherishing the advantages of living in cities, the increasing negative impact of urbanization has to be put on the top of priority list. As urbanization proceeds, the existing pollution problem aggravates with not only increasing quantity of pollutants, but diversity as well. science and {2. have been contributing to urbanization process in both positive and negative ways. Nonetheless, the role of science and {2. in promoting sustainable urbanization is increasingly important. china has been conducting environmental research and development since the early 1970s, and now is capable of supplying most technologies needed for urban environmental protection. To keep pace with the rapid urbanization process in china, environmental research and {2. development should be strengthened. This is mostly dependent on domestic resources with introduction of advanced yet cost\|effective technologies from the rest of the world. With a survey of current urban environmental R & D in china and on\|going activities of the Chinese Academy of sciences (CAS), recommendations on future UCL(university College London)\|CAS collaboration in the domain of urban environment are made.

关键词： science technology urbanization environment.

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Theorems for Testing Local Activity of CNN and Application to Cardiac Purkinje Equations

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International Journal of Minerals,Metallurgy and Materials 2000年第2期14卷 139-146页

作者： Lequan Min(Applied science School, university of science and technology beijing, beijing 100083, china) Applied science School University of Science and Technology Beijing Beijing 100083 China

The theorems for testing the local in one-port cellular neural/inear network (CNN) cells with four local state variables are presented. Using the theorems computes the bifurcation diagrams of the cardiac Purkinje fiber (CPE) equations Which describethe long-lasting action and pace-maker potentials of the Purkinje fiber of the heart. The computer simulation shows that periodic trajectories or convergent trajectories of the CPF Equations can be foun if the cormsponing cell Parameters are located in a positive domainbut nearby edge of chaos. In particular a heart with approximate normal frequency of heartbeat but non-normal electrocardiogram maysuddenly stop by slightly perturbing the parameters of the corresponding CPF Equations when the Paramders are located nearby the edge of chaos in the bifurcation diagrams. This research seems to interpret reasonbly the phenomena that patients with cardiac diseases might suddenly die without warning.

关键词： cellular neural network local activity cardiac Purkinje fiber heartbeat

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Applicability of mass action law to sulphur distribution between slag melts and liquid iron

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Journal of university of science and {2. beijing 2002年第2期9卷 90-98页

作者： Jian Zhang Metallurgy School, university of science and {2. beijing, beijing 100083, china Metall. Sch. Univ. of Sci. and Technol. Beijing Beijing 100083 China

According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2._3-SiO_2.CaO-MgO-MnO-FeO-Fe_2._3-P_2._5-SiO_2.and CaO-MgO-MnO-FeO-Fe_2._3-Al_2._3-P_2._5-SiO_2.slag melts areformulated and sulphur distribution between the slag melts and liquid iron is treated. It is foundthat CaO, MnO and FeO promote desulphurization, while MgO is detrimental to desulphurization. Inaddition, the sulphur distribution coefficients between the slag melts and liquid iron andpresented.

关键词： mass action law coexistence theory of slag structure activity massaction concentration

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Carbon Solubility and Mass Action Concentrations of Fe-Cr-C Melts

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International Journal of Minerals,Metallurgy and Materials 2000年第2期14卷 86-91页

作者： Jtan Zhang(Metallurgy School, university of science and {2. beijing, beijing 100083, china) Metallurgy School University of Science and Technology Beijing Beijing 100083 China

An empirical equation of carbon solubility in Fe-Cr-C melts is regressed based on the experimental data from references. Acalculating model of mass action concentrations for these melts is formulated on the basis of the coexistence theory of metaIlic melts in-volving compound formation, the phase diagram of Cr-C system as well as thermodynamic data of Fe-Cr-C melts. According to the mod-el, the standard Gibbs free energies of formation of CrC and Cr3C2.are obtained. Satisfactory agreement between the calculated and me-asured values shows that the model can reflect the structural characteristics of Fe-Cr-C melts.

关键词： activity, coexistence theory mass action concentration saturated state

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Application of the annexation principle to the study of thermodynamic properties of ternary metallic melts In-Pb-Ag and In-Bi-Sb

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Rare Metals 2002年第2期21卷 142-151页

作者： ZHANG JianMetallurgical Engineering school.university of science and {2. beijing, beijing 100083, china Metallurgical Engineering School University of Science and Technology Beijing 北京 100083

Based on the phase diagrams, measured activities an the annexationprinciple, the calculating models of mass action concentrations forin-Pb-Ag and In-Bi-Sb ternary metallic melts have been *** results of calculation both agree with practice, and obey the lawof mass action, showing that the models formulated can reflect thestructural reality of the corresponding melts and the annexationprinciple is applicable to the them.

关键词： activity mass action concnetration th annexation principle In-PB-Ag

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Laser-field-induced magnon amplification in a magnetic semiconductor quantum well under an external magnetic field

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Journal of university of science and {2. beijing 2003年第5期10卷 69-72页

作者： Peng FengPhysics Department, university of science and {2. beijing, beijing 100083, china Phys. Dept. Univ. of Sci. and Technol. Beijing Beijing 100083 China

The laser-field induced magnon amplification in a magnetic semiconductorquantum well under an external magnetic field was discussed, it is shown that when the laserfrequency is near to the electron cyclotron frequency, no matter how weaker the laser field is, themagnon amplification always occurs. In case of fixed laser frequency, the optical absorption ofmagnons obeys the definite selection rule to the laser field strength. The rate of change of magnonoccupation is calculated, and the amplification condition is given.

关键词： magnon amplification magnetic semiconductor quantum well laser field

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Application of annexation principle to the study of thermodynamic properties of Ag-Bi-In metallic melts

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Journal of university of science and {2. beijing 2003年第1期10卷 18-20页

作者： Jian ZhangMetallurgy school, university of science and {2. beijing, beijing 100083, china Metall. Sch. Univ. of Sci. and Technol. Beijing Beijing 100083 China

Based on the measured activities, the phase diagrams and the annexation principle, the calculating models of mass action concentrations for Ag-Bi and Ag-Bi-In melts have been formulated. The calculated results agree with practice and obey the mass action law, showing that the models formulated can reflect the structural characteristics of both melts. Meanwhile, it confirms that annexation principle is applicable to the Ag-Bi-In metallic melts. The melts involving eulectic which give rise to phase separation, and in which activities exhibit positive deviation from Raoult's law is the basic cause of melts transforming from homogeneous to heterogeneous ones.

关键词： the mass action law annexation principle two phase melts activity, mass action concentration

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