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Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface

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Science china Chemistry 2005年第6期48卷 567-573页

作者： CHENG Caixia1, JIAO Tifeng2. TANG Rupei1, LIU Minghua2.& XI Fu1 1. state key {2. of Polymer physics and Chemistry, Joint {2. of Polymer Science and Materials, institute of Chemistry, chinese Academy of sciences, beijing 100080, china 2. CAS key {2. of Colloid and Interface Science, institute of Chemistry, chinese Academy of sciences, beijing 100080, china 1. state key {2. of Polymer physics and Chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China 2. CAS key laboratory of Colloid and Interface Science Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China

Diblock copolymer of PMMA2.1-b-PEO114 and triblock copolymer of PMMA12.-b- PEO2.7-b-PMMA12. were synthesized and their interfacial properties at the air-water interface were investigated, where both blocks of polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA) are surface active but the former is soluble in water while the latter is not. Both the block copolymers could form monolayers with two obvious transition regions. The first transition point is around 10 mN/m, which could be assigned to the pancake-brush change of the PEO chains. The other is around 18 mN/m, which could be ascribed to the condensed packing of PMMA. The surface morphological changes during the compression of the Langmuir monolayers are inves-tigated by using the AFM and SEM methods for the films deposited at different surface pressure or molecular areas. At a lower surface pressure, a typical morphology of PEO-con- taining lipopolymers is observed. Upon compression, sphere-dominant morphologies were observed. While the diblock copolymer is easy to folding, the triblock copolymer is in favor of formation of circular domains through vesiculation.

关键词： PMMA-PEO, block copolymers, monolayer, Langmuir-Blodgett films, AFM.

Compression behavior of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(2..5) bulk metallic glass up to 2. GPa

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Science china(physics,Mechanics & Astronomy) 2005年第3期48卷 319-324页

作者： LI Gong 1, 2., ZHAN Zaiji 2., LIU Jing 3 , YUN Jinku 1 , SUN Liling 2., LIU Riping 1 , ZHANG Jun 2.& WANG Wenkui 1, 2.1. key laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004,{2. 2. Center for Condensed Matter physics, institute of physics, chinese Academy of sciences, beijing 100080,{2. 3. BSRF, institute of High Energy physics, chinese Academy of sciences, beijing 100039,{2. 1. key laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. Center for Condensed Matter physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 3. BSRF Institute of High Energy Physics Chinese Academy of Sciences 100039 Beijing China

The compression of a Zr41Ti14Cu12.5Ni10Be2..5 bulk metallic glass (BMG) is investigated at room temperature up to 2. GPa using in-situ high pressure energy dispersive X-ray diffraction with a synchrotron radiation source. The pressure-induced structural relaxation is exhibited. It is found that below about 8 GPa, the existence of excess free volume contributes to the rapid structural relaxation, which gives rise to the rapid volumetric change, and the structural relaxation results in the structural stiffness under higher pressure.

关键词： bulk metallic glass, high pressure, structural relaxation, synchrotron radiation.

Large-scale boron nanowire nanojunctions and their highly-oriented arrays

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Science china(physics,Mechanics & Astronomy) 2004年第5期47卷 621-632页

作者： CAO Limin1,2. ZHANG Ze2.& WANG Wenkui1,2.1. key laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004,{2. 2. institute of physics, chinese Academy of sciences, beijing 100080,{2. 1. key laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. institute of physics Chinese Academy of Sciences 100080 Beijing China

Highly oriented multiple boron nanowire nanojunctions with unilateral feather- like morphology were first successfully prepared using a radio-frequency magnetron sputtering method. The branched boron nano-feathers always nucleate and grow on the same sidewall of the stems, and align in parallel to form multiple T- and/or Y-type nanojunctions. The diameters of the branches and the stems are in the range of 2.—40 and 60—80 nm, respectively. The thinner branches and thicker stems of the boron nanowires self-assembled into large-scale, highly ordered arrays on various substrates. During the formation and self-assembly of the arrays, no template or catalyst was needed. We believe that the approach presented here can be used to fabricate heterostructures with bottom-up assembly of a wide variety of one-dimensional nanostructures via the rational design of targets and the proper control of the experimental conditions.

关键词： boron nanowires, nanojunctions, self-assembly, magnetron sputtering.

Nonlinear interactions between gravity waves and background winds

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Progress in Natural Science:Materials International 2007年第6期17卷 639-644页

作者： Liu Xiao1,2.and Xu Jiyao1(1. state key {2. for Space Weather, Center for Space Science and Applied Research, chinese Academy of sciences, beijing 100080, china 2. Graduate University of chinese Academy of sciences, beijing 100039, china) [a]state key {2. for Space Weather Center for Space Science and Applied Research Chinese Academy of Sciences Beijing China [b]Graduate University of chinese Academy of sciences Beijing China

Using the nonlinear propagating gravity waves (GW) model in the two-dimensional compressible atmosphere and the linear GW theory, the process of GW propagation in different background winds, e.g. the direction of the background wind is opposite to (dead wind) or the same as (tail wind) the direction of the horizontal phase velocity of GW, is studied. The results show that the dead wind prolongs the vertical wavelength and accelerates GW propagation. Therefore, GW propagates up to a higher height becomes instable in a short time and eventually induces an inverse jet flow. Then, the vertical wavelength is becoming short due to the nonlinear interactions between GW and the inverse jet flow. The vertical wavelength and group velocity decrease after GW propagates into the tail wind. The initial instable time is delayed. Although most of GW is trapped in the instable region, some of GW propagates above the instable region. Compared with GW propagation in the tail wind, the nonlinear interactions between GW and the dead wind are also strong. In contrast, the linear GW theory predicts that GW can propagate freely in the dead wind. The vertical wavelength simulated by the nonlinear numerical model is different from that predicted by the linear theory greatly after GW propagates into the dead wind.

关键词： gravity waves background winds vertical group velocity vertical wavelength nonlinear interactions.

Gasdynamic characteristics of toroidal shock and detonation wave converging

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Science china(physics,Mechanics & Astronomy) 2005年第6期48卷 739-749页

作者： TENG Honghui1,2.& JIANG Zonglin2.1. key laboratory of High Temperature Gas Dynamics, {2. of Mechanics, chinese Academy of Sci- ences, beijing 100080, china 2. Graduate University of chinese Academy of sciences, beijing 100039, china 1. key laboratory of High Temperature Gas Dynamics Institute of Mechanics Chinese Academy of Sciences 100080 Beijing China 2. Graduate University of chinese Academy of sciences 100039 Beijing China

The modified CCW relation is applied to analyzing the shock, detonation wave converging and the role of chemical reactions in the process. Results indicate that the shock wave is strengthened faster than the detonation wave in the converging at the same initial Mach number. Euler equations implemented with a detailed chemical reaction model are solved to simulate toroidal shock and detonation wave converging. Gasdynamic characteristics of the converging are investigated, including wave interaction patterns, observable discrepancies and physical phenomena behind them. By comparing wave diffractions, converging processes and pressure evolutions in the focusing area, the different effects of chemical reactions on diffracting and converging processes are discussed and the analytic conclusion is demonstrated through the observation of numerical simulations.

关键词： converging, CCW relation, shock wave, detonation wave.

Effective solutions to a global 3D visual system in networking environments

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Science china Earth sciences 2005年第11期48卷 2032-2039页

作者： ZHANG Liqiang1,2. ZHANG Yan3, YANG Chongjun2. LIU Suhong1, REN Yingchao2. RUI Xiaoping2.& LIU Donglin2.1. state key {2. of Remote Sensing sciences, School of Geography and Remote Sensing, beijing Normal University, beijing 100875, china 2. state key {2. of Remote Sensing sciences, institute of Remote Sensing Applications, {12. Academy of sciences, beijing 101001, china 3. institute of Geographical sciences and Natural Resources Research, {12. Academy of sciences, beijing 101001, china 1. state key {2. of Remote Sensing sciences School of Geography and Remote Sensing Beijing Normal University 100875 Beijing China 2. chinese Academy of sciences State Key Laboratory of Remote Sensing SciencesInstitute of Remote Sensing Applications 101001 Beijing China 3. institute of Geographical sciences and Natural Resources Research Chinese Academy of Sciences 101001 Beijing China

The development of Web-based global 3D visual system has made progresses. However, there exist few mature and effective ways for managing, transmitting and visualizing massive spatial data. Based on the related work, the paper illustrates the ellipsoidal quadtree technique for rapid access multi-scale and multiple level geographical data, integrates the streaming with level-of-detail rendering method for transmitting the data on the network, and im-plements large-scale terrain surface simplification using M-band wavelet transforms and mul-tiresolution triangulations. We fulfil a web-based global terrain visual system using COM com-ponents on the basis of the above techniques. The system has a good prospect in the military simulation and city plans.

关键词： massive spatial data, streaming transmission, system architecture, M-band wavelet

Characteristics and geological significance of olivine xenocrysts in Cenozoic volcanic rocks from western Qinling

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Progress in Natural Science:Materials International 2006年第12期16卷 1300-1306页

作者： SU Benxun~ 1,2.**, ZHANG Hongfu~1, XIAO Yan~ 1,2.and ZHAO Xinmiao~ 1,2.(1. state key {2. of Lithospheric Evolution, institute of Geology and Geophysics, chinese Academy of sciences, beijing 10002., china 2. Graduate School of chinese Academy of sciences, beijing 100039, china) [a]state key {2. of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China [b]Graduate School of chinese Academy of sciences Beijing China

Cenozoic volcanic rocks from the Haoti, Dangchang County of the western Qinling Mountains, contain a few clearly-zoned olivines. These olivines are relatively big in grain sizes and usually have cracks or broken features. Their cores have similar compositions （Mg#=90.4-91.0） to those for the peridotitic xenoliths entrained in host volcanic rocks and their rims are close to the compositions of olivine phenocrysts （Mg#=85.5-81.9）. The CaO contents in these zoned olivines are lower than 0.1%. These features demonstrate that the clearly-zoned olivines are xenocrysts and disaggregated from mantle peridotites. The zoned texture was the result of the interaction between the olivine and host magma. Available data show that the volcanic rocks would have been derived from the mantle source metasomatized by subducted hydrathermally-altered oceanic crust. The formation of these Cenozoic volcanic rocks was perhaps related to the rapid uplift of the Tibetan Plateau.

关键词： Western Qinling Dangchang Haoti Cenozoic volcanic rocks olivine xenocrysts zoned texture.

Wet-chemical synthesis and characteristics of Au nanoshell

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Science china Chemistry 2005年第5期48卷 431-435页

作者： LIU Zhongxin1,2. SONG Hongwei1, YU Lixin1,2. YANG Linmei1,2.& PAN Guohui1,2.1. key laboratory of Excited {2. physics, Changchun institute of Optics, Fine Mechanics and physics, chinese Academy of sciences, Changchun 130033, china 2. Graduate School of the chinese Academy of sciences, beijing 100039, china 1. key laboratory of Excited {2. physics Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences 130033 Changchun China 2. Graduate School of the chinese Academy of sciences 100039 Beijing China

Gold nanoshells were prepared by an easy wet-chemical method, with Ag nanoparticles used as the templates. Transmission electron microscopy (TEM) indicated that the shells were sphere in shape, the size was homogenous, being about 2. nm, and no hard ag-glomerates were observed. The plasma resonance absorption of gold was tuned from visible to near-infrared (NIR) with the increased volume of HAuCl4. The temperature grads (?T) of the gold nanoshell hydrosol under the exposure of an 808-nm optical fiber laser with different power den-sities were measured. The highest ?T was 30℃ (5 W/cm2. irradiation area was 2.cm2.. This kind of gold nanoshell hydrosol is a promising material to be used in biomedicine such as photo-thermal cancer therapy, and its special photothermal convert property will photothermally trigger drug release.

关键词： wet-chemical synthesis, Au, nanoshell, NIR absorption, photothermal conversion.

Persistent anomalous flows over the subtropical western Pacific insummer

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chinese Science Bulletin 1998年第8期43卷 672-675页

作者： ZHUANG Shiyu\+1 and JI Liren\+2.1. National Meteorological Centre, china Meteorological Administration, beijing 100081, china 2. LASG, institute of Atmospheric physics, chinese Academy of sciences, beijing 100080, china National Meteorological Ccntre China Meteomlcgical Administration Beijing China LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China

The distribution of global persistent anomalies shows that the subtropical western Pacific is a key region with high_frequency occurrence of persistent anomalies. Analyses of streamfunction anomalies, OLR anomalies etc. suggest that the convective heating related to Indian monsoon might be responsible for the development of WPA. The results of numerical experiment by two linear barotropic models support the observation.

关键词： persistent anomalies subtropical high Indian monsoon anomalous forcing.