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Friction-reducing and antiwear behavior of metal halide-stabilized linear phosphazene derivatives as lubricants for a steel-on-steel contact

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Science china(Technological sciences) 2005年第3期48卷 282-291页

作者： ZHU Jiamei 1,2., LIU Weimin 2.& LIANG Yongmin 2.1. School of chemical Engineering and Technology, china University of Mining and Technology, Xuzhou 2.1008, china 2. state key laboratory of solid lubrication, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 730000, china 1. School of chemical Engineering and Technology China University of Mining and Technology 221008 Xuzhou China 2. state key laboratory of solid lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences 730000 Lanzhou China

A series of novel metal halide-stabilized linear phosphazene derivatives were synthesized. The friction-reducing and antiwear abilities of the resulting products as the lubricants for a steel-on-steel contact were comparatively investigated on an Optimol SRV oscillating friction and wear tester. The morphology of the worn steel surface was observed on a scanning electron microscope, while the chemical states of some typical elements on the worn steel surface were examined by means of X-ray photoelectron spectroscopy. It was found that both the side branch structures and central metals influenced the friction-reducing and antiwear behaviors of the synthetic derivatives as the lubricants, which was related to the different adsorption activities of the organic compounds composed of different organic ingredients and metallic ions on a nascent metal surface. All the synthetic lubricants except for the iron (III) derivative showed increased antiwear abilities with increasing metallic ionic radius. A protective layer originated from the tribochemical reaction together with the adsorbed boundary lubricating layer containing organic fluorine compounds, nitrogen oxide, and Fe 3 (PO 4 ) 2.plays an important role in improving the friction and wear behavior of the steel-on-steel system.

关键词： metal halide-stabilized linear phosphazene derivatives,lubricant,steel,tribological properties.

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Preparation and Characterization of ZrO_2.Nanoparticles Capped by Trioctylphosphine Oxide (TOPO)

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Journal of Wuhan University of Technology(Materials Science) 2011年第4期26卷 611-614页

作者：马剑琪 School of Chemistry and Environmental Science Shaanxi University of Technology state key {2. of solid lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences

Monodisperse ZrO2.nanoparticles capped by trioctylphosphine oxide （TOPO） were prepared in non-aqueous solvent using in-situ synthesis method. Transmission electron microscopy（TEM）, X-ray diffraction（XRD）, X-ray photoelectron spectrometer（XPS）, Fourier transformation infrared spectroscopy （FTIR）, and thermogravimetric analysis（TGA） were adopted to characterize and investigate the size, structure, composition, and the binding manners between organic capping agent TOPO and inorganic ZrO2.nanocores of the as-prepared nanoparticles. In addition, the nanoparticles were also studied to determine their solubility and relative stability. The experimental results show that the prepared nanoparticles contain about 2.% organic capping shell TOPO, 75% inorganic ZrO2.nanocores, and can be easily dissolved and be stably disersed in non-polar organic solvents.

关键词： ZrO2.nanoparticles trioctylphosphine oxide (TOPO) monodisperse solubility

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Wear Behavior of Cu Matrix Composites Reinforced with Mixture of Carbon and Carbon Nanotubes

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Journal of Wuhan University of Technology(Materials Science) 2009年第2期24卷 254-257页

作者：姜金龙 School of Science Lanzhou University of Technology state key {2. of solid lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences

In order to improve wear resistance and decrease the cost, carbon and carbon nanotubes reinforced copper matrix composites were fabricated by the power metallurgy method. The effects of carbon （carbon and carbon nanotubes） volume fraction and applied load on the friction coefficient and wear rate under dry sliding of the composites were investigated at room temperature. By scanning electron microscopy （SEM）, the worn surfaces and debris were observed, and wear mechanism was also analyzed and discussed. The experimental wear process consists of the run-in, steady wear and severe wear process with the increasing of sliding distance. Both the friction coefficient and wear rate of the composites first decrease and then increase with the increasing of carbon volume fraction. The minimum friction coefficient and wear rate are obtained when carbon is 4.0vo1%. The wear mechanisms of the composites change from the adhesive wear and delamination wear to abrasive wear with the increasing of carbon volume fraction.

关键词： C/Cu matrix composite power metallurgy wear behavior

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Characterization and Tribological Behavior of Octadecene,Dodecene and Undecenoic Acid Films on Si Substrate

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Journal of Materials Science & Technology 2005年第5期21卷 671-674页

作者： Jinfang ZHOU+ and Shengrong YANGstate key {2. of solid lubrication, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou730000, china state key {2. of solid lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

The films of octadecene, dodecene, and undecenoic acid were prepared on H-terminated Si surface in the presence of ultraviolet irradiation. The resulted films were characterized with water-contact angle measurement and infrared spectroscopy. The friction-reducing behavior of the prepared films was examined on a static-dynamic friction coefficient measurement apparatus and on an atomic force microscope. It was found that all the reacted films on the Si substrate showed good friction-reducing ability; especially, the film of the octadecene exhibited the best friction-reducing ability. This was attributed to the transfer of the reacted films onto the counter face with formation of a transfer film on the counterpart surface, which led to the transformation of the sliding between the reacted films and the hard ceramic to fiat between the reacted films and its transfer film on the counterpart surface. The macroscopic and microscopic friction behaviors of the prepared films were dependent on their molecular chain lengths. Thus the octadecene reacted film with the highest degree of ordering arrangement showed the best friction-reducing and antiwear abilities in sliding against Si3N4.

关键词： Alkese Reaction film Hydrogen-terminated silicon Tribological behavior

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Asymmetric Catalytic Hydrogenation Using Rhodium Diphosphinites Derived From D-glucose and D-mannitol

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chinese chemical Letters 2000年第7期11卷 587-588页

作者： Peng JIANG Shi Jie LU(state key {2. of Oxo Synthesis and Selective Oxidation, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 730000) chinese Acad Sci Lanzhou Inst Chem Phys State Key Lab Oxo Synth & Select Oxidat Lanzhou 730000 Peoples R China

Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl e... 详细信息

关键词： asymmetric catalysis hydrogenation rhodium diphosphinites alpha-acetamidocinnic acid

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Three Novel Eremophilanolides from Ligularia virgaurea ***

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chinese chemical Letters 2004年第12期15卷 1441-1444页

作者： Quan Xiang WU Yan Ping SHI Li YANG state key {2. of Applied Organic Chemistry, lanzhou University, lanzhou 730000 lanzhou institute of chemical physics chinese academy of sciences (CAS) lanzhou 730000 state key {2. of Applied Organic Chemistry Lanzhou University lanzhou institute of {2. physics Chinese Academy of Sciences (CAS)

From the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala,three novel eremophilane sesquiterpene lactones, 6α, 10α-dihydroxy-1-oxoeremophila- 7(11),8(9)-dien-8, 12.olide, 6β, 10α-dihydroxy-1-oxoeremophila-7 (11), 8 (9)-dien-8, 12.olide and10α-diydroxy-1-oxoeremophila-7(11), 8 (9)-dien-8, 12.olide were isolated. Their structure s wereelucidated by various, spectroscopic methods including intensive 2. NMR techniques (COSY,HMQC, HMBC and ~1H-~1H NOESY) and HR-MS.

关键词： Ligularia virgaurea spp oligocephala Compositae sesquiterpene lactones eremophilanolides.

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Reaction Chemistry of W-Mn/SiO2.Catalyst for the Oxidative Coupling of Methane

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Journal of Natural Gas Chemistry 2003年第1期12卷 1-9页

作者： Shuben Listate key {2. for Oxo Synthesis and Selective Oxidation, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 730000, china state key {2. for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

Reaction chemistry of the OCM reaction on W-Mn/SiO_2.catalyst has beenreviewed in this account. Initial activity and selectivity, stability in a long-term reaction,reaction at elevated pressures and a modelling test in a stainless-steel fluidized-bed reactor showthat W-Mn/SiO_2.has promising performance for the development of an OCM process that directlyproduces ethylene from natural gas. A study on surface catalytic reaction kinetics and used catalyststructure characterization revealed a possible reason why C_2.and CO_x selectivity changed duringthe long-term reaction. Further improvement of the catalyst composition and preparation methodshould be a future direction of study on OCM reaction over W-Mn/SiO_2.catalyst.

关键词： W-Mn/SiO_2.catalyst oxidative coupling of methane elevated pressure methane

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Microstructure and Wear Resistance Evolution of HVOFSprayed WC-(W,Cr)_2.-Ni Coating with Post Heat Treatment In Air Atmosphere

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稀有金属材料与工程 2012年第S1期41卷 388-393页

作者： Hou Guoliang1,2.Zhou Huidi1,An Yulong1,2.Liu Guang1,2.Chen Jianmin1,Chen Jie1,2.1 state key {2. of solid lubrication,lanzhou institute of chemical physics,chinese academy of sciences,lanzhou 730000,china 2.Graduate University,chinese academy of sciences,Beijing 100049,china chinese Acad Sci Lanzhou Inst Chem Phys State Key Lab Solid Lubricat Lanzhou 730000 Peoples R China chinese Acad Sci Grad Univ Beijing 100049 Peoples R China

WC-(W,Cr)2.-Ni coating was prepared on 1Cr18Ni9Ti stainless steel and C-2.6 Ni-base Hastelloy by high velocity oxy-fuel(HVOF)*** effect of post heat treatment in air atmosphere on the microstructure,phase composition,microhardness,fracture toughness,and wear resistance of HVOF-sprayed WC-(W,Cr)2.-Ni coating was *** microstructure and phase composition of the coatings were analyzed by means of field emission scanning electron microscopy(FESEM)and X-ray diffraction(XRD).The microhardness and fracture toughness of the coatings were measured using a microhardness tester and a Vickers hardness ***,dry friction and wear behavior of the coatings sliding against Si3N4 ball was investigated using an oscillating friction and wear tester;and the worn surfaces of the coatings were analyzed by means of scanning electron microscopy(SEM).It was found that heat treatment within 500-800°C resulted in crystallization of amorphous phase in as-sprayed coating,generating nanoscale new phases such as NiWO4,CrWO4 and ***,heat treatment led to increase of the microhardness of as-sprayed coating,and the highest microhardness was obtained after heat treatment at 800°*** fracture toughness and wear resistance of the as-sprayed coating increased with increasing heat treatment temperature up to 700°C but tended to decrease with further elevating *** other words,the mechanical properties and wear resistance of the as-sprayed coatings were worsened owing to excessive growth of oxidation grains and depletion of ductile Ni binder after heat treatment above 700°*** it was suggested that as-sprayed ceramic composite coating should be post heat treated in air at a moderate temperature of 700°C so as to achieve the optimized mechanical properties and wear resistance.

关键词： HVOF WC-(W,Cr)2.-Ni coating post heat treatment microstructure wear resistance

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Ice core dust particulate by XPS-SEM/EDAX——Impact of dust particulate on SO_4^(2.) record in ice cores

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chinese Science Bulletin 1999年第15期44卷 1424-1427页

作者： LI Zhongqin , LU Gongxuan , LIU Baozhong , FU Hongxiang LIU YuTianshan Glaciological Station , lanzhou institute of Glaciology and Geocryology ,{2. , lanzhou 730000,china state key laboratory for Oxo Synthesis and Selective Oxidation, lanzhou institute of chemical physics , chinese academy ofsciences , lanzhou 730000, china, Tianshan Glaciological Station Lanzhou Inst. Glaciol. Geocryology Chinese Academy of Sciences Lanzhou 730000 China state key Lab. Oxo Synthesis S. Lanzhou Inst. of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

The ice core dust particulate sampled from Mt. Xixabangma has been analyzed by means of X-ray photoelectron spectrometer （XPS） and scanning electron microscope with energy dispersion X-ray analysis （SEM/EDAX）. The results show that the contents of SO42. and SO32. in the surface layer of the dust are significantly higher than those in the subsurface layer （with the exception of organic sulfide）. This difference indicates that the surface SOx has been captured and then chemically converted by the atmospheric dust particulate before its deposition with snow, which is obviously different from those inner layer sulfates and sulfites contained by dust itself. In addition, it has been determined by SEM/EDAX that the dust contains relatively high concentrations of transition metal elements such as Fe and Ti oxides which could function as photocatalysts to the conversion of SOx adhered on the surface of the dust, and consequently accelerate the deposition of SOx to snow. Our research also

关键词： ice core records dust partculate sulfate ions.

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Patterned self-assembled film guided electrodeposition

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Science china Chemistry 2004年第2期47卷 120-125页

作者： ZHOU Feng1, LI Bin1,2. XU Tao1, CHEN Miao1, HAO Jingcheng1 & LIU Weimin1 1. state key {2. of solid lubrication, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 730000, china 2. Department of Chemistry, Shandong institute of Education, Jinan 2.0014, china 1. state key {2. of solid lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences 730000 Lanzhou China 2. Department of Chemistry Shandong Institute of Education 250014 Jinan China

The paper describes the fabrication of polypyrrole (PPy) microstructures through patterned self-assembled film guided electrodeposition. Thus the patterned self-assembled monolayer is prepared by microcontact printing (μCP) and used as the template in the electrodeposition of PPy. It has been found that the self-assembled monolayer plays completely different roles on different substrates in directing the deposition of the PPy. Namely, the electrodeposition mainly occurs on the exposed area of the gold substrates patterned with dodecanethiol (DDT) and octadecanelthiol (ODT) and on the indium tin oxide (ITO) substrate patterned with octadecyltrichlorosilane (OTS), while PPy nucleates on the OTS covered area and no deposition is found on the exposed area of a semiconductor substrate (silicon). This is attributed to the co-operative effect between the substrate conductivity and the compatibility of the PPy oligomerwith the covered or exposed area of the substrate surface.

关键词： pattern, conducting polymer, microcontact printing, electrodeposition.

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