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Science China earth sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, China University of Geosciences, Ministry of Education of China, Beijing 100083, China 2. school of {2. sciences and Mineral Resources, China University of Geosciences, Beijing 100083, China Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China Beijing China school of earth {2. and Mineral Resources China University of Geosciences Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

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Paleoceanographic evolution recorded in the northern South China Sea since 4 Ma

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Science China earth sciences 2005年第12期48卷 2166-2173页

作者： HUANG Baoqi1,2. JIAN Zhimin2.& WANG Pinxian2.1. school of earth and Space {2., Peking University, Beijing 100871, China 2. Laboratory of Marine Geology, Tongji University, Shanghai 2.0092. China school of earth and Space {2. Peking University Beijing China Laboratory of Marine Geology Tongji University Shanghai China

Upper water structure over the last 4 million years in the northern South China Sea (SCS) was reconstructed by sea surface temperature (SST) and primary productivity estimated by changes in the abundance of planktonic foraminifer, planktonic foraminifer transfer function, and the accumulation rate of benthic foraminifera. Results of SST and primary productivity show that SST gradually decreased since 4 Ma, but differential seasonal temperature and primary productivity increased in steps mainly at about 3.1, 2.7, 2.1, 1.6, 0.9 and 0.5 Ma. Comparison with tectonics and orbital variations indicates that phased rising of the Tibet since 3.6 Ma, closing of Panama and Indonesian seaways, and orbital changes were responsible for the changes of upper water structure in the SCS, respectively.

关键词： northern South China Sea, upper water structure, Late Pliocene, planktonic foraminifer, ODP 1146.

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Preparation and characterization of a novel adsorbent for removing lipophilic organic from water

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Science China Chemistry 2005年第6期48卷 600-604页

作者： LIU Huijuan1, DAI Ruihua1, QU Jiuhui1 & RU Jia1,2.1. State Key Laboratory of environmental Aquatic Chemistry, Research Center for Eco-environmental {2., Chinese Academy of {2., Beijing 100085, China 2. Graduate school of the Chinese Academy of {2., Beijing 100039, China State Key Laboratory of environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing China Graduate school of the Chinese Academy of sciences Beijing China

A novel composite adsorbent containing a kind of lipid-triolein is studied. The ad-sorbent is prepared by embedding triolein into cellulose acetate (CA) sphere. The preparation method, the physical-chemical properties of the adsorbent and the removal efficiency of two or-ganochlorinated pesticides are studied. The adsorbent is stable in water and no triolein leaks into water for 465 h soaking. The adsorbent has high adsorption capacity for organochlorinated pes-ticides such as dieldrin and aldrin. The results suggest that triolein-containing adsorbent could serve as a good adsorbent for lipophilic organic pollutants. The adsorption rate for lipophilic pol-lutants is very fast and has relation with the logKow of the compounds.

关键词： triolein, cellulose acetate, adsorbent, lipophilic organic, drinking water.

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Pioneer organisms after F-F mass extinction in Dushan region,Guizhou Province,and their significance in establishing new ecosystem

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Science China earth sciences 2006年第5期49卷 449-460页

作者： WANG Yue1, 2. WANG Xunlian1 & SHI Xiaoying1 1. school of earth {2. and Resources, China University of Geo{2., Beijing 100083, China 2. school of Resources and Environment, Guizhou University, Guiyang 550003, China school of earth {2. and Resources China University of Geosciences Beijing China school of Resources and Environment Guizhou University Guiyang China

After mass extinctions, most areas became “ecologically barren areas” lacking or even without ecosystem over an extensive region. Studying the pioneer organisms and the reconstruction process of a new ecosystem in the “ecologically barren area” is very important for revealing the evo- lution after bio-mass extinctions. In the Dushan region, Guizhou Province, China, the trace fossils appeared and flourished evidently earlier than body fossils after Frasnian-Famennian (F-F) mass extinction. The pioneer organisms and pathfinders in the “ecologically barren areas” are the trace-makers that are deposit-feeders with relatively simple structure and conformation on or near the deposit surface. The trace-makers have undergone an evolutionary process that their trace structures changed from simple to complex, and their living and moving areas and spaces enlarged from linear to planar and then to three-dimension spaces. Those characters show that the ability of the trace-makers to deposits and their efficiency of looking for food have been enhanced gradually and that those trace-makers constructed gradually a base for the new ecosystem. This process is similar to that of the trace fossils near the Precambrian-Cambrian boundary. In the Dushan area, only the recovery intervals have been identified for the Famennian body fossils, with no eminent radiation interval recognizable due to the Devonian-Carboniferous (C-D) mass ex- tinction. However, both the recovery and radiation intervals may be clearly recognized in the Famen- nian trace fossils based on their conformation and diversity. The evolution and diversification of the trace fossils in the “ecologically barren area” is considered to have played a role of necessary foun- dation for the recovery of body fossils in the ecological chain. With the gradual disappearance of the unfavourable environment factors resulting in the F-F mass extinction, a new ecosystem was reconstructed in the “ecologically barren area” through a three-

关键词： pioneer organisms, reconstruction of ecosystem, trace fossils, F-F mass extinction, Later Devonian, Dushan region, Guizhou Province, China.

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Adjoint method for the optimum planning of industrial pollutant sources

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Science China earth sciences 2005年第8期48卷 1270-1279页

作者： LIU Feng1,2. HU Fei2.& ZHU Jiang2.1. College of environmental sciences, Peking University, Beijing 100871, China 2. LAPC, Institute of Atmospheric Physics, Chinese Academy of sciences, Beijing 10002., China College of environmental sciences Peking University Beijing China LAPC Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China

The optimum planning of industrial pollutant sources, which optimizes the economic object without violating environmental constraints, is an important and hard task to be conquered. In this paper, an adjoint method is developed to solve the problem. The penalty function is in-troduced to deal with the environmental inequality constraints, and Lagrange function is con-structed to derive the adjoint equation and the gradient of the object function. In this means, the gradient of the object function can be calculated by solving the adjoint equation, and the infor-mation from the gradient is used to make the object function descend and approach to an optimal solution after some iterations. A two-dimensional, simplified model is used for numerical experi-ments. The theoretical derivations are verified by the results of the experiments. Furthermore, the adjoint method is shown to be of excellent convergence and efficiency, which is adaptive to the fast development of air quality numerical models and super computers.

关键词： optimum planning, industrial pollutant sources, adjoint equation, penalty function, gradient.

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Calculating soil moisture by remote sensing and analyzing hydrologic cycle process in the Yellow River basin

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Science China(Technological sciences) 2004年第Z1期47卷 1-13页

作者： YANG Shengtian1 & LIU Changming1, 2.1. school of environmental {2., Beijing Normal University, Beijing 100875, China 2. Institute of Geographic Science and Natural Resources Research, Beijing 100101, China school of environmental {2. Beijing Normal University Beijing China Institute of Geographic Science and Natural Resources Research Beijing China

Based on the AVHRR pathfinder remote sensing data, soil moisture, precipitation and evaporation during the period of 1982.1998, soil moisture of all layers of soil-profile (0—1 m) in the Yellow River basin over the 17 years are calculated by the remote sensing model of calculating soil water. The Yellow River basin is divided into seven subcatchments as control sections at the location of six hydrologic stations (Lanzhou, Toudaoguai, Longmen, Sanmenxia, Huayuankou and Lijin). After calculating soil moisture and obtaining runoff data and precipitation data, the dynamical features of hydrological cycle in the Yellow River basin are analyzed for the period from 1982.to 1988 using water balance method. The conclusions are as follows: It is feasible to calculate the soil water on the macro-scale, in the soil profile with temporal continuity by means of remote sensing and survey in land. Some values of the key water cycle factors in the Yellow River are obtained, which include the annual precipitation of 4000 km3, the evapotranspiration of 3000-3500 km3, and the soil moisture transformation of ?500- 500 km3. Consequently, we analyzed the process of the water cycle in the Yellow River over the 17 years, and the results show that the segment upstream of Lanzhou city is a relatively humid region, and the area of internal waters and the reaches of Shanshan is the most desiccated region. Therefore, the runoff in the depth process is intensive and the runoff-generating process is weak in more arid regions.

关键词： the Yellow River, soil moisture, remote sensing, hydrologic cycle.

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Interdecadal change in Western Pacific Subtropical High and climatic effects

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Journal of Geographical sciences 2002年第2期12卷 79-86页

作者： HE Xue-zhao1, GONG Dao-yi1,2.(1. Laboratory of environmental Change and Natural Disaster Research, Institute of Resources Science, Beijing Normal University, Beijing 100875, China 2. school of earth and environmental sciences, {2. national University Laboratory of environmental Change and Natural Disaster Research Institute of Resources Science 北京 100875 school of earth and {2. sciences Seoul National University 韩国 Seoul 151-742

Western North Pacific Subtropical High is a very important atmospheric circulation system influencing the summer climate over eastern China. Its interdecadal change is analyzed in this study. There is a significant decadal shift in about 1979/1980. Since 1980, the Western North Pacific Subtropical High has enlarged, intensified, and shifted southwestward. This change gives rise to an anti-cyclonic circulation anomaly over the region from the South China Sea to western Pacific and thus causes wet anomalies over the Yangtze River valley. During the summers of 1980-1999, the precipitation is 63.9 mm above normal, while during 1958-1979 it is 2..3 mm below normal. The difference is significant at the 99% confidence level as a t-test shown. The southwestward expanding of the Western North Pacific Subtropical High also leads to a significant warming in southern China, during 1980-1999 the summer mean temperature is 0.37篊 warmer than that of the period 1958-1979. The strong warming is primarily due to the clearer skies associated with the stronger downward air motion as the Western North Pacific Subtropical High expanding to the west and controlling southern China. It is also found that the relative percentage of tropical cyclones in the regions south of 2.篘 is decreasing since the 1980s, but in the regions north of 2.篘 that is increasing at the same time. The Western North Pacific Subtropical High responds significantly to sea surface temperature of the tropical eastern Pacific with a lag of one-two seasons and simultaneously to sea surface temperature of the tropical Indian Ocean. The changes in the sea surface temperatures are mainly responsible for the interdecadal variability of the Western North Pacific Subtropical High.

关键词： Western Pacific Subtropical High interdecadal change climate change

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AFM study on the adsorption and aggregation behavior of dissolved humic substances on mica

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Science China Chemistry 2006年第3期49卷 256-266页

作者： GE Xiaopeng1, ZHOU Yanmei2. Lü Chunhua1 & TANG Hongxiao1 1. State Key Laboratory of environmental Aquatic Chemistry, Research Center for Eco-environmental {2., Chinese Academy of {2., Beijing 100085, China 2. school of Civil Engineering & Architecture, Beijing Jiaotong University, Beijing 100044, China State Key Laboratory of environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing China school of Civil Engineering & Architecture Beijing Jiaotong University Beijing China

Humic substances constitute the major organic fractions of soils, sediments and natural waters, and play a dominant role in the binding, mobilization, transport and ultimate fate of organic contaminants in subsurface systems. In this paper, two humic acid samples, Guanting and Tianjin, with different origin and chemical compositions have been investigated with AFM imaging for their adsorption and aggregation behaviors on mica. While the Tianjin humic sample is found to form small spheres with 2.0 to 330 nm in diameter at lower concentrations, irregular loop-chain assemblies of hundreds of nanometer in diameter with the chain width of about 40 nm are dominant for the Guanting humic sample, which may attribute to the more polar aliphatic fractions in the chemical composition in the latter. The heterogeneous and polydisperse nature of humic substances with multiple structural features, such as sponge-like structures, perforated sheets, aggregate of spheres, branches and chain-like assemblies etc., is apparent at higher concentrations for both humic samples, showing morphologically new evidence for the dominant view of the humic dual-mode sorption model. With naphthalene introduced, the assemblies of Guanting humic substances clearly become more compact with significantly narrowed branches and less porous the perforated sheet-like structures. It is indica- tive of that smaller nanometer scale rings present along the perforated assemblies could potentially represent hydrophobic domains, which may facilitate the adsorption and aggregation of naphthalene onto the natural particle surfaces and therefore lead to an important role of dissolved humic sub- stances in the sorption of environmental pollutants.

关键词： atomic force microscopy (AFM) dissolved humic substances morphology aggregation adsorption

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Pollution characteristics of atmospheric fine particles and their secondary components in the atmosphere of Shenzhen in summer and in winter

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Science China Chemistry 2006年第5期49卷 466-474页

作者： NIU Yuwen1,2.HE Lingyan1,2.HU Min2.ZHANG Jing2.& ZHAO Yunliang2.1. Shenzhen Graduate school of Peking University,Shenzhen 518055,China 2. State Joint Key Laboratory of environmental Simulation and Pollution Control,College of environmental sciences,Peking University,Beijing 100871,China Shenzhen Graduate school of Peking University Shenzhen China State Joint Key Laboratory of environmental Simulation and Pollution Control College of Environmental Sciences Peking University Beijing China

Two field measurements for atmospheric fine particles were conducted in Baoan district of Shenzhen during the summer and winter in 2.04. Totally 30 sets of 2. h samples were collected, and then the mass concentrations and chemical compositions were determined. The seasonal varia- tions and secondary pollution characteristics of fine particles during the sampling periods were dis-cussed with meteorological factors. The results show that seasonal variations of atmospheric particles are significant in Shenzhen. The average mass concentrations of PM2.5 and PM10 in summer were 35 μg·m-3 and 57 μg·m-3, respectively, and those in winter were 99 μg·m-3 and 135 μg·m-3, respec-tively. The concentrations of both PM2.5 and PM10 in winter increased 184% and 137%, respectively, compared to those in summer. PM2.5 accounted for 61% and 75% of PM10 in summer and in winter, respectively, indicating severe fine particle pollution in Shenzhen. During the summer and winter sampling periods, the mean OC/EC ratios were 3.4 and 1.6, respectively. The estimated secondary organic carbon (SOC) averagely accounted for 56% and 6% of the total OC in summer and in winter, respectively, which implies a major contribution of SOC to OC in summer. During the continuous high temperature period in summer, both the concentrations and fractions of secondary aerosol compo-nents in PM2.5 were highly elevated, suggesting severe secondary pollution again. The prevailing wind was from South China Sea in summer, and the air quality was good. The prevailing wind in winter was from China's Mainland to the north, and the polluted air mass led to poor air quality.

关键词： PM2.5, mass concentration, secondary pollution, seasonal variation, Shenzhen.

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Relationship between surface subsidence factor and mining depth of strip pillar mining

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中国有色金属学会会刊：英文版 2011年第S3期21卷 594-598页

作者： GUO Wen-bing1, 2. HOU Quan-lin 1, ZOU You-feng2.1. College of earth Science, Graduate University of Chinese Academy of sciences, Beijing 100049, China 2. {2. of Energy Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China College of earth Science Graduate University of Chinese Academy of Sciences Beijing 100049 China school of Energy Science and Engineering Henan Polytechnic University Jiaozuo 454000 China

Strip pillar mining is one of the most important technical measures to control mining subsidence in China. Mining depth is one of the most important factors that can affect the mining subsidence in strip pillar mining. Six numerical simulation models were set up to simulate the surface subsidence of strip pillar mining in different mining depths. The mining depth in these six models ranges from 300 to 800 m. The simulated results were compared and analyzed. The formula was established based on the simulated results. It demonstrated that the subsidence of strip pillar mining method is related to mining depth. While the other conditions are the same, the subsidence of strip pillar mining increases with the increase of mining depth by logarithmic relationship.

关键词： subsidence factor strip pillar mining mining depth numerical simulation

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