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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

science china {2. sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2. ZHAO Zhidan1,2. ZHANG Hongfei3. ZHANG Benren3.& CHEN Yuelong2.1. State Key Laboratory of Geological Processes and {3. resources, {2. university of Geosciences, beijing 100083. {2. 2. school of earth science and mineral resources, {2. university of Geosciences, beijing 100083. {2. 3. Faculty of earth sciences, {2. university of Geosciences, Wuhan 43.074, {2. 1. State Key Laboratory of Geological Processes and mineral resources China University of Geosciences Beijing 100083 China 2. school of earth science and mineral resources China University of Geosciences Beijing 100083 China 3. Faculty of earth sciences China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.2.). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2.b-Zr/4-Y and Ti/100-Zr-YX3.tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143.Nd/^(144)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(2.6)Pb/^(2.4)Pb (18.054-2..562., ^(2.7)Pb/^(2.4)Pb (15.53.-15.743. and ^(2.8)Pb/^(2.4)Pb(3..068-3..53.). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

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science china {2. sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of Geo{2.s, Ministry of Education of china, beijing 100083. china 2. school of {13. {2.s and mineral resources, china university of Geo{2.s, beijing 100083. china 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. school of earth {2.s and mineral resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

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The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, china

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science china {2. sciences 2004年第9期47卷 846-864页

作者： TIAN Youping1,3. ZHANG Jie2. SONG Linhua1 & BAO Haosheng2.1. Institute of Geographic sciences and Natural {3. Research, Chinese Academy of sciences, beijing 100101, china 2. Department of Geography, Nanjing university, Nanjing 2.0093. china 3. school of earth sciences and {3., china university of Geosciences, beijing 100083. china Institute of Geographic sciences and Natural resources Research Chinese Academy of Sciences Beijing 100101 China Department of Geography Nanjing University Nanjing 210093 China school of earth {2.s and {3. China University of Geosciences Beijing 100083 China

Aerial algae on the surface of carbonate rocks at the Stone Forest, Shilin County, Yunnan Province, china, and their bioerosion were investigated in the field and studied in the laboratory in detail. Through the observation, identification and statistics of more than one hun- dred algal samples and rock samples with the optical microscopes (stereomicroscope, biological microscope) and the scanning electronic microscope (SEM), the relationships between erosional forms on the surface of the Stone Forest and algae and/or algal communities and the genetic mechanism for the formation of erosional forms were analyzed. It is suggested that aerial algae play an active role in bioerosive processes that may affect the formation of karst erosional forms. These effects include both direct and indirect ones. The direct effect is the initiative control (algal shape-controlling role) of algae on the formation of karst forms of various scales, mostly mi- cro-scale (3.) and minor-scale (10-3.10-1m) erosional forms. The algal shape-controlling roles can be divided into the algal individual shape-controlling role and the algal community shape-controlling role. The former mostly controls the formation of micro-scale erosional forms, while the latter mostly controls the formation of micro-scale and smaller minor-scale erosional forms. The indirect effect refers to the promoting role of algae in the formation of karst forms, which may affect the formation of karst forms of all types and scales. The bioerosion of algae accelerates the weathering process of the whole Stone Forest karst landforms.

关键词： aerial algae, bioerosion, the Stone Forest, Yunnan Province, china.

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The species diversity of fusulinaceans and high-frequency sea-level changes in the Carboniferous-Permian boundary section at Xikou, Zhen'an County,Shaanxi Province, china

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science china {2. sciences 2006年第7期49卷 673-683页

作者： ZHANG Haijun1, WANG Xunlian2. DING Lin1, XIA Guoying3.& WANG Lei2.1. Institute of Tibetan Plateau Research, Chinese Academy of sciences, {3. 100085, {2. 2. Faculty of earth sciences and mineral resources, {2. university of Geosciences, {3. 100083. {2. 3. Tianjin Institute of Geology and mineral resources, Tianjin 3.0170, {2. 1. Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China 2. Faculty of earth sciences and {2. resources China University of Geosciences Beijing 100083 China 3. Tianjin Institute of Geology and mineral resources Tianjin 300170 China

The study on the interrelation between sea-level changes and biodiversity with its evolu-tion has great significance for understanding the impact of global changes on organic evolution and exploring the inherent laws of life-environment coevolution in geological history. In this paper, the stratigraphic distribution of fusulinacean fauna in the Carboniferous-Permian boundary section at Xikou, Zhen’an County, Shaanxi Province, is analyzed quantitatively, and the relationship between the species diversity of fusulinaceans and relative sea-level changes is discussed. As a whole, the spe-cies numbers of fusulinacean fauna experience a rapid increase and an obvious decline in Xikou, Zhen’an County, from the Late Carboniferous to the Early Permian. There is a significant increase in species diversity around the Carboniferous-Permian boundary, which is one of the biggest bio-events of the fusulinacean fauna, and represents the radiation of Pseudoschwagerininae subfamily in the studied area. Integrated fusulinacean species diversity into sequence stratigraphic framework, de-tailed study suggests that the species diversity of the fusulinaceans is closely related to its relative stratigraphic location, and is essentially controlled by the sea-level changes, especially by the high-frequency sea-level changes. Generally, the species diversity of fusulinaceans is low, and the number of first and last appearance datum is small in the lower unit of high-frequency depositional cycle formed during the quick rise of the sea level; whereas the species diversity of fusulinaceans is high, and the number of first and last appearance datum is large in the upper unit of high-frequency cycle formed during the slow fall of the sea level. Within the third-order depositional sequence, the species diversity of the fusulinaceans at the first flooding surfaces and the maximum flooding surfaces is low, and it increases upward. The fusulinacean species diversity is low within the transgressive syst

关键词： fusulinaceans, species diversity, high-frequency cyclothem, sequence stratigraphy, sea-level changes, Carboniferous-Permian boundary, Zhen'an, Shaanxi.

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Spatio-temporal carbon isotope variation during the Ediacaran period in South china and its impact on bio-evolution

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science china {2. sciences 2009年第10期52卷 1520-1528页

作者： WANG XinQiang1 & SHI XiaoYing1,2.1 school of earth {2. and mineral resources, china university of Geo{2.s, beijing 100083. china 2.State Key Laboratory of Geological Processes and mineral resources, beijing 100083. china school of earth {2. and {3. resources China University of Geosciences Beijing 100083 China State Key Laboratory of Geological Processes and mineral resources Beijing 100083 China

The Ediacaran period is characterized by the extremely negative carbon isotope anomalies and great biotic evolution in earth history. At least four negative carbon isotope anomalies have been reported from this interval in South china so far. It is traditionally argued that the isotope variations can be used as a useful tool for global correlation of Ediacaran succession; however, more and more researches argued against this idea. We reviewed the previously published carbon isotope data in South china, and distributed the mean values of a certain time to the paleogeographic maps. The results show that the carbon isotope values (δ13.) vary greatly in different environments, but a clear tendency of becoming lighter from shallow platform to deep basin, with a maximum variation up to 1‰ Moreover, the important changes in Ediacaran biota, marked by the introducing of new taxa or ecologic groups, seemed to always postdate the negative anomalies but coincide with the positive shift. If the negative excursions represented the oxidation of a large dissolved organic carbon (DOC) reservoir in the ocean, the diverse Ediacaran organisms and the carbon isotope anomalies may suggest totally different environments: oxic and anoxic/euxinic. We also suggest that the elimination of euxinic state through precipitation of pyrites is one of the important environment factors in prompting the Ediacaran bio-evolution.

关键词： Ediacaran South china carbon isotope spatio-temporal variations bio-evolution

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Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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science china {2. sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2. JIN Zhenmin1,3. QU Jing2.& WANG Lu2.1. State Key Laboratory of Geological Processes and {3. resources, {2. university of Geosciences, Wuhan 43.074, {2. 2. Graduate school of {2. university of Geosciences, Wuhan 43.074, {2. 3. Faculty of earth sciences, {2. university of Geosciences, Wuhan 43.074, {2. 1. State Key Laboratory of Geological Processes and mineral resources China University of Geosciences 430074 Wuhan China 2. Graduate school of china {2. of Geosciences 430074 Wuhan China 3. Faculty of earth sciences China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 3.0 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

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Characteristics and origins of primary fluids and noble gases in mantle-derived minerals from the Yishu area,Shandong Province,china

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science china {2. sciences 2006年第1期49卷 77-87页

作者： MA Jinlong1,2. TAO Mingxin2.3.& YE Xianren2.1. {3. and Environmental school, Lanzhou {2., Lanzhou 73.000, china 2. Key Laboratory of Gas Geochemistry, Institute of Geology and Geophysics, Chinese Academy of sciences, Lanzhou 73.000, china 3. College of {3. science & Technology, beijing Normal {2., beijing 100875, china 1. resources and Environmental school Lanzhou University Lanzhou 730000 China 2. Key Laboratory of Gas Geochemistry Institute of Geology and Geophysics Chinese Academy of Sciences Lanzhou 730000 China 3. College of resources science & Technology Beijing Normal University Beijing 100875 China

Fluids and noble gases of mantle-derived materials are important tracers forthe mantle information. Compositions of primary fluids and noble gases in mantle-derived mineralsfrom the Yishu area, Shandong Province, china, were tested by the methods of heat-bursting andheat-melting respectively. The fluids are mainly composed of CO_2. CO and H_2. which account forabout 90% of the total, and are similar to the mantle-derived rocks from other areas of easternchina; ratios of ~3.e/~4He in almost all samples range from 0.82.Ra to 2.74 Ra, whereas^(40)Ar/^(3.)Ar from 2.9.5 to 758.8. Both ranges are much lower than those of the typical oceanmantle-derived samples (such as MORB) and primarily reflect the influences of the atmosphericcomponents and the radiogenic isotopes. Ratios of C/~3.e range from 2..6 x 10~9 to 1050 x 10~9,N_2.Ar from 92. to 56612. and N_2.~3.e from 2.5 x 10~9 to 2. x 10~9, similar to those in westernUnited States and New Zealand which belong to the tectonic plate collision regions. The ratios fallin the intersect of mantle-crust-atmosphere in the comprehensive tracer-charts, reflecting theinfluences of the atmosphere and the crusts with organic components. Our results suggest that thecomposition of the primary fluids and the isotopic ratios of the noble gases may either reflect theevolution process of mantle-derived rocks connected with the rise and eruption of magma, or theinfluence of the ancient subduction-plate on the continental mantle of this region.

关键词： noble gases, primary fluids, mantle-derived minerals, Yishu area.

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Pioneer organisms after F-F mass extinction in Dushan region,Guizhou Province,and their significance in establishing new ecosystem

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science china {2. sciences 2006年第5期49卷 449-460页

作者： WANG Yue1, 2. WANG Xunlian1 & SHI Xiaoying1 1. school of earth {2.s and resources, china university of Geo{2.s, beijing 100083. china 2. school of resources and Environment, Guizhou university, Guiyang 550003. china 1. school of earth {2.s and {3. China University of Geosciences Beijing 100083 China 2. school of resources and Environment Guizhou University Guiyang 550003 China

After mass extinctions, most areas became “ecologically barren areas” lacking or even without ecosystem over an extensive region. Studying the pioneer organisms and the reconstruction process of a new ecosystem in the “ecologically barren area” is very important for revealing the evo- lution after bio-mass extinctions. In the Dushan region, Guizhou Province, china, the trace fossils appeared and flourished evidently earlier than body fossils after Frasnian-Famennian (F-F) mass extinction. The pioneer organisms and pathfinders in the “ecologically barren areas” are the trace-makers that are deposit-feeders with relatively simple structure and conformation on or near the deposit surface. The trace-makers have undergone an evolutionary process that their trace structures changed from simple to complex, and their living and moving areas and spaces enlarged from linear to planar and then to three-dimension spaces. Those characters show that the ability of the trace-makers to deposits and their efficiency of looking for food have been enhanced gradually and that those trace-makers constructed gradually a base for the new ecosystem. This process is similar to that of the trace fossils near the Precambrian-Cambrian boundary. In the Dushan area, only the recovery intervals have been identified for the Famennian body fossils, with no eminent radiation interval recognizable due to the Devonian-Carboniferous (C-D) mass ex- tinction. However, both the recovery and radiation intervals may be clearly recognized in the Famen- nian trace fossils based on their conformation and diversity. The evolution and diversification of the trace fossils in the “ecologically barren area” is considered to have played a role of necessary foun- dation for the recovery of body fossils in the ecological chain. With the gradual disappearance of the unfavourable environment factors resulting in the F-F mass extinction, a new ecosystem was reconstructed in the “ecologically barren area” through a three-

关键词： pioneer organisms, reconstruction of ecosystem, trace fossils, F-F mass extinction, Later Devonian, Dushan region, Guizhou Province, china.

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On the siltation of the middle Yangtze River

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science china {2. sciences 2004年第5期47卷 463-480页

作者： YIN Hongfu1, CHEN Guojin2. LI Chang抋n1 & WEI Yuan3.1. school of earth {2.s, china university of Geo{2.s, Wuhan 43.074, china 2. Hydrogeological Team, Hubei Bureau of Geology and mineral resources, Jingzhou 43.100, china 3. Geological Survey of Jiangxi Province, Nanchang 3.02.1, china china Univ Geosci Sch Earth Sci Wuhan 430074 Peoples R China Hubei Bur Geol & mineral resources Hydrogeol Team Jinzhou 434100 Peoples R China Geol Survey Jiangxi Province Nanchang 3300201 Peoples R China

About 5.2.108 t/a of silts from the upper reach of the Yangtze River are transported through Yichang into the middle Yangtze River. The middle Yangtze itself and its tributaries yield ca. 0.8×108 t silts annually. Of this total 6×108 t/a input of silts, ca. 1.2.108 t/a are deposited within the river artery and lakes, while ca 4.83.108 t/a are at first transported into the lower reach through Datong, and then either deposited along the river and the Yangtze Delta, or output into the sea. Along the middle Yangtze River silting generally exceeds scouring, but the spatial and temporal distributions of scour-and-fill, as well as its distribution in the river valley transections, are uneven. Along the Yichang-Chenglingji and Jiujiang-Datong Segments of the middle Yangtze, scouring exceeds or equals silting. Silting mainly occurs along the Luoshan-Wuhan-Huangshi Segments with Wuhan as the pivotal point, as well as in the Dongting and Poyang Lakes. Even in these silting-dominated areas, there are times and parts of segments that scouring prevails. As to the transections, generally the river channel of main stream is scouring-dominated, forming V-shaped sections to a depth of 2.3. m or more, whereas the floodplains and bar islands are silting-dominated, forming wide and relatively high flats, which are often artificially transformed into protected embankments. Because the Jingjiang Levee separates the Jianghan Plain from Yangtze to the south, little has been deposited in that plain except a few sediments from the Han River—a tributary of the middle Yangtze. This factor plus the tectonic sag of that plain has made the altitude of plain surface several meters lower than that of the levee in most of the areas. Sil-tation along the Luoshan-Wuhan-Huangshi Segments has resulted in the elevation of flood level in this and upstream segments. River channel scouring plus floodplain silting have caused the transections of the middle Yangtze valley typically with deep channel and height

关键词： the middle Yangtze, scour-and-fill, siltation, silt utilization.

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Re-Os(ICP-MS)dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

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science china {2. sciences 2005年第10期48卷 1672-1677页

作者： YANG Gang1,2. DU Andao1, LU Jiren3. QU Wenjun1 & CHEN Jiangfeng2.1. National Research Center of Geoanalysis, beijing 10003., {3. 2. Laboratory for {2. Material Cycling, school of {2. and Space sciences, university of science and Technology of {3., Hefei 2.002., {3. 3. Institute of mineral Resource, Chinese Academy of Geological sciences, beijing 10003., {3. National Research Center of Geoanalysis beijing china Laboratory for earth Material Cycling School of Earth and Space Sciences University of Science and Technology of China Hefei China Institute of mineral Resource Chinese Academy of Geological sciences {2. {3.

Massive sulfide ore from the Jinchuan Ni-Cu-PGE deposit was dated by Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measurement. An isochron giving an age of 83. ± 3. Ma, initial 187Os/188Os ratio of 0.2.9 ± 0.018 (MSWD = 1.7) and γOs = 13. ± 15 is obtained. The Re-Os age obtained agrees, within analytical uncertainties, with previous SHRIMP zircon U-Pb age of 82. ± 8 Ma (n=5, MSWD = 4.3.. The result suggests that the deposit was formed at Neoproterozoic and that the formation of the Jinchuan Ni-Cu-PGE sulfide deposit may be closely related to the plume activity, which were attributed to the breakup of the Rodinia supercontinent. The high γOs of the massive ores sug-gests that crustal material was involved in the formation of the Jinchuan deposit, however, the quantity of the added crustal material is less than 10%.

关键词： Jinchuan Ni-Cu-PGE deposit, Re-Os dating, ICP-MS.

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