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Gas formation mechanism of marine carbonate source rocks in china

Science china Earth Sciences 2005年第4期48卷 441-453页

作者： ZHAO Wenzhi1, WANG Zhaoyun1, HE Haiqing2. ZHANG Mingjie3. WANG Hongjun1, WANG Yunpeng4 & QIN Yong5 1. research institute of {2. Exploration & development, petrochina, beijing 100083. china 2. petrochina Exploration & Production, beijing 100011, china 3. Department of Geology, Lanzhou University, Lanzhou 73.000, china 4. Guangzhou Geochemical institute, Chinese Academy of Sciences, Guangzhou 510640, china 5. china University of Mining and Technology, Xuzhou 2.1000, china 1. research institute of {2. Exploration & {3. 100083 PetroChinaBeijin China 2. petrochina Exploration & Production 100011 Beijing China 3. Department of Geology Lanzhou University 730000 Lanzhou China 4. Guangzhou Geochemical institute Chinese Academy of Sciences 510640 Guangzhou China 5. china University of Mining and Technology 221000 Xuzhou China

By breaking through the conventional ideology on the study of gas-formation mechanism of source rocks which focused on merely the characteristics of source rocks them- selves, and based on the development and distribution characteristics of marine carbonate source rocks in the medium-to-bottom parts of the Chinese superimposed sedimentary basins as well as various processes in the course of gas generation and reservoir forming, the complex hydrocarbon-generating model of carbonates is established. Such a model concerns not only the “three-stage” gas formation characteristics of carbonates, but also the gas generation process due to a thermal cracking of oil and the re-generation process of gas from heated secondary organic matters during the gas-generation and reservoir-forming course. The high-quality hy- drocarbon generating matter of marine carbonate source rocks determined a high gas-oil ratio and tended to form paleo-oil-reservoirs, representing an enrichment process of organic matters. The thermal cracking of oil in palaeo-oil-reservoirs is an important means for the effective forma- tion of gas reservoirs. The secondary organic matters in carbonate reservoirs may regenerate gas after a secondary deep burial, thus becoming an effective gas source.

关键词： carbonate, three-stage hydrocarbon generation, inhibitive effect of maturity, oil-cracking gas, second-ary asphalt gas.

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Quantitative studies of hydrocarbon loss of the Silurian bitumen sandstone in the Tarim Basin

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Science china Earth Sciences 2008年第S2期51卷 101-107页

作者： JIANG ZhenXue1,2.PANG XiongQi1,2.LIU LuoFu1,2.WANG XianDong3.ZHANG Jun4 & LI HongYi1,2.1 Basin and Reservoir research Center,china University of {2.,beijing 102.49,china 2.State Key Laboratory of {2. Resource and Prospecting,china University of {2.,beijing 102.49,china 3.research institute of Exploration and {12.,Daqing Oilfield Company Ltd,Daqing 163.12.china 4 {2. Exploration and Production institute of SINOPEC,beijing 100083.china china Univ Petr Basin & Reservoir Res Ctr Beijing 102249 Peoples R China china Univ Petr State Key Lab Petr Resource & Prospecting Beijing 102249 Peoples R China Daqing Oilfield Co Ltd Res Inst Explorat & Dev Daqing 163712 Peoples R China SINOPEC Petr Explorat & Prod Inst Beijing 100083 Peoples R China

The evolution of Tarim Basin experienced several tectonic movements,of which Caledonian movement caused a serious damage to reservoirs of Silurian. The earlier reservoirs size and the later hydrocarbon loss are two key factors to exploration prospect of Silurian. On the basis of net thickness of bituminous sandstone and recovery coefficient of crude oil converting to bitumen,the scale of the hydrocarbon loss of palaeo-accumulation in bitumen sandstone of Silurian was calculated (86.3.×108t). The deter-mination of net thickness of bitumen sandstone was completed mainly by several methods,such as physical property demarcation,observing lithology,grains with oil inclusion (GOI) technology,and quantitative grains fluorescence (QGF) technology. The samples of black sandstone and white sand-stone were collected and compared by means of the methods mentioned above. The results showed that there was little hydrocarbon,or none,in the white sandstone. The recovery coefficient was ob-tained by the analyses of plentiful physical parameters of crude oil and bitumen sandstone,based on the hypothesis that nonhydrocarbon compounds and bitumen were invariable in the process of bitu-men forming. The calculated result,which is more scientific and actual,indicates the exploration pros-pect is more promising in Silurian of the Tarim Basin.

关键词： Tarim Basin Silurian bitumen sandstone hydrocarbon loss quantitative research recovery coefficient

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Curve fitting and optimal interpolation on CNC machines based on quadratic B-splines

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Science china(Information Sciences) 2011年第7期54卷 1407-1418页

作者： ZHANG Mei 1,YAN Wei 2.YUAN ChunMing 1,WANG DingKang 1 & GAO XiaoShan 1 1 Key Laboratory of Mathematics Mechanization,Academy of Mathematics and Systems Science,Chinese Academy of Sciences,beijing 100190,china 2.{2. institute of petroleum Exploration and development,beijing 100083.china 1. Key Laboratory of Mathematics Mechanization Academy of Mathematics and Systems Science Chinese Academy of Sciences Beijing 100190 China2. Research Institute of Petroleum Exploration and Development Beijing 100083 China

In this paper,curve fitting of 3.D points generated by G01 codes and interpolation based on quadratic B-splines are *** points of G01 codes are selected using an adaptive ***,quadratic B-splines are obtained as the fitting curve by interpolating these feature *** required in implementing the velocity planning algorithm mentioned by Timer et *** very complicated because of the appearance of high-order *** improved time-optimal method for the quadratic B-spline curves is presented to circumvent this *** algorithms are verified with simulations as well as on real CNC machines.

关键词： quadratic B-spline G01 codes feature point velocity planning interpolation

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A hydrocarbon enrichment model and prediction of favorable accumulation areas in complicated superimposed basins in china

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petroleum Science 2010年第1期7卷 10-19页

作者： Pang Xiongqi Meng Qingyang Jiang Zhenxue Liu Luofu Lu Xiuxiang State Key Laboratory of petroleum Resources and Prospecting China University of Petroleum Beijing 102249 China Basin and Reservoir research Center China University of Petroleum Beijing 102249 China research institute of {2. Exploration and {3. PetroChina Beijing 100083 China

The geologic conditions of superimposed basins in china are very complicated. This is mainly shown by multi-phase structural evolution, multiple sets of source-reservoir-cap rock combinations, multiple stages of hydrocarbon generation and expulsion from source rocks, multi-cycle hydrocarbon enrichment and accumulation, and multi-phase reservoir adjustment and reconstruction. The enrichment, accumulation and distribution of hydrocarbon is mainly controlled by the source rock kitchen, paleo- anticline, regional cap rock and intensity of tectonic movement. In this paper, the T-BCMS model has been developed to predict favorable areas of hydrocarbon accumulation in complicated superimposed basins according to time and spatial relationships among five key factors. The five factors include unconformity surface representing tectonic balancing （B）, regional cap rock representing hydrocarbon protection （C）, paleo-anticline representing hydrocarbon migration and accumulation （M）, source rock kitchen representing hydrocarbon generation and expulsion （S） and geological time （T）. There are three necessary conditions to form favorable areas of hydrocarbon accumulation. First, four key factors BCMS should be strictly in the order of BCMS from top to bottom. Second, superimposition of four key factors BCMS in the same area is the most favorable for hydrocarbon accumulation. Third, vertically ordered combination and superimposition in the same area of BCMS should occur at the same geological time. The model has been used to predict the most favorable exploration areas in Ordovician in the Tarim Basin in the main hydrocarbon accumulation periods. The result shows that 95% of the discovered Ordovician hydrocarbon reservoirs are located in the predicted areas, which indicates the feasibility and reliability of the key factor matching T-BCMS model for hydrocarbon accumulation and enrichment.

关键词： Complicated superimposed basin key factor matching T-BCMS model favorable area for hydrocarbon accumulation hydrocarbon distribution prediction

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Wave tectono-sedimentary processes in Tarim basin

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Science china Earth Sciences 2005年第11期48卷 1949-1959页

作者： JIN Zhijun1,2. ZHANG Yiwei1 & CHEN Shuping1 1. Key Laboratory for Hydrocarbon Accumulation, Ministry of Education, china University of petroleum, {2. 102.49, china 2. Exploration and Production research institute, china petroleum & Chemical Corporation, beijing 100083. china 1. Key Laboratory for Hydrocarbon Accumulation Ministry of Education China University of Petroleum 102249 Beijing China 2. Exploration and Production research institute China Petroleum & Chemical Corporation 100083 Beijing China

Based on the unconformities, the formation times of structures, and geological wave filtering applied to basin fills of typical wells around the Manjiaer area in the Tarim basin, the wave tectono-sedimentary processes in the Tarim Basin are discussed. The results of geological wave filtering of basin fills of typical wells show that, in time domain, the evolution of the Tarim basin was controlled by various wave processes with the periods of 740±Ma, 2.0±Ma, 100±Ma and 3.±Ma. The analyses of basin fills, basin subsidence and unconformities show that the trends of the sedimentary facies belts, depocenters, and centers of subsidence migrated and interchanged periodically with periods of 2.0±Ma. These show the propagation of wave movements in space domain. The wave evolution of the Tarim basin is of significance to understanding the formation of the oil and gas reservoirs in the basin.

关键词： Tarim basin, tectonics, sedimentation, crustal undation, wave evolution

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Review and Comprehensive Analysis of Composition and Origin of High Acidity Crude Oils

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china petroleum Processing & Petrochemical Technology 2011年第1期13卷 6-15页

作者： Cai Xinheng Tian Songbai (research institute of {2. Processing,SINOPEC,{3. 100083.china) SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China

High acidity crude oils have an advantage over normal oils in terms of their price,but can cause corrosion and refinery *** are the so-called opportunity crudes and likely to be important reserved resources in the 2.st *** on high acidity crude oils are becoming more and more *** on the existing research achievements,this article has given an overview of the chemical composition and acid distribution of high acidity oils,and also analyzed their origin types and potential influence factors.

关键词： high acidity oils total acid number acid composition origin influence factors

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CHARACTERISTICS　OF　COAL－FORMED　GAS　ACCUMULATION　BELTS　IN　THE　EAST　PART　OF　THE　CENTRAL－ASIA　COAL－FORMED　GAS　ACCUMULATION　DOMAIN　──SERIES　STUDY　Ⅲ　ON　THE　CENTRAL－ASIA　COAL－FORMED　GAS　ACCUMULATION　DOMAIN

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石油勘探与开发 1995年第5期22卷 87-95页

作者： Dai Jin-xing Li Xian-qi(research institute of {2. Exploration and {3., CNPC. beijing, 100083. P. R. china)

ＣＨＡＲＡＣＴＥＲＩＳＴＩＣＳＯＦＣＯＡＬ－ＦＯＲＭＥＤＧＡＳＡＣＣＵＭＵＬＡＴＩＯＮＢＥＬＴＳＩＮＴＨＥＥＡＳＴＰＡＲＴＯＦＴＨＥＣＥＮＴＲＡＬ－ＡＳＩＡＣＯＡＬ－ＦＯＲＭＥＤＧＡＳＡＣＣＵＭＵＬＡＴＩＯＮＤＯＭＡ... 详细信息

ＣＨＡＲＡＣＴＥＲＩＳＴＩＣＳＯＦＣＯＡＬ－ＦＯＲＭＥＤＧＡＳＡＣＣＵＭＵＬＡＴＩＯＮＢＥＬＴＳＩＮＴＨＥＥＡＳＴＰＡＲＴＯＦＴＨＥＣＥＮＴＲＡＬ－ＡＳＩＡＣＯＡＬ－ＦＯＲＭＥＤＧＡＳＡＣＣＵＭＵＬＡＴＩＯＮＤＯＭＡＩＮ──ＳＥＲＩＥＳＳＴＵＤＹⅢＯ...

关键词： GAS FORMED COAL ACCUMULATION BELTS ASIA EAST

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Application of C5-C13.light hydrocarbons in depositional environment diagnosis

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Progress in Natural Science:Materials International 2008年第9期18卷 1129-1137页

作者： Peirong Wanga,b,, Guanjun Xu a,c, Tingrong Xiaoc, Dajiang Zhanga,c, Bin Zhanga,c a Key Laboratory of petroleum Geochemistry, china National petroleum Corporation,{3. b Department of Organic Geochemistry, Yangtze University, Jingzhou 43.02., china c Central Laboratory of petroleum Geology, research institute of petroleum Exploration and development, petrochina,{3. Key Laboratory of petroleum Geochemistry China National Petroleum Corporation Beijing 100083 China Department of Organic Geochemistry Yangtze University Jingzhou 434023 China Central Laboratory of petroleum Geology Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083 China

Based on the geological background and Gammacerane/C3.H(S + R) ratios, source rock depositional environments of the studied oil samples (194) from 13.oilfields were classified into three groups according to salinity:saline-lacustrine facies, fresh to brackish lacustrine facies (including limnetic facies), and semi-saline to saline facies (including marine facies of the Tarim Basin).C5-C13.compound groups in the crude oils were separated by GC, and about 2.6 compounds were qualitatively *** geochemical application of the C6-C13.compound groups and their ratios between each group with individual carbon number was *** studies show that (1) C6-C13.compound groups and their ratios in the crude oils could serve as new reliable parameters for oil-oil correlation because the C6-C13.light fractions are the major oil component, especially in light oil or condensate, in which they account for almost 90% of the whole oil;(2. the compound groups of C7 light hydrocarbons in oils derived from difierent depositional environments with difierent salinity have difierent characteristics;(3. C6-C13.compound groups and ratios may be afiected by other factors such as maturity, but they are mainly controlled by salinity of depositional waters.

关键词： Light hydrocarbons Crude oil Depositional environment Salinity

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The productivity evaluation model and its application for finite conductivity horizontal wells in fault block reservoirs

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petroleum Science 2010年第4期7卷 530-535页

作者： Jiang Hanqiao Ye Shuangjiang Lei Zhanxiang Wang Xing Zhu Guojin Chen Minfeng Key Laboratory of petroleum Engineering Ministry of Education China University of Petroleum Beijing 102249 China research institute of {2. Exploration and {3. PetroChina Beijing 100083 China research institute of {2. National Offshore Oil Corporation Beijing 100027 China

It is very difficult to evaluate the productivity of horizontal wells in fault block reservoirs due to the influence of fault *** the basis of the method of images and source-sink theory,a semianalytical model coupling reservoir and finite conductivity horizontal wellbore flow dynamics was built,in which the influence of fault sealing was taken into *** distribution of wellbore flow and radial inflow profiles along the horizontal interval were also *** impact of the distance between the horizontal well and the fault on the well productivity was quantitatively *** on this analysis,the optimal distance between the horizontal well and the fault in banded fault block reservoirs could be *** to the field application,the relative error calculated by the model proposed in this paper is within ±15%.It is an effective evaluation method for the productivity of horizontal wells in fault block *** productivity of the horizontal well increases logarithmically as the distance between the horizontal well and the fault *** optimal distance between the horizontal well and the fault is 0.2.-0.3.times the horizontal well length.

关键词： Fault block reservoir horizontal well finite conductivity productivity evaluation well location design

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Isotopic compositions of small shelly fossil Anabarites from Lower Cambrian in Yangtze Platform of South china: Implications for palaeocean temperature

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Progress in Natural Science:Materials International 2007年第10期17卷 1185-1191页

作者： Chen Yongquan1,2. Jiang Shaoyong1, Ling Hongfei1, Yang Jinghong1 and Wan Defan3.1. State Key Laboatory for Mineral Deposits research and Center for Marine Geochemistry research, Department of Earth Sciences, Nanjing University, Nanjing 2.0093. {2. 2. Tarim Oilfield Company Exploration & development research institute, Ku’erle 841000, {2. 3. institute of Mineral Resources, Chinese Academy of Geological Sciences, beijing 10003., {2.) State Key Laboatory for Mineral Deposits research and Center for Marine Geochemistry research Department of Earth Sciences Nanjing University Nanjing 210093 China arim Oilfield Company Exploration & development research {2. Ku’erle 841000 China institute of Mineral Resources Chinese Academy of Geological Sciences Beijing 100037 China

Anabarites belong to small shelly fossils (SSF), which occur widely in the Lower Cambrian strata of Yangtze Platform in South china. They are phosphate shell in composition and represent the earliest stage of the Cambrian bioradiation of Bilateria, the so-called "Cambrian Explosion". In this study, we attempted to separate Anabarites fossils from Lower Cambrian dolostones, and we obtained samples of both the fossils (SSF) and the granular phosphates (GP). Isotopic analyses were performed on samples of SSF, GP, and matrix dolostone (DH-2.). The results showed that the δ3.Si values of the quartz filling in fossils celoms, and the siliceous materials in granular phosphates are -0.6‰ and -0.7‰, which is different from normal sedimentary siliceous rocks from the Lower Cambrian strata (0—0.7‰) as reported by Li et al., but is consistent with the data for siliceous rocks and cherts of submarine hydrothermal origin. It is likely that a later hydrothermal replacement could have taken place in the SSF-bearing sedimentary rocks. The oxygen isotope values of the phosphate of SSF and GP are 16.8‰ and 17.0‰, respectively. These are significantly higher than the Neoproterozoic phosphate ores (10.9‰—13.9‰) as reported by Ling et al., hence, late diagenesis and hydrothermal replacement may not have caused a significant change in the oxygen isotope compositions of the small shelly fossils, and the calculated temperatures (2..4—2..3.) for palaeo-seawater using a SSF phosphate oxygen isotope thermometer are therefore considered here as the upper limit of seawater temperature in the Early Cambrian ocean of the Yangtze Platform.

关键词： Anabarites oxygen isotope silicon isotope paleo-temperature.

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