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Mechanism of production increasing of coalbed gas for the pinnate horizontal well and sensitivity effect of parameters on gas production

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Chinese Science Bulletin 2005年第S1期50卷 163-170页

作者： ZHANG Dongli & WANG Xinhai sinopec exploration & {2. {3. {4., beijing 100083. China College of Geoscience of Yangtze University, Jingzhou 4.3}02., China 1. sinopec exploration & {2. {3. {4. 100083 Beijing China 2. College of Geoscience of Yangtze University 434023 Jingzhou China

The mechanism of production increasing for the pinnate horizontal well is analyzed with the simulation technique. It is pointed out that the whole horizontal well-bore spreading widely and evenly in coal layers makes the stratum pressure drop evenly and fast, which increases the chance of desorption and diffusion and area controlled. This is the basic reason that the pinnate horizontal well can increase production. How such stratum parameters as permeability, Langmuir constants and adsorption time constant affect the gas production for the pinnate horizontal well is also studied with numerical simulations. Either for the vertical well or the pinnate horizontal well, bigger stratum permeability, steeper relative permeability curve, smaller residual gas saturation, higher gas content and stratum pressure are more favorable for gas production increasing. Langmuir constants decide the change of desorption quantity and influence the gas production through changing the extent of steep of isothermal adsorption curves in the pressure dropping area. The adsorption time constant only influences the time that gas production arrives at the maximum value for the vertical well, but it almost has no influence on the gas production for the pinnate horizontal well because the equivalent adsorption time constant is reduced.

关键词： coalbed gas pinnate horizontal well mechanism numerical simulation sensitivity effect.

Gas formation mechanism of marine carbonate source rocks in China

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Science China Earth Sciences 2005年第4期48卷 441-453页

作者： ZHAO Wenzhi1, WANG Zhaoyun1, HE Haiqing2. ZHANG Mingjie3. WANG Hongjun1, WANG Yunpeng4.& QIN Yong5 1. research institute of Petroleum {2. & Development, PetroChina, beijing 100083. China 2. PetroChina {2. & production, beijing 100011, China 3. Department of Geology, Lanzhou University, Lanzhou 73.000, China 4. Guangzhou Geochemical institute, Chinese Academy of Sciences, Guangzhou 51064., China 5. China University of Mining and Technology, Xuzhou 2.1000, China 1. research institute of Petroleum {2. & Development 100083 PetroChinaBeijin China 2. PetroChina exploration & production 100011 Beijing China 3. Department of Geology Lanzhou University 730000 Lanzhou China 4. Guangzhou Geochemical institute Chinese Academy of Sciences 510640 Guangzhou China 5. China University of Mining and Technology 221000 Xuzhou China

By breaking through the conventional ideology on the study of gas-formation mechanism of source rocks which focused on merely the characteristics of source rocks them- selves, and based on the development and distribution characteristics of marine carbonate source rocks in the medium-to-bottom parts of the Chinese superimposed sedimentary basins as well as various processes in the course of gas generation and reservoir forming, the complex hydrocarbon-generating model of carbonates is established. Such a model concerns not only the “three-stage” gas formation characteristics of carbonates, but also the gas generation process due to a thermal cracking of oil and the re-generation process of gas from heated secondary organic matters during the gas-generation and reservoir-forming course. The high-quality hy- drocarbon generating matter of marine carbonate source rocks determined a high gas-oil ratio and tended to form paleo-oil-reservoirs, representing an enrichment process of organic matters. The thermal cracking of oil in palaeo-oil-reservoirs is an important means for the effective forma- tion of gas reservoirs. The secondary organic matters in carbonate reservoirs may regenerate gas after a secondary deep burial, thus becoming an effective gas source.

关键词： carbonate, three-stage hydrocarbon generation, inhibitive effect of maturity, oil-cracking gas, second-ary asphalt gas.

AN APPROACH TO CUTTINGS FLUOROLOGGING USING HEXANE AS A SUBSTITUTE

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石油勘探与开发 1997年第4期24卷 92-96页

作者： Zhao Juying(research institute of Petroleum {2. and Devempment, CNPC, {3., {4.

It is discovered that carbon tetrachloride is a fluorescence quencher in crude oil detedion with cottings fluorologging. Hexane, which has many advantages as a substitute for carbon tetrachloride, is proposed. In this paper, four typical comparison results of fluorescence spectra of crude oil samples and some of field cores and cuttings are *** sensitivity of fluorescence analysis is increased by 10 to 3. times when we substitute hexane for carbon tetrachloride as the solvent of crude oil. We also find that the lighter the crude oil,the more Obvious the increase in analysis sensitivity. lt challenges the old concopt that coal-derived oil, condensate and some light oils do not emit fluorescence. The merit of hexane system in eliminating or reducing the fluorescent interference of modified asphalts in drilling fluids for cuttings fluorologging has also been discussed.

关键词： Cuttings logging Fluorescence analysis Hexane Carbon tetrachloride Crude oil (Fluorescence quench)

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塔河油田似层状储集体的发现及勘探方向

石油学报 2003年第5期24卷 4-9页

作者：张抗中国石化石油勘探开发研究院北京100083

自 2.0 0 1年以来 ,塔河油田南部下奥陶统一间房组的油气突破证实了对存在似层状储集体的推测。加里东期表生岩溶和深溶作用的发育及其在成藏中的作用 ,启发人们应以网络状和似层状储集体并重的思路 ,以“大岩溶”(成藏过程中多期表生... 详细信息

自 2.0 0 1年以来 ,塔河油田南部下奥陶统一间房组的油气突破证实了对存在似层状储集体的推测。加里东期表生岩溶和深溶作用的发育及其在成藏中的作用 ,启发人们应以网络状和似层状储集体并重的思路 ,以“大岩溶”(成藏过程中多期表生和深溶岩溶 )和“大隆起”(与最大侵蚀期侵蚀基准面以上的整个古隆起及其演化过程 )

关键词：塔里木盆地塔河油田奥陶系碳酸盐岩岩溶油气勘探方向

Detection of water in petroleum inclusions and its implications

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Science Bulletin 2006年第12期51卷 1501-1507页

作者： CAO Jian1, YAO Suping1, HU Wenxuan1, ZHANG Yijie2. WANG Xulong3. ZHANG Yueqian3.& TANG Yong3.1. State Key Laboratory for Mineral Deposit {4., Department of Earth Sciences, Nanjing University, Nanjing 2.0093. China 2. {4. {2. of exploration and Development, PetroChina, Bei- jing 100083. China 3. {4. {2. of exploration and Development, Xinjiang Oilfield Company, PetroChina, Karamay 83.000, China State Key Laboratory for Mineral Deposit research Department of Earth Sciences Nanjing University Nanjing 210093 China research institute of {2. and Development PetroChina Beijing 100083 China research institute of {2. and Development Xinjiang Oilfield Company PetroChina Karamay 834000 China

FTIR spectra of inclusions sampled from fault-zone reservoirs of the northwestern Junggar Basin show that water, with different abundances, does exist in petroleum inclusions. It is thus implied that petroleum inclusions can seldom form without water. Different inclusions hosted in one single grain, and formed in one oil charging phase, have a largely varied ratio of water to oil and slightly changed CH3.CH2.ratio. This likely provides evidence for fault-related episodic migration and accumulation of hydrocarbons.

关键词： water in petroleum inclusions forming mechanism of inclusions episodic migration and accumulation of hydrocarbons FTIR microspectroscopy Junggar Basin.

Final Temperature Prediction Model of Molten Steel in RH-TOP Refining Process for IF Steel production

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Journal of Iron and Steel research International 2012年第3期19卷 1-5页

作者： WANG Yu-nan1, BAO Yan-ping1, CUI Heng2. CHEN Bin3. JI Chen-xi3.(1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology beijing, beijing {2. China 2. Engineering research institute, University of Science and Technology beijing, beijing {2. China 3. Shougang research institute of Technology, beijing 10004., China) [a] State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Beijing 100083 China [b] Engineering research institute University of Science and Technology Beijing Beijing 100083 China [c] Shougang research institute of Technology Beijing 100041 China

In order to precisely control the final temperature of molten steel in RH （Ruhrstahl Heraeus）-TOP blowing refining, the final temperature prediction models of molten steel in RH-TOP blowing refining process for Interstitial Free （IF） steel production were established under the condition of oxygen blowing and non-oxygen blowing respec- tively. The results show that the beginning molten steel temperature of refining and the amount of added scrap were influential factors, the baking temperature in vacuum chamber was a factor that had small influence. When the model was operated, the hitting probability was above 95%（under the condition of both oxygen blowing and non-oxygen blo- wing） of prediction deviation ±10℃. The accuracy is analyzed.

关键词： RH-TOP molten steel temperature prediction model

β-delayed proton decays near the proton drip line

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Science China(Physics,Mechanics & Astronomy) 2005年第3期48卷 257-267页

作者： XU Shuwei 1 , LI Zhankui 1 , XIE Yuanxiang 1 , HUANG Wenxue 1 , SHU Nengchuan 2., CHEN Yongshou 2., XU Furong 3., WANG Kun 4., PAN Qiangyan 1 , WANG Xudong 1 , YU Yong 1 & XING Yebing 1 1. institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 73.000, China 2. Nuclear Physics Department, China institute of Atomic Energy, {2. 102.13. China 3. Department of Technical Physics, Peking University, {2. 100871, China 4. Shanghai institute for Nuclear research, Shanghai 2.1800, China 1. institute of Modern Physics Chinese Academy of Sciences 730000 Lanzhou China 2. Nuclear Physics Department China Institute of Atomic Energy 102413 Beijing China 3. Department of Technical Physics Peking University 100871 Beijing China 4. Shanghai institute for Nuclear research 201800 Shanghai China

We briefly reviewed the experimental study on a-delayed proton decays near the proton drip line published by our group during the period of 1996―2.04. namely the first observation of the a-delayed proton decays of 9 new nuclides in the rare-earth region and the new measurements of a-delayed proton decays of 5 nuclides in the mass ～90 region near the N = Z line with the aid of the “p-?” coincidence in combination with a He-jet tape transport system. In the meantime some important experimental technique details were supplemented. The experimental results, including the half -lives, spins, parities, deformations and production reaction cross sections for the 14.nuclei were summarized and compared with the current nuclear-model predictions, and then the following points were represented. (1) The experimental half-lives for 85Mo and 92.h as well as the predicted “waiting point” nuclei 89Ru and 93.d are 5―10 times longer than the theoretical predictions given by M?ller et al. using a macroscopic-microscopic model. It considerably influences the predictions of the abundances of the nuclides produced in the rp-process. (2. The current-model predictions are not consistent with the experimental assignments of the spins and parities for the proton drip-line nuclei 14.0}o and 12.Pm. However, the nuclear potential energy surface (PES) calculated by using a Woods- Saxon-Strutinsky method reproduced the experimental results. (3. The Alice code overestimated the production reaction cross sections of the studied 9 rare-earth nuclei by one order of magnitude or two, while HIVAP code overestimated them by one order of magnitude approximately.

关键词： proton drip line, β-delayed proton decay, He-jet tape transport system, "p-γ" coincidence, spin, parity, deformation, production reaction cross section.

Alkaline diagenesis and its genetic mechanism in the Triassic coal measure strata in the Western Sichuan Foreland Basin,China

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Petroleum Science 2009年第4期6卷 354-365页

作者： Jiang Zaixing Qiu Longwei Chen Guiju College of Energy China University of GeosciencesBeijing 100083China College of Earth Resources and Information China University of PetroleumShandong 257062China sinopec exploration and {2. {3. {4. Beijing 100083China

The reservoir of the upper Triassic Xujiahe Formation (T3.) in the Western Sichuan Foreland Basin is a set of terrigenous clastic rocks in an environment of coal measure sediments. Diagenesis greatly controls the physical properties of the reservoir through different responses of minerals to acidic and alkaline diagenetic environment. The dissolution of unstable components such as feldspar, rock fragments, carbonate cement, and clay minerals is the major source of secondary pores under acidic diagenesis, while the dissolution of quartz increases the reservoir space in the fault-fold zone of Longmen Mountain and Leikoupo paleo-hills. The dissolution of quartz is a result of cross-formation flow of fluid in the Himalaya epoch and the invasion of alkaline formation water from the Triassic Leikoupo and Jialingjiang formations through fault and fracture systems. In the vertical succession, acidic dissolution occurs at a shallow depth of less than 2.180 m, and alkaline dissolution occurs at a greater depth of more than 2.2.0 m. The reservoir space is formed by the influence of both acidic and alkaline dissolution in the depth interval of 2.180–2.2.0 m.

关键词： Sichuan Basin upper Triassic alkaline diagenesis porosity genetic mechanism

Geological characteristics of large gas provinces and large gas fields in China

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Science China Earth Sciences 2008年第S1期51卷 14-35页

作者： ZOU CaiNeng &TAO ShiZhen research institute of Petroleum {2. and Development,PetroChina,{3. {4.China PetroChina Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China

Based on the examination of the global researches on oil and gas provinces and large gas fields and the analysis of the features,attributes and distribution of large gas provinces and gas fields,this paper puts forward three indicators of determining large oil and gas provinces:spatial indicator,reservoir-forming indicator and resource *** classifies the gas accumulated areas and large gas provinces in China and analyzes the controlling factors on the distribution of large gas provinces and large gas fields:the lateral distribution is mainly controlled by high-energy sedimentary facies and constructive diagenetic facies,palaeo-highs and their periclinal zones,deep faults,etc,and the vertical distribution is mainly controlled by unconformities,series of evaporates and deep low-velocity highly-conductive beds,*** also reveals the main geological characteristics of large gas provinces and large gas fields in *** gas fields in four-type basins have their own characteristics and onland large gas fields are dominantly developed in foreland basins and craton basins;there are three types of gas sources,of which,coal is the main source with high gas generating intensity and varying origins;reservoir rocks of the large gas fields(provinces)are of various types and dominated generally by low-middle permeability and porosity pore-type reservoirs;structural traps and litho-stratigraphic traps coexist in Chinese large gas fields and form dense high abundance and large-area low and middle-abundance large gas fields;most of the large gas fields have late hydrocarbon-generation peaks and reservoir formation,and experienced the process of multiple-stage charging and late finalization; large gas provinces(fields)have good sealing and preservation conditions,and evaporates seals are largely developed in large and extra-large gas *** paper intends to shed light on the exploration and development of large gas fields(provinces)through analyzing their geological

关键词： large gas province large gas field indicator of large oil and gas provinces forming condition distribution characteristics geological feature