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Geochemical characteristics and origin of gases from the Upper,Lower Paleozoic and the Mesozoic reservoirs in the Ordos Basin,china

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Science china Earth Sciences 2008年第S1期51卷 183-194页

作者： HU AnPing 1 ,Li Jian 2 ,ZHANG WenZheng 3 ,LI ZhiSheng 2 ,HOU Lu 4 &LIU QuanYou 5 1 Department of Earth Sciences,Zhejiang University,Hangzhou 310027,china 2 Langfang Branch,Reasearch institute of petroleum exploration and development,Petrochina,Langfang 065007,china 3 institute of exploration and development,Petrochina Changqing Oilfield Company,Xi’an 710021,china 4 University of petroleum,beijing102249,china 5 Petrochina research institute of petroleum exploration and development,beijing 100083,china 1. Department of Earth Sciences Zhejiang University Hangzhou 310027 China2. Langfang Branch Reasearch Institute of Petroleum Exploration and Development PetroChina Langfang 065007 China3. Institute of Exploration and Development PetroChina Changqing Oilfield Company Xi’an 710021 China4. University of Petroleum Beijing 102249 China5. PetroChina Research Institute of Petroleum Exploration and Development Beijing 100083 China

The Ordos Basin,the second largest sedimentary basin in china,contains the broad distribution of natural gas *** far,several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin,each having over 1000×10 8 m 3 of proven gas reserves,and several gas pools have also been discovered in the *** paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs,and then discussed their *** hydrocarbons preserved in the Upper Paleozoic,the elevatedδ13C values of methane,ethane and propane indicate that the gases would be mainly coal-formed gases;the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different *** the Lower Paleozoic,theδ13C 1 values are mostly similar with those in the Upper Paleozoic,but theδ13C 2.andδ13C 3 values are slightly lighter,suggesting that the gases would be mixing of coal-type gases as a main member and oil-type *** are multiple reversals in carbon isotopes for gaseous alkanes,especially abnormal reversal for methane and ethane(i.e.δ13C 1 >δ13C 2.),inferring that gases would be mixed between high-mature coal-formed gases and oil-type *** the Mesozoic,the δ13Cvalues for gaseous alkanes are enriched in 12.,indicating that the gases are mainly derived from sapropelic sources;the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different *** contrast to the Upper Paleozoic gases,the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane,which may be caused by gases generated from different kerogen types. Finally,according toδ13C 1 -Ro relationship and extremely low total organic carbon contents,the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source,bycontrast, the Upper Pale

关键词： Ordos Basin natural gas chemical composition carbon isotope genesis

Identification of marine natural gases with different origin sources

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Science china Earth Sciences 2008年第S1期51卷 148-164页

作者： WANG YunPeng 1 ,ZHAO ChangYi 2.,WANG ZhaoYun 2.,WANG HongJun 2.,TIAN Jin 1 ,ZOU YanRong 1 &LIU JinZhong1 1State Key Laboratory of Organic Geochemistry,Guangzhou institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,china 2.0} of Geology,research institute of petroleum exploration and development,Petrochina,beijing 100083,china State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China institute of Geology Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083

Kinetic experiments of gas generation for typical samples of marine gas precursors including low-maturity kerogen,residual kerogen and oil as well as dispersed liquid hydrocarbon(DLH)in source rocks were performed by closed system,and the evolution trends of molecular and isotopic compositions of natural gases from different precursors against the maturity(R0%)at laboratory conditions were *** diagrams of gas origin were calibrated by using the experimental data.A diagram based on the ratio of normal and isomerous butane and pentane(i/nC4-i/nC5)was proposed and used to identify the origins of the typical marine natural gases in the Sichuan Basin and the Tarim Basin, *** the maturities of natural gases were estimated by using the statistical relationships between the gaseous molecular carbon isotopic data and maturities(δ13C-R 0 %)with different *** results indicate that the molecular and isotopic compositions of simulated gases from different precursors are different from each *** example,the dryness index of the oil-cracking gas is the lowest;the dryness indices of gases from DLH and kerogen in closed system are almost the same;and the dryness index of gases from residual kerogen is extremely high,indicating that the kerogen gases are very dry;the contents of non-hydrocarbon gases in kerogen-cracking gases are far higher than those in oil-cracking and DLH-cracking *** molecular carbon isotopes of oil-cracking gases are the lightest,those of kerogen in closed system and GLH-cracking gases are the second lightest,and those of cracking gases from residual kerogen are the *** calibration results indicate that the diagrams of ln(C1/C2.-ln(C2.C3)andδ13C2.δ13C3-ln(C2.C3)can discriminate primary and secondary cracking gases,but cannot be used to identify gas origin sources,while the diagram of i/nC4-i/nC5 can differentiate the gases from different *** application results of these diagrams show that gas mixtures ext

关键词： marine organic matter gas origin sources kerogen oil-cracking gas origin identification carbon isotope

Formation mechanism of carbonate cemented zones adjacent to the top overpressured surface in the central Junggar Basin,NW china

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Science china Earth Sciences 2010年第4期53卷 529-540页

作者： YANG Zhi1,2.ZOU CaiNeng1,3,HE Sheng2.LI QiYan1,HE ZhiLiang3,WU HengZhi5,CAO Feng1,MENG XianLong4,WANG FuRong2.& XIAO Qilin2. State Key Laboratory of EOR,research institute of {2. exploration & development,Petrochina,beijing 100083,china 2.Key Laboratory of Tectonics and {2. Resources of Ministry of Education,china University of Geosciences,Wuhan 430074,china 3 State Key Laboratory of EOR,research institute of {2. exploration & development,Petrochina,beijing 100083,china 4 research institute of {2. exploration and Production,SINOPEC,beijing 100083,china 5 Southwest Branch Company,SINOPEC,Chengdu 610051,china 1. State Key Laboratory of EOR Research Institute of Petroleum Exploration & Development PetroChina Beijing 100083 China2. Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education China University of Geosciences Wuhan 430074 China3. State Key Laboratory of EOR Research Institute of Petroleum Exploration & Development Petrochina Beijing 100083 China5. Southwest Branch Company SINOPEC Chengdu 610051 China4. Research Institute of Petroleum Exploration and Production SINOPEC Beijing 100083 China

Carbonate cemented zones are normally adjacent to the top overpressured surface in the central Junggar Basin,NW *** carbon and oxygen isotopic compositions and petrological investigations of carbonate cements in the carbonate cemented zones indicate that:(1) carbonate cements are composed dominantly of ferrocalcite,ferroan dolomite,and ankerite;(2. carbonate cements are formed under a high temperature circumstance in the subsurface,and organic fluid migration has an important effect on the formation of them;and(3) carbon and oxygen ions in the carbonate cements migrate from the underlying overpressured *** suggests that the occurrence of carbonate cemented zones in this region results from multiple phases of organic fluid expulsion out of the overpressure compartment through geological *** study provides a plausible mechanism of the formation of carbonate cemented zones adjacent to the top overpressured surface in the clastic sedimentary basins,and has an important implication for understanding the internal correlation between the formation of carbonate cemented zones adjacent to top overpressured surface and geofluids expulsion out of overpressured system.

关键词： carbonate cemented zones formation mechanism stable carbon and oxygen isotopic top overpressured surface central Junggar Basin coal-bearing strata

Present geotemperature and its suggestion to natural gas generation in Xujiaweizi fault-depression of the northern Songliao Basin

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Science china Earth Sciences 2008年第S1期51卷 207-220页

作者： ZHOU QingHua 1,2.,FENG ZiHui 3 &MEN GuangTian 3 1 research institute of {2. exploration and development,Petrochina,beijing 100083,china 2.Geological Logging Subcompany of Daqing Oil Field Company Ltd.,Daqing 163411,china 3 research institute of {2. exploration and development of Daqing Oil field Company Ltd.,Daqing 163732.china Petrochina Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China Daqing Oil Field Co Ltd Geol Logging Subco Daqing 163411 Peoples R China Daqing Oil field Co Ltd Res Inst Petr Explorat & Dev Dacling 163732 Peoples R China

According to stastistic of present geotemperatures at the depths of 1000,2.00,3000 and 4000 m,respectively in the Xujiaweizi fault-depression of the north Songliao Basin,the result indicates that Xujiaweizi fault-depression falls in the high geotemperature area,with the higher geothermal gradient in the depression layer than that in the fault-depression *** geothermal gradient decreases with the increasing of the *** thermal conductivity of rock greatly controls the geothermal *** main factors constraining the current geotemperature include thermal configuration of the earth's crust, deep faults,distribution and abundance of *** high geotemperature is in favour of generation of deep gas.

关键词： Xujiaweizi fault-depression geotemperature geothermal gradient thermal conductivity of rock deep layer natural gas

Geological analysis and physical modeling of structural pumping in high effective formation of Kela 2.gas field

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Science china Earth Sciences 2006年第10期49卷 1070-1078页

作者： ZHAO Wenzhi1, WANG Hongjun1, SHAN Jiazeng2. WANG Zecheng1 & XU Dafeng1 1. research institute of {2. exploration and development, Petrochina, beijing 100083, china 2. institute of Geology and Geophysics, Chinese Academy of Sciences, beijing 10002., china 1. research institute of {2. exploration and development Petrochina Beijing 100083 China 2. institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China

In a 3-D closed geological body, in case “structural expanding” inside is induced by stress, it can produce the pressure difference between the expanding cell and surrounding rock, then generate a pumping force directed toward the cell and accelerate the directional flow of fluid in the strata. The structural style and conditions of gas reservoir-formation in the Kuqa depression are favorable to the structural pumping. According to similarity principle, a physical modeling of structure formation and gas filling process of the Kela 2.gas field has justified the occurrence of structural pumping and its important role in gas-reservoir formation with high efficiency under the compressive and well-sealed circumstance. Therefore, authors propose that structural pumping is an important mechanism of gas reservoir-formation with high efficiency in the Kuqa depression.

关键词： Kela 2 gas field, structural pumping, gas-reservoir formation mechanism, high efficiency,physical modeling.

Structural characteristics and petroliferous features of Tarim Basin

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Chinese Science Bulletin 2002年第S1期47卷 1-11页

作者： JIA Chengzao~1 & WEI Guoqi~2.1. Petrochina Company Limited, beijing 100011,{2. 2. Langfang Branch of research institute of petroleum exploration & development, Petrochina, Langfang 065007,{2. 1. Petrochina Company Limited 100011 Beijing China 2. Langfang Branch of research institute of {2. exploration & development PetroChina 065007 Langfang China

Using the modern tectonic geology theories andmethods such as the plate tectonic analysis, the paleo-struc-ture analysis, the structural-Iithofacies analysis, and the faultrelated fold and petroleum system, and combining with theseismic data, well drilling data and the circumferential fieldgeology, study on the structural characteristics and petro-leum prospect in the Tarim Basin has been carried out. Re-sults show that the Tarim Basin is a large superimpositionand combination basin with continental crustal basement,composed of a Paleozoic craton and Meso-Cenozoic forelandbasins. The characteristics of the basin are: the kernel partof the basin is the marine facies Paleozoic craton, superim-posed 4 continental facies foreland basins. Though the scaleof the paleozoic craton of the Tarim Basin is relatively small,the structure is steady. The petroleum prospect of the Paleo-zoic craton is: multiphase pool-generation and accumulationcontrolled by ancient uplift. The Meso-Cenozoic forelandbasins in the Tarim Basin, which are distributed on the era-tonic circumference and are a long-term subsidence, turnedinto rejuvenated foreland basins after the Meso-Cenozoicperiod. The petroleum prospects are: coal-bed generatinghydrocarbon, abundant natural gas, pool-generation in laterand recent periods, the oil and gas distribution controlled bythe foreland thrust belt. The structural characteristics ofTarim provide it with a superimposition and combinationpetroleum system of multiple resources, multiple reservoirsand multiphase pool-generation. The oil and gas explorationprospect covers two large fields: the Paleozoic craton and theMeso-Cenozoic foreland thrust belt.

关键词： Tarim superimposition and combination basin craton foreland basin superimposition and combination petroleum system.

Wave tectono-sedimentary processes in Tarim basin

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Science china Earth Sciences 2005年第11期48卷 1949-1959页

作者： JIN Zhijun1,2. ZHANG Yiwei1 & CHEN Shuping1 1. Key Laboratory for Hydrocarbon Accumulation, Ministry of Education, china University of petroleum, {2. 102.49, china 2. exploration and Production research institute, china petroleum & Chemical Corporation, beijing 100083, china 1. Key Laboratory for Hydrocarbon Accumulation Ministry of Education China University of Petroleum 102249 Beijing China 2. exploration and Production research {2. China Petroleum & Chemical Corporation 100083 Beijing China

Based on the unconformities, the formation times of structures, and geological wave filtering applied to basin fills of typical wells around the Manjiaer area in the Tarim basin, the wave tectono-sedimentary processes in the Tarim Basin are discussed. The results of geological wave filtering of basin fills of typical wells show that, in time domain, the evolution of the Tarim basin was controlled by various wave processes with the periods of 740±Ma, 2.0±Ma, 100±Ma and 30±Ma. The analyses of basin fills, basin subsidence and unconformities show that the trends of the sedimentary facies belts, depocenters, and centers of subsidence migrated and interchanged periodically with periods of 2.0±Ma. These show the propagation of wave movements in space domain. The wave evolution of the Tarim basin is of significance to understanding the formation of the oil and gas reservoirs in the basin.

关键词： Tarim basin, tectonics, sedimentation, crustal undation, wave evolution

THE CHARACTERISTICS OF REMOTE SENSING TECTONICS IN QIANGTANG-CHANGDU MASSIF, QINGHAI-TIBET PLATEAU

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地学前缘 2000年第S1期7卷 435-437页

作者： Zhao Zhengzhang 1,Ye Hefei 2.Li Yongtie 2.1 china National petroleum Corporation, {2. 10072.,china 2.research institute of petroleum exploration and development, cnpc, beijing 100083,china)

The northern Tibet plateau is the core of generalized Qinghai—Tibet plateau. The main part of Qiangtang—Changdu massif, which is 45×10 4km 2.and more than 5000m in altitude, conforms to the northern Tibet plateau in area.1 The shape features and boundary conditions of Qiangtang—Changdu massif\;(1) Qiangtang—Changdu massif shows huge flat\|lying “S” area In MSS7 mosaic image, Qiangtang—Changdu massif extends in west and east, and appears a long\|elliptic huge block composed of feathered and dendritic textures.. Noticeably, there are two similar texture “tails" in the west and east ends of the massif. The western tail turns and constringes to the north, and eastern tail to the south. Thereby, the massif shows huge “S" area. According to the regional analysis, the eastern tail locates between Shaluli Mt.\|Taniantaweng Mt. and Mujiang River, and western part through Bangong\|Co connects with Pamirs along Karakoram Mt. In regional tectonics, the massif locates between Lazhulong\|Xijinwulan\|Co\|Jinshajiang River and Bangong\|Co\|Dongqiao\|Nujiang River fault belts.

关键词： Qiangtang—Changdu massif remote sensing boundary condition circular structure deformin g features mechanic characteristic dynamics

Hydrogen isotopic compositions, distributions and source signals of individual n-alkanes for some typical crude oils in Lunnan Oilfield, Tarim Basin, NW china

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Science china Earth Sciences 2005年第8期48卷 1220-1226页

作者： LU Hong1, LI Chao1, SUN Yongge1, PENG Ping’an1 & XIAO Zhongyao2.1. State Key Laboratory of Organic Geochemistry, Guangzhou institute of Geochemistry, Chinese Academy of Sciences, Guangzhou510640, china 2. Tarim {2. institute of exploration and development of petroleum, china petroleum, Korla 841000, china 1. State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. Tarim research institute of {2. and development of petroleum China Petroleum 841000 Korla China

Isotopic compositions of carbon-bound hydrogen in individual n-alkanes from sev-eral typical crude oil samples from Lunnan Oilfield, Tarim Basin, NW china, were firstly measured using newly developed gas chromatography-thermal conversion-isotope ratio mass spectrometry. The similar range of δ D of individual n-alkanes of crude oils among reservoirs of different geo-logical times reflects that hydrocarbons are all derived from the same marine depositional envi-ronment. Compared to the theoretic value (?150‰) and the reported δ D values (nC13―nC2., ?160‰―?90‰) of individual n-alkanes for Ordovician-sourced crude oils in the Canadian Wil-liston Basin, the hydrogen isotopic composition of individual n-alkanes in crude oils from Lunnan Oilfield is characterized by heavy hydrogen isotopic values (nC12.nC2., ?12.‰―?60‰). In terms of the factors that control the fractionation of hydrogen isotopes, relatively saline deposi-tional environment and higher thermal maturation were attributed to the heavy δ D values of in-dividual n-alkanes in crude oils from Lunnan Oilfield.

关键词： hydrogen isotopes, individual n-alkanes, distribution, hydrocarbon source, Lunnan Oilfield.