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Structural characteristics and petroliferous features of Tarim Basin

Chinese Science Bulletin 2002年第S1期47卷 1-11页

作者： JIA Chengzao~1 & WEI Guoqi~2.1. petrochina Company Limited, Beijing 100011, china {2., petrochina, langfang 065007, china petrochina Company Limited Beijing China langfang branch of {2. institute of petroleum exploration & development PetroChina Langfang China

Using the modern tectonic geology theories andmethods such as the plate tectonic analysis, the paleo-struc-ture analysis, the structural-Iithofacies analysis, and the faultrelated fold and petroleum system, and combining with theseismic data, well drilling data and the circumferential fieldgeology, study on the structural characteristics and petro-leum prospect in the Tarim Basin has been carried out. Re-sults show that the Tarim Basin is a large superimpositionand combination basin with continental crustal basement,composed of a Paleozoic craton and Meso-Cenozoic forelandbasins. The characteristics of the basin are: the kernel partof the basin is the marine facies Paleozoic craton, superim-posed 4 continental facies foreland basins. Though the scaleof the paleozoic craton of the Tarim Basin is relatively small,the structure is steady. The petroleum prospect of the Paleo-zoic craton is: multiphase pool-generation and accumulationcontrolled by ancient uplift. The Meso-Cenozoic forelandbasins in the Tarim Basin, which are distributed on the era-tonic circumference and are a long-term subsidence, turnedinto rejuvenated foreland basins after the Meso-Cenozoicperiod. The petroleum prospects are: coal-bed generatinghydrocarbon, abundant natural gas, pool-generation in laterand recent periods, the oil and gas distribution controlled bythe foreland thrust belt. The structural characteristics ofTarim provide it with a superimposition and combinationpetroleum system of multiple resources, multiple reservoirsand multiphase pool-generation. The oil and gas explorationprospect covers two large fields: the Paleozoic craton and theMeso-Cenozoic foreland thrust belt.

关键词： Tarim superimposition and combination basin craton foreland basin superimposition and combination petroleum system.

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歧口凹陷歧深1井气源综合对比

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天然气地球科学 2009年第3期20卷 392-399页

作者：国建英于学敏李剑王东良崔会英李志生中国矿业大学北京100083 中国石油勘探开发研究院廊坊分院河北廊坊065007 中国石油大港油田勘探开发研究院天津大港300280

歧深1井是一口位于渤海湾盆地黄骅坳陷歧口凹陷滨海断鼻的深层探井,在482..0～5088m沙三段地层用10.32.m油嘴日产气54611m3。天然气甲烷、乙烷碳同位素异常重,δ13C1值在-35.7‰～-32.7‰之间,δ13C2.在-19.1‰～-15.2.之间。通过对... 详细信息

歧深1井是一口位于渤海湾盆地黄骅坳陷歧口凹陷滨海断鼻的深层探井,在482..0～5088m沙三段地层用10.32.m油嘴日产气54611m3。天然气甲烷、乙烷碳同位素异常重,δ13C1值在-35.7‰～-32.7‰之间,δ13C2.在-19.1‰～-15.2.之间。通过对该井沙三段烃源岩热解气碳同位素和轻烃的研究,并结合天然气组分、碳同位素和轻烃以及储层包裹体的特征,认为该天然气属于高成熟天然气,主要来自研究区埋深更大的沙三段烃源岩,具有多期充注的特征。证实歧口凹陷存在高成熟,甚至过成熟天然气,进一步明确歧口凹陷深层天然气勘探要以沙二段、沙三段为主要目的层。

关键词：碳同位素轻烃天然气成因分析歧深1井歧口凹陷黄骅坳陷

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水溶气运移成藏物理模拟实验技术

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天然气地球科学 2004年第1期15卷 32-36页

作者：刘朝露李剑方家虎胡国艺严启团李志生马成华孙庆武中国矿业大学(北京) 北京100083 中国石油勘探开发研究院廊坊分院河北廊坊065007

通过自行设计的天然气运移成藏物理模拟仪,对实际岩芯样品进行了高压水溶气运移成藏的物理模拟实验,目的是研究水溶作用对天然气运移指标产生的影响以及水溶气甲烷和乙烷碳氢同位素、C2./总烃、iC4/nC4等8项地球化学参数的变化。实验结... 详细信息

通过自行设计的天然气运移成藏物理模拟仪,对实际岩芯样品进行了高压水溶气运移成藏的物理模拟实验,目的是研究水溶作用对天然气运移指标产生的影响以及水溶气甲烷和乙烷碳氢同位素、C2./总烃、iC4/nC4等8项地球化学参数的变化。实验结果表明:随着运移距离的增加,水溶气中的非烃CO2.量普遍增大,烃类气体"甲烷化"趋势明显,C2.以上的含量随碳数升高而降低(至C5含量基本可以忽略不计),轻烃组分中的苯和甲苯含量由低(气源)到高(运移距离近)再变低(运移距离远),甲烷碳和氢同位素变化幅度均不大(仍具有略偏正的特征)。认为这些地球化学参数的变化特征对水溶气气藏的识别和油气运移的研究均具有重要的参考价值。

关键词：水溶气运移成藏物理模拟天然气岩芯地球化学参数

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Distribution and fractionation mechanism of stable carbon isotope of coalbed methane

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Science china Earth Sciences 2006年第12期49卷 1252-1258页

作者： QIN Shengfei1, TANG Xiuyi2. SONG Yan1 & WANG Hongyan3 1. research institute of {2. exploration and development, petrochina, Beijing 100083, china 2. Anhui Science and Technology College, Huainan 2.2.00, china 3. langfang branch, research institute of {2. exploration and development, petrochina, langfang 065007, china research institute of {2. exploration and development PetroChina Beijing China Anhui Science and Technology College Huainan China langfang branch Research Institute of Petroleum Exploration and Development PetroChina Langfang China

The stable carbon isotope values of coalbed methane range widely, and also are gener- ally lighter than that of gases in normal coal-formed gas fields with similar coal rank. There exists strong carbon isotope fractionation in coalbed methane and it makes the carbon isotope value lighter. The correlation between the carbon isotope value and Ro in coalbed methane is less obvious. The coaly source rock maturity cannot be judged by coalbed methane carbon isotope value. The carbon isotopes of coalbed methane become lighter in much different degree due to the hydrodynamics. The stronger the hydrodynamics is, the lighter the CBM carbon isotopic value becomes. Many previous investigations indicated that the desorption-diffusion effects make the carbon isotope value of coalbed methane lighter. However, the explanation has encountered many problems. The authors of this arti- cle suggest that the flowing groundwater dissolution to free methane in coal seams and the free methane exchange with absorbed one is the carbon isotope fractionation mechanism in coalbed methane. The flowing groundwater in coal can easily take more 13CH4 away from free gas and com- paratively leave more 12.H4. This will make 12.H4 density in free gas comparatively higher than that in absorbed gas. The remaining 12.H4 in free gas then exchanges with the adsorbed methane in coal matrix. Some absorbed 13CH4 can be replaced and become free gas. Some free 12.H4 can be ab- sorbed again into coal matrix and become absorbed gas. Part of the newly replaced 13CH4 in free gas will also be taken away by water, leaving preferentially more 12.H4. The remaining 12.H4 in free gas will exchange again with adsorbed methane in the coal matrix. These processes occur all the time. Through accumulative effect, the 12.H4 will be greatly concentrated in coal. Thus, the stable carbon isotope of coalbed methane becomes dramatically lighter. Through simulation experiment on wa- ter-dissolved methane, it had been proved that the f

关键词： coalbed methane,methane stable carbon isotope,fractionation mechanism,accumulative effect.

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Natural gas geochemistry and its origins in Kuqa depression

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Science china Earth Sciences 2008年第S1期51卷 174-182页

作者： LIU QuanYou 1 ,QIN ShengFei 1 ,LI Jian 2.,LIU WenHui 3 ,ZHANG DianWei 3 ,ZHOU QingHua 1 &HU AnPing 1 1 research institute of {2. exploration and development,petrochina,Beijing 100083,china 2.langfang branch of research institute of {2. exploration and development,petrochina,langfang 065007,china 3 exploration and Production research institute,SINOPEC,Beijing 100083,china research institute of {2. exploration and development PetroChina Beijing China langfang branch of {2. institute of petroleum exploration and development PetroChina Langfang China exploration and Production research {2. SINOPEC Beijing China

According to gas compositional and carbon isotopic measurement of 114 gas samples from the Kuqa depression,accumulation of the natural gases in the depression is dominated by hydrocarbon gases, with high gas dryness(C1/C1-4)at the middle and northern parts of the depression and low one towards east and west sides and southern *** carbon isotopes of methane and its homologues are relatively enriched in 13 C,and the distributive range ofδ13C 1 ,δ13C 2.andδ13C 3 is-32.―-36‰,-2.‰―-2.‰and-2.‰―-2.‰,*** general,the carbon isotopes of gaseous alkanes become less negative with the increase of carbon ***δ13C CO2.value is less than-10‰in the Kuqa depression,indicating its organogenic *** distributive range of 3 He/ 4 He ratio is within n×10-8 and a decrease in 3 He/ 4 He ratio from north to south in the depression is *** on the geochemical parameters of natural gas above,natural gas in the Kuqa depression is of characteristics of coal-type gas *** possible reasons for the partial reversal of stable carbon isotopes of gaseous alkanes involve the mixing of gases from one common source rock with different thermal maturity or from two separated source rock intervals of similar kerogen type,multistages accumulation of natural gas under high-temperature and over-pressure conditions,and sufficiency and diffusion of natural gas.

关键词： Kuqa depression natural gas stable carbon isotope gas origin

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Geochemical characteristics and origin of gases from the Upper,Lower Paleozoic and the Mesozoic reservoirs in the Ordos Basin,china

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Science china Earth Sciences 2008年第S1期51卷 183-194页

作者： HU AnPing 1 ,Li Jian 2.,ZHANG WenZheng 3 ,LI ZhiSheng 2.,HOU Lu 4 &LIU QuanYou 5 1 Department of Earth Sciences,Zhejiang University,Hangzhou 31002.,china 2.langfang {2.,Reasearch institute of petroleum exploration and development,petrochina,langfang 065007,china 3 institute of exploration and development,petrochina Changqing Oilfield Company,Xi’an 71002.,china 4 University of petroleum,Beijing102.49,china 5 petrochina research institute of petroleum exploration and development,Beijing 100083,china Department of Earth Sciences Zhejiang University Hangzhou China langfang branch Reasearch Institute of Petroleum Exploration and Development PetroChina Langfang China institute of exploration and {2. PetroChina Changqing Oilfield Company Xi’an China University of petroleum Beijing China petrochina research {2. of petroleum exploration and development Beijing China

The Ordos Basin,the second largest sedimentary basin in china,contains the broad distribution of natural gas *** far,several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin,each having over 1000×10 8 m 3 of proven gas reserves,and several gas pools have also been discovered in the *** paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs,and then discussed their *** hydrocarbons preserved in the Upper Paleozoic,the elevatedδ13C values of methane,ethane and propane indicate that the gases would be mainly coal-formed gases;the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different *** the Lower Paleozoic,theδ13C 1 values are mostly similar with those in the Upper Paleozoic,but theδ13C 2.andδ13C 3 values are slightly lighter,suggesting that the gases would be mixing of coal-type gases as a main member and oil-type *** are multiple reversals in carbon isotopes for gaseous alkanes,especially abnormal reversal for methane and ethane(i.e.δ13C 1 >δ13C 2.),inferring that gases would be mixed between high-mature coal-formed gases and oil-type *** the Mesozoic,the δ13Cvalues for gaseous alkanes are enriched in 12.,indicating that the gases are mainly derived from sapropelic sources;the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different *** contrast to the Upper Paleozoic gases,the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane,which may be caused by gases generated from different kerogen types. Finally,according toδ13C 1 -Ro relationship and extremely low total organic carbon contents,the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source,bycontrast, the Upper Pale

关键词： Ordos Basin natural gas chemical composition carbon isotope genesis

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The special sealing mechanism of caprock for Quaternary biogenetic gas in Sanhu area,Qaidam Basin,china

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Science china Earth Sciences 2008年第S1期51卷 45-52页

作者： LI Jian 1 ,YAN QiTuan 1 ,ZHANG Ying 1 ,LIU GuangDi 2.&WANG XiaoBo 1 1 research institute of {2. exploration and development-langfang,langfang 065007,china 2.University of {2.,Beijing 102.49,china research institute of {2. exploration and development-langfang Langfang China University of petroleum Beijing China

The Quaternary biogenetic gas reservoirs in the east of Qaidam Basin have many characteristics such as late forming time,shallow burial depth,low diagenetic grade,high porosity and high permeability and so *** cannot be considered as caprock according to the traditional evaluation ***, the large scale and high efficient biogenetic gas reservoirs of the Qaidam Basin are really formed under these kinds of caprocks,so it does have some specialty in its sealing *** at the special sealing mechanism,some simulating experiments have been *** research results show that the sealing ability of biogenetic gas caprock is related with water saturation,the caprock that is saturated with salt water can effectively block seepage and ***,the multiple reservoir-caprock groups have accumulated sealing effect,causing the formation of big gas *** evaluation method with traditional caprock parameters cannot be adopted in evaluating the study area.

关键词： Qaidam Basin biogenetic gas caprock sealing mechanism diffusion water saturation accumulated sealing

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Preliminary study on the origin identification of natural gas by the parameters of light hydrocarbon

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Science china Earth Sciences 2008年第S1期51卷 131-139页

作者： HU GuoYi 1,2.3 ,LI Jian 1,2.,LI Jin 1,2.,LI ZhiSheng 1,2.,LUO Xia 1,2.,SUN QingWu 1,2.&MA ChengHua 1,2.1 research institute of {2. exploration and development(langfang branch),petrochina,langfang 065007,china 2.The Key Laboratory of Gas Formation and development,petrochina,langfang 065007,china 3 College of Geo-Resources and Information,china University of {2.,Beijing 102.00,china research institute of {2. exploration and development (langfang branch) Petrochina Langfang China The Key Laboratory of Gas Formation and development Petrochina Langfang China College of Geo-Resources and Information China University of Petroleum Beijing China

The light hydrocarbon composition of 2.9 natural gas samples and individual light hydrocarbon carbon isotopes of 53 natural gas samples from typical humic-sourced gas and sapropelic-sourced gas in the four basins of china have been determined and *** identification parameters for humic-sourced gas and sapropelic-sourced gas are proposed or *** differences of compound-specificδ13C value of individual light hydrocarbon between humic-sourced gas and sapropelic-sourced gas have been *** humic-sourced gas has the distribution ofδ13C benzene > -2.‰,δ13C toluene >-2.‰,δ13C cyclohexane >-2.‰andδ13C methyl cyclohexane >-2.‰,while the sapropelicsourced gas has the distribution ofδ13C benzene 2.‰,δ13C toluene 2.‰,δ13C cyclohexane 2.‰and δ13C methyl cyclohexane 2.‰.Among the components of C7 light hydrocarbon compound,such as normal heptane(nC7),methyl cyclohexane(MCH)and dimethyl cyclopentane(ΣDMCP),etc,relative contents of nC7 and MCH are influenced mainly by the source organic matter type of natural ***,it is suggested that the gas with relative content of nC7 of more than 30%and relative content of MCH of less than 70%is sapropelic-sourced gas,while gas with relative content of nC7 of less than 35%and relative content of MCH of more than 50%is humic-sourced *** components of C5-7 aliphatics, the gas with relative content of C5-7 normal alkane of more than 30%is sapropelic-sourced gas,while the gas with relative content of C5-7 normal alkane of less than 30%is humic-sourced *** paremeters have been suggested to identify humic-sourced gas and sapropelic-sourced gas.

关键词： natural gas humic-sourced gas sapropelic-sourced gas carbon isotope light hydrocarbon parameters

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Geochemical characteristics of pyrolysis gas from epimetamorphic rocks in the northern basement of Songliao Basin,Northeast china

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Science china Earth Sciences 2008年第S1期51卷 140-147页

作者： YANG Chun 1 ,LUO Xia 2.,LI Jian 2.,LI ZhiSheng 2.,LIU QuanYou 3 &Wang YuLin 4 1 Department of Earth Sciences,Zhejiang University,Hangzhou 31002.,china 2.research {2. of petroleum exploration and development(langfang branch),langfang 065007,china 3 research {2. of petroleum exploration and development,Beijing 100083,china 4 Department of Source and Environment,Liaoning Technical University,Fuxin 12.000,china Department of Earth Sciences Zhejiang University Hangzhou China research institute of {2. exploration and development (langfang branch) Langfang China research institute of {2. exploration and development Beijing China Department of Source and Environment Liaoning Technical University Fuxin China

The Xushen gas field,located in the north of Songliao Basin,is a potential giant gas area for china in the *** proved reserves have exceeded 1000×10 8 m 3 by the end of ***,the origin of natural gases from the deep strata is still in *** rocks as a potential gas source are widely spreading in the northern basement of Songliao *** to pyrolysis experiments for these rocks in the semi-confined system,gas production and geochemistry of alkane gases are discussed in this *** Carboniferous-Permian epimetamorphic rocks were heated from 300℃to 550℃,with temperature interval of 50℃.The gas production was quantified and measured for chemical and carbon isotopic *** show thatδ13C 1 is less than?2.‰,carbon isotope trend of alkane gas isδ13C 1 2.2.>δ13C 3 ,these features suggest that the gas would be coal-type gas at high-over maturity,not be inorganic gas with reversal trend of gaseous alkanes (δ13C 1 >δ13C 2.>δ13C 3 ).These characteristics of carbon isotopes are similar with the natural gas from the basin basement,but disagree with gas from the Xingcheng ***,the mixing gases from the pyrolysis gas with coal-typed gases at high-over maturity or oil-typed gases do not cause the reversal trend of carbon *** gas generation intensity for epimetamorphic rocks is 3.0×10 8 ―2..8×10 8 m 3 /km 2.,corresponding to Ro from 2.0%to 3.5%for organic matter.

关键词： Northern Songliao Basin epimetamorphic rock pyrolysis experiment gas generation potential carbon isotope

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Geological characteristics of large gas provinces and large gas fields in china

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Science china Earth Sciences 2008年第S1期51卷 14-35页

作者： ZOU CaiNeng &TAO ShiZhen research institute of {2. exploration and development,petrochina,Beijing 100083,china research institute of {2. exploration and development PetroChina Beijing China

Based on the examination of the global researches on oil and gas provinces and large gas fields and the analysis of the features,attributes and distribution of large gas provinces and gas fields,this paper puts forward three indicators of determining large oil and gas provinces:spatial indicator,reservoir-forming indicator and resource *** classifies the gas accumulated areas and large gas provinces in china and analyzes the controlling factors on the distribution of large gas provinces and large gas fields:the lateral distribution is mainly controlled by high-energy sedimentary facies and constructive diagenetic facies,palaeo-highs and their periclinal zones,deep faults,etc,and the vertical distribution is mainly controlled by unconformities,series of evaporates and deep low-velocity highly-conductive beds,*** also reveals the main geological characteristics of large gas provinces and large gas fields in *** gas fields in four-type basins have their own characteristics and onland large gas fields are dominantly developed in foreland basins and craton basins;there are three types of gas sources,of which,coal is the main source with high gas generating intensity and varying origins;reservoir rocks of the large gas fields(provinces)are of various types and dominated generally by low-middle permeability and porosity pore-type reservoirs;structural traps and litho-stratigraphic traps coexist in Chinese large gas fields and form dense high abundance and large-area low and middle-abundance large gas fields;most of the large gas fields have late hydrocarbon-generation peaks and reservoir formation,and experienced the process of multiple-stage charging and late finalization; large gas provinces(fields)have good sealing and preservation conditions,and evaporates seals are largely developed in large and extra-large gas *** paper intends to shed light on the {2. and development of large gas fields(provinces)through analyzing their geological

关键词： large gas province large gas field indicator of large oil and gas provinces forming condition distribution characteristics geological feature

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