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Role of gallium wetting layer in high-quality ZnO growth on sapphire (0001) substrates

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Science China(physics,Mechanics & Astronomy) 2004年第5期47卷 612-620页

作者： ZENG Zhaoquan1,3. WANG Yong2. DU Xiaolong1, MEI Zengxia1, KONG Xianghe3. JIA Jinfeng1, XUE Qikun1 & ZHANG Ze2. 4 1. State Key laboratory for Surface {3.,{2., Chinese academy of sciences, beijing 100080, China 2. laboratory of electron microscopy,{2., Chinese academy of sciences, beijing 100080, China 3. College of {3. and Engineering, Qufu Normal University, Qufu 2.3.65, China 4. {12. University of Technology, {12. 10002., China State Key laboratory for Surface physics Institute of Physics Chinese Academy of Sciences Beijing China College of physics and Engineering Qufu Normal University Qufu China laboratory of electron {2. Institute of Physics Chinese Academy of Sciences Beijing China beijing University of Technology Beijing China

A Ga wetting layer was used to modify the surface structure of sapphire (0001) substrate to prepare high-quality ZnO film by radio frequency plasma-assisted molecule beam epitaxy. We found that this Ga layer plays a crucial role in eliminating 3. rotation domains, controlling polarity and decreasing defect density in ZnO epilayers, as demonstrated by in situ reflection high energy electron diffraction, ex situ high resolution X-ray diffraction and high resolution cross-sectional transmission electron {2.. Zn-polar film of ZnO was determined by convergent beam electron diffraction. A Ga bilayer model is proposed to understand the effects of the Ga wetting layer on high-quality ZnO growth.

关键词： Ga wetting layer, sapphire, polarity, defect density, zinc oxide, rf-MBE, RHEED, HRXRD, TEM, CBED.

Research progress in the inner surface modification of metal tubes by plasma processing

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Progress in Natural Science:Materials International 2006年第11期16卷 1119-1126页

作者： ZHANG Guling~ 1,2.**, WU Xingfang~1, GU Weichao~2. CHEN Guangliang~2. FENG Wenran~2. NIU Erwu~2. LI Li~2. L Guohua~2. CHEN Huan~2. FAN Songhua~2. LIU Chizi~2.and YANG Size~2.1. School of Material Science and Engineering, University of Science and Technology beijing, beijing 100083. China 2. beijing National laboratory for Condensed Matter physics, institute of physics, Chinese academy of sciences, beijing 100080, China) School of Material Science and Engineering University of Science and Technology Beijing Beijing 100083 China beijing National laboratory for Condensed Matter {2. Institute of Physics Chinese Academy of Sciences Beijing 100080 China

The recent progress in inner surface hardening of tubes by plasma processing is summerized. Several techniques of inner surface plasma source ion implantation and deposition are introduced, and their advantages and disadvantages are discussed. The basic principles, technical features and new progress of inner surface plasma source ion implantation methods for metal tubes, which were developed in our laboratory, are described in detail. And perspectives of the future technical development for inner surface ion implantation of tubes are presented.

关键词： PSII metal tubes inner surface surface modification.

A mixed method for measuring low-frequency acoustic properties of macromolecular materials

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Science China(physics,Mechanics & Astronomy) 2006年第6期49卷 729-739页

作者： LIU Hongwei1,YAO Lei1,3.ZHAO Hong1,3.ZHANG Jichuan2.3.& XUE Zhaohong2.1. National Key laboratory of Acoustics,{3. of Acoustics,Chinese {2. of sciences,beijing 100080,China 2. {3. of Chemistry,Chinese {2. of sciences,beijing 100080,China 3. Graduate University of Chinese {2. of sciences,beijing 100049,China National Key laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Beijing China Graduate University of Chinese academy of sciences Beijing China institute of Chemistry Chinese Academy of Sciences Beijing China

A mixed method for measuring low-frequency acoustic properties of macro-molecular materials is presented. The dynamic mechanical parameters of materials are first measured by using Dynamic Mechanical Thermal Apparatus(DMTA) at low frequen-cies,usually less than 100 Hz; then based on the Principles of Time-Temperature Super-position (TTS),these parameters are extended to the frequency range that acousticians are concerned about,usually from hundreds to thousands of hertz; finally the extended dynamic mechanical parameters are transformed into acoustic parameters with the help of acoustic measurement and inverse analysis. To test the feasibility and accuracy,we measure a kind of rubber sample in DMTA and acquire the basic acoustic parameters of the sample by using this method. While applying the basic parameters to calculating characteristics of the sample in acoustic pipe,a reasonable agreement of sound absorp-tion coefficients is obtained between the calculations and measurements in the acoustic pipe.

关键词： low-frequency acoustic properties,dynamic mechanical properties,Principles of Time-Temperature Superposition,acoustic pipe,sound absorption coefficient.

Approaches to improving critical current density of YBCO superconducting thick films deposited by electrophoresis

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Science China(physics,Mechanics & Astronomy) 2004年第2期47卷 165-172页

作者： ZHU Yabin1,2. ZHOU Yueliang2. LIU Zhen2. WANG Shufang2. CHEN Zhenghao2. L?Huibin2. YANG Guozhen2. XIAO Ling3. REN Hongtao3. JIAO Yulei3.& ZHENG Minghui3.1. Department of physics, College of Science, beijing Jiaotong University, beijing 100044, China 2. laboratory of Optical physics,{13. and Center for Condensed Matter physics, Chinese academy of sciences, beijing 100080, China 3. General Research institute for Nonferrous Metals, beijing 100088, China Correspondence should be addressed to Zhu Yabin (email: ybzhu@***) Department of physics College of Science Beijing Jiaotong University Beijing China laboratory of Optical physics{2. and Center for Condensed Matter physics Chinese Academy of Sciences Beijing China General Research institute for Nonferrous Metals Beijing China

Fabrication of YBCO superconducting thick films by electrophoresis has been widely reported. However, the value of critical current density (J c) is far from what the practical application requires. The superconducting thick films are obtained using top-seeded melt growth method with different proportional Y2.aCuO5 (Y2.1) addition. High-pressure oxygen has been used in the annealing process to improve the uniformity of the oxygen content in the superconducting thick films. When 40mol% Y2.1 powder is added to the YBa2.u3.7–5 (Y12.) powder,J c for the superconducting thick film by approaches described above reaches 7.008×103.A/cm2.(77 K, 0 T), which is greater than the value ever reported.

关键词： YBCO thick films, electrophoretic deposition, melt-textured.

Modeling of elastic wave propagation on a curved free surface using an improved finite-difference algorithm

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Science China(physics,Mechanics & Astronomy) 2004年第5期47卷 633-648页

作者： WANG Xiuming1,3.& ZHANG Hailan2.1. CSIRO Petroleum, ARRC, PO BOX 113., Technology Park, Bentley, WA 6102. Australia 2. {3. of Acoustics, Chinese academy of {2., beijing 100080, China 3. Present address: {3. of Acoustics, Chinese academy of {2., beijing 100080, China CSIRO Petroleum ARRC Bentley Australia institute of Acoustics Chinese Academy of Sciences Beijing China

Based on existing direct and imaging methods of a staggered finite-difference scheme, an improved algorithm for staggered finite-difference is proposed to implement rugged topographic free boundary conditions. This method assumes that the free surface can be implemented with horizontal and vertical free surface segments and their corners; the free surface passes through the grid points of shear stress components, instead of the normal stress components. Imaging is carried out for stress components in both horizontal and vertical directions, thus increasing the accuracy. To update particle- velocities, imaging and updating are first performed in the horizontal direction, and then in the vertical direction. The numerical results for elastic flat horizontal free surface with the imaging method and those for flat free surfaces of various slope angles with the proposed method are compared, and are shown to be in good agreement. The advantage of the proposed method is that only the stresses are dealt with in implementing the free surface into the staggered algorithm, which improves computation efficiency.

关键词： elastic wave simulation, curved free surface, staggered finite-difference, algorithm stability.

Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface

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Science China Chemistry 2005年第6期48卷 567-573页

作者： CHENG Caixia1, JIAO Tifeng2. TANG Rupei1, LIU Minghua2.& XI Fu1 1. State Key laboratory of Polymer {3. and Chemistry, Joint laboratory of Polymer Science and Materials, institute of Chemistry, Chinese academy of sciences, beijing 100080, China 2. CAS Key laboratory of Colloid and Interface Science, institute of Chemistry, Chinese academy of sciences, beijing 100080, China State Key laboratory of Polymer physics and Chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences Beijing China CAS Key laboratory of Colloid and Interface Science Institute of Chemistry Chinese Academy of Sciences Beijing China

Diblock copolymer of PMMA2.1-b-PEO114 and triblock copolymer of PMMA12.-b- PEO2.7-b-PMMA12. were synthesized and their interfacial properties at the air-water interface were investigated, where both blocks of polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA) are surface active but the former is soluble in water while the latter is not. Both the block copolymers could form monolayers with two obvious transition regions. The first transition point is around 10 mN/m, which could be assigned to the pancake-brush change of the PEO chains. The other is around 18 mN/m, which could be ascribed to the condensed packing of PMMA. The surface morphological changes during the compression of the Langmuir monolayers are inves-tigated by using the AFM and SEM methods for the films deposited at different surface pressure or molecular areas. At a lower surface pressure, a typical morphology of PEO-con- taining lipopolymers is observed. Upon compression, sphere-dominant morphologies were observed. While the diblock copolymer is easy to folding, the triblock copolymer is in favor of formation of circular domains through vesiculation.

关键词： PMMA-PEO, block copolymers, monolayer, Langmuir-Blodgett films, AFM.

Pattern phenomena in an rf discharge dusty plasma system

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Science China(physics,Mechanics & Astronomy) 2006年第5期49卷 588-596页

作者： HUANG Feng1,2. YE Maofu2.& WANG Long2.1. College of Science, China Agricultural University, {3. 100083. China 2. institute of physics, Chinese {2. of sciences, beijing 100080, China College of Science China Agricultural University Beijing China institute of physics Chinese Academy of Sciences Beijing China

Various dust patterns are observed in an rf discharge dusty plasma system. According to the dust growth process from small to large in size, the formation of different dust patterns can be divided into two stages: the small-particle stage (or dust cloud stage), and the large-particle stage (or dust crystal stage). The evolution relations between different dust patterns with gas pressure changing are investigated. Dust voids, dust acoustic waves and strong turbulence modes are presented at the small-particle stage. The self-organized dust lattices and dust clusters are investigated at the large-particle stage. The static structure of a dust lattice is characterized by means of the pair correlation function. Dust clusters formed by particles with different numbers and the regular evolution of the clusters with gas pressure are also investigated. The packing sequences of dust clusters are verified through two-dimensional confined molecular dynamics simulations.

关键词： dusty plasma dust patterns

Interannual variability of Antarctic Oscillation and its influence on East Asian climate during boreal winter and spring

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Science China Earth sciences 2006年第5期49卷 554-560页

作者： FAN Ke1,2.3.& WANG Huijun2.1. Nansen-Zhu International Research Center, institute of Atmospheric {3., Chinese {2. of sciences, beijing 10002., China 2. Department of Atmospheric Science, Yunnan University, Kunming 650091, China 3. Graduate University of the Chinese {2. of sciences, beijing 100049, China Nansen-Zhu International Research Center Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China Department of Atmospheric Science Yunnan University Kunming China Graduate University of the Chinese academy of sciences Beijing China

The interannual variability of Antarctic Oscillation (AAO) and its influence on East Asian climate during both boreal winter and spring are addressed. The results show that the positive AAO anomaly decreases the cold activity over East Asia during both boreal winter and spring. AAO-related barotropic meridional teleconnection from Antarctic to Arctic is found through analysis of mean me- ridional circulations. This meridional teleconnection is remarkable over Eurasia during boreal winter and over the Pacific Ocean during boreal spring. The results also show that zonal mean zonal wind at high latitudes in Southern Hemisphere has well positive correlation with that of Eurasia during boreal winter and has negative correlation with Pacific North American teleconnection (PNA) during boreal spring, which again display the meridional teleconnection. Thus, local meridional teleconnection is a possible linkage for interaction of circulations at mid-high latitudes between both hemispheres.

关键词： Antarctic Oscillation, Eurasian west wind, meridional teleconnection, mean meridional circulation.

Algebraically explicit analytical solu-tions for the unsteady non-Newtonian swirling flow in an annular pipe

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Science China(physics,Mechanics & Astronomy) 2006年第4期49卷 396-400页

作者： CAI Ruixian1 & GOU Chenhua1,2.1. institute of Engineering Thermophysics, Chinese {2. of sciences, beijing 100080, China 2. Graduate School, Chinese {2. of sciences, beijing 100080, China institute of Engineering Thermophysics Chinese Academy of Sciences Beijing China Graduate School Chinese Academy of Sciences Beijing China

This paper presents two algebraically explicit analytical solutions for the incompressible unsteady rotational flow of Oldroyd-B type in an annular pipe. The first solution is derived with the common method of separation of variables. The second one is deduced with the method of separation of variables with addition developed in recent years. The first analytical solution is of clear physical meaning and both of them are fairly simple and valuable for the newly developing computational fluid dynamics. They can be used as the benchmark solutions to verify the applicability of the existing numerical computational methods and to inspire new differencing schemes, grid generation ways, etc. Moreover, a steady solution for the generalized second grade rheologic fluid flow is also presented. The correctness of these solutions can be easily proven by substituting them into the original governing equation.

关键词： analytical solution, Oldroyd-B type fluid, swirling flow, non-Newtonian.