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Genesis of ^(2.0)Th excess in basalts from mid-ocean ridges and ocean islands:Constraints from the global U-series isotope database and major and rare earth element geochemistry

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Science China Earth sciences 2010年第10期53卷 1486-1494页

作者： ZHANG GuoLiang1,2.& ZENG ZhiGang1 1 key laboratory of Marine {2. and Environment,{2. of Oceanology,chinese academy of sciences,Qingdao 2.6071,China 2.Graduate University of chinese academy of sciences,Beijing 100049,China 1. key laboratory of Marine {2. and Environment Institute of Oceanology Chinese Academy of Sciences Qingdao 266071 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Based on 2.0Th-2.8U disequilibrium and major element data from mid-ocean ridge basalts(MORBs) and ocean island basalts(OIBs),this study calculates mantle melting parameters,and thereby investigates the origin of 2.0Th excess.(2.0Th/2.8U) in global MORBs shows a positive correlation with Fe8,Po,Na8,and Fmelt(Fe8 and Na8 are FeO and Na2. contents respectively after correction for crustal fractionation relative to MgO = 8 wt%,Po=pressure of initial melting and Fmelt=degree of melt),while 2.0Th excess in OIBs has no obvious correlation with either initial mantle melting depth or the average degree of mantle ***,compared with the MORBs,higher(2.0Th/2.8U) in OIBs actually corresponds to a lower melting *** suggests that the 2.0Th excess in MORBs is controlled by mantle melting conditions,while the 2.0Th excess in OIBs is more likely related to the deep garnet *** vast majority of calculated initial melting pressures of MORBs with excess 2.0Th are between 1.0 and 2.5 GPa,which is consistent with the conclusion from experiments in recent years that DU>DTh for Al-clinopyroxene at pressures of >1.0 *** initial melting pressure of OIBs is 2.2.3.5 GPa(around the spinel-garnet transition zone),with their low excess 2.6Ra compared to MORBs also suggesting a deeper mantle ***,excess 2.0Th in MORBs and OIBs may be formed respectively in the spinel and garnet stability *** addition,there is no obvious correlation of K2./TiO2.with(2.0Th/2.8U) and initial melting pressure(Po) of MORBs,so it is proposed that the melting depth producing excess 2.0Th does not tap the spinel-garnet transition *** and MORBs in both(2.0Th/2.8U) vs.K2./TiO2.and(2.0Th/2.8U) *** plots fall in two distinct areas,indicating that the mineral phases which dominate their excess 2.0Th are ***/Yb-Ce curves of fast and slow ridge MORBs are similar,while,in comparison,the Ce/Yb-Ce curve for OIBs shows more influence from *** mechanism

关键词： excess 2.0Th clinopyroxene garnet spinel-lherzolite mid-ocean ridge ocean island

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PGE patterns of ores of Dajing Cu-polymetallic deposit in Linxi County, Inner Mongolia:Indicator to source of metallogenic elements

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chinese Science Bulletin 2002年第13期47卷 1119-1124页

作者： CHU Xuelei, SUN Min & ZHOU Meifuinstitute of geology and {2., chinese academy of sciences, Beijing 10002., China key laboratory of Mineral Resources, institute of geology and geophysics, chinese academy of sciences, Beijing 100101, China Department institute of geology and {2. Chinese Academy of Sciences Beijing China key laboratory of Mineral Resources Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China Department of Earth sciences The University of Hong Kong Hong Kong China

By comparing PGE patterns of sulfide ores with that of basic-ultrabasic dikes occurring in the Dajing Cu-polymetallic deposit, we discover that there are similar positive slopes between the basic-ultrabasic dikes and the black ores composed mainly of sphalerite and galena, reflecting affinity of their source. The PGE patterns of the yellow ores composed basically of chalcopyrite, arsenopyrite and pyrite are actually different. One is close to the pattern of the mantle 1herzolite, and others resemble the pattern of the basic rocks. However, the concentrations of Ru are higher in the yellow ores, reflecting that sulfur attains or approaches saturation in their parent magma. The PGE characteristics of ores and dikes show that the magmas derived from the deep of crust and the metallogenic elements were supplied mainly by growth material of the crust. In addition, the mantle-derived magma also offered some elements.

关键词： Da Hinggan area polymetallic deposit PGE pattern hypomagma.

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Environmental records of lacustrine sediments in different time scales:Sediment grain size as an example

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Science China Earth sciences 2004年第10期47卷 954-960页

作者： CHEN Jing’an1, WAN Guojiang1, David Dian Zhang2. ZHANG Feng1 & HUANG Ronggui1 1. State key laboratory of Environmental {2., {2. of {2., chinese academy of sciences, Guiyang 550002. China 2. Department of Geography and geology, University of Hong Kong, Pokfulam Road, Hong Kong, China 1. State key laboratory of Environmental {2. Institute of Geochemistry Chinese Academy of Sciences 550002 Guiyang China 2. Department of Geography and geology University of Hong Kong Pokfulam Road Hong Kong China

Sediment grain size is a conventional proxy of climatic changes. Larger sediment grain size is often interpreted to indicate dry climate during lower lake level while smaller sedi- ment grain size implies wet climate during higher lake level. Through detailed study on sediment grain sizes in Lake Erhai and Lake Chenghai, this paper reveals the different indication signifi- cances of sediment grain sizes in different time scales, different resolution investigations. For long time-scale and low resolution (102. or 103a) studies, larger sediment grain size indicates lower lake level, smaller lake area and drier climate while smaller sediment grain size indicates higher lake level, larger lake area and wetter climate. For short time-scale and high resolution (a or 10a) studies, larger sediment grain size reflects more rainfall and wetter climate while smaller sediment grain size reflects less rainfall and drier climate. Environmental information revealed by lacustrine sediment records is often different in different time scales because of the variance of sedimentation resolution, sampling resolution and dating precision. Therefore, paleoclimate im- plications of environmental proxies in long time-scale and low resolution investigations could not be mechanically applied to short time-scale and high resolution studies. Only after synthetically analyzing the influence manner and extent of all factors on the sediment records in different time scales, can credible conclusions be obtained.

关键词： lacustrine sediment, environmental record, grain size, time scale.

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Ambient noise near the sea-route

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Science China(Physics,Mechanics & Astronomy) 2009年第1期52卷 40-45页

作者： HE Li1,2. LI ZhengLin1,3 & PENG ZhaoHui1 1 National laboratory of Acoustics, institute of Acoustics,{2., Beijing 100190, China 2.3},{2., Beijing 10002., China 3 NanHai laboratory of Acoustics, institute of Acoustics,{2., Haikou 5702.6, China National laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Beijing 100190 China institute of geology and {2. Chinese Academy of Sciences Beijing 100029 China NanHai laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Haikou 570206 China

Ambient noise data measured in an experiment conducted in shallow water near a sea-route were analyzed. It was observed that, at low frequency, the horizontal correlation has an obvious difference from that predicted by the classical ambient noise model. The theoretical analyses show that this phenomenon is caused by wind noise together with the discrete shipping noise nearby. An ambient noise model was proposed to include the effects caused by both the noise sources. Data measured at different times verify that the proposed model can be used to forecast the ambient noise field in shallow water near the sea-route.

关键词： ambient noise model horizontal correlation discrete ships

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Environmental characteristics of Mid-Holocene recorded by lacustrine sediments from Lake Daihai, north environment sensitive zone, China

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Science China Earth sciences 2006年第9期49卷 968-981页

作者： SUN Qianli1,2. ZHOU Jie1, SHEN Ji3, CHEN Peng1,2. WU Feng1,2.& XIE Xiuping1,2.1. State key Lab of Loess and Quaternary geology, {2. of Earth Environment,{2., Xi’an 710075, China 2. Graduate University of{2., Beijing 100039, China 3. Nanjing {2. of Geography and Limnology,{2., Nanjing 2.0008, China 1. State key Lab of Loess and Quaternary geology Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China 2. Graduate University of chinese academy of sciences Beijing 100039 China 3. Nanjing institute of Geography and Limnology Chinese Academy of Sciences Nanjing 210008 China

Climate proxies, such as total organic carbon and nitrogen (TOC, TN), carbonate content (CaCO3), grain-size and pollen of the sediment core retrieved from enclosed Lake Daihai which lies in the north China environment sensitive zone are analyzed to reconstruct the environment evolution of the area based on high-resolution radiocarbon chronology. The results reveal that the TOC and TN contents of the sediments correlate well with pollen percentage and pollen flux variations during the Holocene, and both reach their peak values simultaneously at 6.7―3.5 ka BP (calendar age, 7.6―3.6 ka BP). Since 6.7 ka BP, both the CaCO3 and organic matter contents of the core have simultaneous variations, and their high values also occur during 6.7―3.5 ka BP. While during 9.0―6.7 ka BP (calendar age, 10―7.6 ka BP) relatively lower level of organic matter content and pollen flux corre- spond to the higher level of carbonate content. The above relations suggest that during 6.7―3.5 ka BP, the productivity and effective precipitation were greatly improved in the lake drainage area, and this would probably strengthen the hydrodynamic conditions, enhancing organic matter, pollen and carbonate inputs from terrestrial sources. Such processes would account for the enrichment of both organic matter and carbonate in the sediments. While during 9.0―6.7 ka BP, the lower level of or- ganic matter, pollen flux but high carbonate content show depressed productivity and declined vege- tation coverage. The higher carbonate content at this stage would have probably resulted from the higher evaporation ratio of the lake water under relatively drier climate conditions. Therefore, it is in- ferred that during 6.7―3.5 ka BP, the climate was more humid with abundant rainfalls and vegetation was more flourishing in the Lake Daihai area. This can be seen as Holocene Climate Optimum (HCO). As a result, this has evident discrepancies with the traditional notion that the HCO occurs at Early Holocene or early Mid

关键词： Lake Daihai, Mid-Holocene, lacustrine sediments, environmental characteristics.

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Crustal structure of Gondwana-and Yangtze-typed blocks:An example by wide-angle seismic profile from Menglian to Malong in western Yunnan

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Science China Earth sciences 2005年第11期48卷 1828-1836页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2. TENG Jiwen1, Lü Qingtian3, LI Jiliang1, SUN Shanxue1 & WANG Xinzheng1 1. institute of geology and geophysics, chinese academy of sciences, Beijing 10002., China 2. {2. of geophysics, chinese Seismological Bureau, Beijing 100081, China 3. {2. of Deposition Resource, chinese academy of Geological sciences, Beijing 100037, China 1. institute of geology and geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of geophysics Chinese Seismological Bureau 100081 Beijing China 3. institute of Deposition Resource Chinese Academy of Geological Sciences 100037 Beijing China

The wide-angle seismic profile between Menglian and Malong crosses the Baoshan block (Gondwana-typed), and Simao and southwestern Yangtze blocks (Yangtze-typed). By in-terpreting the wide-angle seismic data, we obtained the seismic crust/upper mantle structure of P-wave velocities together with the seismic reflections of these three blocks, Changning- Menglian and Mojiang suture zones among the mentioned three blocks. Our interpreting results demonstrate that the P-wave crustal velocity of Simao block is slower than that of Baoshan and southwestern Yangtze block and the crustal thickness gradually thickens from the Baoshan block, Simao to southwestern Yangtze block. Crustal reflection patterns of these three blocks have dis-tinct differences too. For the Gondwana-typed blocks, seismic reflections in the upper crust are well developed while in middle-lower crust they are very weak. The crustal reflections in the Yangtze block are very well developed. The crustal reflection patterns in Simao and southwest-ern Yangtze blocks are distinguishable. The average thickness of the crust in the studied area is about 40 km. And we make some discussions on the crustal thickening model of the three blocks in western Yunnan and tectonic setting of seismic developing and interaction of Gondwana and Yangtze blocks.

关键词： Gondwana blocks,Yangtze blocks,wide-angle profile,crustal structure,tectonic setting

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Petrology and mineral chemistry of new ureilites found in Grove Mountains, Antarctica

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Progress in Natural Science:Materials International 2008年第4期18卷 431-439页

作者： Bingkui Miaoa,b,, Yangting Linb, Guiqin Wangc, Daode Wangc, Ziyuan Ouyangd a key laboratory of Geological Engineering Center of Guangxi Province, Guilin University of Technology, Guilin 541004, China b State key laboratory of Lithospheric Evolution,{2., chinese academy of sciences, Beijing 10002., China c key laboratory of Isotope Geochronology and geochemistry, Guangzhou institute of geochemistry, chinese academy of sciences, Guangzhou 510640, Chinad National Astronomical Observatories, chinese academy of sciences, Beijing 100012. China key laboratory of Geological Engineering Center of Guangxi Province Guilin University of Technology Guilin 541004 China State key laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China key laboratory of Isotope Geochronology and {2. Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China

Petrography and mineral chemistry of two new ureilites, GRV 02.512.and 02.931, from the Grove Mountains, Antarctica, are reported in this paper. GRV 02.512.exhibits a typical ureilite texture, and consists of 48.3% olivine, 9.4% pigeonite and 38.1% carbo- naceous interstitial material and/or reduction product. GRV 02.931 has a cataclastic porphyritic texture, and consists of 19.1% olivine and 14.1% pigeonite embedded in 66.3% carbonaceous interstitial material and/or reduction product. The coarse-grained olivine and pigeonite in both meteorites have homogeneous cores, and they are FeO-rich within the range of the ferroan subgroup (subgroup I) of olivine-pigeonite ureilites. All olivine grains of the meteorites show reduction zones along boundaries and cracks. Abundant diamond coexists with graphite as graphite-rich patches and veins in the carbonaceous interstitial material. Petrogenesis of both meteorites and the origin of diamond are discussed.

关键词： Meteorite Achondrite Ureilite Diamond Antarctica

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Geomorphologic evidence of phased uplift of the northeastern Qinghai-Tibet Plateau since 14 million years ago

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Science China Earth sciences 2004年第9期47卷 822-833页

作者： LU Huayu1, WANG Xiaoyong1, AN Zhisheng1, MIAO Xiaodong1, ZHU Rixiang3, MA Haizhou2. LI Zhen4, TAN Hongbing2.& WANG Xianyan1 1. State key laboratory of Loess and Quaternary {2., {2. of Earth Environment, chinese academy of sciences, Xi’an 710075 China 2. Qinghai {2. of Salt Lakes, chinese academy of sciences. Xining 810008, China 3. institute of geology and geophysics, chinese academy of sciences, Beijing 10002., China 4. Department of Geography, Qinghai Normal University, Xining 810008, China chinese Acad Sci Inst Earth Environm State Key Lab Loess & Quaternary Geol Xian 710075 Peoples R China chinese Acad Sci Qinghai Inst Salt Lakes Xining 810008 Peoples R China chinese Acad Sci Inst Geol & Geophys Beijing 100029 Peoples R China Qinghai Normal Univ Dept Geog Xining 810008 Peoples R China

A typical sequence of fluvial terraces and aeolian deposits overlying these ter- races were multidisciplinary investigated. New evidences for uplift process of the northeastern Qinghai-Tibetan Plateau in the past 14 million years were obtained. At least 11 river terraces along Huangshui, the first-class tributary of Yellow River, at the Xining-Huzhu region are identi- fied. While the first one (T1) is classified as an accumulation terrace, the others are all basement river terraces, which consist of the Tertiary sandstone and siltstone bedrock, fluvial gravel and pebbles and the overlying aeolian loess-Red Clay deposit. Samples from the aeolian deposits were examined for paleomagnetic stratigraphic reconstruction (1030 samples), luminescence dating (16 samples), magnetic susceptibility and grain-size distribution (more than 4000 sam- ples). The luminescence dating and stratigraphic correlation suggest that terraces of Tll, T10, T8, T7, T3, T2. T1 were formed at 14, 11.3, 1.55, 1.2. 0.15, 0.07 and 0.01 million years ago, re- spectively. Sedimentological analysis and geomorphological observation indicate that formation and evolution of these terraces were mainly driven by tectonic uplift. Therefore, the terrace se- quence provides an ideal geological record, of the uplift process of the northeastern during the past 14 million years, and the timings of the terraces formation are regarded as the timings of tectonic uplift. The significant uplifting events took place at 14, 11.3, 1.2.and 0.15 mil- lion years ago, respectively. The fluvial incision at the Xining-Huzhu region is less than 100 m during a period of ~12.million years in the Miocene era (between the Tll and T9), while the Huangshui River had incised 432.m during the past 1.2.million years (from T7 to the present floodplain). The river incision process clearly demonstrates that accelerated rising of the north- eastern Qinghai-Tibet Plateau during the late Cenozoic, and provides new evidence of previous thoughts

关键词： river terrace, tectonic uplift, loess-Red Clay, the past 14 million years, northeastern Qinghai-Tibet Plateau.

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Cosmogenic ^(2.)Ne concentrations and exposure ages of summit bedrocks in the Grove Mountains,Antarctica

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Science China Earth sciences 2010年第4期53卷 518-521页

作者： KONG Ping1,2.DING Lin2.LAI QingZhou2.& HUANG FeiXin3 1 key laboratory of the Earth’s Deep Interior,{2. of {2. and geophysics,chinese academy of sciences,Beijing 10002.,China 2.key laboratory of Continental Collision and Plateau Uplift,{2. of Tibetan Plateau Research,chinese academy of sciences,Beijing 100085,China 3 {2. of Mineral Resources Research,China Metallurgical {2. Bureau,Beijing 10002.,China 1. key laboratory of the Earth’s Deep Interior Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China2. Key Laboratory of Continental Collision and Plateau Uplift Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China3. Institute of Mineral Resources Research China Metallurgical Geology Bureau Beijing 100025 China

Various sources of 2.Ne and 2.Ne exist in surface rocks:cosmogenic,in situ nucleogenic from internal U and Th,trapped crustal nucleogenic and trapped *** paper reports the first measurement,in China,of cosmogenic 2.Ne and 2.Ne in surface *** developed a unique sample pre-treatment procedure that effectively removed inclusions inside quartz grains,and thus maximally reduced nucleogenic contributions of 2.Ne and ***-heating experiments show that concen-trations of cosmogenic 2.Ne and 2.Ne in summit bedrock samples R92.2.and R92.3 from Grove Mountains,Antarctica,are(3.83±0.87)×108 and(5.2.±0.51)×108 atoms/g,*** corresponding minimum exposure ages are 2.2.0.5 and 3.0±0.3 *** indicates that the ice sheet in East Antarctica was uncovered the crest of Mount Harding,a typical nunatak in Grove Mountains,since at least mid-Pliocene.

关键词： 2.Ne cosmogenic nuclide exposure age Antarctica Grove Mountains

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Discovery of seep carbonate nodules as new evidence for gas venting on the northern continental slope of South China Sea

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chinese Science Bulletin 2006年第10期51卷 1228-1237页

作者： CHEN Zhong1,2.3, YAN Wen1,2.3, CHEN Muhong1,3, WANG Shuhong1,2.3, LU Jun1,3, ZHANG Fan1,3, XIANG Rong1,3, XIAO Shangbin1,3, YAN Pin1,2.3 & GU Senchang1,2.3 1. South China Sea institute of Oceanology, chinese {2. of Sci-ences, Guangzhou 510301, China 2. Guangzhou Center for gas Hydrate Research, chinese academy of sciences, Guangzhou 510301, China 3. key laboratory of Marginal Sea geology, South China Sea institute of Oceanology and Guangzhou institute of geochemistry, chinese academy of sciences, Guangzhou 510301, China South China Sea institute of Oceanology Chinese Academy of Science Guangzhou China Guangzhou Center for gas Hydrate Research Chinese Academy of Sciences Guanzhou China key laboratory of Marginal Sea {2. South China Sea Institute of Oceanology and Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China

Seep carbonate nodules were firstlycollected from the southwestern Dongsha area onnorthern continental slope of South China Sea formineralogical and geochemical studies. The resultsof X-ray diffraction show that carbonate nodules arecomposed of Fe-rich domolite,siderite and a few cal-cite and aragonite, as well as a small quantity ofnon-carbonate minerals such as goethite, quartz andclay minerals. Fe-rich dolomite and siderite charac-terized by euhedral microcrystalline structure weredirectly precipitated at cold seeps. The δ 13C valuesfor Fe-rich dolomite and siderite in the bulk nodulesvary from ?18.2.‰ to ?36.07‰, and the δ 18O valuesrange from 0.42.to 2.76‰. Their moderate depleted13C reflects that carbon origin is possibly thermoge- netic gas or mixed gas, which is evidence of gasventings in the seafloor. Moreover, massive wormtube fossils related to cold seeps were found on thesurfaces of carbonate nodules, and the conduitsand/or channels in semi-solidified nodules whichwere not filled by carbonate or sediment were alsoobserved. A preliminary conclusion is that activemicro gas venting with a conduit/channel diameterrange from 2.0 μm to 600 μm possibly exists inmodern seafloor of the carbonate nodule area.

关键词：渗出碳酸盐节碳氧同位素甲烷渗漏天然气水化物

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