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geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations

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Science china Earth Sciences 2006年第9期49卷 904-914页

作者： WANG Xiaorui1, GAO Shan1,2. LIU Xiaoming1, YUAN Honglin1, HU Zhaochu1, ZHANG Hong1,3 & WANG Xuance4 1. State key laboratory of Continental Dynamics, Department of {2., Northwest University, Xi`an 710069, china 2. State key laboratory of Geological Processes and Mineral Resources, china University of Geosciences, Wuhan 430074, china 3. Shenyang institute of {2. and Mineral Resources, Shenyang 110032. china 4. Guangzhou institute of {12., chinese academy of Sciences, Guangzhou 510640, china 1. State key laboratory of Continental Dynamics Department of Geology Northwest University Xi’an 710069 China 2. State key laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China 3. Shenyang institute of geology and Mineral Resources Shenyang 110032 China 4. Guangzhou institute of geochemistry Chinese Academy of Sciences Guangzhou 510640 China

85 volcanic rocks of the Yixian Formation from the Sihetun type section werecollected and analyzed for geochemical and isotopic compositions. Major element compositionsindicate that the Sihetun volcanic rocks are high magnesium andesites with some basalts occurring atthe bottom of section. The Sihetun high magnesium andesites (SiO_2.= 52.82.59.31 wt%, Al_2._3=14.15-16.35wt%) show many characteristics of adakites such as depletion in heavy rare-earth elements(HREE; Yb = 1.03-1.88 μg/g) and Y(12.2. μg/g) and high Sr (62.-132. μg/g) and Sr/Y(32.88), withhigh La_N/Yb_N ratio (10-2.). They share similar major and trace element characteristics to volcanicrocks from the Xinglonggou Formation except their lower Nd isotope ratios (^(143)Nd/^(144)Nd(130Ma) = 0.5118-0.5119, ε_(Nd) (130Ma) = -11.6-13.8, ^(87)Sr/^(86)Sr (130 Ma) = *** were interpreted in a way that eclogite that formed at the base of thickened Archean lowercrust of the North china craton foundered into the convecting mantle and subsequently melted andinteracted with peridotite. However, compared to the Xinglonggou volcanic rocks, the source of theSihetun magma contained more ancient continental crustal material in order to explain its evolved Ndisotopes. The age of the Sihetun Formation was 12. to 130 Ma, and this indicates that delaminationlasted to the early Cretaceous period. The Sr contents and Sr/Y ratios of the Sihetun high-Mgandesites show significant negative correlations with SiO_2.for samples with SiO_2.> 56%. Thesesuggest that the Sr and Sr/Y values were reduced due to fractional crystallization of ***, the effect of crystallization on volcanic Sr and Sr/Y ratio has to be taken intoaccount.

关键词： High-Mg andesite, Adakite, Yixian Formation, North china Craton, delamination.

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Geomorphologic evidence of phased uplift of the northeastern Qinghai-Tibet Plateau since 14 million years ago

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Science china Earth Sciences 2004年第9期47卷 822-833页

作者： LU Huayu1, WANG Xiaoyong1, AN Zhisheng1, MIAO Xiaodong1, ZHU Rixiang3, MA Haizhou2. LI Zhen4, TAN Hongbing2.& WANG Xianyan1 1. State key laboratory of Loess and Quaternary {2., institute of Earth Environment, chinese academy of Sciences, Xi’an 710075 china 2. Qinghai institute of Salt Lakes, chinese academy of Sciences. Xining 810008, china 3. institute of geology and geophysics, chinese academy of Sciences, Beijing 10002., china 4. Department of Geography, Qinghai Normal University, Xining 810008, china chinese Acad Sci Inst Earth Environm State Key Lab Loess & Quaternary Geol Xian 710075 Peoples R China chinese Acad Sci Qinghai Inst Salt Lakes Xining 810008 Peoples R China chinese Acad Sci Inst Geol & Geophys Beijing 100029 Peoples R China Qinghai Normal Univ Dept Geog Xining 810008 Peoples R China

A typical sequence of fluvial terraces and aeolian deposits overlying these ter- races were multidisciplinary investigated. New evidences for uplift process of the northeastern Qinghai-Tibetan Plateau in the past 14 million years were obtained. At least 11 river terraces along Huangshui, the first-class tributary of Yellow River, at the Xining-Huzhu region are identi- fied. While the first one (T1) is classified as an accumulation terrace, the others are all basement river terraces, which consist of the Tertiary sandstone and siltstone bedrock, fluvial gravel and pebbles and the overlying aeolian loess-Red Clay deposit. Samples from the aeolian deposits were examined for paleomagnetic stratigraphic reconstruction (1030 samples), luminescence dating (16 samples), magnetic susceptibility and grain-size distribution (more than 4000 sam- ples). The luminescence dating and stratigraphic correlation suggest that terraces of Tll, T10, T8, T7, T3, T2. T1 were formed at 14, 11.3, 1.55, 1.2. 0.15, 0.07 and 0.01 million years ago, re- spectively. Sedimentological analysis and geomorphological observation indicate that formation and evolution of these terraces were mainly driven by tectonic uplift. Therefore, the terrace se- quence provides an ideal geological record, of the uplift process of the northeastern during the past 14 million years, and the timings of the terraces formation are regarded as the timings of tectonic uplift. The significant uplifting events took place at 14, 11.3, 1.2.and 0.15 mil- lion years ago, respectively. The fluvial incision at the Xining-Huzhu region is less than 100 m during a period of ~12.million years in the Miocene era (between the Tll and T9), while the Huangshui River had incised 432.m during the past 1.2.million years (from T7 to the present floodplain). The river incision process clearly demonstrates that accelerated rising of the north- eastern Qinghai-Tibet Plateau during the late Cenozoic, and provides new evidence of previous thoughts

关键词： river terrace, tectonic uplift, loess-Red Clay, the past 14 million years, northeastern Qinghai-Tibet Plateau.

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Cycladophora davisiana(Radiolarian)in the Bering Sea during the late Quaternary:A stratigraphic tool and proxy of the glacial Subarctic Pacific Intermediate Water

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Science china Earth Sciences 2005年第10期48卷 1698-1707页

作者： WANG Rujian1 & CHEN Ronghua2.1. State key laboratory of Marine {2., Tongji University, Shanghai 2.0092. china 2. The key laboratory of Submarine Geoscience, State Oceanic Administration, Hangzhou 310012. china State key laboratory of Marine {2. Tongji University Shanghai china The key laboratory of Submarine Geoscience State Oceanic Administration Hangzhou{2.

Cycladophora davisiana (Radiolarian) contents are counted in two cores of the Ber-ing Sea and correlated well with the oxygen isotopic records of ice in the deep core obtained by the Greenland Ice Sheet Project II (GISP 2. and deep-sea sediments (SPECMAP) of the world oceans. Millennial scale climatic events, for example, Younge Dryas and B?lling/Aller?d events, Heinrich1 and Dansgaard-Oeschger1events, recorded by C. davisiana percents are distin-guished from Core B4-2. C. davisiana events b, c1, c2. d, e1 and e2. respectively, corresponding to oxygen isotopic 2.0, 3.1, 3.3, 4.0, 5.1 and 5.3, are identified from Core B2.9. High resolution re-cords of C. davisian are tuned to the oxygen isotopic records in GISP 2.and SPECMAP and the depth-age frameworks are established in the two cores, supplying a stratigraphic base for future paleoceanographic and paleoclimatic studies. High C. davisiana during the glacial periods in the two cores indicate that they can serve as a proxy of the glacial Subarctic Pacific Intermediate Water, which verifies the glacial Subarctic Pacific Intermediate Water brought from the Bering Sea.

关键词： Cycladophora davisiana, stratigraphic tool, YD and B/A events, Heinrich 1 and D/O1 events, proxy of glacial Subarctic Pacific Intermediate Water, late Quaternary, Bering Sea.

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Enrichment mechanism of gold during the process of lateritization in southern area of the Yuanmou ancient landmass, Yunnan, china

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chinese Science Bulletin 1999年第S2期44卷 90-91页

作者： SUN Chengxing~1, WANG Shijie~1, DAI Fusheng~2.and LUO Yi~2.1. State key laboratory of Environmental {2., institute of {2., chinese academy of Sciences, Guiyang 550002. china 2. Department of geology, Kunming University of Science and Technology, Kunming 650093, china State key laboratory of Environmental {2. Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China Department of geology Kunming University of Science and Technology Kunming 650093 China

SINCE the first discovery of lateritic gold deposit which is easier to mining and dressing at Boddington inWestern Australia at the beginning of the 1980s, geologists have paid much attention to it, and it wasfound in tropical and subtropical regions. However, recently the metallogenetic mechanism has notbeen understood very well. In this note we reported some research results on the enrichment mechanism ofgold during the process of lateritization in the case of three lateritic profiles with some degree of gold enrichment located in southern area of the Yuanmou ancient landmass, Yunnan Province. The parent rocks of the investigated profiles （about 5-8 m thick） is metamorphic schist, in whichmean content of gold is 13.3×10-9. Samples were collected from two pits at Xujie （Mouding County）and an outcrop of gully at Menglingou （Yuanmou County）, dried in air and ground in agate mortar to

关键词： gold enrichment lateritizafion Yunnan.

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Petrology and mineral chemistry of new ureilites found in Grove Mountains, Antarctica

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Progress in Natural Science:Materials International 2008年第4期18卷 431-439页

作者： Bingkui Miaoa,b,, Yangting Linb, Guiqin Wangc, Daode Wangc, Ziyuan Ouyangd a key laboratory of Geological Engineering Center of Guangxi Province, Guilin University of Technology, Guilin 541004,{2. b State key laboratory of Lithospheric Evolution, institute of geology and geophysics, chinese academy of Sciences, Beijing 10002.,{2. c key laboratory of Isotope Geochronology and geochemistry, Guangzhou {12. of geochemistry, chinese academy of Sciences, Guangzhou 510640,{2.d National Astronomical Observatories, chinese academy of Sciences, Beijing 100012.{2. key laboratory of Geological Engineering Center of Guangxi Province Guilin University of Technology Guilin 541004 China State key laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China key laboratory of Isotope Geochronology and {2. Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China

Petrography and mineral chemistry of two new ureilites, GRV 02.512.and 02.931, from the Grove Mountains, Antarctica, are reported in this paper. GRV 02.512.exhibits a typical ureilite texture, and consists of 48.3% olivine, 9.4% pigeonite and 38.1% carbo- naceous interstitial material and/or reduction product. GRV 02.931 has a cataclastic porphyritic texture, and consists of 19.1% olivine and 14.1% pigeonite embedded in 66.3% carbonaceous interstitial material and/or reduction product. The coarse-grained olivine and pigeonite in both meteorites have homogeneous cores, and they are FeO-rich within the range of the ferroan subgroup (subgroup I) of olivine-pigeonite ureilites. All olivine grains of the meteorites show reduction zones along boundaries and cracks. Abundant diamond coexists with graphite as graphite-rich patches and veins in the carbonaceous interstitial material. Petrogenesis of both meteorites and the origin of diamond are discussed.

关键词： Meteorite Achondrite Ureilite Diamond Antarctica

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The microtine distribution and its environmental significance since the Middle Pleistocene in Zhangping Caves of the Qinling Mountains

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Science china Earth Sciences 2008年第2期51卷 294-299页

作者： LI YongXiang1 & XUE XiangXu1,2.1 State key laboratory of Continental Dynamics, Department of {2., Northwest University, institute of Cenozoic {2. and Environment, Xi’an 710069, china 2.institute of Earth Environment, State key laboratory of Loess and Quaternary {2., chinese academy of Sciences, Xi’an 710075, china 1. State key laboratory of Continental Dynamics Department of Geology Northwest University Institute of Cenozoic Geology and Environment Xi’an 710069 China 2. institute of Earth Environment State Key Laboratory of Loess and Quaternary Geology Chinese Academy of Sciences Xi’an 710075 China

Three microtine species are recovered from the Zhangping Caves of the Qingling Mountains, namely Microtus oeconomus, Caryomys inez and Caryomys eva. They are climate-sensitive ones with different ecological habits, therefore their distribution well corresponds to environmental variations. Statistical comparison of the distribution of fossil microtines and their counterparts nowadays displays that the climate variation of the studied area and its contiguity since the middle Pleistocene are: warm and humid at 493 ka ago, cool and humid at 2.9 ka ago―cold and humid at 2.5 ka ago―cool and humid at 2. ka ago, and warm and dry at present.

关键词： environmental variation since Middle Pleistocene microtine fossils Zhangping Caves of the Qinling Mountains

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Identification of marine natural gases with different origin sources

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Science china Earth Sciences 2008年第S1期51卷 148-164页

作者： WANG YunPeng 1 ,ZHAO ChangYi 2.,WANG ZhaoYun 2.,WANG HongJun 2.,TIAN Jin 1 ,ZOU YanRong 1 &LIU JinZhong1 1State key laboratory of Organic {2.,Guangzhou institute of {2.,chinese academy of Sciences,Guangzhou 510640,china 2.3} of geology,Research institute of Petroleum Exploration and Development,Petrochina,Beijing 100083,china State key laboratory of Organic {2. Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China institute of geology Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083

Kinetic experiments of gas generation for typical samples of marine gas precursors including low-maturity kerogen,residual kerogen and oil as well as dispersed liquid hydrocarbon(DLH)in source rocks were performed by closed system,and the evolution trends of molecular and isotopic compositions of natural gases from different precursors against the maturity(R0%)at laboratory conditions were *** diagrams of gas origin were calibrated by using the experimental data.A diagram based on the ratio of normal and isomerous butane and pentane(i/nC4-i/nC5)was proposed and used to identify the origins of the typical marine natural gases in the Sichuan Basin and the Tarim Basin, *** the maturities of natural gases were estimated by using the statistical relationships between the gaseous molecular carbon isotopic data and maturities(δ13C-R 0 %)with different *** results indicate that the molecular and isotopic compositions of simulated gases from different precursors are different from each *** example,the dryness index of the oil-cracking gas is the lowest;the dryness indices of gases from DLH and kerogen in closed system are almost the same;and the dryness index of gases from residual kerogen is extremely high,indicating that the kerogen gases are very dry;the contents of non-hydrocarbon gases in kerogen-cracking gases are far higher than those in oil-cracking and DLH-cracking *** molecular carbon isotopes of oil-cracking gases are the lightest,those of kerogen in closed system and GLH-cracking gases are the second lightest,and those of cracking gases from residual kerogen are the *** calibration results indicate that the diagrams of ln(C1/C2.-ln(C2.C3)andδ13C2.δ13C3-ln(C2.C3)can discriminate primary and secondary cracking gases,but cannot be used to identify gas origin sources,while the diagram of i/nC4-i/nC5 can differentiate the gases from different *** application results of these diagrams show that gas mixtures ext

关键词： marine organic matter gas origin sources kerogen oil-cracking gas origin identification carbon isotope

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Boron isotopic fractionation in laboratory inorganic carbonate precipitation:Evidence for the incorpora-tion of B(OH)_3 into carbonate

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Science china Earth Sciences 2008年第12期51卷 1776-1785页

作者： XIAO YingKai1,2. LI HuaLing1,3, LIU WeiGuo4, WANG XiuFang1 & JIANG ShaoYong5 1 Qinghai institute of Salt Lakes, chinese {2. of Sciences, Xining 810008, china 2.State key laboratory of Environmental geochemistry, institute of geochemistry, chinese {2. of Sciences, Guiyang 550002. china 3 Nanjing institute of geology and Mineral Resources, Nanjing 2.0016, china 4 State key laboratory of Loess and Quaternary geology, institute of Earth Environment, chinese {2. of Sciences, Xi’an 710075, china 5 State key laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 2.0093, china 1. Qinghai institute of Salt Lakes Chinese Academy of Sciences Xining 810008 China 2. State key laboratory of Environmental {2. Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China 3. Nanjing institute of geology and Mineral Resources 210016 Nanjing China 4. State key laboratory of Loess and Quaternary {2. Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China 5. State key laboratory for Mineral Deposits Research Department of Earth Sciences Nanjing University Nanjing 210093 China

A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.34 was conducted, and the boron isotopic fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3) between carbonate and B(OH)3 in seawater range 0.937 and 0.965, with an average value of 0.953. Our results together with those reported by Sanyal and collabo-rators show that the αcarb-3 values between carbonate and B(OH)3 in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ 11B4-pH curves and neither do they exactly parallel any theoretical δ 11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3 with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4- in carbonate . Hence, in the reconstruction of the paleo-pH of sea-water from boron isotopes in marine biogenic carbonates, the use of theoretical boron isotopic frac-tionation factor (α4-3) between B(OH)4- and B(OH)3 is not suitable. Instead, an empirical equation should be established.

关键词： boron isotopic fractionation biogenic carbonate B(OH)3 incorporation

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A new method for spatio-temporal prediction of rainfall-induced landslide

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Science china Earth Sciences 2006年第4期49卷 421-430页

作者： DING Jixin1,2. YANG Zhifa2. SHANG Yanjun2. ZHOU Shenghua1 & YIN Juntao3 1. china Non-ferrous Metals Resource Geological Survey, Beijing 100012. china 2.{2., chinese academy of Sciences, key laboratory of Engineering Geomechanics, Beijing 10002., china 3. School of Geoscience & Environmental Engineering, Central South University, Changsha 410083, china 1. china Non-ferrous Metals Resource Geological Survey Beijing 100012 China 2. institute of geology and geophysics Chinese Academy of Sciences Key Laboratory of Engineering Geomechanics Beijing 100029 China 3. School of Geoscience & Environmental Engineering Central South University Changsha 410083 China

Geological condition and rainfall are two most principal conditions inducing landslides in the Chongqing region. By analyzing the forming conditions of rainfall-induced landslides, a new method for spatio-temporal prediction of rainfall-induced landslide is brought forward on the basis of grading and overlapping geological condition and rainfall factor in this paper. At first, semi-quantitative assessment and grading for the geological condition of a certain area or slope can be carried out with the multi-factor interactive matrix. Then the severity of rainfall in that area is grading according to the maximum daily rainfall and the total rainfall in a rainfall course. Finally, the “landslide probability judgement factor” can be worked out through grading and overlapping “geological condition influenc- ing factor” and “rainfall influencing factor”, by which the landslide can be graded into 4 grades, they are landslide extremely easily happening, landslide easily happening, landslide difficultly happening and landslide hardly ever happening respectively. More accurate spatio-temporal prediction of rain- fall-induced landslides can come true on the ground of detailed geological survey of some dangerous slopes in an area and more precise weather forecast. Finally, the reliability and feasibility of carrying out the spatio-temporal prediction of rainfall-induced landslides with the method of “two factors” grading and overlapping are validated by the example of Jipazi landslide.

关键词： rainfall-induced landslide, geological condition, rainfall, two factors, grading and overlapping, interactive matrix, spatio-temporal prediction.

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Research on the dynamics of the South china Sea opening:Evidence from analogue modeling

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Science china Earth Sciences 2006年第10期49卷 1053-1069页

作者： SUN Zhen1,2, ZHOU Di1, ZHONG Zhihong3, XIA Bin2, QIU Xuelin1, ZENG Zuoxun4 & JIANG Jianqun5 1. CAS key laboratory of Marginal Sea geology, South china Sea institute of Oceanology, chinese academy of Sciences, Guangzhou 510301, china 2. CAS key laboratory of Marginal Sea geology, Guangzhou institute of geochemistry, chinese academy of Sciences, Guangzhou 510640, china 3. Department of Technology, Shenzhen Branch of CNOOC, Guangzhou 510240, china 4. Faculty of Earth Sciences, china University of Geosciences, Wuhan 430074, china 5. Hainan Oil & gas Exploration Company, Liaohe Oilfield Petrochina, Panjin 124010, china 1. CAS key laboratory of Marginal Sea {2. South China Sea Institute of Oceanology Chinese Academy of Sciences Guangzhou 510301 China 2. CAS key laboratory of Marginal Sea {2. Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 3. Department of Technology Shenzhen Branch of CNOOC Guangzhou 510240 China 4. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China 5. Hainan Oil & gas Exploration Company Liaohe Oilfield PetroChina Panjin 124010 China

Independent of Indochina extrusion, the South china Sea experienced a process from passive continental rifting to marginal sea drifting. According to the fault patterns in the Beibu Gulf basin and the Pearl River Mouth basin, the continental rifting and early spreading stage from 32.to 2. Ma were controlled by extensional stress field, which shifted clockwise from southeastward to south southeastward. From 2. Ma on, the sea spread in NW-SE direction and ceased spreading at around 15.5 Ma. Integrated geological information with the assumption that the South china Sea developed along a pre-Cenozoic weakness zone, we did analogue experiments on the South china Sea evolu- tion. Experiments revealed that the pre-existing weakness zone goes roughly along the uplift zone between the present Zhu-1 and Zhu-2.depression. The pre-existing weakness zone is composed of three segments trending NNE, roughly EW and NEE, respectively. The early opening of the South china Sea is accompanied with roughly 15° clockwise rotation, while the SE sub-sea basin opened with SE extension. Tinjar fault was the western boundary of the Nansha block (Dangerous Ground), while Lupar fault was the eastern boundary of the Indochina, NW-trending rift belt known as Zengmu basin developed between above two faults due to block divergent of Indochina from Nansha. In the experiment, transtensional flower structures along NW-trending faults are seen, and slight inversion occurs along some NE-dipping faults. The existence of rigid massifs changed the orientations of some faults and rift belt, and also led to deformation concentrate around the massifs. The rifting and drifting of the South china Sea might be caused by slab pull from the proto South china Sea subducting toward Borneo and/or mantle flow caused by India-Asia collision.

关键词： South china Sea, rifting and drifting, clockwise rotation, analogue modeling, rigid massifs.

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