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CHEMICAL STRUCTURE DEPENDENCE OF THE INTERNAL ENERGY CONTRIBUTION IN RUBBER ELASTICITY

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chinese Journal of Polymer Science 2001年第5期19卷 447-449页

作者： Juan Sun Xiao-zhen Yang Polymer Physics Laboratory Center for Molecular sciences, institute of {2. chinese academy of sciences Beijing 100080 China 中科院化学所高分子物理及化学国家重点实验室北京

Conformational elasticity theory recently developed has been used to explore the internal energy contribution to the elastic force f(e)/f as a function of strain for poly(cis-1,4-isoprene) and poly(trans-1,4-isoprene). Calculated f(e)/f values are in good agreement with those obtained experimentally. Results show that behavior of f(e)/f is mainly contributed by chemical structure, or intramolecular interaction, supporting the experimental observations, and that the internal energy contribution is strain dependent.

关键词： conformational elasticity theory internal energy contribution poly(cis-1,4-isoprene) poly(trans-1,4-isoprene)

Effect of concentration on surfactant micelle shapes——A molecular dynamics study

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Science China chemistry 2005年第5期48卷 470-475页

作者： GAO Jian1,2. GE Wei1 & LI Jinghai1 1. Multiphase Reaction Laboratory, institute of Process Engineering, chinese academy of sciences, Beijing 100080, China 2. Graduate School of The chinese academy of sciences, Beijing 100085, China Multiphase Reaction Laboratory Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate School of The chinese academy of sciences Beijing China

Many aspects of the behavior of surfactants have not been well understood due to the coupling of many different mechanisms. Computer simulation is, therefore, attractive in the sense that it can explore the effect of different mechanisms separately. In this paper, the shapes, structures and sizes of sodium dodecylbenzenesulfonate (SDBS) micelles under different con-centrations in an oil/water mixture were studied via molecular dynamics (MD) simulations using a simplified atomistic model which basically maintains the hydrophile and lipophile properties of the surfactant molecules. Above the critical micellar concentration (cmc), surfactant molecules ag-gregate spontaneously to form a wide variety of assemblies, from spherical to rodlike, wormlike and bilayer micelles. Changes in their ratios of the principle moments of inertia (g1/g3, g2.g3) in-dicated the transition of micelle shapes at different concentrations. The aggregation number of micelle is found to have a power-law dependence on surfactant concentration.

关键词： surfactant, MD simulation, sodium dodecylbenzenesulfonate, micelle shape.

Biodegradable amphiphilic block copolymers containing functionalized PEO blocks:Controlled synthesis and biomedical potentials

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Science China chemistry 2010年第3期53卷 519-527页

作者： ZHANG Yu1,2.SUN PeiJian1,2.& GAN ZhiHua1 1CAS Key Laboratory of Engineering Plastics,institute of chemistry,{2.,Beijing 100190,China 2.raduate University of {2.,Beijing 100039,China CAS Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of Sciences Beijing China Graduate University of chinese academy of sciences Beijing China

A series of controllable amphiphilic block copolymers composed of poly(ethylene oxide)(PEO) as the hydrophilic block and poly(ε-caprolactone)(PCL) as the hydrophobic block with the amino terminal group at the end of the PEO chain(PCL-b-PEO-NH2. were *** on the further reaction of reactive amino groups,diblock copolymers with functional carboxyl groups(PCL-b-PEO-COOH) and functional compounds RGD(PCL-b-PEO-RGD) as well as the triblock copolymers with thermosensitive PNIPAAm blocks(PCL-b-PEO-b-PNIPAAM) were *** well-controlled structures of these copolymers with functional groups and blocks were characterized by gel permeation chromatography(GPC) and 1H NMR *** copolymers with functionalized hydrophilic blocks were fabricated into microspheres for the examination of biofunctions via cell culture experiments and in vitro drug *** results indicated the significance of introducing functional groups(e.g.,NH2.COOH and RGD) into the end of the hydrophilic block of amphiphilic block copolymers for biomedical potentials in tissue engineering and controlled drug release.

关键词： amphiphilic block copolymers biodegradable polymers functional terminal group cell growth drug release

Synthesis of Peptoid Nucleic Acid with Thymine as Nucleic Base

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chinese Chemical Letters 2000年第9期11卷 771-774页

作者： Yun WU Jie Cheng XU Shanghai institute of Organic chemistry, {2., Shanghai 2.0032 Shanghai Inst. of Organic chemistry Chinese Academy of Sciences Shanghai 200032 China

The synthesis of peptoid nucleic acid bearing thymine as nucleobase has been achieved. This modified oligonucleotide showed good hybridization with DNA.

关键词： peptoid peptide nucleic acid solid phase synthesis thymine

Geometry of Broad Line Regions of Active Galactic Nuclei

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chinese Journal of Astronomy and Astrophysics 2008年第1期8卷 50-62页

作者： Xiao-Rong Lü1 Key Laboratory for Particle Astrophysics, institute of High Energy Physics, chinese academy of sciences, Beijing 100049 2.Graduate School of chinese academy of sciences, Beijing 100049 Key Laboratory for Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 Graduate School of chinese academy of sciences Beijing 100049

It has long remained an open question as to the geometry of the broad line region （BLR） in active galactic nuclei （AGNs）. The reverberation mapping technique which measures the response of the broad emission lines to the ionizing continuum, when combined with multiwavelength continuum fitted by sophisticated accretion disks, provides a way of probing the BLR geometry. We analyze a sample of 35 AGNs, which have been monitored by the reverberation mapping campaign. In view of energy budget, the reverberation-based BH masses are found to be in agreement with those obtained by accretion disk models in two thirds of the present sample while the reverberation mapping methods underestimate the BH masses in about one third of objects, as also suggested by CoUin et al. in a recent work. We point out that there are obviously two kinds of BLR geometry, which are strongly dependent on the Eddington ratio, and separated by the value LBol/LEdd - 0.1. These results prefer a scenario of the disk and wind configuration of the BLR and identify the Eddington ratio as the physical driver regulating the wind in the BLR.

关键词： accretion, accretion disks - galaxies active - galaxies Seyfert - quasars general

Strengthening of the boreal winter Hadley circulation and its connection with ENSO

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Progress in Natural Science:Materials International 2007年第11期17卷 1327-1333页

作者： Ma Jie1,2.and Li Jianping2.1. College of Atmospheric sciences, Lanzhou University, Lanzhou 730000, China 2. LASG, institute of Atmospheric Physics, {2., Beijing 10002., China) College of Atmospheric sciences Lanzhou University Lanzhou 730000 China LASG Institute of Atmospheric Physics Chinese Acad. of Sci. Beijing 100029 China

Empirical orthogonal function (EOF) analysis is carried out for the year-to-year variability of the boreal winter (DJF) mass stream function of the mean meridional circulation (MMC) during the period 1948—2.05. The results demonstrate that it is dominated by the equatorially asymmetric and symmetric modes. Further analysis shows that the former mode is linked with the boreal winter Hadley cell mainly on the decadal time-scale, and the latter on the interannual time-scale. The asymmetric mode index (AMI) with a clear upward trend contributes to the decadal strengthening of the boreal Hadley circulation, and is closely correlated with the tropical SST warming, especially in the region of Indo-west Pacific warm pool (INWP). Furthermore, the AMI also contributes to the abrupt change of the correlation coefficient between the boreal Hadley circulation and ENSO after 1976. The symmetric mode index (SMI) with robust and stable linkage with ENSO shows a significant interannual variability, suggesting that the variability of the Hadley circulation is mainly associated with ENSO on the interannual time-scale.

关键词： the Hadley circulation interannual time-scale decadal time-scale

Compression behavior of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(2..5) bulk metallic glass up to 2. GPa

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Science China(Physics,Mechanics & Astronomy) 2005年第3期48卷 319-324页

作者： LI Gong 1, 2., ZHAN Zaiji 2., LIU Jing 3 , YUN Jinku 1 , SUN Liling 2., LIU Riping 1 , ZHANG Jun 2.& WANG Wenkui 1, 2.1. Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China 2. Center for Condensed Matter Physics, institute of Physics, chinese academy of sciences, Beijing 100080, China 3. BSRF, institute of High Energy Physics, chinese academy of sciences, Beijing 100039, China Key Laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao China Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing China BSRF Institute of High Energy Physics Chinese Academy of Sciences Beijing China

The compression of a Zr41Ti14Cu12.5Ni10Be2..5 bulk metallic glass (BMG) is investigated at room temperature up to 2. GPa using in-situ high pressure energy dispersive X-ray diffraction with a synchrotron radiation source. The pressure-induced structural relaxation is exhibited. It is found that below about 8 GPa, the existence of excess free volume contributes to the rapid structural relaxation, which gives rise to the rapid volumetric change, and the structural relaxation results in the structural stiffness under higher pressure.

关键词： bulk metallic glass, high pressure, structural relaxation, synchrotron radiation.

SYNTHESIS AND CHARACTERIZATION OF A NOVEL FLUORINE-CONTAINING HYDROPHOBICALLY ASSOCIATING POLYMER

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chinese Journal of Polymer Science 1999年第3期17卷 281-288页

作者： Jin Yang Wei-yuan Huang Laboratory of Organofluorine chemistry, Shanghai institute of Organic chemistry, chinese academy of sciences, Shanghai 2.0032. China 中科院上海有机化学所上海 200032 中科院上海有机化学所上海

In this article, the synthesis and characterization of a novel fluoromonomer and its copolymer with acrylamide is reported. 2.perfluoroamyl-4-hydroxylquinoline 2.was synthesized from ethyl 2. 2.dihydroperfluoroheptanoate in high yields. The monomer 4 was then synthesized from 2.in two steps readily in high yields. Synthesis and characterization of copolymers of acrylamide (AM) and the fluoromonomer were investigated. The composition and intrinsic viscosity of these copolymers were studied. It was found that the rheological properties of aqueous solutions of polyacrylamide were modified significantly when a small proportion of the fluoromonomer 4 was incorporated on investigating the viscosity-concentration profiles, pseudoplasticity of these solutions and the effect of the presence of surfactant. These results could be explained by the hydrophobic association of the fluorocarbon segments in the aqueous solutions of these copolymers.

关键词： hydrophobically associating polymer fluorine-containing acrylate perfluoroalkylation with RFI/Na2.2.4

Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers

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Science China chemistry 2010年第8期53卷 1620-1633页

作者： GENG YanHou1,HUANG Li1,2.WU ShuPeng1,2.& WANG FoSong1 1State Key Laboratory of Polymer Physics and chemistry Changchun institute of Applied chemistry,chinese academy of sciences,Changchun 13.02.,China 2.raduate University of chinese academy of sciences,Beijing 100049,China State Key Laboratory of Polymer Physics and chemistry Changchun institute of Applied chemistry Chinese Academy of Sciences Changchun China Graduate University of chinese academy of sciences Beijing China

Kumada chain-growth polycondensation (KCGP) is a novel method for the synthesis of well-defined conjugated *** the Ni-catalyst can transfer in an intramolecular process to the propagating chain end,the polymerization follows chain-growth *** this newly developed method,various conjugated polymers,such as polythiophenes,poly(p-phenylene) (PPP),polypyrrole (PPy),and polyfluorene with controlled molecular weights and relatively narrow polydispersities (PDIs),have been ***,the polymerizations for poly(3-alkylthiophene)s (P3ATs),PPP,and PPy exhibited quasi-living characteristics,which allows preparing polymer brushes,fully-conjugated block copolymers,and macroinitiators and macro-reactants for the synthesis of rod-coil block *** the current review,the progress in this new area is summarized.

关键词： chain growth polycondensation conjugated polymers Kumada reaction block copolymers polymer brush