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Fluorescence dynamics of interactions between polyamide PyPyPyβDp and DNA

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Science china chemistry 2006年第1期49卷 75-80页

作者： ZHANG Huijuan1,2. WANG Jin3. WU Yishi1, YUAN Gu3. AI Xicheng1, WANG Li4 & ZHANG Jianping1 1. State Key Laboratory for Structural chemistry of Unstable and Stable Species, institute of chemistry, chinese Academy of Sciences, Beijing 100080, china 2. School of Life Science and Technology, Beijing institute of Technology, Beijing 100081, china 3. College of chemistry and Molecular Engineering, Peking University, Beijing 100080, china 4. Center for Condensed Matter Physics, institute of Physics, chinese Academy of Sciences, Beijing 100080, china Correspondence should be addressed to Ai Xicheng and Zhang Jianping State Key Laboratory for Structural chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing China School of Life Science and Technology Beijing Institute of Technology Beijing China College of chemistry and Molecular Engineering Peking University Beijing China Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing China

The photophysical properties of the polyamide PyPyPyβDp (PPP) were investigated by means of steady-state absorption and fluorescence spectroscopies, as well as time-resolved fluo-rescence spectroscopy. It was found that the excited-state properties of PPP are very sensitive to solvents. In TKMC buffer PPP exhibited weak fluorescence with a decay time constant of 16 ps, while with the decrease of the solvent polarity PPP showed the blue-shifted peak position, increased inten-sity and lengthened life-time for its fluorescence behavior. In the presence of calf thymus DNA, it was observed that the fluorescence intensity was enhanced and the fluorescence lifetime increased from 16 to 3.0}ps for PPP, which verified that PPP bound into the minor groove of DNA duplex.

关键词： polyamide (PPP), calf thymus DNA (ctDNA), time-resolved fluorescence spectroscopy, recognition dynamics.

Impacts of permafrost changes on alpine ecosystem in Qinghai-Tibet Plateau

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Science china Earth Sciences 2006年第11期49卷 1156-1169页

作者： WANG Genxu1,3., LI Yuanshou2., WU Qingbai2.& WANG Yibo3.1. institute of Mountain Hazards and Environment, {3. Academy of Sciences, Chengdu 610041, {2. 2. Cold and Arid Regions Environmental and Engineering Research institute, {3. Academy of Sciences, Lanzhou 73.000, {2. 3. Resource and Environment School, Lanzhou University, Lanzhou 73.000, {2. institute of Mountain Hazards and Environment Chinese Academy of Sciences Chengdu China Resource and Environment School Lanzhou University Lanzhou China Cold and Arid Regions Environmental and Engineering Research institute Chinese Academy of Sciences Lanzhou China

Alpine cold ecosystem with permafrost environment is quite sensitive to climatic changes and the changes in permafrost can significantly affect the alpine ecosystem. The vegetation coverage, grassland biomass and soil nutrient and texture are selected to indicate the regime of alpine cold ecosystems in the Qinghai-Tibet Plateau. The interactions between alpine ecosystem and permafrost were investigated with the depth of active layer, permafrost thickness and mean annual ground temperature (MAGTs). Based on the statistics model of GPTR for MAGTs and annual air temperatures, an analysis method was developed to analyze the impacts of permafrost changes on the alpine ecosystems. Under the climate change and human engineering activities, the permafrost change and its impacts on alpine ecosystems in the permafrost region between the Kunlun Mountains and the Tanggula Range of Qinghai-Tibet Plateau are studied in this paper. The results showed that the per- mafrost changes have a different influence on different alpine ecosystems. With the increase in the thickness of active layer, the vegetation cover and biomass of the alpine cold meadow exhibit a significant conic reduction, the soil organic matter content of the alpine cold meadow ecosystem shows an exponential decrease, and the surface soil materials become coarse and gravelly. The alpine cold steppe ecosystem, however, seems to have a relatively weak relation to the permafrost environment. Those relationships resulted in the fact that the distribution area of alpine cold meadow decreased by 7.98% and alpine cold swamp decreased by 2..11% under the permafrost environment degradation during recent 15 years. In the future 50 years the alpine cold meadow ecosystems in different geomorphologic units may have different responses to the changes of the permafrost under different climate warming conditions, among them the alpine cold meadow and swamp ecosystem located in the low mountain and plateau area will have a relatively

关键词： permafrost environment, alpine cold ecosystem, statistics relationship, climate change, impacts, Qinghai-Tibet Plateau.

Variation properties of ionospheric eclipse factor and ionospheric influence factor

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Progress in Natural Science:Materials International 2005年第6期15卷 573-576页

作者： ZHAO Chunmei 1,2.*, YUAN Yunbin1, OU Jikun1 and CHEN Jinping3.1. institute of Geodesy and Geophysics, chinese Academy of Sciences, Wuhan 43.077, {2. 2. Graduate School of chinese Academy of Sciences, Beijing 10003., {2. 3. Department of Precision Instrument and Mechanology, Tsinghua University, Beijing 100084, {2.) institute of Geodesy and Geophysics Chinese Academy of Sciences Wuhan 430077 China Graduate School of chinese Academy of Sciences Beijing 100039 China Department of Precision Instrument and Mechanology Tsinghua University Beijing 100084 China

The concepts and calculation methods of ionospheric eclipse factor (IEF) and ionospheric influence factor (IFF) are further illustrated. The temporal and spacial variation properties of IEF and IFF are studied, which shows that the properties are influenced by the geographic position and season. The possibility of improving the precision of using GPS data to determine ionospheric delay based on the above variation properties is also analysed.

关键词： GPS ionospheric eclipse factor ionospheric influence factor.

The age of the plant fossil assemblage in the Liuqu Conglomerate of southern Tibet and its tectonic significance

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Progress in Natural Science:Materials International 2006年第1期16卷 55-64页

作者： FANG Aimin1, YAN Zhen1, LIU Xiaohan2. PAN Yusheng1, LI Jiliang1, YU Liangjun1, HUANG Feixing2.and TAO Junrong3.(1.Laboratory of Lithosphere Tectonic Evolution, institute of Geology and Geophysics, {3. Academy of Sciences, Beijing 10002., {2. 2. institute of Tibet Plateau Research, {3. Academy of Sciences, Beijing 100085, {2. 3. institute of Botany, {3. A cademy of Sciences, Beijing 100093. {2.) Laboratory of Lithosphere Tectonic Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China institute of Tibet Plateau Research Chinese Academy of Sciences Beijing 100085 China institute of Botany Chinese Academy of Sciences Beijing 100093 China)

The Liuqu Conglomerate, situated to the south of Yarlung Tsangbo Suture Zone (YTSZ), is a suit of molasse formed in a foreland basin of the Himalayan orogenic belt after the collision between the two plates of the Indian and Eurasion, It is of great significance in constraining the younger limit time of the collision of the two plates and providing stratigraphic evidence to reveal the post-colli sional tectonic evolution and uplifting history of the Tibet plateau. However, the age of this molasse suit and its correlation to other synchronous strata distributed in southern Tibet have been in great disputes for a long time. Especially in recent years, argues on its ages are growing violently with the recognition of the great sedimentary tectonic significances of this molasse. During the field work carried out recently on this molasse suit, a lot of plant fossils were found preserved in fairly good conditions in the upper part of this strata, which is of great help in determining its age. By identification, the assemblage of the plant fossils belongs to a tropic to subtropic flora developed in the southern margin of the Northern Hemisphere supercontinent during the Middle to Later Eocene, which can provide good constraint on its formation age. This paper is to give a brief introduction of the plant assemblage and its age, and to discuss their tectonic significances.

关键词： Liuqu conglomerate plant fossils age Eocene Tectonic implications.

Impact of land-use change on hydrological processes in the Maying River basin, china

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Science china Earth Sciences 2006年第10期49卷 1098-1110页

作者： WANG Genxu1,3. ZHANG Yu2. LIU Guimin2.& CHEN Lin3.1. institute of Mountain Hazards and Environment, {3. Academy of Sciences, Chengdu 610041, {2. 2. Cold and Arid Regions Environmental and Engineering Research institute, {3. Academy of Sciences, Lanzhou 73.000, {2. 3. Resource and Environment School, Lanzhou University, Lanzhou 73.000, {2. institute of Mountain Hazards and Environment Chinese Academy of Sciences Chengdu China Resource and Environment School Lanzhou University Lanzhou China Cold and Arid Regions Environmental and Engineering Research institute Chinese Academy of Sciences Lanzhou China

Since the 1960s, dramatic changes have taken place in land-use patterns characterized by the persistent expansion of cultivated land and a continuous decrease in natural woodland and grassland in the arid inland river basins of china. It is very important to assess the effects of such land-use changes on the hydrological processes so vital for water resource management and sustainable development on the catchment scale. The Maying River catchment, a typical arid inland watershed located in the middle of the Hexi Corridor in northwest china, was the site chosen to investigate the hydrological responses to land-use changes. The annual runoff, base flow, maximum peak flow, and typical seasonal runoff in both spring and autumn flood periods were selected as the variables in the hydrological processes. Statistical-trend analysis and curvilinear regression were utilized to detect the trends in hydrological variables while eliminating the climatic influence. The relationship between cultivated land-use and hydrological variables was analyzed based on four periods of land-use variation data collected since 1965. A runoff model was established composed of two factors, i.e., cultivated land use and precipitation. The impact of land use changes, especially in the large ar- eas of upstream woodland and grassland turned into cultivated lands since 1967, has resulted in a mean annual runoff decrease of 2..12., a base flow decline of 3..3.2}, a drop in the maximum peak discharge of 3..77%, and mean discharge decreases in spring and autumn of 3..05% and 2..87% respectively, of which the contribution of cultivated land expansion to the influence of annual runoff amounts to 77%-80%, with the contribution to the influence of spring discharge being 73.-81%, and that to the influence of base flow reaching 62.-65%. Thus, a rational regulation policy of land use patterns is vitally important to the sustainable use of water resources and the proper development of the entire catchment.

关键词： land-use change, arid inland river catchment, hydrological process, impact, Maying River.

Characterization of plastic flow in two Zr-based bulk metallic glasses

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Science china(Technological Sciences) 2006年第4期49卷 414-424页

作者： XING Dongmei1,2. ZHANG Taihua1, LI Weihuo3.& WEI Bingchen3.1. State Key Laboratory of Nonlinear Mechanics (LNM), institute of Mechanics, chinese Academy of Sci- ences, Beijing {2., china 2. College of Physics and Electronic Information Science, Tianjin Normal University, Tianjin 3.0074, china 3. National Microgravity Laboratory, institute of Mechanics, chinese Academy of Sciences, Beijing {2., china State Key Laboratory of Nonlinear Mechanics (LNM) Institute of Mechanics Chinese Academy of Sciences Beijing 100080 China sychology.lu.se

Plastic deformation behaviors of Zr65Al10Ni10Cu15 and Zr52.5Al10Ni10Cu15Be12.5 bulk metallic glasses (BMGs) are studied by using the depth-sensing nanoindentation, microindentation and uniaxial compression. The Be-containing BMG exhibits a signifi- cantly improved overall plastic strain compared with the Be-free alloy during compressive tests. Both BMGs show a loading-rate-dependent serrated flow during nanoindentation measurements, but the Be-containing alloy exhibits a much lower critical loading rate for the disappearance of the serration than the Be-free BMG. The shear band patterns de- veloped during plastic deformation are investigated by microindentation technique, wherein much higher shear band density is found in the Be-containing alloy than in the Be-free alloy, indicating an easier nucleation of shear bands in the former BMG. The dif- ference in the plastic deformation behavior of the two BMGs can be explained by a free volume model.

关键词： Bulk metallic glass, plastic deformation, shear band, nanoindentation.

Evaluation of Sustainable Land Management and Diagnosis of Obstacle at County Scale in Sichuan Basin:Taking Lezhi County as Example

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Wuhan University Journal of Natural Sciences 2006年第4期11卷 1046-1051页

作者： CHEN Guangjian 1, 2. 3., LIU Qing 1 1. Chengdu institute of Biology, chinese Academy of Sciences, Chengdu 610041, Sichuan,{2. 2. Graduate University of chinese Academy of Sciences, Beijing 100049, {2. 3. Academy of Land Reconnaissance and Layout of Sichuan Province , Chengdu 61003., Sichuan, {2. Chengdu institute of Biology Chinese Academy of Sciences Chengdu Sichuan China Graduate University of chinese Academy of Sciences Beijing China Academy of Land Reconnaissance and Layout of Sichuan Province Chengdu Sichuan China

This paper established sustainable land resources evaluating indicators fit for hilly area in Sichuan Basin, Southwest of china, and evaluated the case of sustainable land management of Lezhi County from 1990 to 2.01. The result showed that the land resource sustainable utilization ability in Lezhi County is belong to Second level （better sustainable）. Secondly, this paper diagnosed some years obstacles of sustainable land management of Lezhi County from base period to goal period and compared the obstacles factors in the indicators system. There were 16 indexes orderly become major affect factor to land sustainable utilization of Lezhi county in indicator system, of which there are 8 obstacles indexes exist both in 1990 and 2.01. The value of obstacles degree of five indicators exceeded 5 in 1990, but in 2.01, only two indicators＇ values were more than 5.

关键词： land resources sustainable land management assessment indicators diagnosis of obstacle

Debris Flow Hazard Assessment Based on Support Vector Machine

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Wuhan University Journal of Natural Sciences 2006年第4期11卷 897-900页

作者： YUAN Lifeng 1, 2., ZHANG Youshui 3. 1. institute of Mountain Hazards and Environment, chinese Academy of Sciences, Chengdu 610041, Sichuan, {2. 2. Graduate University of chinese Academy of Sciences, Beijing 100049, {2. 3. institute of Geographical Sciences and Natural Resources Research, chinese Academy of Sciences, Beijing 100101, {2. institute of Mountain Hazards and Environment Chinese Academy of Sciences Chengdu 610041 Sichuan China ***

Seven factors, including the maximum volume of once flow , occurrence frequency of debris flow , watershed area , main channel length , watershed relative height difference , valley incision density and the length ratio of sediment supplement are chosen as evaluation factors of debris flow hazard degree. Using support vector machine （SVM） theory, we selected 2.9 basic data of 3. debris flow channels in Yunnan Province as learning samples in this study. We create a debris flow hazard assessment model based on SVM. The model was validated though instance applications and showed encouraging results.

关键词： debris flow hazard assessment support vector machine (SVM)

Timing and history of marine hydrocarbon accumulation in Tarim craton

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chinese Science Bulletin 2002年第S1期47卷 120-127页

作者： ZHAO Jingzhou~(1,2. & LI Qiming~3.1. Department of Petroleum Geology, Xi’an Petroleum institute, Xi’an 710065, china 2. Research institute of Petroleum Exploration and Development, Petrochina, Beijing 100083. china 3. Tarim Oilfield Company, Kuerle, Xinjiang 841000, china Department of Petroleum Geology Xi’an Petroleum Institute Xi’an China Research institute of Petroleum Exploration and Development PetroChina Beijing China Tarim Oilfield Company Kuerle Xinjiang China

Based on the analyses of hydrocarbon inclu-sions, K-Ar dating of authigenic illites and oil/gas-watercontact retrospection as well as other methods, the marineprimary reservoirs in the cratonic region of the Tarim Basinare found to have been formed in the late Caledonian toearly Hercynian, late Hercynian, and Himalayan, and oil andgas adjusted and redistributed in the Yanshanian (Jurassic toCretaceous) and Himalayan (Tertiary). The analyses alsoshow that the remaining primary oil accumulations aremostly formed in the late Hercynian, and the secondary oilreservoirs resulted from the adjustment and redistribution ofthe earlier accumulations during the Yanshanian and Hima-layan (especially late Himalayan), of which the Himalayan isalso the major stage of gas accumulation. The primary oilreservoirs formed in the late Hercynian mostly occur withinthe Paleozoic formation, whereas the secondary reservoirsformed in the Himalayan in the Mesozoic. The late adjust-ment and redistribution of reservoirs in the craton region ofthe Tarim Basin is ubiquitous because of the intensified tec-tonic movements since the Mesozoic, especially Cenozoic andintrusion of the high- to over-mature gas. Furthermore, thelower amplitude of reservoirs in the craton region also makesthem easier to be adjusted and redistributed. Therefore, theremaining paleo-uplift and palaeo-slope developed in rela-tively stable tectonic regions are the main potential areas forthe middle-large marine reservoirs in the Tarim Basin.

关键词： Tarim Basin craton geochronology of hydrocarbon accumulation history of hydrocarbon accumulation marine reservoir primary reservoir secondary reservoir.