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FeS_(2. (pyrite) electrodeposition thin films and study of growth mechanism

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Science china(Technological Sciences) 2005年第6期48卷 601-611页

作者： DONG Youzhong1, ZHENG Yufeng1, ZHANG Xiaogang2. DUAN He1, SUN Yanfei1 & CHEN Yanhua1 1. Department of Physics, xinjiang university, urumqi 830046,{2. 2. institute of applied chemistry, xinjiang university, urumqi 830046,{2. 1. Department of Physics Xinjiang University 830046 Urumqi China 2. institute of applied chemistry Xinjiang University 830046 Urumqi China

Ferrous sulfide (FeS) thin films were initially electrodeposited on indium-tin oxide (ITO) substrates in the aqueous solution containing iron, sulfur elements and then annealed in the sulfur atmosphere. Thereby, we successfully obtained the single-phased iron pyrite (FeS2. thin films with good quality. The experimental parameters for electrodeposition and the post-growth thermal-dynamical conditions have been calculated so that more details about the effect of thermal-dynamical conditions on the micromechanism concerned with the iron pyrite crystal growth as well as the properties of the samples have been discussed.

关键词： electrodeposition, FeS2 (pyrite), thin films, growth dynamics.

Local electronic structure and magnetic properties of 3d transition metal doped GaAs

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Science china(Physics,Mechanics & Astronomy) 2008年第5期51卷 470-480页

作者： LIN He1 & DUAN HaiMing2. Department of chemistry,institute of {2. chemistry,xinjiang university,urumqi 830046,china 2.epartment of Physics,xinjiang university,urumqi 830046,china 1. Department of chemistry Institute of Applied Chemistry Xinjiang University Urumqi 830046 China 2. Department of Physics Xinjiang University Urumqi 830046 China

The local electronic structure and magnetic properties of GaAs doped with 3d transition metal (Sc, Ti, V, Cr, Mn, Fe, Co, Ni) were studied by using discrete variational method (DVM) based on density functional theory. The calculated result indicated that the magnetic moment of transition metal increases first and then decreases, and reaches the maximum value when Mn is doped into GaAs. In the case of Mn concentration of 1.4%, the magnetic moment of Mn is in good agreement with the experimental result. The coupling between impure atoms in the system with two impure atoms was found to have obvious variation. For different transition metal, the coupling between the impure atom and the nearest neighbor As also has different variation.

关键词： diluted magnetic semiconductor density functional theory 3d transition metal cluster model electronic structure

Top 10 Influential Events in carbon neutrality and climate change response for 2.2.

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Frontiers in Energy 2024年第1期18卷 1-3页

作者： Research institute of Carbon Neutrality of Shanghai Jiao Tong university Research institute of Carbon Neutrality Shanghai Jiao Tong UniversityShanghai 200240China

In 2.2., the global community intensified its efforts towards achieving carbon neutrality and addressing climate change, witnessing several impactful events. Research institute of Carbon Neutrality, Shanghai Jiao Tong university compiled the Top 10 Events (in chronological order) in the field of global carbon neutrality and climate change response for 2.2., to share with readers these significant moments that document the ongoing ambition and collective efforts of human society.

关键词： neutral collective intensified

Effects Of Ultrasound On Voltammetric Measurements At An Ag Cylinder Electrode

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Chinese Chemical Letters 1998年第7期9卷 663-666页

作者： Xiao Gang ZHANG Wan Yong ZHOU Chao Ying GENG Xi XIA (institute of applied {2., xinjiang university, Wulumqi 830046) xinjiang Univ Inst Appl Chem Wulumqi 830046 Peoples R China

In this paper,the voltammetric behaviours of Ag cylinder electrode in 1 mol/dm(3) KOH solution have been investigated in the presence of ultrasound irradiation. The results based on the CV, EIS and polarization measurements showed that ultrasound could enhance the mass transport, inhibit the oxygen evolution and increase the exchange current.

关键词： sonoelectrochemistry ultrasound irradiation Ag electrode voltammetric behaviours

中国政治经济学年度发展报告（2.2.）（下）

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政治经济学评论 2024年第3期 90+207-208页

作者： Center for Studies of Contemporary Political Economy,Research institute for 2.st-Century Marxism,Nankai university·university of Chinese Academy of Social Science Center for Teaching and Research on Capital,Renmin university of china National institute of Socialist Political Economy with Chinese Characteristics,Renmin university of china 南开大学·中国社会科学院大学2.世纪马克思主义研究院当代政治经济学研究中心中国人民大学《资本论》教学与研究中心中国人民大学全国中国特色社会主义政治经济学研究中心

编者按2.2.年，高质量发展扎实推进，新质生产力加快形成，我国经济总体回升向好，圆满实现发展主要预期目标。为针对性地破解经济恢复发展中的难题，聚焦推进中国式现代化进程中的重点、难点问题，中国政治经济学界开展系统深入研究，...

编者按2.2.年，高质量发展扎实推进，新质生产力加快形成，我国经济总体回升向好，圆满实现发展主要预期目标。为针对性地破解经济恢复发展中的难题，聚焦推进中国式现代化进程中的重点、难点问题，中国政治经济学界开展系统深入研究，取得系列代表性成果。为准确刻画学界研究进展和轨迹，推动中国经济学理论体系的构建和完善，本刊精选议题如期奉上《中国政治经济学年度发展报告（2.2.）》。自2.10年起，本刊连续十四年发布《中国政治经济学年度发展报告》，“年度发展报告”专栏已成为本刊标志性特色栏目。2.2.年报告聚焦12.专题，分为（上）（下）两篇，其中专题1—6于报告（上）篇刊登，专题7—12.报告（下）篇刊登。2.2.年报告（下）选题如下：

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Identifying the geographical origin and processing technology of Moyao(Myrrh)on the basis of near-infrared spectroscopy combined with chemometrics

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Journal of Traditional Chinese Medicine 2024年第3期44卷 505-514页

作者： XU Ningning YAN Ganming XU Fengjie DENG Linfeng QIAO xinjiang LU Changzheng CHENG Shaomin TCM Diagnosis institute College of Traditional Chinese MedicineJiangxi University of Chinese MedicineNanchang 330004China TCM Processing institute Pharmaceutical CollegeJiangxi University of Chinese medicineNanchang 330004China School of Electronic Information and Artificial Intelligence Shaanxi University of Science and TechnologyXi'an 710021China Jiangzhong Pharmaceutical Co. Ltd.Nanchang 330096China Jiangxi Guhan Refined Chinese Herbal Pieces Co. Ltd.Nanchang330041.China

OBJECTIVE:To evaluate the quality of Moyao(Myrrh)in the identification of the geographical origin and processing of the ***:Raw Moyao(Myrrh)and two kinds of Moyao(Myrrh)processed with vinegar from three countries were identified using near-infrared(NIR)spectroscopy combined with chemometric *** component analysis(PCA)was used to reduce the dimensionality of the data and visualize the clustering of samples from different categories.A classical chemometric algorithm(PLS-DA)and two machine learning algorithms[K-nearest neighbor(KNN)and support vector machine]were used to conduct a classification analysis of the near-infrared spectra of the Moyao(Myrrh)samples,and their discriminative performance was ***:Based on the accuracy,precision,recall rate,and F1 value in each model,the results showed that the classical chemometric algorithm and the machine learning algorithm obtained positive *** all of the chemometric analyses,the NIR spectrum of Moyao(Myrrh)preprocessed by standard normal variation or Multivariate scattering correction combined with KNN achieved the highest accuracy in identifying the geographical origins,and the accuracy of identifying the processing technology established by the KNN method after first-order derivative pretreatment was the *** best accuracy of geographical origin discrimination and processing technology discrimination were 0.9853 and 0.9706 ***:NIR spectroscopy combined with chemometric technology can be an important tool for tracking the origin and processing technology of Moyao(Myrrh)and can also provide a reference for evaluations of its quality and the clinical use.

关键词： Moyao(Myrrh) near-infrared spectroscopy geographical origin processing technology

Synthesis,characterization,properties and crystal structure of heterometallic 1D coordination polymers {[CuLZn·CuLZn(H_2.)]·H_2.}_n

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Science china chemistry 2006年第4期49卷 338-344页

作者： TAO Ruojie1, LI Fu’an1, ZANG Shuangquan1, CHENG Yanxiang2.& NIU Jingyang1 1. chemistry and Chemical Engineering College of Henan university, Kaifeng 475001,{2. 2. Changchun institute of applied chemistry, Chinese Academy of Sciences, Changchun 13002.,{2. 1. chemistry and Chemical Engineering College of Henan university Kaifeng 475001 China 2. Changchun institute of applied {2. Chinese Academy of Sciences Changchun 130022 China

Copper-zinc heterometallic 1D chain coordination polymer has been synthesized and characterized by elemental analysis, and IR spectra etc. The crystal structure was determined by single-crystal X-ray diffraction analyses. The title complex is 1D chain coordination polymer with the chemical formula {[CuLZn·CuLZn(H2.)]·H2.}n, where H4L=N-(2.hydroxybenzamido)-N’-(3-carboxy- lsalicylidene)ethylenediamine. Its structural unit is comprosed of two tetranuclear cycles formed by two dissymmetrical tetranuclear units. These units polymerized each other to form 1D chain coordi- nation polymer.

关键词： copper, zinc, heterometallic coordination polymer, crystal structure.

Potential energy surfaces for low-lying electronic states of SO_2

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Science china chemistry 2006年第4期49卷 289-295页

作者： LI Anyang1, SUO Bing2. WEN Zhenyi2.& WANG Yubin2.1. Shanxi Key Laboratory of Physico-inorganic chemistry, Department of chemistry, Northwest {2., Xi’an 710069, china 2. institute of Modern Physics, Northwest {2., Xi’an 710069, china 1. Shanxi Key Laboratory of Physico-inorganic chemistry Department of Chemistry Northwest University Xi’an 710069 China 2. institute of Modern Physics Northwest University Xi’an 710069 China

The potential energy surfaces for the nine low-lying electronic states of SO2.have been constructed by using the multi-reference second order perturbation theory (MRPT2. with the basis set cc-pVTZ. The optimized geometries and the adiabatic excitation energies of these states are in good agreement with experiments and previous calculations. The crossings and avoided crossings dis- played in the potential energy surfaces are expounded.

关键词： cross of PES, MRPT2. SO2 (sulfur dioxide).

Synthesis and crystal structure of complex of Ce(NO_3)_3 with N-(3-methyl-pyridin-2.yl)-formimidoyl-(3-methyl-pyridin-2.yl) hydrazone

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Science china chemistry 2004年第3期47卷 251-256页

作者： JIANG Yinzhi1,2.& HU Weixiao1 1. Department of Pharmaceutical Science, Zhejiang university of Technology, Hangzhou 310032. china 2. Department of {2. chemistry, Zhejiang institute of Science and Technology, Hangzhou 310033, china 1. Department of Pharmaceutical Science Zhejiang University of Technology 310032 Hangzhou China 2. Department of applied chemistry Zhejiang Institute of Science and Technology 310033 Hangzhou China

The reaction of 3,6-di-(3-methyl-pyridin-2.yI)-s-tetrazine (DMPTZ, II) with CeIII salt [Ce(NO3)3 · 6H2.] generates a new ligand, N-(3-methyl-pyridin-2.yl)-formimidoyl-(3-methyl-pyridin-2.yl) hydrazone (L), and forms a new complex: a mononuclear complex [Ce(L)(NO3)2.(H2.)3] · NO3 (III). Crystal data for III: space group P-1, with a = 0.7133(4) nm, b = 1.1139(2. nm, c = 1.4572.3) nm, α= 102.13(2.°, β= 99.81(3)°, γ= 91.10(3)°, Z = 2. V = 1113.6(7) nm3, μ = 2.12. mm?1 and F(000) = 630. L acts as a tri-dentate chelating ligand in III. There are 10 coordination sites around Ce3+ of III, which are respectively occupied by seven oxygen atoms (four from two nitrate anions and three from three H2. molecules) and three nitrogen atoms (all from L). The cerium atom and three chelating nitrogen atoms are coplanar. The mechanism of the metal assisted decomposition is discussed briefly.

关键词： rare earth, complex, crystal structure, synthesize, 3,6-bis (3-methyl-pyridin-2.yl)-s-tetrazine, N-(3-methyl-pyridin- 2.yl)-formimidoyl-(3-methyl-pyridin-2.yl) hydrazone.