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Electron microscopy study of the sakhaite from endogenous borate deposit in Hunan, china

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Science china Earth Sciences 2004年第3期47卷 232-238页

作者： LIU Xiangwen1,2. YANG Guangming2. ZOU Huamin3, QU Jing1 & ZHAO Wenxia4 1. graduate school,{2. university of geosciences, wuhan 43.074,{2. 2. Test Center,{2. university of geosciences, wuhan 43.074,{2. 3. Physics and Technology College, {12. university, {12. 430072.{2. 4. Test Center, Zhongshan university, Guangzhou 5102.5,{2. china Univ Geosci Grad Sch Wuhan 430074 Peoples R China china Univ Geosci Test Ctr Wuhan 430074 Peoples R China wuhan Univ Phys & Technol Coll Wuhan 430072 Peoples R China Zhongshan Univ Test Ctr Guangzhou 510275 Peoples R China

Sakhaite specimens from an endogenous borate deposit in Hunan Province, china have been studied in detail by means of transmission electron microscopy (TEM). The selected area electron diffraction (SAED) patterns obtained with different crystal zone axes show that the crystal system is cubic, with a = 1.463 nm. The convergent beam electron diffraction (CBED) patterns indicate that the point group and space group of sakhaite is m3m and Fd3m, respec-tively. The space group of synthetic sakhaite determined by Chichagov (1974) is F4132. The possible reasons why the space groups of the natural and the synthetic sakhaites are different are discussed.

关键词： sakhaite, space group, convergent beam electron diffraction (CBED).

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Science china Earth Sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of {2., Ministry of Education of china, Beijing 100083, china 2. school of Earth Sciences and Mineral Resources, china university of {2., Beijing 100083, china 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. school of Earth Sciences and Mineral Resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

Analytical method of Cr stable isotope and its application to water pollution survey

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Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2.3,MA Teng 4,5,LING WenLi 1,2.LIU CunFu 4,5 & LI Li 4,5 1Faculty of Earth Science,china university of {2.,wuhan 43.074,china 2.tate Key Laboratory of Geological Processes and Mineral Resources,china university of {2.,wuhan 43.074,china 3 {12. school,china university of {2.,wuhan 43.074,china 4 Biogeological and Environmental Geology Laboratory of Ministry of Education(china university of {2.) ,wuhan 43.074,china 5 Sino-Hungary Joint Laboratory of Environmental Sciences and Health,china university of {2.,wuhan 43.074,china Faculty of Earth Science China University of Geosciences Wuhan 430074 China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China graduate school China University of Geosciences Wuhan 430074 China Biogeological and Environmental Geology Laboratory of Ministry of Education (china university of {2.) Wuhan 430074 China Sino-Hungary Joint Laboratory of Environmental Sciences and Health China University of Geosciences Wuhan 430074 China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

Geothermal and fluid flowing simulation of ore-forming antimony deposits in Xikuangshan

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Science china Earth Sciences 2006年第8期49卷 862-871页

作者： YANG Ruiyan1,2. MA Dongsheng2. BAO Zhengyu3, PAN Jiayong2. CAO Shuanglin2.& XIA Fei2.1. school of Mathematics and Physics, china {2. of geosciences, wuhan 43.074, china 2. State Key Laboratory for Research of Mineral Deposits, Nanjing {2., Nanjing 2.0093, china 3. Faculty of Earth Sciences, china {2. of geosciences, wuhan 43.074, china 1. school of Mathematics and Physics China University of Geosciences Wuhan 430074 China 2. State Key Laboratory for Research of Mineral Deposits Nanjing University Nanjing 210093 China 3. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

The Xikuangshan Antimony Deposit located in the Mid-Hunan Basin, china, is the larg- est antimony deposit in the world. Based on the hydrogeological and geochemical data collected from four sections, Xikuangshan-Dajienao (AO), Xikuangshan-Dashengshan (BO), Xikuang- shan-Longshan (CO) and Dafengshan (DO) in the Basin, an advanced metallogenic model related to deep-cyclic meteoric water of Xikuangshan Antimony Deposit is put forward in this paper using a model of heat-gravity-driving fluid flow transportation. The simulation results show that the ore-forming fluid of the deposit mainly comes from the Dashengshan and Longshan areas where BO and CO sections are located if the overall basin keeps a constant atmospheric precipitation and infiltration rate during mineralization, and that the average transportation speed of the ore-forming fluids is about 0.2.0.4 m/a.

关键词： ore-forming fluid, numerical simulation, geothermal field, geofluid transport, Xikuangshan, antimony deposits.

Adaptive quasi-likelihood estimate in generalized linear models

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Science china Mathematics 2005年第6期48卷 829-846页

作者： CHEN Xia & CHEN Xiru school of Mathematics and Statistics, wuhan {2., wuhan 430072. china graduate school, Chinese Academy of Science, Beijing 100049, china 1. school of Mathematics and Statistics Wuhan University 430072 Wuhan China 2. graduate school Chinese Academy of Science 100049 Beijing China

This paper gives a thorough theoretical treatment on the adaptive quasilikelihood estimate of the parameters in the generalized linear models. The unknown covariance matrix of the response variable is estimated by the sample. It is shown that the adaptive estimator defined in this paper is asymptotically most efficient in the sense that it is asymptotic normal, and the covariance matrix of the limit distribution coincides with the one for the quasi-likelihood estimator for the case that the covariance matrix of the response variable is completely known.

关键词： generalized linear models, quasi likelihood estimate, adaptive estimate.

Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china Earth Sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2. ZHAO Zhidan1,2. ZHANG Hongfei3, ZHANG Benren3 & CHEN Yuelong2.1. State Key Laboratory of Geological Processes and Mineral Resources, china university of {2., Beijing 100083, china 2. school of Earth Science and Mineral Resources, china university of {2., Beijing 100083, china 3. Faculty of Earth Sciences, china university of {2.,{12., china 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China 2. school of Earth Science and Mineral Resources China University of Geosciences Beijing 100083 China 3. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.2.). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2.b-Zr/4-Y and Ti/100-Zr-YX3 tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143)Nd/^(144)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(2.6)Pb/^(2.4)Pb (18.054-2..562., ^(2.7)Pb/^(2.4)Pb (15.537-15.743) and ^(2.8)Pb/^(2.4)Pb(38.068-38.530). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

A Principal Theorem of Normal Discretization Schemes for Operator Equations of the First Kind

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wuhan university Journal of Natural Sciences 2001年第4期6卷 767-768页

作者： Du Nai lin 1, Wang Hannah 2.1.school of Mathematics and Statistics, wuhan {2., wuhan 430072. china 2. school of Foreign Languages and Literature,wuhan {2.,wuhan 430072.china wuhan university School of Mathematics and Statistics Wuhan China (GRID:grid.49470.3e) (ISNI:***) wuhan university School of Foreign Languages and Literature Wuhan China (GRID:grid.49470.3e) (ISNI:***)

The authors announce a newly-proved theorem of theirs. This theorem is of principal significance to numerical computation of operator equations of the first kind.

关键词： operator equation of the first kind normal discretization scheme pure pseudoinverse

Rate of strong consistency of quasi maximum likelihood estimate in generalized linear models

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Science china Mathematics 2004年第6期47卷 882-893页

作者： YUE Li & CHEN Xiru school of Mathematics and Statistics, wuhan {2., wuhan 430072. china graduate school, Chinese Academy of Sciences, Beijing 100039, china 1. school of Mathematics and Statistics Wuhan University 430072 Wuhan China 2. graduate school Chinese Academy of Sciences 100039 Beijing China

Under the assumption that in the generalized linear model (GLM) the expectation of the response variable has a correct specification and some other smooth conditions, it is shown that with probability one the quasi-likelihood equation for the GLM has a solution when the sample size n is sufficiently large. The rate of this solution tending to the true value is determined. In an important special case, this rate is the same as specified in the LIL for iid partial sums and thus cannot be improved anymore.

关键词： quasi-likelihood function generalized linear models strong consistency

Evaluation Method of Web Site Structure Based on Web Structure Mining

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wuhan university Journal of Natural Sciences 2003年第3A期8卷 791-796页

作者： Li Jun\|e 1 , Zhou Dong\|ru 2.1. Computer Center,wuhan university, wuhan 430072. Hubei, china 2. school of Computer,wuhan university, wuhan 430072. Hubei,china wuhan university Computer Center Wuhan Hubei China (GRID:grid.49470.3e) (ISNI:***) wuhan university School of Computer Wuhan Hubei China (GRID:grid.49470.3e) (ISNI:***)

The structure of Web site became more complex than before. During the design period of a Web site, the lack of model and method results in improper Web structure, which depend on the designer's experience. From the point of view of software engineering, every period in the software life must be evaluated before starting the next period's work. It is very important and essential to search relevant methods for evaluating Web structure before the site is completed. In this work, after studying the related work about the Web structure mining and analyzing the major structure mining methods (Page\|rank and Hub/Authority), a method based on the Page\|rank for Web structure evaluation in design stage is proposed. A Web structure modeling language WSML is designed, and the implement strategies for evaluating system of the Web site structure are given out. Web structure mining has being used mainly in search engines before. It is the first time to employ the Web structure mining technology to evaluate a Web structure in the design period of a Web site. It contributes to the formalization of the design documents for Web site and the improving of software engineering for large scale Web site, and the evaluating system is a practical tool for Web site construction.

关键词： web structure mining page\|rank web structure evaluation modeling language for web structure