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Evaluation of the Interfacial Adhesion between Brittle Coating and Ductile Substrate by Cross-Sectional Indention

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材料热处理学报 2004年第5B期25卷 1187-1190页

作者： SUJian-yu ZHANGKun CHENGuang-nan InstituteofMechanics ChineseAcademyofSciencesBeijingChina／／GraduateSchooloftheChineseAcademyofSciencesBeijingChina InstituteofMechanics ChineseAcademyofSciencesBeijingChina

The cross-sectional indentation method is extended to evaluate the interfacial adhesion between brittle coating and ductile substrate. The experimental results on electroplated chromium coating/steel substrate show that the interfacial separation occurs due to the edge chipping of brittle coating. The corresponding models are established to elucidate interfacial separation processes. This work further highlights the advantages and potential of this novel indentation method.

关键词：分界面附着刻痕可锻衬底应力涂层铬钢

Compression behavior of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(2..5) bulk metallic glass up to 2. GPa

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Science china(Physics,Mechanics & Astronomy) 2005年第3期48卷 319-324页

作者： LI Gong 1, 2., ZHAN Zaiji 2., LIU Jing 3 , YUN Jinku 1 , SUN Liling 2., LIU Riping 1 , ZHANG Jun 2.& WANG Wenkui 1, 2.1. Key Laboratory of Metastable Materials Science and Technology, Yanshan university, Qinhuangdao 066004, china 2. Center for Condensed Matter Physics, Institute of Physics, {2. Academy of Sciences, beijing 100080, china 3. BSRF, Institute of High Energy Physics, {2. Academy of Sciences, beijing 10003., china 1. Key Laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 3. BSRF Institute of High Energy Physics Chinese Academy of Sciences 100039 Beijing China

The compression of a Zr41Ti14Cu12.5Ni10Be2..5 bulk metallic glass (BMG) is investigated at room temperature up to 2. GPa using in-situ high pressure energy dispersive X-ray diffraction with a synchrotron radiation source. The pressure-induced structural relaxation is exhibited. It is found that below about 8 GPa, the existence of excess free volume contributes to the rapid structural relaxation, which gives rise to the rapid volumetric change, and the structural relaxation results in the structural stiffness under higher pressure.

关键词： bulk metallic glass, high pressure, structural relaxation, synchrotron radiation.

^(13)C NMR spectra of tectonic coals and the effects of stress on structural components

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Science china Earth Sciences 2005年第9期48卷 1418-1437页

作者： JU Yiwen1,2. JIANG Bo1, HOU Quanlin2. WANG Guiliang1 & NI Shanqin2.1. College of Mineral Resource and Geosciences, china university of Mining and Technology, Xuzhou 2.1008, china 2. Laboratory of Computational Geodynamics, College of Geosciences, graduate School of chinese Academy of Sciences, beijing 100049, china 1. College of Mineral Resource and Geosciences China University of Mining and Technology 221008 Xuzhou China 2. Laboratory of Computational Geodynamics College of Geosciences Graduate School of Chinese Academy of Sciences 100049 Beijing China

High-resolution 13C Nuclear Magnetic Resonance (NMR) spectra of different kinds of tectonic coals were obtained using the NMR (CP/MAS+TOSS) method. On the basis of this, after simulation synthesis and division of spectra, the relative contents of carbon functional groups were calculated. Combined with results of Ro, max, XRD testing and element analysis, stress effects on the composition of macromolecular structures in tectonic coals were studied further. The results showed that Ro, max was not only the important index for describing coal rank, but was also effective for estimating the stress effect of tectonic coals. Under tectonic stress ac- tion, Ro, max was the most direct indicator of the coal structure and chemical components. Changes in the stacking Lc of the coal basic structure unit (BSU) and La/Lc parameters could distinguish the temperature and stress effects on metamorphic-deformed environments, and re- flected the degree of structural deformation. Therefore, on the whole, Lc and La/Lc can be used to index of the degree of structural deformation of tectonic coals. In different metamorphic and de- formed environments, different kinds of tectonic coals are formed under structural stress. The changes in characteristics of the macromolecular structure and chemical composition are such that as the increase in structural deformation becomes stronger, from the brittle deformation coal to ductile deformation coal, the ratio of width at the half height of the aromatic carbon and ali- phatic carbon peaks (Hfa/Hfal ) was increased. As carbon aromaticity was raised further, carbon aliphaticity reduced obviously and different compositions of macromolecular structure appeared as a jump and wave pattern except for in wrinkle structure coal, which might result chiefly from stress effects on the macromolecular structure of different kinds of tectonic coals. The macro- moecular changes of wrinkle structure coal are reflected mainly on physical structure. In the metamorphi

关键词： tectonic coal, NMR, macromolecular structure, chemical component, stress effect.

Effect of rock mass structure and block size on the slope stability——Physical modeling and discrete element simulation

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Science china(Technological Sciences) 2005年第z1期48卷 1-17页

作者： LI Shihai1, LIAN Zhenzhong1,2.& J. G. Wang3 1. Institute of Mechanics, chinese Academy of Sciences, beijing 100080,{2. 2. graduate School, chinese Academy of Sciences, beijing 100060,{2. 3. Tropical Marine Science Institute, National university of Singapore, Singapore 1192.0 chinese Acad Sci Inst Mech Beijing 100080 Peoples R China chinese Acad Sci Grad Sch Beijing 100060 Peoples R China Natl Univ Singapore Trop Marine Sci Inst Singapore 119260 Singapore

This paper studies the stability of jointed rock slopes by using our improved three-dimensional discrete element methods (DEM) and physical modeling. Results show that the DEM can simulate all failure modes of rock slopes with different joint configurations. The stress in each rock block is not homogeneous and blocks rotate in failure development. Failure modes depend on the configuration of joints. Toppling failure is observed for the slope with straight joints and sliding failure is observed for the slope with staged joints. The DEM results are also compared with those of limit equilibrium method (LEM). Without considering the joints in rock masses, the LEM predicts much higher factor of safety than physical modeling and DEM. The failure mode and factor of safety predicted by the DEM are in good agreement with laboratory tests for any jointed rock slope.

关键词： rock masses, slope stability, DEM simulation, block size effect, joints configuration effect, limit equilibrium method.

Observation results of relativistic electrons detected by Fengyun-1 satellite and analysis of relativistic electron enhancement (REE) events

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Science china(Physics,Mechanics & Astronomy) 2008年第12期51卷 1947-1956页

作者： YANG XiaoChao1,2. & WANG ShiJin1 1 Center for Space Science and Applied Research, chinese Academy of Sciences, beijing 100190,{2. 2.graduate university of chinese Academy of Sciences, beijing 100049,{2. 1. Center for Space Science and Applied Research Chinese Academy of Sciences Beijing 100190 China 2. graduate university of {2. Academy of Sciences Beijing 100049 China

The space particle component detector on Fengyun-1 satellite which works at the sun-synchronous orbit of about 870 km altitude has detected relativistic electrons for a long time. In comparison with the SAMPEX satellite observations during 1999–2.04, the relativistic electron data from Fengyun-1 satellite from June 1999 to 2.05 are used to analyze the relativistic electron enhancement (REE) events at the low earth orbit, and the possible correlation among REE events at the low earth orbit, high-speed solar wind and geomagnetic storms is discussed. The statistical result presents that 45 REE events are found in total during this time period, and the strong REE events with the maximum daily average flux > 400 cm?2.srt-1·s?1 occur mostly during the transition period from solar maximum to solar minimum. Among these 45 REE events, four strong REE events last a longer time period from 2.-to 51-day and correlate closely with high speed solar wind and strong geomagnetic storms. Meanwhile, several strong geomagnetic storms occur continuously before these REE events, and these continuous geomagnetic storms would be an important factor causing these long-lasting strong REE events. The correlation analysis for overall 45 events indicates that the strength of the REE events correlates with the solar wind speed and the strength of the geomagnetic storm, and the correlation for strong REE events is much stronger than that for weak REE events.

关键词： relativistic electron enhancement low earth orbit high-speed solar wind geomagnetic storm

Ionization state of cosmic hydrogen by early stars and quasars

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Research in Astronomy and Astrophysics 2009年第6期9卷 665-681页

作者： Xiao-Chun Mao1,2.1 National Astronomical Observatories, chinese Academy of Sciences, beijing 100012.{2. 2.graduate university of chinese Academy of Sciences, beijing 100049,{2. National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China graduate university of {2. Academy of Sciences Beijing 100049 China

Cosmic hydrogen is reionized and maintained in its highly ionized state by the ultraviolet emission attributed to an early generation of stars and quasars. The Lyα opacity observed in absorption spectra of high-redshift quasars permits more stringent constraints on the ionization state of cosmic hydrogen. Based on density perturbation and structure formation theory, we develop an analytic model to trace the evolution of the ionization state in the post-overlap epoch of reionization, in which the bias factor is taken into account. For quasars, we represent an improved luminosity function by utilizing a hybrid approach for the halo formation rate that is in reasonable agreement with the published measurements at 2.≤ z ≤ 6. Comparison with the classic Press-Schechter mass function of dark matter halos, we demonstrate that the biased mass distribution indeed enhances star formation efficiency in the overdense environment by more than 2. per cent following the overlap of ionized bubbles. In addition, an alternative way is introduced to derive robust estimates of the mean free path for ionizing photons. In our model, star-forming galaxies are likely to dominate the ionizing background radiation beyond z = 3, and quasars contribute equally above a redshift of z ～ 2.5. From 5 ≤ z ≤ 6, the lack of evolution in photoionization rate can thus be explained by the relatively flat evolution in star formation efficiency, although the mean free path of ionizing photons increases rapidly. Moreover, in the redshift interval z ～ 2.- 6, the expected mean free path and Gunn-Peterson optical depth obviously evolve by a factor of ～ 500 and ～50 respectively. We find that the relative values of critical overdensities for hydrogen ionization and collapse could be 430% at z ≈2.and 2. at z ≈6, suggesting a rapid overlap process in the overdense regions around instant quasars following reionization. We further illustrate that the absolute estimates of the fraction of neutral hydrogen computed fr

关键词： cosmology theory -- formation galaxies -- quasars general -- diffuse radiation -- intergalactic medium

Representation of microscale ocean wavenumber spectrum correct to the second order

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Science china Earth Sciences 2005年第4期48卷 549-554页

作者： YUAN Yeli2.& HUA Feng1,2.3 1. Institute of Oceanology, chinese Academy of Sciences, Qingdao 2.6071, china 2. Key Laboratory of Marine Science and Numerical Modeling, State Oceanic Administration, Qingdao 2.6061, china 3. graduate School of the chinese Academy of Sciences, beijing 10003., china 1. Key Laboratory of Marine Science and Numerical Modeling State Oceanic Administration 266061 Qingdao China 2. Institute of Oceanology Chinese Academy of Sciences 266071 Qingdao China 3. graduate School of the chinese Academy of Sciences 100039 Beijing China

In this paper, the analytical representations of four wave source functions in high-frequency spectrum range are given on the basis of ocean wave theory and dimensional analysis, and the perturbation method is used to solve the governing equations of ocean wave high-frequency spectrum on the basis of the temporally stationary and locally homogeneous scale relations of microscale wave. The microscale ocean wavenumber spectrum correct to the second order has an explicit structure, its first order part represents the equilibrium between dif- ferent source functions, and its second order part represents the contribution of microscale wave propagation.

关键词： temporally stationary and locally homogeneous, source function in high-frequency spectrum range, microscale ocean wavenumber spectrum.

Assessing the Carrying Capacity of Tourist Resorts: An Application of Tourists’ Spatial Behavior Simulator Based on GIS and Multi-Agent System

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Wuhan university Journal of Natural Sciences 2005年第4期10卷 779-784页

作者： ZHANG Ren-jun 1,2.1. Institute of Mountain Hazards and Environment, chinese Academy of Sciences, Chengdu 610041, Sichuan, china 2. {2.d School of the chinese Academy of Sciences, beijing 10003., china chinese Academy of Sciences Institute of Mountain Hazards and Environment Chengdu Sichuan China (GRID:grid.9227.e) (ISNI:***) graduated School of the chinese Academy of Sciences Beijing China (GRID:grid.9227.e) (ISNI:***)

Based on the study of visitors' individual spatial behaviors, a tourists'spatial behavior simulator (TSBS) to assess the carrying capacity of tourist resorts was developed,TSBS employs GIS (Geographic Information System) to manage the spatial data,and Multi-Agent systemto simulate the actions of individual visitors. By utilizing TSBS, visitors' travel patterns such aslocation, cost, and state can be analyzed and predicted. Based on this analysis and prediction, themodel of assessing the carrying capacity of resorts is built. Our results show that TSBS will be aneffective tool to accurately assess the carrying capacity of tourist resorts.

关键词： tourist resort carrying capacity TSBS GIS Multi-Agent simulator

Photogeneration of the free radicals and singlet oxygen by chrysophanol from rheum

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Science china Chemistry 2004年第5期47卷 381-387页

作者： RAO Jing1,2. XIE Jie1, ZHAO Jingquan1 & ZHU Teng2.1. Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, The chinese Academy of Sciences, beijing 100080,{2. 2. university of Science and Technology beijing, beijing 10083,{2. 1. Key Laboratory of Photochemistry Center for Molecular Science Institute of Chemistry The Chinese Academy of Sciences 100080 Beijing China 2. university of Science and Technology beijing 10083 Beijing China

In the current work, chryosphanol (MHAQ) was isolated and purified from rheum, and the photosensitization activities were studied. In nitrogen-saturated DMSO solution, irradia- tion of chryosphanol (MHAQ) with visible light (>430 nm) produced the semiquinone radical anions (MHAQ??), which was intensified significantly by an electron donor NADH, suggesting electron transfer between the excited and ground state photosensitizer molecules. In an air-saturated DMSO solution, superoxide radical anions (O2.), trapped by DMPO, were detected. ?? It was proved that O2.was not originated from the singlet oxygen (1O2. but dependent on DMPO, ?? chrysophanol, oxygen and the irradiation time. The singlet oxygen and OH could also be pro- ? duced by the photosensitization of the photosensitizer. These suggest that chrysophanol pos- sesses the photosensitization activity via Type I mechanism and Type II mechanism. To evaluate the photosensitization activities of MHAQ, emodin and mixed anthraquinone derivatives ex- tracted from rheum, the relative productivities of O2.were estimated to be 1.8, 1.1 and 1.0 re- ?? spectively and the quantum yields for singlet oxygen to be 0.36, 0.53 and 0.14 respectively. Therefore, these low-cost pigments may be potentially used as phototherapeutic medicine for some kind of vascular diseases or photo-activated pesticides.

关键词： chrysophanol, ESR, semiquinone radical anions, superoxide radical anions, hydroxyl radical, singlet oxygen.