检索结果-南通市图书馆

Preparation of Pt/K_2.a_2.i_3._(10) and its photo-catalytic activity for hydrogen evolution from methanol water solution

在线全文

学校读者我要写书评

暂无评论

Science china Chemistry 2006年第2期49卷 162-168页

作者： CUI Wenquan1,3. LIU Li2. FENG Liangrong1, XU Chenghua1, LI Zijian1, Lü Shaojie1 & QIU Fali1 1. Chengdu Institute of Organic Chemistry, chinese academy of {2., Chengdu 610041, china 2. Chemistry Department, Sichuan University of Science & Engineering, Zigong 643.3., china 3. graduate school of the chinese academy of {2., Beijing 10003., china Correspondence should be addressed to Qiu Fali 1. Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu 610041 China 3. graduate school of the {2. {3. of sciences Beijing 100039 China 2. Chemistry Department Sichuan University of Science & Engineering Zigong 643033 China

A layered perovskite-type oxide K2.a2.i3.10 was prepared with high-temperature solid-state reaction, and characterized with X-ray diffraction (XRD) and ultraviolet-visible diffuse re-flectance spectroscopy (UV-Vis DRS). Platinum was loaded onto K2.a2.i3.10 as a co-catalyst with different methods. The dispersion of platinum on K2.a2.i3.10 was determined with HOT method. The photocatalytic activity of Pt/K2.a2.i3.10 was studied. This catalyst showed much higher activity in hydrogen evolution reaction than Ni/K2.a2.i3.10. The effects of different amounts of loaded platinum and several preparation methods were evaluated. The best achieved hydrogen evolution rate was 2.3.88 μmol·h?1 by Pt(2.)/K2.a2.i3.10. A possible band structure and mechanism were discussed based on the results.

关键词： photocatalysis hydrogen platinum K_2.a_2.i_3._(10) support

Study on growth and properties of novel γ-LiAlO_2.substrate

在线全文

学校读者我要写书评

暂无评论

Science china(Technological sciences) 2006年第2期49卷 188-193页

作者： ZOU Jun1,2. ZHOU Shengming1, XU Jun1 & ZHANG Rong3.1. Shanghai Institute of Optics and Fine Mechanics, chinese academy of {2., Shanghai 2.1800, china 2. graduate school of chinese academy of {2., Beijing 10003., china 3. Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 2.0093. china 1. Shanghai Institute of Optics and Fine Mechanics Chinese Academy of Sciences Shanghai 201800 China 2. graduate school of {2. academy of sciences Beijing 100039 China 3. Laboratory of Solid State Microstructures and Department of Physics Nanjing University Nanjing 210093 China

Transparent γ-LiAlO2.single crystal has been grown by Temperature Gradient technique. The surface of the wafer annealed in O2.atmosphere at 1100°C for 70 h became opaque and Li-poor phase (LiAl5O8); while, that annealed in Li-rich atmosphere kept transparent and smooth. The full-width at half maximum value dropped to 3. arcsecs when the wafer was annealed in Li-rich atmosphere. That annealed in O2.atmosphere increased to 78 arcsec. Compared with absorption spectra, we can conclude that the 196 nm absorption peak was caused by Li vacancies and the 73. nm peak was caused by O vacancies.

关键词： γ-LiAlO2 crystal, scanning electron micrograph (SEM), absorption spectra.

Teleconnection between the Indian summer monsoon onset and the Meiyu over the Yangtze River Valley

在线全文

学校读者我要写书评

暂无评论

Science china Earth sciences 2008年第7期51卷 1021-1035页

作者： LIU YunYun1,2.3.& DING YiHui2.1 chinese {3. of Meteorological {2., Beijing 100081, china 2.National Climate Center, Beijing 100081, china 3.graduate University of chinese {3. of {2., Beijing 100049, china 1. chinese academy of Meteorological {2. Beijing 100081 China 2. National Climate Center Beijing 100081 China 3. graduate University of chinese {2. of {3. Beijing 100049 China

Based on the Indian and chinese precipitation data and the NCEP-NCAR reanalysis circulation data, the relationship between the Indian summer monsoon (ISM) onset and the Meiyu over the Yangtze River Valley has been discussed by the methods of correlation analysis and composite analysis. The results show that the date of ISM onset over Kerala in the southwestern coast of the Indian Peninsula is about two weeks earlier than the beginning of the Meiyu over the Yangtze River Valley. After the outbreak of ISM, the teleconnection mode sets up from the western coast of India via the Bay of Bengal (BOB) to the Yangtze River Valley and southern Japan. It is different both in time and space from the telecon- nection mode which is from the northwest of India via the Tibetan Plateau to northern china. The for- mer mode is defined as the "south" teleconnection of the Asian summer monsoon, forming in the pe- riod of ISM onset; while the latter mode is called the "north" teleconnection, mainly occurring in the Asian monsoon culminant period. During the process of the "south" teleconnection’s formation, the Asian monsoon circulation has experienced a series of important changes: ISM onset, the northward movement of the south Asia high (SAH), the onset vortex occurrence, the eastward extension of the stronger tropical westerly belt, and the northeastward jump of the western Pacific subtropical high (WPSH), etc. Consequently, since ISM sets up over Kerala, the whole Asian continent is covered by the upper SAH after about two weeks, while in the mid- and lower troposphere, a strong wind belt forms from the Arabian Sea via the southern India, BOB and the South china Sea (SCS), then along the western flank of WPSH, to the Yangtze River Valley and southern Japan. With the northward moving of the subtropical jet streams, the upper westerly jet stream and the low level jet have been coupled ver- tically over east Asia, while the Yangtze River Valley happens to locate in the ascending motion

关键词： Indian summer monsoon (ISM) the Meiyu over the Yangtze River Valley teleconnection mode

Mechanism and Defense on Malicious Code

在线全文

学校读者我要写书评

暂无评论

Wuhan University Journal of Natural sciences 2005年第1期10卷 83-88页

作者： WEN Wei-ping 1,2.3. QING Si-han 1,2.3.1. Institute of Software, the chinese {3. of {2., Beijing 100080, china 2.Engineering Research Center for Information Security Technology, the chinese {3. of {2., Beijing 100080, china 3.graduate school of the chinese {3. of {2., Beijing 100080, china Institute of Software the Chinese Academy of Sciences Beijing 100080 China

With the explosive growth of network applications, the threat of the malicious code against network security becomes increasingly serious. In this paper we explore the mechanism of the malicious code by giving an attack model of the malicious code, and discuss the critical techniques of implementation and prevention against the malicious code. The remaining problems and emerging trends in this area are also addressed in the paper.

关键词： malicious code attacking model mechanism defense system security network security

Chronology of Holocene lacustrine sediments in Co Ngoin, central Tibetan Plateau

在线全文

学校读者我要写书评

暂无评论

Science china Earth sciences 2006年第9期49卷 991-1001页

作者： WU Yanhong1, WANG Sumin1& HOU Xinhua1,3.1. Key Laboratory of Lake Sedimentation and Environment, Nanjing Institute of Geography and Limnology, chinese academy of {2., Nanjing 2.0008, china 2. Institute of Tibetan Plateau Research, chinese academy of {2., Beijing 10085, china 3. graduate University of chinese academy of {2., Beijing {12., china 1. Key Laboratory of Lake Sedimentation and Environment Nanjing Institute of Geography and Limnology Chinese Academy of Sciences Nanjing 210008 China 2. Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 10085 China 3. graduate University of chinese {2. of {3. Beijing 100039 China

Chronology is the basis for using lacustrine sediments to reconstruct the history of en-vironmental change. Radioactive-nuclides such as 14C, 2.0Pb and 13.Cs dating are mainly used to establish the chronology for recent several ten thousand years. Because of being mixed with “dead carbon”, the measured 14C age is always older than the actual age which is recognized as “reservoir effect”. Cs is a kind of active metal element, and easy to migrate vertically in the sediment that leads to the error of the time marker. 2.0Pb dating should make sure to select CIC model or CRS model. On the Tibetan Plateau, most of the lakes are alkaline closed lake where Cs is more moveable in the sediment and the reservoir effect caused by “dead carbon” on 14C dating is stronger. Based on the analysis on results of 14C, 2.0Pb and 13.Cs of the lacustrine sediments from Co Ngoin, central Tibetan Plateau, we use the simple regression method to re-calculate the 14C calendar ages, and establish the time sequence for cores CE-1 and CE-2.with result of 2.0Pb CRS model for the upper 3. cm and re-calculated 14C calendar age for sediments bellow 3. cm. Since 1400 cal. a BP, sedimentation inter-rupted for more than 1000 years. According to this time sequence, variations of environmental proxies confidently reflect the major climatic events in Holocene.

关键词： 14C, 2.0Pb and 13.Cs, chronology, lacustrine sediments, climatic event, Co Ngoin, central Tibetan Plateau.

Wet-chemical synthesis and characteristics of Au nanoshell

在线全文

学校读者我要写书评

暂无评论

Science china Chemistry 2005年第5期48卷 431-435页

作者： LIU Zhongxin1,2. SONG Hongwei1, YU Lixin1,2. YANG Linmei1,2.& PAN Guohui1,2.1. Key Laboratory of Excited State Physics, Changchun Institute of Optics, Fine Mechanics and Physics, chinese academy of {2., Changchun 13.03., china 2. graduate school of the chinese academy of sciences, Beijing 10003., china 1. Key Laboratory of Excited State Physics Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences 130033 Changchun China 2. graduate school of the chinese academy of sciences 100039 Beijing China

Gold nanoshells were prepared by an easy wet-chemical method, with Ag nanoparticles used as the templates. Transmission electron microscopy (TEM) indicated that the shells were sphere in shape, the size was homogenous, being about 2. nm, and no hard ag-glomerates were observed. The plasma resonance absorption of gold was tuned from visible to near-infrared (NIR) with the increased volume of HAuCl4. The temperature grads (?T) of the gold nanoshell hydrosol under the exposure of an 808-nm optical fiber laser with different power den-sities were measured. The highest ?T was 3.℃ (5 W/cm2. irradiation area was 2.cm2.. This kind of gold nanoshell hydrosol is a promising material to be used in biomedicine such as photo-thermal cancer therapy, and its special photothermal convert property will photothermally trigger drug release.

关键词： wet-chemical synthesis, Au, nanoshell, NIR absorption, photothermal conversion.

A formal model of fair exchange protocols

在线全文

学校读者我要写书评

暂无评论

Science in china(Series F) 2005年第4期48卷 499-512页

作者： QING Sihan1,2.3.& LI Gaicheng1,2.3.1. Engineering Research Center for Information Security Technology, Institute of Software, chinese Aca- demy of {3., Beijing 100080,{2. 2. Beijing Zhongke Ansheng Corporation of Information Technology, Beijing 100080,{2. 3. graduate school of the chinese academy of {3., Beijing 10003.,{2. 1. Engineering Research Center for Information Security Technology Institute of Software Chinese Academy of Sciences 100080 Beijing China 2. Beijing Zhongke Ansheng Corporation of Information Technology 100080 Beijing China 3. graduate school of the {2. {3. of sciences 100039 Beijing China

Based on the study of existing fair exchange protocols, this paper sets up an accurate formal model by stepwise refinement. In the process of refinement an unreliable channel is employed to simulate an attack behavior. The model provides a novel formal definition of exchanged items, and presents the formal goals for fairness, accountability, etc., reflecting the inherent requirements for fair exchange protocols across-the-board. In order to check, prove, and design fair exchange protocols effectively and efficiently, the model puts forward a novel property of abuse-freeness which applies to all fair exchange protocols, gives a formal definition for trust strand of the third party, and presents general criteria of designing a secure and effective fair exchange protocol. Taking a typical fair exchange protocol as an example, this paper presents the analysis steps of fair exchange protocols appealing to our model. An unknown attack is uncovered. The analysis reveals the process of a complete attack, discovering deeper reasons for causing an attack. Finally, we modify the flawed protocol and the revised protocol ensures the desirable properties.

关键词： events local causal relation local temporal relation global relation exchanged item security goals.

Mass Spectrometric Evidence of Heparin Disaccharides for the Catalytic Characterization of A Novel Endolytic Heparinase

在线全文

学校读者我要写书评

暂无评论

Acta Biochimica et Biophysica Sinica 2004年第12期36卷 840-844页

作者： Yapeng CHAO1,3. Shaoxiang XIONG2. Xiulan CHENG1, and Shijun QIAN1* 1Institute of Microbiology, chinese academy of {2., Beijing 100080, china 2.enter of Mass Spectrometry, Institute of Chemistry, chinese academy of {2., Beijing 100080, china 3.10} school of the chinese academy of {2., Beijing 10003., china Institute of Microbiology Chinese Academy of SciencesBeijing 100080 China graduate school of the {2. {3. of sciencesBeijing 10003. China Center of Mass Spectrometry Institute of Chemistry Chinese Academy of SciencesBeijing 100080 China

Heparinase from different sources can eliminate heparin or/and heparan sulfate into various low-molecular weight heparins with different characteristics. Porcine intestinal mucosa heparin was de- graded into a series of oligosaccharides by a novel heparinase from the species Sphingobacterium. Disaccha- ride components from the digests were separated and purified by ultrafiltration and HPLC. Five major peaks appeared as three types according to their retention time. The mass spectrometry of peak I mainly gave the non-sulfated disaccharide with the mass of 3.9 Da. Peak II and III were indicated as two major monosulfated disaccharides with molecular mass of 417 and 459 Da respectively. Moreover, the peak III represented an N- acetyl disaccharide. Both peak IV and V showed the same mass of 496 Da, hinting that they were disulfate- substituted disaccharides. No trisulfate-substituted disaccharides were detected in the mixture of the heparin digest though they were abundant in the heparin structure. The results revealed that the heparinase might specifically cut the sites with low sulfated domain in heparin.

关键词： electrospray ionization-mass spectrometry heparin disaccharides heparinase high perfor- mance liquid chromatography Sphingobacterium sp.

Preparation and characterization of a novel adsorbent for removing lipophilic organic from water

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science china Chemistry 2005年第6期48卷 600-604页

作者： LIU Huijuan1, DAI Ruihua1, QU Jiuhui1 & RU Jia1,2.1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental sciences, chinese {2. of sciences, Beijing 100085, china 2. graduate school of the chinese academy of sciences, Beijing 10003., china 1. State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences 100085 Beijing China 2. graduate school of the chinese academy of sciences 100039 Beijing China

A novel composite adsorbent containing a kind of lipid-triolein is studied. The ad-sorbent is prepared by embedding triolein into cellulose acetate (CA) sphere. The preparation method, the physical-chemical properties of the adsorbent and the removal efficiency of two or-ganochlorinated pesticides are studied. The adsorbent is stable in water and no triolein leaks into water for 465 h soaking. The adsorbent has high adsorption capacity for organochlorinated pes-ticides such as dieldrin and aldrin. The results suggest that triolein-containing adsorbent could serve as a good adsorbent for lipophilic organic pollutants. The adsorption rate for lipophilic pol-lutants is very fast and has relation with the logKow of the compounds.

关键词： triolein, cellulose acetate, adsorbent, lipophilic organic, drinking water.