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Isotopic feature and uranium dating of the volcanic rocks in the Okinawa Trough

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中国科学：地球科学英文版 2006年第4期49卷 375-383页

作者： HUANG Peng1,2. LI Anchun1, HU Ningjing2.3. FU Yongtao1& MA Zhibang4 1. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 2.6071,{3. 2. graduate {2. of the Chinese Academy of Sciences, beijing 10003.,{3. 3. Institute of Soil Science, Chinese Academy of Sciences, Nanjing 2.0008,{3. 4. Institute of Geology and Geophysics, Chinese Academy of Sciences, beijing 10002.,{3. Institute of Oceanology Chinese Academy of Sciences Qingdao China graduate school of the Chinese Academy of Sciences Beijing China Institute of Soil Science Chinese Academy of Sciences Nanjing China Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

Volcanic rocks from the northern and middle Okinawa Trough were dated by ura- nium-series dating method. Differential fractions using magnetic procedure were designed to separate samples. New report on the ages and isotopic data of rocks in the northern trough (especially black pumice) was discussed. Based on the uranium dates and Sr-Nd isotopic ratio, magmatic evolution process of the Okinawa Trough was noted. Firstly, there have been wide silicic volcanic activities in the Okinawa Trough from late Pleistocene to present, and the volcanic rocks can be divided into three subgroups. Secondly, magma generally came from PREMA source area under the Okinawa Trough. Magmatic evolution in the northern trough was similar to the middle, but different to the south. Finally, volcanic activities indicated that opening of the southern Okinawa Trough did not happen due to the collision between Luson Arc and Eurasian Plate until the early Pleistocene.

关键词： Okinawa Trough, black pumice, uranium-series dating, Sr-Nd isotopic ratio, magmatic evolution.

Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

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Science china Chemistry 2006年第4期49卷 363-370页

作者： LI Xiaobin1,2. CAO Hongbin1 & ZHANG Yi1 1. Institute of Process Engineering, Chinese Academy of Sciences, beijing 100080, china 2. {2. school of the Chinese Academy of Sciences, beijing 10003., china Institute of Process Engineering Chinese Academy of Sciences Beijing China graduate school of the Chinese Academy of Sciences Beijing China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3.65), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 45.0 kg/m3.to 2..4 kg/m3.with the increase of water level from 3.pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1 μm to 3.6 μm with the increase of water level from 3.pph to 7 pph, respectively. At the same time, poorer dimen- sional stability was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.

A NOTE ON THE CONSISTENCY OF LS ESTIMATES IN LINEAR MODELS

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Chinese Annals of Mathematics,Series B 2001年第4期22卷 471-474页

作者： CHEN XIRU The graduate school at {2., University of Science and Technology of{3., beijing 10003.,{3.. The graduate school at {2. University of Science and Technology of China Beijing 100039 China

It is well known that when the random errors are iid. with finite variance, the week and the strong consiStency of LS estimate of multiple regression coefficients are equivalent. This note, by constructing a counter-example, shows that this equivalence no longer holds true in case that the random errors possess only the r-th moment with 1≤5 T ＜ 2.

关键词： Linear regression model Consistency LS estimate

Analysis and Modeling on the Spatial Structure of Urban Land Use: A Case of Jinan, china

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Chinese Journal of Population,Resources and Environment 2007年第2期5卷 34-40页

作者： Zhao Huixia1, 3. Zhang Zulu2. Jiang Luguang 1 1. Institute of Geographical Sciences and Natural Resources Research, Chinese Academy of Sciences, beijing 100101, china 2. College of Population, Resources and Environment, Shandong Normal University, Jinan Shandong 2.0014, china 3. graduate school of the Chinese Academy of Sciences, beijing 10003., china Institute of Geographical Sciences and Natural Resources Research Chinese Academy of Sciences Beijing 100101 China graduate school of the Chinese Academy of Sciences Beijing 100039 China College of Population Resources and Environment Shandong Normal University Jinan Shandong 250014 China

Based on the data of urban land use obtained by remote sensing interpretation from aero images in 1986 and 2.04, the spatial structure of Jinan is studied in this paper with the method of Geographic Information System (GIS). According to the proportion of land for residence, industry and commerce, the urban district can be distinguished into three rings. Compared with the traditional theory of the ring structure in Western coun- tries, they have many distinctive characteristics. The main func- tions of the inner ring include residence, business and banking, but the proportion of residential land (more than 50%) is considerably higher than that of the cities in Western countries. The land proportion for residence and industry in the intermediate ring is equal on the whole. The main land of the outside ring is for industrial use. From 1986 to 2.04, great changes have taken place on the land proportion of different types of use. In the inner ring, the land for residential and industrial use has shrunk much while the land for commercial use has increased. In the intermediate ring, the changes of the three types of land use were not very much and the temporal variation was relatively stable. On the contrary, the structure in the outside ring varies acutely. Though most of it is also for industrial use, the proportion of residential land has in- creased much. The three rings can also be divided into several sectors respectively, according to the function of land use clusters. New trends and mechanisms of the changes of land use impacting the urban structure were proposed in the end of the paper.

关键词： urban land use ring structure sector structure Jinan

Wet-chemical synthesis and characteristics of Au nanoshell

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Science china Chemistry 2005年第5期48卷 431-435页

作者： LIU Zhongxin1,2. SONG Hongwei1, YU Lixin1,2. YANG Linmei1,2.& PAN Guohui1,2.1. Key Laboratory of Excited State Physics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 13.03., china 2. graduate {2. of the Chinese Academy of Sciences, beijing 10003., china Key Laboratory of Excited State Physics Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences Changchun China graduate school of the Chinese Academy of Sciences Beijing China

Gold nanoshells were prepared by an easy wet-chemical method, with Ag nanoparticles used as the templates. Transmission electron microscopy (TEM) indicated that the shells were sphere in shape, the size was homogenous, being about 2. nm, and no hard ag-glomerates were observed. The plasma resonance absorption of gold was tuned from visible to near-infrared (NIR) with the increased volume of HAuCl4. The temperature grads (?T) of the gold nanoshell hydrosol under the exposure of an 808-nm optical fiber laser with different power den-sities were measured. The highest ?T was 3.℃ (5 W/cm2. irradiation area was 2.cm2.. This kind of gold nanoshell hydrosol is a promising material to be used in biomedicine such as photo-thermal cancer therapy, and its special photothermal convert property will photothermally trigger drug release.

关键词： wet-chemical synthesis, Au, nanoshell, NIR absorption, photothermal conversion.

Discovery of Cu-Zn,Cu-Sn intermetallic minerals and its significance for genesis of the Mianning-Dechang REE Metallogenic Belt,Sichuan Province,china

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Science china Earth Sciences 2006年第6期49卷 597-603页

作者： XIE Yuling1, HOU Zengqian2. XU Jiuhua1, YUAN Zhongxin2. BAI Ge2.& LI Xiaoyu3.1. Civil and Environmental Engineering {3., University of Science and Technology beijing, beijing 100083. china 2. Institute of Geology, Chinese Academy of Geological Sciences, beijing 10003., china 3. The 109th Geological Team, Sichuan Bureau of Mineral Exploration, Chengdu 610100, china Civil and Environmental Engineering school University of Science and Technology Beijing Beijing China Institute of Geology Chinese Academy of Geological Sciences Beijing China The 109th Geological Team Sichuan Bureau of Mineral Exploration Chengdu China

Mianning-Dechang Himalayan REE Metallogenetic Belt in Sichuan Province lies along the western margin of the Yangtze Craton. We have conducted detailed mineralogical studies on ore minerals collected from Maoniuping and Dalucao, the two largest deposits in the belt. With optical microscope, SEM/EDS, and EPMA, three rare intermetallic minerals, i.e., zinccopperite (Cu2.n), Sn- bearing native copper, and Cu-bearing jupiter were found to occur in the main ore along with barite, fluorite, apatite, sulfide and bastnaesite. Since the conditions under which zinccopperite and Sn- bearing native copper formed are quite unique, finding of these minerals, for the first time in domestic REE deposits, has significant implications for the genesis of the ore deposits in which they occur. In comparison with Cu-Zn intermetallic minerals in other occurrences, we propose that the formation of this REE metallogenetic belt is associated with fast upwelling of the Himalayan magma from deep source.

关键词： Mianning-Dechang REE metallogenetic belt, Cu-bearing intermetallic minerals, EPMA, genesis significance, deep source magmatic activity.

Re-Os(ICP-MS)dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

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Science china Earth Sciences 2005年第10期48卷 1672-1677页

作者： YANG Gang1,2. DU Andao1, LU Jiren3. QU Wenjun1 & CHEN Jiangfeng2.1. National Research Center of Geoanalysis, beijing 10003.,{3. 2. Laboratory for Earth Material Cycling, {2. of Earth and Space Sciences, University of Science and Technology of{3., Hefei 2.002.,{3. 3. Institute of Mineral Resource, Chinese Academy of Geological Sciences, beijing 10003.,{3. National Research Center of Geoanalysis University of Science and Technology of china Chinese Academy of Geological Sciences

Massive sulfide ore from the Jinchuan Ni-Cu-PGE deposit was dated by Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measurement. An isochron giving an age of 83. ± 3. Ma, initial 187Os/188Os ratio of 0.2.9 ± 0.018 (MSWD = 1.7) and γOs = 13. ± 15 is obtained. The Re-Os age obtained agrees, within analytical uncertainties, with previous SHRIMP zircon U-Pb age of 82. ± 8 Ma (n=5, MSWD = 4.3.. The result suggests that the deposit was formed at Neoproterozoic and that the formation of the Jinchuan Ni-Cu-PGE sulfide deposit may be closely related to the plume activity, which were attributed to the breakup of the Rodinia supercontinent. The high γOs of the massive ores sug-gests that crustal material was involved in the formation of the Jinchuan deposit, however, the quantity of the added crustal material is less than 10%.

关键词： Jinchuan Ni-Cu-PGE deposit, Re-Os dating, ICP-MS.

Estimating surface evapotranspiration using combined MODIS and CBERS-02.data

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Science china(Technological Sciences) 2005年第S2期48卷 145-160页

作者： XIN Xiaozhou1,2. LIU Qinhuo1, TANG Yong1,3. TIAN Guoliang1, GU Xingfa1, LI Xiaowen1,2. ZHENG Hongsheng4 & CHEN Jiayi4 1. State Key Laboratory of Remote Sensing Science, Institute of Remote Sensing Applications, Chinese Academy of Sciences, beijing 100101,{3. 2. Research Center for Remote Sensing and GIS, Department of Geography, beijing Normal University, beijing 100875,{3. 3. graduate University of Chinese Academy of Sciences, beijing 10003.,{3. 4. Department of Atmospheric Physics, Peking University, beijing 100871,{3. State Key Laboratory of Remote Sensing Science Institute of Remote Sensing Applications Chinese Academy of Sciences Beijing 100101 China Research Center for Remote Sensing and GIS Department of Geography Beijing Normal University Beijing 100875 China graduate University Chinese Academy of Sciences Beijing 100039 China Department of Atmospheric Physics Peking University Beijing 100871 China

Spatial scale error is one of the most serious problems in the estimates of land surface heat fluxes of sensible and latent from satellite-borne data such as MODIS 1km resolution reflectance and emissive data. One of the feasible and economic ways to decrease the spatial scale error is to use high resolution land use class data together with the MODIS data. CBERS-02.data were used to produce land use class of Baiyangdian area, Hebei Province, china in the autumn of 2.04. The area ratio of each class in MODIS pixel was calculated, and used to derive the heat fluxes of the mixed pixel. The results showed that the estimated heat fluxes of soil, sensible and latent have been changed remarkably after using the high resolution land class data. It could be concluded from the comparison between simulated and ground-measured fluxes as well as the theoretical analysis that high resolution land class data are useful to diminishing the scale error of heat fluxes estimated from low resolution satellite data.

关键词： surface evapotranspiration spatial scale error MODIS CBERS land class.

Preparation and characterization of a novel adsorbent for removing lipophilic organic from water

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Science china Chemistry 2005年第6期48卷 600-604页

作者： LIU Huijuan1, DAI Ruihua1, QU Jiuhui1 & RU Jia1,2.1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, beijing 100085, china 2. {2. school of the Chinese Academy of Sciences, beijing 10003., china State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing China graduate school of the Chinese Academy of Sciences Beijing China

A novel composite adsorbent containing a kind of lipid-triolein is studied. The ad-sorbent is prepared by embedding triolein into cellulose acetate (CA) sphere. The preparation method, the physical-chemical properties of the adsorbent and the removal efficiency of two or-ganochlorinated pesticides are studied. The adsorbent is stable in water and no triolein leaks into water for 465 h soaking. The adsorbent has high adsorption capacity for organochlorinated pes-ticides such as dieldrin and aldrin. The results suggest that triolein-containing adsorbent could serve as a good adsorbent for lipophilic organic pollutants. The adsorption rate for lipophilic pol-lutants is very fast and has relation with the logKow of the compounds.

关键词： triolein, cellulose acetate, adsorbent, lipophilic organic, drinking water.