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chinese Chemical Letters 2005年第4期16卷 468-470页

作者： Chao CHE, Zhong Ning ZHANG StateKey Laboratory IntegratedManagementofInsectsandRodents,Institute of Zoology, chinese academy of sciences, beijing 100080{2. school of the chinese academy of sciences, beijing 100039 StateKey Laboratory ofIntegratedManagementofInsectsandRodents Institute of ZoologyChinese Academy of Sciences graduate school of the{2.

Total synthesis of (3Z, 6Z, 9S, 10R)-9, 10-epoxy-3, 6-heneicosadiene, sex pheromone component of Hyphantria cunea (Drug), was achieved using Sharpless AE kinetic resolution and alkylative epoxide rearrangement as ke... 详细信息

关键词： Sex pheromone Hyphantria cunea (Drug) Sharpless kinetic resolution asymmeric synthesis.

Microcosmic analysis of ductile shearing zones of coal seams of brittle deformation domain in superficial lithosphere

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Science China Earth sciences 2004年第5期47卷 393-404页

作者： JU Yiwen1,2. WANG Guiliang2. JIANG Bo2.& HOU Quanlin1 1. graduate school,{2., beijing 100039, China 2. College of Mineral Resources and Geosciences, China University of Mining & Technology, Xuzhou 2.1008, China chinese Acad Sci Grad Sch Beijing 100039 Peoples R China China Univ Min & Technol Coll Mineral Resources & Geosci Xuzhou 221008 Peoples R China

The ductile shearing zones of coal seams in a brittle deformation domain in super-ficial lithosphere are put forward based on the study on bedding shearing and ductile rheology of coal seams. The macrocosmic and microcosmic characteristics include wrinkle fold, mymonitized zones and ductile planar structure of coal seams, etc., while the microcosmic characteristics may also include different optic-axis fabrics and the anisotropy of vitrinite reflectance as well as the change of chemical structure and organic geochemistry components. The forming mechanism is analyzed and the strain environment of ductile shearing zones of coal seams discussed. The result indicates that, in the superficial brittle deformation domain, the coal seams are easy to be deformed, resulting in not only brittle deformation but also ductile shearing deformation under the action of force. Because of simple shearing stress, the interlayer gliding or ductile rheology may take place between coal seams and wall rocks. Therefore, many ductile shearing zones come into being in superficial lithosphere (<5 km). The research on ductile shearing zone of brittle de-formation domain in superficial lithosphere is significant not only theoretically for the study of ductile shearing and ductile rheology of the lithosphere but also practically for the structural movement of coal seams, the formation and accumulation of coal-bed methane, and the preven-tion and harness of gas burst in coal mine.

关键词： brittle deformation domain, interlayer gliding, ductile rheology, ductile shearing zones of coal seams, coal mymonite, vitrinite reflectance anisotropy.

Teleconnection between the Indian summer monsoon onset and the Meiyu over the Yangtze River Valley

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Science China Earth sciences 2008年第7期51卷 1021-1035页

作者： LIU YunYun1,2.3 & DING YiHui2.1 chinese academy of Meteorological{2., beijing 100081, China 2.National Climate Center, beijing 100081, China 3 graduate University of chinese academy of sciences, beijing 100049, China 1. chinese academy of Meteorological{2. Beijing 100081 China 2. National Climate Center Beijing 100081 China 3. graduate University of chinese academy of sciences Beijing 100049 China

Based on the Indian and chinese precipitation data and the NCEP-NCAR reanalysis circulation data, the relationship between the Indian summer monsoon (ISM) onset and the Meiyu over the Yangtze River Valley has been discussed by the methods of correlation analysis and composite analysis. The results show that the date of ISM onset over Kerala in the southwestern coast of the Indian Peninsula is about two weeks earlier than the beginning of the Meiyu over the Yangtze River Valley. After the outbreak of ISM, the teleconnection mode sets up from the western coast of India via the Bay of Bengal (BOB) to the Yangtze River Valley and southern Japan. It is different both in time and space from the telecon- nection mode which is from the northwest of India via the Tibetan Plateau to northern China. The for- mer mode is defined as the "south" teleconnection of the Asian summer monsoon, forming in the pe- riod of ISM onset; while the latter mode is called the "north" teleconnection, mainly occurring in the Asian monsoon culminant period. During the process of the "south" teleconnection’s formation, the Asian monsoon circulation has experienced a series of important changes: ISM onset, the northward movement of the south Asia high (SAH), the onset vortex occurrence, the eastward extension of the stronger tropical westerly belt, and the northeastward jump of the western Pacific subtropical high (WPSH), etc. Consequently, since ISM sets up over Kerala, the whole Asian continent is covered by the upper SAH after about two weeks, while in the mid- and lower troposphere, a strong wind belt forms from the Arabian Sea via the southern India, BOB and the South China Sea (SCS), then along the western flank of WPSH, to the Yangtze River Valley and southern Japan. With the northward moving of the subtropical jet streams, the upper westerly jet stream and the low level jet have been coupled ver- tically over east Asia, while the Yangtze River Valley happens to locate in the ascending motion

关键词： Indian summer monsoon (ISM) the Meiyu over the Yangtze River Valley teleconnection mode

Compositions of heavy minerals in Northeastern China sandlands and provenance analysis

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Science China Earth sciences 2007年第11期50卷 1715-1723页

作者： XIE Jing1,2.& DING ZhongLi1 1 Institute of Geology and Geophysics, chinese academy of sciences, beijing 10002., China 2.2. University of chinese academy of sciences, beijing 100049, China 1. Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China 2. graduate University of chinese academy of sciences Beijing 100049 China

Sand samples deposited since the Last Glacial Maximum (LGM) from the Hulun Buir, Horqin and Otin-dag sandlands were measured for their assemblages of heavy minerals and chemical compositions of detrital garnets and tourmalines. Heavy mineral assemblages of these three sandlands consist mainly of garnet, ilmenite, epidote and minor amphibole and magnetite. Garnets consist mainly of high Mg type-A ones (58% on average), and minor type-B ones. Toumalines are mainly composed of Mg-rich and minor Fe-rich ones. Compared with those of central-southern Mongolia and central Tarim, these three sandlands are derived from the Phanerozoic rocks of the Central Asian Orogenic Belt and the Archean and Paleoprotorozoic basement rocks of the North China Craton. Our results provide direct evidence that the present-day sands may be reworked from LGM ones. Differences of heavy mineral composi-tions occur between the samples of the three sandlands and Taklimakan Desert, indicating that the material of the western arid regions contributes little to the eastern sandlands.

关键词： heavy minerals,provenance,Northeastern China,garnet,tourmaline

Temporal-spatial variations of euphotic depth of typical lake regions in Lake Taihu and its ecological environmental significance

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Science China Earth sciences 2006年第4期49卷 431-442页

作者： ZHANG Yunlin1, 2. QIN Boqiang1, HU Weiping1, WANG Sumin1, CHEN Yuwei1 & CHEN Weimin1 1. Nanjing Institute of Geography & Limnology, chinese academy of sciences, Nanjing 2.0008, China 2. graduate school of the chinese academy of sciences, beijing 100039, China 1. Nanjing Institute of Geography & Limnology Chinese Academy of Sciences Nanjing 210008 China 2. graduate school of the chinese academy of sciences Beijing 100039 China

By using the data of underwater irradiance measured in the different lakeregions of Lake Taihu during 1998—2.04 and total suspended solids (TSS), wind speeds of the total13 stations in typical lake regions during 1993—2.03, this paper analyzes the factors ofinfluencing on PAR (pho-tosynthetically available radiation) attenuation, euphotic depth, andpresents the temporal and spatial variations of euphotic depth of typical lake regions in LakeTaihu, and the spectral distributions of euphotic depth at station 2. The results show that theconcentration of TSS is the most important factor impacting PAR attenuation, followed by chlorophylla; chromophoric dissolved organic matter (CDOM) has little impact on the PAR euphotic depth. During1993—2.03, the mean yearly PAR euphotic depths of the typical lake regions ranged from 1.04 to1.95 m with a mean value of 1.35±0.2. m. The PAR euphotic depth fell into 3 spatial zone types:Type Ⅰ, the lowest, including the lake center and the inflows of rivers; Type Ⅱ, intermediate,including Meiliang Bay, Wulihu Lake and Gonghu Bay; Type Ⅲ, the greatest, including the East LakeTaihu; corresponding mean depths were approximately 1.1, 1.4, 2.0 m, respectively. The seasonalvariations of euphotic depths were not quite the same in different lake regions. In the lake center,the mean values of PAR euphotic depth in summer and autumn were significantly greater than those inwinter and spring; in the Meiliang Bay, winter means were significantly greater than in the otherthree seasons; in the East Lake Taihu, winter means were significantly less than in the other threeseasons. However, no distinct seasonal change was recorded in the Wulihu Lake, Gonghu Bay and theinflows of rivers. The spectral distributions of euphotic depth present a minimal value at the bluelight wave band of 400 nm, and a peak at the green light wave band of around 580 nm. In 1998 and1999, based on the seasonal many-day continuous measurements, the PAR euphotic depths at station 2.

关键词： lake taihu euphotic depth diffuse attenuation coefficient total suspendedsolid ecological

SHRIMP zircon U-Pb geochronology of early Mesozoic felsic igneous rocks from the southern Lancangjiang and its tectonic implications

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Science China Earth sciences 2006年第10期49卷 1032-1042页

作者： PENG Touping1,2. WANG Yuejun1, FAN Weiming1, LIU Dunyi3, SHI Yuruo3 & MIAO Laicheng4 1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou Institute of Geochemistry, chinese academy of sciences, Guangzhou 510640, China 2. graduate University of chinese academy of sciences, beijing 100039, China 3. SHRIMP isotope Laboratory, chinese academy of Geological sciences, beijing 100037, China 4. Institute of Geology and Geophysics, chinese academy of sciences, beijing 10002., China Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China graduate University of chinese academy of sciences Beijing China SHRIMP isotope Laboratory Chinese Academy of Geological Sciences Beijing China Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

The SHRIMP zircon U-Pb geochronology of three typical samples, including two monzo nitic granites from the Lincang batholith and a rhyolite from the Manghuai Formation are presented in the southern Lancangjiang, western Yunnan Province. The analyses of zircons for the biotite monzonitic granites from the northern (02.X-137) and southern (2.JH-10) Lincang batholith show the single and tight clusters on the concordia, and yield the weighted mean 2.6Pb/2.8U ages of 2.9.4 ± 3.0 Ma and 2.0.4 ± 3.6 Ma, respectively, representing the crystallized ages of these granites. The zircons for the rhyolitic sample (02.X-95) from the Manghuai Formation give a weighted mean 2.6Pb/2.8U age of 2.1.0 ± 5.0 Ma. These data suggest that the igneous rocks from the Lincang granitic batholith and Manghuai Formation have a similar crystallized age. In combination with other data, it is inferred that both were generated at a narrow age span (~2.0 Ma) and were originated from the postcollisional tectonic regime. An early Proterozoic 2.6Pb/2.8U apparent age of 1977±44 Ma is additionally obtained from one zircon from the biotite monzonitic granite (southern Lincang batholith), indicative of devel- opment of the early Proterozoic Yangtze basement in the region. These precisely geochronological data provide important constraints on better understanding the Paleozoic tectonic evolution of the Tethys, western Yunnan Province.

关键词： SHRIMP zircon U-Pb dating, Middle Triassic, Lincang granitic batholith, Manghuai Formation rhyolite, southern Lancangjiang.

Isotopic feature and uranium dating of the volcanic rocks in the Okinawa Trough

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中国科学：地球科学英文版 2006年第4期49卷 375-383页

作者： HUANG Peng1,2. LI Anchun1, HU Ningjing2.3, FU Yongtao1& MA Zhibang4 1. Institute of Oceanology, chinese academy of sciences, Qingdao 2.6071, China 2. graduate school of the chinese academy of sciences, beijing 100039, China 3. Institute of Soil Science, chinese academy of sciences, Nanjing 2.0008, China 4. Institute of Geology and Geophysics, chinese academy of sciences, beijing 10002., China 1. Institute of Oceanology Chinese Academy of Sciences Qingdao 266071 China 2. graduate school of the chinese academy of sciences Beijing 100039 China 3. Institute of Soil Science Chinese Academy of Sciences Nanjing 210008 China 4. Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China

Volcanic rocks from the northern and middle Okinawa Trough were dated by ura- nium-series dating method. Differential fractions using magnetic procedure were designed to separate samples. New report on the ages and isotopic data of rocks in the northern trough (especially black pumice) was discussed. Based on the uranium dates and Sr-Nd isotopic ratio, magmatic evolution process of the Okinawa Trough was noted. Firstly, there have been wide silicic volcanic activities in the Okinawa Trough from late Pleistocene to present, and the volcanic rocks can be divided into three subgroups. Secondly, magma generally came from PREMA source area under the Okinawa Trough. Magmatic evolution in the northern trough was similar to the middle, but different to the south. Finally, volcanic activities indicated that opening of the southern Okinawa Trough did not happen due to the collision between Luson Arc and Eurasian Plate until the early Pleistocene.

关键词： Okinawa Trough, black pumice, uranium-series dating, Sr-Nd isotopic ratio, magmatic evolution.

Strong decays of N~*(1535) in an extended chiral quark model

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Science China(Physics,Mechanics & Astronomy) 2009年第10期52卷 1452-1457页

作者： AN ChunSheng1,2.3 & ZOU BingSong1,2.3 1 Institute of High Energy Physics,chinese academy of{2.,beijing 100049,China 2.Theoretical Physics Center for Science Facilities,chinese academy of{2.,beijing 100049,China 3 graduate University of chinese academy of sciences,beijing 100049,China Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China Theoretical Physics Center for Science Facilities Chinese Academy of Sciences Beijing 100049 China graduate University of chinese academy of sciences Beijing 100049 China

The strong decays of the N*(1535) resonance are investigated in an extended chiral quark model by including the low-lying $ qqqq\bar q $ components in addition to the qqq component. The results show that these five-quark components in N*(1535) contribute significantly to the N*(1535) → Nπ and N*(1535) → Nη decays. The contributions to the Nη decay come from both the lowest energy and the next-tolowest energy five-quarks components, while the contributions to the Nπ decay come from only the latter one. Taking these contributions into account, the description for the strong decays of N*(1535) is improved, especially for the puzzling large ratio of the decays to Nη and Nπ.

关键词： N*(1535) strong decays five-quark components

One-dimensional unsteady general solution for Wang bioheat transfer equation with heat source proportional to temperature

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Progress in Natural Science:Materials International 2006年第7期16卷 766-768页

作者： GOU Chenhua and CAI Ruixian ( Institute of Engineering Thermophysics, chinese academy of sciences, beijing 100080, China {2. school, chinese academy of sciences, beijing 100080, China) [a]Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing China [b]graduate school Chinese Academy of Sciences Beijing China

An analytical general solution is derived for the non-Fourier Wang bioheat transfer model with special internal heat production. It is valuable for finding the special solutions with specified conditions and for expanding the understanding of the non-Fourier heat conduction phenomena in living tissues, for example, the controversial temperature fluctuation effects. This analytical solution can also be used as the benchmark solution to check the numerical calculations and to develop various numerical computational approaches. Because there is an arbitrary function in the expression of internal heat production, this solution can actually be applied to many types of internal heat production distributions.

关键词： bioheat transfer model non-fourier effect analytical solution

Transient species and its properties of melatonin

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Science China Chemistry 2006年第4期49卷 308-314页

作者： ZHU Hongping1,2. ZHANG Zhaoxia1,2. ZHAO Hongwei1, WANG Wenfeng1 & YAO Side1 1. Shanghai Institute of Applied Physics, chinese academy of sciences, Shanghai 2.1800, China 2. graduate University of the chinese academy of sciences, beijing 100049, China 1. Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201800 China 2. graduate University of the chinese academy of sciences Beijing 100049 China

The photo-physical and photo-chemical properties of melatonin (ML) werestudied by 2.6 nm laser flash photolysis (LFP). ML undergoes photo-ionization to produce radicalcation of ML (ML^(·+))and hydrated electrons (e_(aq)^-), while excited triplet state ~3ML~* is alsoformed during photolysis. The oxidation via one electron transfer from ML to SO_4^(·+) and thetriplet state of riboflavin (~3RF~*) has been also investigated and the rate constants for theprocess have been determined to be 8.0x10^9 and 1.4x10^9 L·mol^(-1)·s^(-1) respectively. Theradical cation of 2.2.'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS^(·+)) scavengingcapacities of melatonin and other antioxidants are compared in this paper.

关键词： melatonin, laser flash photolysis, photoionization, triplet state.