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Effects of Ca substitution and surface treatment on electrochemical performances of Ml_(1.0-x) Ca_xNi_(4.0) Co_(0.6) Al_(0.4) hydrogen storage alloy electrodes

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中国有色金属学会会刊：英文版 1999年第3期9卷 487-492页

作者： Chen Weixiang(陈卫祥) 1, Qi Jianqin(祁建琴) 1, Chen Changpin(陈长聘) 2.1. department of physics 2. department of Materials Science and Engineering, Zhejiang university, Hangzhou 31002., P. R. china 浙江大学物理系浙江杭州浙江大学材料科学与工程系浙江杭州

The influences of Ca substitution for Ml and surface treatment on electrochemical performances of Ml 1.0- x Ca x Ni 4.0 Co 0.6 Al 0.4 hydrogen storage alloy electrode were investigated. Ca substitution with x 2.for Ml could improve its discharge capacity, but Ca substitution with x >0.2.could decrease the capacity. It was also found that Ca substitution deteriorates the electrocatalytic activity, high rate dischargeability and cycling durability of the alloy electrode. In order to improve these properties of Ml 1.0- x Ca x Ni 4.0 Co 0.6 Al 0.4 alloy electrode, the alloy was treated in 6 mol/L KOH+0.02.mol/L KBH 4 solution. The results showed that the surface treatment improves the electrochemical performances such as the electrocatalytic activity, high rate dischargeability and cycling durability of the alloy electrode. :The influences of Ca substitution for Ml and surface treatment on electrochemical performances of Ml 1.0- x Ca x Ni 4.0 Co 0.6 Al 0.4 hydrogen storage alloy electrode were investigated. Ca substitution with x 2.for Ml could improve its discharge capacity, but Ca substitution with x >0.2.could decrease the capacity. It was also found that Ca substitution deteriorates the electrocatalytic activity, high rate dischargeability and cycling durability of the alloy electrode. In order to improve these properties of Ml 1.0- x Ca x Ni 4.0 Co 0.6 Al 0.4 alloy electrode, the alloy was treated in 6 mol/L KOH+0.02.mol/L KBH 4 solution. The results showed that the surface treatment improves the electrochemical performances such as the electrocatalytic activity, high rate dischargeability and cycling durability of the alloy electrode.

关键词： hydrogen storage alloy electrode Ca substitution surface modification

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Constraints on Cardassian universe from Gamma ray bursts

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Science china(physics,Mechanics & Astronomy) 2010年第9期53卷 1720-1725页

作者： WANG TaiShan1 & LIANG Nan2.1 department of physics & Center for Astrophysics,Tsinghua university,Beijing 100084,china 2.department of Astronomy,Beijing normal university,Beijing 100875,china Tsinghua university Department of Physics &amp Center for Astrophysics Beijing China (GRID:grid.12527.33) (ISNI:***) Beijing normal university Department of Astronomy Beijing China (GRID:grid.20513.35) (ISNI:***)

Constraints on the original Cardassian model and the modified polytropic Cardassian model are examined from the recently derived 42.gamma-ray bursts(GRBs) data calibrated with the method that can avoid the circularity *** results show that GRBs can be an optional observation to constrain the Cardassian *** the GRBs data with the newly de-rived size of baryonic acoustic oscillation peak from the Sloan Digital Sky Survey(SDSS),and the position of the first acoustic peak of the Cosmic Microwave Background radiation(CMB) from Wilkinson Microwave Anisotropy Probe(WMAP),we find Ωm0=0.2.+0.02.0.02.n=0.06+0.07-0.08(1σ) for the original Cardassian model,and Ωm0=0.2.+0.2.-0.02.n=-0.09+0.2.-1.91,β=0.82.2.10-0.62.1σ) for the modified polytropic Cardassian model.

关键词： Cardassian Gamma ray burst Cosmic Microwave Background baryonic acoustic oscillation

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Studies on the microstructure,optical and electrical properties of organic microcavity devices based on a porous silicon reflector

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Science china(Technological Sciences) 2005年第2期48卷 191-201页

作者： XIONG Zuhong1, FAN Yongliang2. ZHAN Yiqiang2. ZHANG Songtao2. DING Xunmin2.& HOU Xiaoyuan2.1. School of physics, Southwest china-{2. university, Chongqing 400715, china 2. Surface physics Laboratory (National Key Laboratory), Fudan university, Shanghai 2.0433, china Surface physics Laboratory (National Key Laboratory) Fudan University

A novel type of microcavity organic light-emitting diode based on a porous silicon distributed Bragg reflector (PS-DBR) has first been achieved and its microstructure, optical, and electrical properties have also been investigated in detail. The microcavity is made up of the central active organic multilayer sandwiched between a top silver film and a bottom PS-DBR, formed by electrochemical etching of p++-Si substrate. The field- emission scanning electron microscopy cross-section images show the nanometer-scale layered structure and flat interfaces inside the microcavity. The reflectivity (relative to an Al mirror) of the PS-DBR is up to 99%, and the stopband is about 160 nm wide. Resonant cavity mode appears as a tip in the reflectivity spectrum of the Si-based organic multilayer films, which is a symbol that the Si-based organic multilayer structure is indeed a microcavity. The peak widths of the electroluminescence (EL) spectra from the cavities emitting green and red light are greatly reduced from 85 nm and 70 nm to 8 nm and 12.nm, respectively, as compared with those measured from non-cavity structures. Note that the EL emission from the cavity devices is single-mode, and the off-resonant optical modes are highly suppressed. Moreover, increases of a factor of about 6 and 4 of the resonant peak intensity from the cavities emitting green and red light are also observed, respectively. In addition, the current-brightness-voltage characteristics and effect parameters on the lifetime of the cavity devices are also discussed. The present technique for obtaining enhanced EL emission from Si-based organic microcavity may also be another novel effective method for realizing Si-based optoelectronics device integration.

关键词： electrochemical etching, Si-based microcavity, electroluminescence, organic light-emitting diodes.

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Molecular modeling and spectroscopic studies on the binding of guaiacol to human immunoglobulin

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Science china Chemistry 2006年第6期49卷 550-559页

作者： HE Wenying1,2. YAO Xiaojun1, LIU Pengjun2. GAO Zhenxia2.& HU Zhide1 1. department of Chemistry, Lanzhou university, Lanzhou 730000,{2. 2. department of Chemistry, Hainan normal university, Hainan 571158,{2. department of Chemistry Lanzhou University Lanzhou China department of Chemistry Hainan Normal University Hainan China

The fluorogenic property of guaiacol was exploited for the first time to analyze the interaction with target protein as a probe by molecular modeling, fluorescence, circular dichroism (CD) and Fourier transform infrared (FT-IR) spectroscopy. Molecular docking was performed to reveal the possible binding mode or mechanism and suggested that guaiacol can strongly bind to human immu- noglobulin (HIgG). It is considered that guaiacol binds to HIgG mainly by a hydrophobic interaction and there are two hydrogen bond interactions between the drug and the residues LEU 80 and ASP 65, which is in good agreement with the results from the experimental thermodynamic parameters (the enthalpy change △H0 and the entropy change △S0 were calculated to be 65.55 kJ·mol-1 and 132.95 J·mol-1·K-1 according to the Vant’ Hoff equation). Data obtained by the fluorescence spectroscopy indicated that binding of guaiacol with HIgG leads to dramatic enhancement in the fluorescence emission intensity along with significant occurrence of efficient Frster resonance energy transfer (FRET) from the residue of HIgG to the protein bound guaiacol. From the low value of fluorescence anisotropy (r = 0.06), it is argued that the probe molecule is located in the motionally unrestricted environment of the protein. The alterations of protein’s secondary structure in the presence of guaiacol in aqueous solution were quantitatively calculated by the evidences from FT-IR and CD spectroscopes.

关键词： guaiacol, human immunoglobulin, molecular modeling, fluorescence enhancement, Fourier transform infrared (FT-IR) spectroscopy, circular dichroism (CD).

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Joint density of hitting time and point to an ellipse for Brownian motion

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Chinese Science Bulletin 1997年第24期42卷 2054-2058页

作者： YIN Chuancun ZHAO Xuelei department of Mathematics, Qufu normal {2., Qufu 2.3165, china 2. Institute of Mathematics, Shantou {2., Shantou 515063, china department of Mathematics Qufu Normal University Qufu 273165 China

IT is well known that the distribution of hitting time, hitting point, last exiting time, and lastexiting point for Brownian motion to balls has been extensively studied. A similar investi-gation of rectangles or cubes has also been well done. However, analogous questions for Brow-nian motion to ellipsoid are rarely concerned. Bai and Cai obtained the distribution of

关键词： Brownian motion hitting time hitting point ellipse.

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Two-dimensional simulation of Poiseuille-Rayleigh-Bénard flows in binary fluids with Soret effect

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Progress in Natural Science:Materials International 2007年第12期17卷 1389-1396页

作者： Hu Jun1 and Yin Xieyuan2.1. Institute of Applied physics and Computational Mathematics, Beijing 100088, china 2. {2. of Modern Mechanics, university of Science and Technology of china, Hefei 2.002., china) Institute of Applied physics and Computational Mathematics Beijing 100088 China department of Modern Mechanics University of Science and Technology of China Hefei 230027 China

Poiseuille-Rayleigh-Bénard flows in binary fluids with Soret effect are directly simulated by a mixed finite element method. A temperature perturbation is used as an initial disturbed source for the basic parallel flows. The whole spatio-temporal evolution of the binary fluid flows is exhibited: initially only the disturbed mode with the wavenumber k=π is amplified while others are damped, and continuously the amplified mode grows further and the nonlinear effect becomes important; after a nonlinear evolution transition the flow system evolves finally into a periodic right traveling wave.

关键词： Poiseuille-Rayleigh-Bénard flow Soret effect through-flow.

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Mathematical stencil and its application in finite difference approximation to the Poisson equation

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Science china Mathematics 2005年第10期48卷 1421-1429页

作者： FENG Hui~1 ZHANG Baolin~(1,2. & LIU Yang~1 1. department of Mathematics,Wuhan university,Wuhan 430072.{2. 2. Laboratory of Computational physics,Institute of Applied physics and Computational Mathematics,Beijing 100088. china department of Mathematics Wuhan University Wuhan China Laboratory of Computational physics Institute of Applied Physics and Computational Mathematics Beijing China

The concept of mathematical stencil and the strategy of stencil elimination for solving the finite difference equation is presented, and then a new type of the iteration algorithm is established for the Poisson equation. The new algorithm has not only the obvious property of parallelism, but also faster convergence rate than that of the classical Jacobi iteration. Numerical experiments show that the time for the new algorithm is less than that of Jacobi and Gauss-Seidel methods to obtain the same precision, and the computational velocity increases obviously when the new iterative method, instead of Jacobi method, is applied to polish operation in multi-grid method, furthermore, the polynomial acceleration method is still applicable to the new iterative method.

关键词： mathematical stencil, stencil elimination, Poisson equation, finite difference, iterative algorithm,parallelism.

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Dimension and measure theoretic entropy of a subshift in symbolic space

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Chinese Science Bulletin 1997年第14期42卷 1193-1196页

作者： CHEN Ercai and XIONG Jincheng1. department of Astronomy, Nanjing university, Nangjing 2.0093,{2. 2. department of Mathematics, South{2. normal university, Guangzhou 510631,{2. department of Astronomy Nanjing University Nangjing China department of Mathematics South China Normal University Guangzhou China

1 Definitions and resultsWITH the development of the theory of dynamical systems and fractal geometry, one provedthat symbolic dynamics is a powerful tool to study chaos and fractals. It is useful to study thefractal characteristics of symbolic dynamics. In the present note we shall point out the relationbetween the dimension and measure theoretic entropy of any subshift in symbolic space. Weprove here that the Bowen’s formula for Hausdorff dimension holds without Markov struc-ture. A variational principle for dimension is obtained.

关键词： symbolic space subshift measure theoretic entropy dimension.

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Effects of enhancing p2.^(waf1) on proliferation and expression of G1 cyclins and CDKs in human breast cancer cells

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Chinese Science Bulletin 1999年第16期44卷 1489-1493页

作者： SANG Jianli, WANG Yongchao and YE Yingjiang1. Laboratory of Cell Biology , department of Biology , Beijing normal {2. , Beijing 100875 , china 2. The Second Hospital, Beijing Medical {2., Beijing 100044, china Laboratory of Cell Biology Department of Biology Beging Normal University Beijing China The Second Hospital Beijing Medical University Beijing China

The cyclin-dependent kinase inhibitor p2.( waf1/cip1/sdi1) is an important negative regulator in control of cell cycle. Its functions of inhibiting cancer cell growth and its effects on expression of Gl phase cyclins and related CDKs are a worthy topic for study. The plasmid expressing p2. with high level was transformed to human breast cancer cells, and the expression of p2. in cells was enhanced, then the cell growth rate, anchorage-independent growth and tu-morigenecity were tested, at the same time the expression levels of cyclinD1, CDK4,

关键词： p2.waf1 breast cancer cell cyclin CDK.

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A new definition of restricted Lie superalgebras

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Chinese Science Bulletin 2000年第4期45卷 316-321页

作者： WANG Ying & ZHANG Yongzheng1. department of Mathematics, Harbin Institute Technology, Harbin 150001, china 2. department of Mathematics, Northeast normal university, Changchun 13002., china department of Mathematics Harbin Institute Technology Harbin China department of Mathematics Northeast Normal University Changchun China

A new definition of restricted Lie superalgebras has been given; some important results on the representation theory of restricted Lie superalgebra have been obtained.

关键词： restricted Lie superalgebra p-mapping p-semilinear mapping α-representation.

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