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Variation of the Fe/Mn ratio of ferromanganese crusts from the Central North Pacific: implication for paleoclimate changes

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Progress in Natural Science:Materials International 2005年第6期15卷 530-537页

作者： LU Zunli1**, LING Hongfei1*, ZHOU Feng1, JIANG Shaoyong1, CHEN Xiaoming1 and ZHOU Huaiyang2.1. State Key Laboratory for Mineral Deposits Research, department of earth {2., Nanjing university, Nanjing 2.0093, China 2. guangzhou Institute of Geochemistry, Chinese Academy of {2., guangzhou 510640, China)department of earth & Environmental Science, university of Rochester State Key Laboratory for Mineral Deposits Research Department of Earth Sciences Nanjing University Nanjing 210093 China guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China

Contents of Fe, Mn and other elements in four ferromanganese crusts recovered from the central North Pacific are analyzed at high depth-resolution by electron microprobe for reconstructing factors controlling their deposition. Manganese (IV) in hydrogenetic ferromanganese crusts is mainly supplied as colloidal precipitates from the Oxygen Minimum Zone (OMZ), which concentrates high amounts of dissolved Mn (II). The iron is derived from carbonate dissolution and silicate particles of eolian dust. An increase in paleoproductivity during cooler climate would potentially lead to a decrease in Mn deposition due to enlargement of the OMZ which has a “temporary storage” effect for Mn. On the other hand, not affected by the OMZ, the iron entering the Fe-Mn crust would likely increase with the eolian dust input and surface productivity at glacial stages. As a result, the increasing Fe/Mn ratio should indicate a cooling climate. This is supported by the following observations. In the profile of the past 1 Ma, the variations of Fe/Mn ratio coincide with benthic oxygen isotope fluctuation in glacial-interglacial cycles. Three episodes with high Fe/Mn ratios, approximately at 2.6, 1.8 and 0.8 Ma, are detected within the past 3 Ma and coincide with major climate transitions and cooling events. The secular evolution pattern of Fe/Mn ratio in the Cenozoic is similar to the Pb isotope evolution which is mainly controlled by eolian dust and related to climate. The Fe/Mn evolution pattern is also broadly consistent with the global deep-sea oxygen isotope records. Therefore, Fe/Mn ratio recorded in the ferromanganese crusts may be a new proxy for climate change.

关键词： Fe/Mn ratio ferromanganese crust central North Pacific paleoclimate.

Effect of an impurity on 3-electron quantum dots in magnetic fields

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Science China(Physics,Mechanics & Astronomy) 2004年第5期47卷 521-530页

作者： LIU Yimin1,2. HUANG Gangming1 & BAO Chengguang1 1. department of Physics, zhongshan university,{2., China 2. department of Physics, Shaoguan university, Shaoguan 512.05, China department of Physics Zhongshan University Guangzhou China department of Physics Shaoguan University Shaoguan China

The ground-state property of a 2.dimensional 3-electron quantum dot (QD) subjected to an external magnetic fieldB and affected by an impurity is studied. The impurity is located at thez-axis by a distanced from the plane of the dot. The evolution of the angular momentumL o and the spinS o of the ground state in accordance withB andd has been calculated, and the results are summarized and plotted in a (L o,S o) diagram. The spatial distribution of the electrons (the size and the geometric features) and the optical absorption have also been investigated. The (L o S o) diagram indicates thatL o andS o may jump whend and/orB vary. It was found that, due to the constraints arising from symmetry, each symmetric geometry is accessible only to a specific group of states having specificL o andS o.

关键词： quantum dot, ground state, charged impurity, magnetic field.

Discovery of Permian island-arc basalts in the Cenxi area and the tectonic significance──A piece of evidence for the paleo-Tethyan tectonic belt in western Guangdong and eastern Guangxi

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Chinese Science Bulletin 1998年第21期43卷 1838-1842页

作者： ZHANG Boyou 1, ZHAO Zhenhua 1, SHI Manquan 1, YANG Shufeng 2.and CHEN Hanlin 2.1. guangzhou Institute of Geochemistry, Chinese Academy of sciences, guangzhou 510640, China 2. department of earth sciences, Zhejiang university, Hangzhou 31002., China guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China department of earth {2. Zhejiang University Hangzhou China

Cenxi Permian basalts are the late Palaeozoic island-arc type basalts first found in South China. REE and trace element characteristics and distribution patterns show that this volcanic formation, which has been isotopically dated at 2.1 MaB.P. by the 39Ar/ 40Ar method, is of an active continental marginal island arc type, and that the tectonic environment at that time was an island-arc marginal sea or minor ocean basin related with the paleo-Tethyan tectonic belt in western Guangdong-eastern Guangxi.

关键词： spilite-keratophyre pillow lava Permian continental margin paleo-Tethyan evolution.

The microbial metallogeny of weathering crust REE deposits in South China

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Chinese Science Bulletin 1999年第S2期44卷 71-73页

作者： CHEN Binghui~(1,2., WANG Zhimei~3, HUANG Limei~3, WU Fuhai~3, CHEN Jingde~2.and XU Wenlie~2.1. department of earth {2., Nanjing university, Nanjing 2.0093, China 2. department of earth sciences, zhongshan university, guangzhou 5102.5, China 3. Guangdong Pharmaceutical College, guangzhou 5102.4, China department of earth {2. Nanjing University Nanjing 210093 China department of earth {2. Zhongshan University Guangzhou 510275 China Guangdong Pharmaceutical College Guangzhou 510244 China

VERY little is known about the roles of microorganisms in the metallogeny of weathering crust REE deposits, although there has been much literature on REE behavior in weathering conditions. The present note deals with the microorganisms in 4 weathering profiles of an REE deposit and their roles in migration and accumulation of REE in weathering conditions. 1 Cultivation and identification of microorganisms Under strict sterilization, samples were collected from various parts of 4 weathering profiles of granites in a weathering crust REE deposit in South China. The samples were then cultivated for microorganisms with ordinary agars as culture media and then the cultivated microorganisms were dyed and identifiedunder a microscope. The sampled positions and cultivated numbers of microbial colonies are shown

关键词： microbial metallogeny weathering crust REE deposit South China.

Geochemical constraints from hydrothermal fluid inclusions of altered deformation zone type Au(Ag)deposits in Yunkai area, South China

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Chinese Science Bulletin 1999年第S2期44卷 230-232页

作者： WANG Zuwei~1, ZHANG Haihua~2. YAO Dongliang~2.and ZHOU Yongzhang~3 1. department of Geography, Tianjin Normal university, Tianjin 300071, China 2. {2. Institute of Geochemistry, Chinese Academy of sciences, {2. 510640, China 3. department of earth sciences, zhongshan university, guangzhou 5102.5, China eeszhou@*** department of Geography Tianjin Normal University Tianjin 300071 China guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China department of earth {2. Zhongshan University Guangzhou 510275 China

THE altered deformation zone type Au (Ag) deposits share an important part from the precious metallicore deposits in the Yunkai area, South China. Their formation is a history of poly-stage evolution. Pre- liminary source strata, Calidoniam metamorphism, Indosinian-Yanshanian ductile shear deformation andassociated hydrotheraml alteration all play certain roles in the history. This note discusses the geochemical conditional of the hydrothermal fluids during mineralization. Two representative ore deposits, the Pangxidong Ag(Au) deposit and Hetai Au deposits are selectedfor this study. They are hosted in altered ductile shear zones. Wall-rock hydrothermal alteration is bothspatially and temporally associated with the development of the ductile shear system. Silicification occurred throughout the whole alteration process. There are three groups of quartz: thepredeformational quartz, the early stage hydrothermal quartz, and the late stage hydrothermal quartz asso-

关键词： precious metallic deposit fluid inclusions mineralizing fluid South China.

Some properties on multivariate filter banks with a matrix factorization

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Progress in Natural Science:Materials International 2005年第2期15卷 20-30页

作者： LIAN Qiaofang1, XIAO Hongying2. and CHEN Qiuhui3(1. department of Mathematics, Beijing Jiaotong university, Beijing 100044, China 2. Institute of Mathematics, Academy of Mathematics and System {2., Chinese Academy of {2., Beijing 100080, China 3. department of Scientific Computing and Computer Applications, zhongshan university, guangzhou 5102.5, China) Dept. of Mathematics Beijing Jiaotong Univ. Beijing 100044 China Inst. of Mathematics Acad. of Math. and System Sci. Chinese Acad. of Sciences Beijing 100080 China Dept. of Scientific Computing Zhongshan Univ. Guangzhou 510275 China

A class of multivariate filter banks with a matrix factorization has been developed by Chen et al. The main purpose of this paper is to discuss some further properties of this kind of filter bank, such as the completeness, accuracy of the corresponding scaling functions and the relationships with Daubechies' wavelets and the multi-wavelets provided by Chui and Lian. Moreover, some examples are given to show that this kind of filter bank has a higher accuracy for the scaling functions.

关键词： filter banks completeness accuracy matrix factorization

Geochemical behavior of elements at fossil sea floor water/sediment interface

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Chinese Science Bulletin 1999年第S2期44卷 232-233页

作者： ZHANG Haihua~1, XIA Yu~1, WANG Zuwei~2.and ZHOU Yongzhang~3 1. guangzhou Institute of Geochemistry, Chinese Academy of Science, guangzhou 510640, China 2. {2. of Geography, Tianjin Normal university, Tianjin 300071, China 3. {2. of earth sciences, zhongshan university, guangzhou 5102.5, China guangzhou Institute of Geochemistry Chinese Academy of Science Guangzhou 510640 China department of Geography Tianjin Normal University Tianjin 300071 China department of earth {2. Zhongshan University Guangzhou 510275 China

THIS note deals with the geochemical behavior of elements near the water/sediment interface of a fossil seafloor. The Nandan-Hechi basin, located in northwest Guangxi, Southern China, is selected for exemplified study. It is an elongated basin, and developed on a Caledonian basement. Its Devonian strata hosthydrtothermally sedimentary formations, and are typical of the intra-platformal basin facies sediments oversouthern China. A steady sedimentary sequence may be observed, commonly going from carboniferouspelite at bottom, upward through bedded chert, thickly banded argillaceous limestone, thinly bandedsiliceous limestone and small lensiod argillaceous limestone in the middle, to coarse lensoid siliceousand/or argillaceous limestone at the top. The chert and some argillaceous limestone are related to hydrothermally sedimentary origin. The present study focuses on the lensoid argillaceous limestone formation. This formation contains the following characteristic sedimentary structures: small lensoid structure,vermiform structure, wave-shaped banded structure, massive structure, white framboid structure, andcage netting structure.

关键词： water/sediment interface sedimentation periodicity sedimentary geochemistry basin.

Eclogites in the interior of the Tibetan Plateau and their geodynamic implications

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Chinese Science Bulletin 2009年第15期54卷 2556-2567页

作者： ZHANG KaiJun1,2.& TANG XianChun2.3 1 department of earth {2., Nanjing university, Nanjing 2.0093, China 2.guangzhou Institute of Geochemistry, Chinese Academy of {2., guangzhou 510640, China 3 Graduate university of Chinese Academy of {2., Beijing 100049, China department of earth {2. Nanjing University Nanjing China guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Graduate university of Chinese Academy of sciences Beijing China

Eclogites have been recently reported in the interior of the Tibetan Plateau, including in the central Qiangtang metamorphic belt, in the Basu metamorphic massif of the eastern Bangong-Nujiang suture zone, and at Songdo and Pengco in the eastern Lhasa terrane. Some typical ultrahigh-pressure (UHP) metamorphic phenomena, e.g., garnet exsolution from clinopyroxene, were documented in the Basu and Pengco eclogites. The UHP metamorphism in the interior of the Tibetan Plateau marked by these eclogites generally took place in the Early Mesozoic. Along with exhumation of these eclogites, (post-) collision-related magmatism extensively occurred around the central Qiangtang belt, the eastern Ban-gong-Nujiang suture zone, and the eastern Lhasa terrane. The occurrence of these Early Mesozoic ec-logites manifests an out-of-sequence evolution of the Tethys, and they could be a product of diachro-nous collision between the eastern Qiangtang terrane and the irregular continental margin of the united western Qiangtang-Lhasa plate, along the linked eastern Bangong-Nujiang-central Qiangtang zone. The collision-related magmatic rocks could have been originated from lithospheric thickening, melting, or detachment due to the collision. The presence of UHP metamorphic rocks in central Qiangtang and Basu implies likely continental deep-subduction, and the denudation of these two metamorphic zones could have served as the source of the Triassic turbidites in the Songpan-Garzê complex and the Ju-rassic turbidites in the western Bangong-Nujiang zone, respectively. However, studies of the eclogites in the interior of the Tibetan Plateau just began, and many principal aspects still remain to be explored, such as their distributions, typical lithologies and minerals, temperature-pressure conditions, timing of formation and exhumation, protoliths and tectonic setting, and relationship with the evolution of the Tethys and large-scale basins in Tibet.

关键词：地球动力学意义青藏高原榴辉岩

Exploring effective policies for underground water management in artificial oasis: a system dynamics analysis of a case study of Yaoba Oasis

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Journal of Environmental sciences 2001年第4期13卷 476-480页

作者： XU Hong gang (earth and Environment School, zhongshan university, {2. 65002.. ) 中山大学广东 650021

The development of oasis along the edge of the Tengerli Desert, where underground water is available, is one of the major strategies to reallocate 'ecological refuges' from their seriously degraded grasslands to agriculturally cultivable land. Yet, underground water resources, the major constraint, hate not been fully integrated in the development process. Therefore, the decline of water resources and deterioration of water quality caused by over-consumption of water resources has begun to hinder further development and has even fed to the abandonment of some oasis. A system dynamics modeling approach is applied to analyze the water use and water management structures in Yaoba Oasis as a case study. The study attempts to identify the characteristics of major feedback loops, which dominate the over-use of underground water resources leading to the deterioration of water resources in quantity and quality.

关键词： system dynamics delay underground water management oasis feedback analysis