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I-V and C-V properties of TiO_2.thin film by pulsed-laser reactive deposition

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Chinese Science Bulletin 1998年第16期43卷 1344-1349页

作者： FU Zhengwen 1, ZHOU Mingfei 1, ZHANG Shengkun 2.CHEN Lianyao 2.and QIN Qizong 1 1. Laser Chemistry Institute, Fudan University, Shanghai 2.0433, china 2. department of physics, Fudan University, Shanghai 2.0433, china Laser Chemistry Institute Fudan University Shanghai China department of Pnysics Fudan University Shanghai China

TiO-2.thin films have bee deposited on p-Si(111) substrates by pulsed-laser ablation of metallic Ti target in the O-3 ambient. The current-voltage and capacitance-voltage of the Al/TiO-2.Si capacitors are measured. The results show that the dielectric constant of thin film after being annealed at 700℃ is found to be 46, and the border trap density and the interface state density at the TiO-2.p-Si interface are 1.8×10 12.cm -2.and 2.10 12.eV -1·cm -2. respectively. The conduction mechanisms of as-deposited films are also discussed.

关键词： TiO-2 dielectric properties electrical properties pulsed-laser deposition.

The dynamical properties of Rydberg hydrogen atom near a metal surface

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Science china(physics,Mechanics & Astronomy) 2005年第6期48卷 667-675页

作者： GE Meihua1, ZHANG Yanhui1, WANG Dehua2. DU Mengli3 & LIN Shenglu1 1. college of physics and Electronics, Shandong Normal University, Jinan 2.0014,{2. 2. department of Mathematics and physics, Shandong Institute of Architecture and Engineering, Jinan 2.0014,{2. 3. Institute of Theoretical physics, Chinese Academy of Sciences, Beijing 100080,{2. college of physics and Electronics Shandong Normal University Jinan China department of Mathematics and physics Shandong Institute of Architecture and Engineering Jinan China Institute of Theoretical physics Chinese Academy of Sciences Beijing China

The dynamical properties of Rydberg hydrogen atom near a metal surface are presented by using the methods of phase space analysis and closed orbit theory. Transforming the coordinates of the Hamiltonian, we find that the phase space of the system is divided into vibrational and rotational region. Both the Poincaré surface of section and the closed orbit theory verify the same conclusion clearly. In this paper we choose the atomic principal quantum number as n = 2.. The dynamical character of the exited hydrogen atom depends sensitively on the atom-surface distance d. When d is sufficiently large, the atom-surface potential can be expressed by the traditional van der Waals force and the system is integrable. When d becomes smaller, there exists a critical value dc. For d > dc, the system is near-integrable and the motion is regular. While chaotic motion appears for d < dc, and the system tends to be non-integrable. The trajectories become unstable and the electron might be captured onto the metal surface.

关键词： Rydberg hydrogen atom, van der Waals interaction, Poincaré surface of section, closed orbit theory, chaos.

TFEL of Ce^(3+) in zine sulpho-oxide

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Chinese Science Bulletin 1998年第14期43卷 1179-1183页

作者： YU Lei\+1, LOU Zhidong\+1, XU Chunxiang\+1, XU Zheng\+2.and XU Xurong\+2.1. Institute of Material physics, Tianjin Institute of Technology, Tianjin 300191, china {2., Northern Jiaotong University, Beijing 100044, china Institute of Material physics Tianjin Institute of Technology Tianjin China department of physics Northern Jiaotong University Beijing China

A new TFEL material ZnS X O 1-X : Ce 3+ is prepared. The EL brightness of ZnS X O 1-X : Ce 3+ is at least one order higher than that of ZnS: Ce 3+ at the same doping concentration of Ce 3+ . The EL emission wavelength of ZnS X O 1-X : Ce 3+ (\%X\%=0.5) ranges from 400 to 600 nm. The emission of ZnS X O 1-X : Ce 3+ may be used as the blue part of white TFEL.

关键词： thin_film electroluminescence (TFEL) filter layered optimization zine sulpho_oxide.

The refined theory of deep rectangular beams based on general solutions of elasticity

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Science china(physics,Mechanics & Astronomy) 2006年第3期49卷 291-303页

作者： GAO Yang1 & WANG Minzhong2.1. college of Science, china Agricultural University, Beijing 100083, china 2. State Key Laboratory for Turbulence and Complex Systems and department of Mechanics and Engi- neering Science, Peking University, Beijing 100871, china college of Science China Agricultural University Beijing China State Key Laboratory for Turbulence and Complex Systems and department of Mechanics and Engineering Science Peking University Beijing China

The problem of deducing one-dimensional theory from two-dimensional the- ory for a homogeneous isotropic beam is investigated. Based on elasticity theory, the re- fined theory of rectangular beams is derived by using Papkovich-Neuber solution and Lur’e method without ad hoc assumptions. It is shown that the displacements and stresses of the beam can be represented by the angle of rotation and the deflection of the neutral surface. Based on the refined beam theory, the exact equations for the beam without transverse surface loadings are derived and consist of two governing differential equations: the fourth-order equation and the transcendental equation. The approximate equations for the beam under transverse loadings are derived directly from the refined beam theory and are almost the same as the governing equations of Timoshenko beam theory. In two ex- amples, it is shown that the new theory provides better results than Levinson’s beam the- ory when compared with those obtained from the linear theory of elasticity.

关键词： deep rectangular beams,the refined theory,Papkovich-Neuber solution,Lur'e method,governing equation

Preparation and Characterization of Chitosan/Carboxymethylated Konjac Glucomannan Blend Films

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Wuhan University Journal of Natural Sciences 2002年第1期7卷 107-112页

作者： Zheng Hua 1 , Du Yu-min 2.1. department of Chemical Engineering, Wuhan University of Technology, Wuhan 430070, Hubei, china 2. {2. of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072. Hubei, china department of Chemical Engineering Wuhan University of Technology Wuhan Hubei China college of Chemistry and Molecular Sciences Wuhan University Wuhan Hubei China

In order to improve the mechanical and water swelling properties of the chitosan (CS) film, a series of transparent films were prepared by blending 2.(weight) chitosan acetic acid solution with 1.5%(weight) carboxymethylated konjac glucomannan (CMKGM) aqueous solution according to predetermined ratio and drying at 30°C. The morphological structure, miscibility, thermal stability, mechanical properies, and swelling capacity of the blend films were studied by infrared (IR), X-ray diffraction (XRD), differential thermal analysis (DTA), scanning electron micrograph (SEM), and measurements of the mechanical properties and swelling properties. The results demonstrated that there was strong interaction and good miscibility between CS and CMKGM resulted from intermolecular hydrogen bonding and electrostatic force. The mechanical properties in dry state and wet state, thermostability, and water swelling properties of the blend films were obviously improved. The best values of the tensile strength in the dry and wet state achieved 89 MPa and 49 MPa, respectively, when the CMKGM content was 30%(weight). The CS/ CMKGM blend films provided promising biomedical applications.

关键词： Key words chitosan carboxymethylated konjac glucomannan blend films structure characterization

Utilization of a spiropyran derivative in a polymeric film optode for selective fluorescent sensing of zinc ion

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Science china Chemistry 2006年第3期49卷 246-255页

作者： ZHANG Ying1, SHAO Na1, YANG Ronghua1, LI Ke’an1, LIU Feng1, CHAN Winghong2.& MO Tian2.1. college of Chemistry and Molecular Engineering, Peking University, Beijing 100871, china 2. {2. of Chemistry, Hong Kong Baptist University, Hong Kong, china college of Chemistry and Molecular Engineering Peking University Beijing China department of Chemistry Hong Kong Baptist University Hong Kong China

A new spiropyran derivative was synthesized and first utilized in a polymericfilm-based optical sensor for zinc ion. Spiropyrans, combining the characteristics of metal bindingand signal transduction, show potential function in the design of optical chemical sensors(optodes) toward metal ions. When embedded in a plasticized poly (vinyl chloride) (PVC) membrane,the newly synthesized spiropyran derivative 1 exhibits obvious fluorescence enhancement at 630 nm inthe presence of zinc ion in aqueous solution. With the optimum condition described, the optodemembrane responds to zinc ion over a dynamic range of 4.94x10^(-7) to 4.15x10^(-4)mol·L^(-1), witha detection limit of 1.51x10^(-7) mol·L^(-1). The membrane not only displays excellentphotostability, reproducibility and reversibility, but also exhibits high selectivity toward zincion over transition metal ions including Hg^(2.), Cd^(2.), Pb^(2.), Cu^(2.), Fe^(3+) and commoncationic ions presented in the physiological fluids.

关键词： spiropyran, sensor, PVC membrane, zinc ion, fluorescent spectroscopy.

The refined theory of transversely isotropic piezoelectric rectangular beams

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Science china(physics,Mechanics & Astronomy) 2006年第4期49卷 473-486页

The problem of deducing one-dimensional theory from two-dimensional theory for a transversely isotropic piezoelectric rectangular beam is investigated. Based on the piezoelasticity theory, the refined theory of piezoelectric beams is derived by using the general solution of transversely isotropic piezoelasticity and Lur'e method without ad hoc assumptions. Based on the refined theory of piezoelectric beams, the exact equations for the beams without transverse surface loadings are derived, which consist of two governing differential equations: the fourth-order equation and the transcendental equation. The approximate equations for the beams under transverse loadings are derived directly from the refined beam theory. As a special case, the governing differential equations for transversely isotropic elastic beams are obtained from the corresponding equations of piezoelectric beams. To illustrate the application of the beam theory developed, a uniformly loaded and simply supported piezoelectric beam is examined.

关键词： rectangular beams, the refined theory, piezoelectric, transversely isotropic.

Transitional function of DG to CA3 in the hippocampus

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Progress in Natural Science:Materials International 2007年第12期17卷 1436-1444页

作者： Yan Chuankui1 and Liu Shenquan2.1. department of Mathematics, Hangzhou Normal University, Hangzhou 310036, china 2. department of Applied Mathematics, School of Mathematical Sciences, South china University of Technology, Guangzhou 510640, china) department of Mathematics Hangzhou Normal University Hangzhou 310036 China department of Applied Mathematics School of Mathematical Sciences South China University of Technology Guangzhou 510640 China

Using single cell channel model, the transmission features of CA3-DG network in the hippocampus are investigated. The influence of the stimulation on discharge pattern of pyramidal neurons is analyzed, which shows that it starts with period spiking discharges, followed by period-doubling bifurcation to chaos, and period 3 discharge evolving into chaos, and ultimately a period of bursting discharges. By the synaptic model, the CA3-DG network model is constructed, which analyzes the summation of postsynaptic currents in the network, the influence of postsynaptic current on discharge rhythm as well as the mechanism of bursting discharges. The strong capacity of spatiotemporal encoding in the network indicates the features of CA3 network during the information transmission process in the hippocampus. The modeling result with time delay of the synaptic transmission is in accordance with the experimental phenomena of action potential in the hippocampus.

关键词： hippocampus CA3-DG period-doubling bifurcation chaos.

Lipschitz continuity of best approximations and Chebyshev centers

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Chinese Science Bulletin 1998年第3期43卷 185-188页

作者： LI Chong 1 and WANG Xinghua 2.1. Center for Mathematical Sciences, Zhejiang University, Hangzhou 31002., china 2. department of Mathematics, Hangzhou University, Hangzhou 31002., china Center for Mathematical Sciences Zhejiang University Hangzhou China department of Mathematics Hangzhou University Hangzhou China

The Lipschitz continuity results are given for best approximations and Chebyshev centers. Consequently, the open problem presented by Septycki and Vleck is solved completely.

关键词： best approximation Chebyshev center uniform convexity.