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Study on the two and three-parameter working stability regions of 3.-TZP suspension

Science China(Technological Sciences) 2006年第5期49卷 547-568页

作者： CHEN Youqiang1, 2. ZHANG Xinni3. CHEN Sha’ou3.& QI Ping3.1. department of chemistry, Qingdao {2., Qingdao 2.6071, China 2. department of chemistry, tsinghua university, beijing 100084, China 3. department of Physics, Qingdao {2., Qingdao 2.6071, China department of chemistry Qingdao University Qingdao China department of chemistry Tsinghua University Beijing China department of Physics Qingdao University Qingdao China

We determined the variation tendency of viscosity (η) at various solids load- ing (α) for 3.-TZP suspension as a function of dispersant concentration (Cw) using vis- cosity measurement, measured the diameter of particles as a function of Cw in very dilute suspension using light scattering method, and obtained the surface features of the sedi- ment of suspension with different Cw using SEM. We also discussed the influence of the microstructure of adsorbed polymer layers on particles and their interactions in the dis- persing medium on the stability of suspension. Then two different stable states and two different unstable states for 3.-TZP suspension were given. Accordingly, the (Cw, η), (Cw, α), and (α, η) two-parameter, and (Cw, α, η) three-parameter stability maps were con- structed. Based on the DLVO theory calculations, the dispersant concentration, particle distance (r), and interparticle potential energy (VT) maps with various solids loading for 3.-TZP aqueous suspension were also constructed. In (Cw, r) two-parameter coordinate system, the stable motion region map for particles was established. The Cw, α, and VT,max (the highest potential energy) surface of the potential barrier map was obtained through calculation and simulation on the basis of the surfaces of Cw, r, VT maps introduced above. The (Cw, α) two-parameter stability map was then obtained from the Cw, α, VT,max map. The results showed that this theoretical map can qualitatively prove the experimentally obtained results—the existence of different dispersed states of particles in suspension system and the variation tendency of suspension stability with changing each parame- ter—were reasonable.

关键词： 3.-TZP, suspension, stability, DLVO theory, interparticle potential energy.

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A MESSAGE-DRIVING FORMALISM FOR MODELING AND SIMULATION OF MULTI-AGENT SUPPLY CHAIN SYSTEMS

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Journal of Systems Science and Systems Engineering 2011年第4期20卷 385-399页

作者： Wenzhe TAN1 Yueting CHAI2.Yi LIU3.1department of Automation, tsinghua university, {2., {3., China 2.0} of Automation, tsinghua university, {2., {3., China 3.1} of Automation, tsinghua university, {2., {3., China department of Automation Tsinghua University Beijing China

To acquire a competitive advantage in the expanding market, manufacturing enterprises should be able to manage their supply chains as effectively as possible. It is now becoming popular to model supply chains as multi-agent systems and use discrete event simulation to learn more about their behaviors or investigate the implications of alternative configurations. In order to enhance the computational efficiency and keep the simulation credibility, this paper proposes a message-driving formalism for the simulation of multi-agent supply chain systems. Through the message-driving formalism, the problem of shared variables is addressed and the parallel operation of agents is implemented. Simulation experiments with a prototype implementation show that the message-driving formalism is able to provide credible results in significantly less simulation time.

关键词： Supply chain multi-agent system modeling and simulation parallel discrete event simulation message-driving formalism

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Surface effects of monolayer-protected gold nanoparticles on the redox reactions between ferricyanide and thiosulfate

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Science China chemistry 2005年第5期48卷 424-430页

作者： LI Di1, SUN Chunyan1, HUANG Yunjie1, LI Jinghong1,2.& CHEN Shaowei3.1. State Key Laboratory of Electroanalytical chemistry, Changchun Institute of Applied chemistry, Chinese Academy of Sciences, Changchun 13.02., China {2., tsinghua university, beijing 100084, China 3. department of chemistry, university of California, Santa Cruz, Santa Cruz, CA 95064, USA State Key Laboratory of Electroanalytical chemistry Changchun Institute of Applied chemistry Chinese Academy of Sciences Changchun China department of chemistry Tsinghua University Beijing China department of chemistry University of California Santa Cruz Santa Cruz USA

Electron transfer through the self-assembled monolayers (SAMs) on gold nanopar-ticles is investigated by using the monolayer protected gold nanoclusters (MPCs) as elec-tron-transfer mediators. 3.Mercaptopropionic acid (MPA) and 11-meraptoundecanoic acid (MUA) MPCs were employed to catalyze the redox reaction between potassium ferricyanide and sodium thiosulfate. The catalytic mechanism was proposed that the MPCs act as diffusing elec-tron-mediators and electron transfers to and from the MPCs surface. Therefore the electron transfer rate through the capping layers would be proportional to the MPCs catalyzed reaction rate, which was monitored by the UV absorbance of ferricyanide. The calculated apparent rate constant was orders of magnitude smaller than that of the maximum of tunneling current, which was attributed to the splited energy level of the nanoscale particles.

关键词： electron transfer, three-dimensional self-assembled monolayers, redox reaction, electron transfer mediator, surface effect.

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Luminescence of Eu^(2.) in Strontium Aluminum Oxide System with Long Decay Property

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Chinese Chemical Letters 1998年第4期9卷 401-402页

作者： Yong QIU and Hai Tao SUN(department of chemistry,{2.,{3.) department of chemistry Tsinghua University Beijing 100084 China

A long decay luminescent powder based upon the strontium aluminum oxide system with Eu2. as the activator was produced. It was found that the variation of the molar ratio of Al to Sr leads to a change in emission colo... 详细信息

关键词： luminescence of Eu^(2.) strontium aluminum oxide emission

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SIMULATION　CALCULATION　FOR　CHEMICAL　SPECIATION　OF　LEAD　BY　FEEDBACK　NEURAL　NETWORK

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Chinese Chemical Letters 1996年第3期7卷 265-266页

作者： Hua MO Bo DENG(department of chemistry,{2.,{3., 100084.) department of chemistry Tsinghua University Beijing 100084

The chemical speciations of Ph2. in the aqueous solution can becalculated using a Feedback Neural Network. The effects of CO3.2.), random errorand temperature on the simulation results were discussed. The results show... 详细信息

关键词： LEAD OF SPECIATION FEEDBACK CALCULATION BY

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Solving the input data in error correc-tion of optical fabrication by finite Fourier coefficient algorithm

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Science China(Technological Sciences) 2006年第1期49卷 50-60页

作者： CHENG Haobo1,2. SUN Guozheng3.& FENG Zhijing2.1. department of Optical Engineering, {3. Institute of Technology, {3. 100081, China 2. department of Precision Instruments and Mechanology, tsinghua university, beijing 100084, China 3. China North Industries Group Corporation, {3. 100089, China department of Optical Engineering Beijing Institute of Technology Beijing China department of Precision Instruments and Mechanology Tsinghua University Beijing China China North Industries Group Corporation Beijing China

A free-form lens (FFL) is a special surface that is difficult to be fabricated. FFL are usually fabricated by computer-controlled optical surfacing (CCOS) technique. During CCOS, the material removal amount is determined by the unit removal function (URF) convoluting with the input data――the dwell time. When the removal amount and the URF are known, how to solve the input data involves the special algorithm――deconvolution. Usually, the input data are solved by virtue of low pass filter or iterative methods. However, an approximation solution would destroy the machining stability nec-essary to perform precisely CCOS. In this paper, to solve the input data, a new method that is based on the finite Fourier coefficient is put forward. It can give a continuous and accurate solution for fabricating choice. Several parameters are simulated, which influ-ence the process of CCOS, and evaluating on the effect of the method is also carried out. Experimental results verify that this method is suitable for guiding the manufacturing of high precision FFL.

关键词： optical fabrication, computer controlled optical surfacing, free-form lens, finite Fourier coefficient, error correction.

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Closed and endoreversible chemical oscillation

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Chinese Journal of chemistry 1994年第3期12卷 199-205页

作者： LI, Ru-Shengdepartment of chemistry,{2.,{3., China department of chemistry Tsinghua University Beijing 100084 China

Based on a simple nonideal chemical reaction model, the closed system with reversible nonideal reactions and illumination is shown to be able to exhibit sustained oscillation. The essential points in the occurrence of such oscillations are the nonideality of reacting media, which gives rise to multiple chemical equilibria, and the energy flow through illumination and heat conduction, which gives rise to spontaneous transitions repeatedly between the multiple equilibrium states. During the oscillation, reacting media undergo only reversible chemical transformation and all irreversibilities are restricted to the coupling of the system to external world. This oscillation provides an example of the so-called endoreversible machine and a possible way to convert radiation energy of the light directly into mechanical energy.

关键词： Chemical oscillation closed system nonideality endoreversible machine illumination.

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SOME PROPERTIES OF LSQR FOR LARGE SPARSE LINEAR LEAST SQUARES PROBLEMS

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Journal of Systems Science & Complexity 2010年第4期23卷 815-821页

作者： Zhongxiao JIA department of Mathematical Sciences,tsinghua {2.,{3. 100084,China. department of Mathematical Sciences Tsinghua University Beijing China

It is well-known that many Krylov solvers for linear systems,eigenvalue problems,andsingular value decomposition problems have very simple and elegant formulas for residual *** not only allow us to further understand the methods theoretically but also can be usedas cheap stopping criteria without forming approximate solutions and residuals at each step beforeconvergence takes *** for large sparse linear least squares problems is based on the Lanczosbidiagonalization process and is a Krylov ***,there has not yet been an analogouslyelegant formula for residual *** paper derives such kind of *** addition,the authorgets some other properties of LSQR and its mathematically equivalent CGLS.

关键词： CGLS krylov subspace lanczos bidiagonalization least squares lsqr normal equations.

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A SINGLE-PERIOD INVENTORY SYSTEM WITH A GENERAL S-SHAPED UTILITY AND EXPONENTIAL DEMAND

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Journal of Systems Science and Systems Engineering 2010年第2期19卷 227-236页

作者： Wei GENG1 Xiaobo ZHAO2.Deng GAO3.department of Industrial Engineering,tsinghua {2.,beijing 100084,China department of Industrial Engineering Tsinghua University Beijing China

We discuss a single-period inventory system with a general S-shaped utility function and exponential demand. It is shown that there exists a state-dependent order-up-to policy to be optimal. Behaviors of optimal polic... 详细信息

关键词： Inventory S-shaped utility function order-up-to policy

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Variation properties of ionospheric eclipse factor and ionospheric influence factor

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Progress in Natural Science:Materials International 2005年第6期15卷 573-576页

作者： ZHAO Chunmei 1,2.*, YUAN Yunbin1, OU Jikun1 and CHEN Jinping3.1. Institute of Geodesy and Geophysics, Chinese Academy of Sciences, Wuhan 43.077, China 2. Graduate School of Chinese Academy of Sciences, beijing 10003., China 3. {3. of Precision Instrument and Mechanology,{2., beijing 100084, China) Institute of Geodesy and Geophysics Chinese Academy of Sciences Wuhan 430077 China Graduate School Chinese Academy of Sciences Beijing 100039 China department of Precision Instrument and Mechanology Tsinghua University Beijing 100084 China

The concepts and calculation methods of ionospheric eclipse factor (IEF) and ionospheric influence factor (IFF) are further illustrated. The temporal and spacial variation properties of IEF and IFF are studied, which shows that the properties are influenced by the geographic position and season. The possibility of improving the precision of using GPS data to determine ionospheric delay based on the above variation properties is also analysed.

关键词： GPS Ionospheric eclipse factor Ionospheric influence factor

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