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SILICA-SUPPORTED NICKEL AND ZIRCONIUM CATALYSTS FOR BRANCHED POLYETHYLENE

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chinese Journal of Polymer Science 2003年第4期21卷 453-458页

作者：孙文华 State Key Laboratory of Engineering Plastics The center for Molecular sciences {2. of Chemistry chinese Academy of sciences beijing 100080 china State Key Laboratory of Engineering Plastics The Center for Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China

8-Aminoquinoline nickel dichloride and bis(cyclopentadienyl)zirconium dichloride (Cp_2.rCl_2. were supportedsimultaneously on silica to produce branched polyethylene successfully by combined polymerization. The supportedpolymerization results showed that the molecular weight of polyethylene increased while the molecular weight distributionbecame wider and the molecular chains of oligomers remaning in the final solution became shorter as compared to theoligomers obtained in polymerization processes with pure 8-aminoquinoline nickel dichloride catalysis, as well as theCp_2.rCl_2.and nickel combination system. With decreasing amount of Ni catalyst in the supported catalyst, the molecular chains of oligomers in the resulting solution became shorter, while α-olefin selectivity increased.

关键词： 8-Aminoquinoline nickel dichloride, Cp_2.rCl_2 Silica supported catalysts Branched polyethylene

Inconsistency between WMAP data and released map

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chinese Science Bulletin 2010年第10期55卷 907-909页

作者： LIU Hao1 & LI TiPei1,2.3 1 Key Laboratory of Particle Astrophysics,institute of High Energy physics,chinese Academy of sciences,beijing 100049,china 2.Department of physics & center for Astrophysics,Tsinghua University,beijing 100084,china 3 Department of Engineering physics & center for Astrophysics,Tsinghua University,beijing 100084,china Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing China Department of physics & center for Astrophysics Tsinghua University Beijing China Department of Engineering physics & center for Astrophysics Tsinghua University Beijing China

A remarkable inconsistency between the calibrated differential time-ordered data (TOD) of the Wilkinson Microwave Anisotropy Probe (WMAP) mission,which is the input for map-making,and the cosmic microwave background (CMB) temperature maps published by the WMAP team is revealed,indicating that there must exist a serious problem in the map making routine of the WMAP *** inconsistency is easy to be confirmed without the use of WMAP map-making *** view of the importance of this issue for cosmology study,we invite readers to check it by themselves.

关键词：威尔金森微波各向异性探测器 WMAP 地图制作宇宙微波背景有序数据制作软件 TOD CMB

Label-free high-throughput and real-time detections of protein interactions by oblique-incidence reflectivity difference method

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Science china(physics,Mechanics & Astronomy) 2014年第4期57卷 615-618页

作者： HE LiPing LIU Shuang DAI Junbeijing National Laboratory for condensed {2. physics institute of physics chinese Academy of sciences Lü HuiBin JIN KuiJuan YANG GuoZhen beijing National Laboratory for condensed {2. physics Institute of Physics Chinese Academy of Sciences

Selected Mouse IgG of 1 mg/mL as target was fabricated on microarray for 500 sample ***-free and real-time reaction dynamic processes were detected between the microarrays with Goat Anti-mouse IgG of 0.02.mg/mL using the obliqueincidence reflectivity difference(OIRD)*** obtained the reaction results and the reaction dynamic curves of 500 protein *** addition,we also used label-free detection of protein microarrays of 10080 sample dots,including BSA and different concentrations of Mouse IgG and Rabbit IgG,by *** obtained reaction results between the protein microarray with 1 mg/mL Goat Anti-mouse IgG and 1 mg/mL Goat Anti-rabbit IgG are reported *** results show that OIRD can be not only label-free high-throughput detection method for biological microarrays but also label-free real-time detection in the interaction processes of biomolecules.

关键词： oblique-incidence reflectivity difference(OIRD) label-free real-time high-throughput

EFFECT OF PARTICLE SIZE ON THE FILMING PROCESS OF POLYSTYRENE LATEX STUDIED BY AFM

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chinese Journal of Polymer Science 2002年第6期20卷 509-515页

作者： Xiao-zhong Qu Yi Shi Liu-sheng Chen Xi-gao Jin State Key Laboratory of Polymer physics & Chemistry, center for Molecular Science,{2. of Chemistry, chinese Academy of sciences, beijing 100080 china State Key Lab. of Polymer Phy./Chem. Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China

The film formation process of micro-PS particles (diameter 742.nm) and nano-PS particles (diameter 2. nm) was studied by atomic force microscopy and differential scanning calorimetry. During a step heating process, the particles were annealed for 0.5 h at each selected temperature. It was found that the deformation and interdiffusion temperatures of the micro-PS particles are ca. 12.-130degreesC and 140-150degreesC, that of the nano-PS particles are 90degreesC and 100-110degreesC respectively. The DSC traces of nano-PS particles showed that there was an exothermic peak near T-g after annealing for 0.5 h at the selected temperatures below 90degreesC; otherwise, the exothermic peak disappeared after annealing at 100degreesC or above. Compared with the micro-PS particles, the sintering process of nano-PS particles occurs at much lower temperature determined by the confined state of polymer chains with higher conformational energy in nano-particles, and completes in a much narrower temperature range driven mainly by the larger total surface energy.

关键词： polystyrene latex filming process particle size effect

A new algorithm for microwave radiometer remote sensing of sea surface salinity and temperature

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Science china Earth sciences 2006年第11期49卷 1204-1211页

作者： YIN Xiaobin1, LIU Yuguang1, WANG Zhenzhan2.& XIU Peng1 1. Physical Oceanography Laboratory, Ocean University of china, Qingdao 2.6003, china 2. {2. for Space and Applied Research, chinese Academy of sciences, beijing 100080, china Physical Oceanography Laboratory Ocean University of China Qingdao China center for Space and Applied Research Chinese Academy of Sciences Beijing China

The microwave radiation of the sea surface, which is denoted by the sea surface brightness temperature, is not only related with sea surface salinity (SSS) and temperature (SST), but also influenced by sea surface wind. The errors of wind detected by satellite sensor have significant influences on the accuracy of SSS and SST retrieval. The effects of sea surface wind on sea surface brightness temperature, i.e. △Th,v, and the relations among △Th,v, wind speed, sea surface tempera- ture, sea surface salinity and incidence angle of observation are investigated. Based on the investi- gations, a new algorithm depending on the design of a single radiometer with double polarizations and multi-incidence angles is proposed. The algorithm excludes the influence of sea surface wind on SSS and SST retrieval, and provides a new method for remote sensing of SSS and SST.

关键词： microwave radiometer, sea surface temperature, sea surface salinity, wind, brightness temperature.

Systematic distortion in cosmic microwave background maps

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Science china(physics,Mechanics & Astronomy) 2009年第5期52卷 804-808页

作者： LIU Hao 1,3 &LI TiPei 1,2.1Key Laboratory of Particle Astrophysics,institute of High Energy physics,chinese Academy of sciences,beijing 100049,china 2.7} for Astrophysics,Tsinghua University,beijing 100084,china 3 Graduate University of chinese Academy of sciences,beijing 100049,china Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing China Graduate University of chinese Academy of sciences Beijing China center for Astrophysics Tsinghua University Beijing China

To minimize instrumentally the induced systematic errors,cosmic microwave background(CMB)anisotropy experiments measure temperature differences across the sky using pairs of horn antennas, temperature map is recovered from temperature difference obtained in sky survey through a map-making *** inspect and calibrate residual systematic errors in the recovered temperature maps is important as most previous studies of cosmology are based on these *** analyzing pixel-ring coupling and latitude dependence of CMB temperatures,we find notable systematic devia- tion from CMB Gaussianity in released Wilkinson Microwave Anisotropy Probe(WMAP)*** detected deviation cannot be explained by the best-fit LCDM cosmological model at a confidence level above 99%and cannot be ignored for a precision cosmology study.

关键词： cosmology cosmic microwave background methods data analysis

The relationship between the canonical ENSO and the phase transition of the Antarctic oscillation at the quasi-quadrennial timescale

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Acta Oceanologica Sinica 2010年第6期29卷 26-34页

作者： LIU Changzheng XUE Feng National Climate center Beijing 100081 China LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China

A correlation analysis is performed to investigate the relationship between El Nino-Southern Oscillation （ENSO） and the Antarctic oscillation （AAO） at the quasi-quadrennial （QQ） *** is found that the cold tongue index （CTI） and the AAO index （AAOI） are negatively correlated with about a 7-month lead-time,while they are positively correlated with about a 15-month *** further explore this relationship,complex empirical orthogonal function analysis is employed in the QQ sea level pressure （SLP） anomalies from 1951 to *** results indicate that,during the ENSO cycle,there exists one kind of global tropical wave of wavenumber 1 （GTW1） propagating *** the traveling of GTW1,the tropical SLP anomaly tends to intrude into the southern ***,three strong signals travel synchronously along the circumSouth-Pacific path,and a relatively weak signal extends eastward and poleward over the South Ocean in the Atlantic-Indian Ocean *** the propagation of these signals,the AAO phase tends to be reversed *** a result,there exists an evident lead-lag correlation between CTI and *** can be concluded that ENSO plays a key role in the phase transition of AAO at the QQ *** is also noticed that this regular relationship is only evident in the canonical ENSO events,for which sea surface temperature （SST） anomalies extend westward from the tropical eastern *** the other hand,the similar relationships are not found among those atypical ENSO events for which SST anomalies spread eastward from the central Pacific,such as the 1982.1983 ENSO event.

关键词： ENSO Antarctic oscillation the quasi-quadrennial timescale the global tropical wave of wavenumber 1

Summer Arctic sea fog

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Acta Oceanologica Sinica 2001年第2期20卷 183-196页

作者： Xie Simei, Xue Zhenhe, Jiang Dezhong, Zou Bin, Qu Shaohou (1. National Research center for Marine Environment Forecasts, beijing 100081,{2. 2. institute of Atmospheric physics, chinese Academy of sciences, beijing 10002.,{2.) Natl. Res. Ctr. for Marine Envrn. Fo Beijing 100081 China

Synchronous or quasi-synchronous sea-land-air observations were conducted using advanced sea ice, atmospheric and marine instruments during china's First Arctic Expedition. *** on the Precious data from the expedition, it was found that in the Arctic Ocean, most part of which is covered with ice or is mixed with ice, various kinds of sea fog formed such as advection fog, radiation fog and vapor fog. Each kind he its own characteristic and mechanics of creation. In the southern part of the Arctic Ocean, due to the sufficient warm and wet flow there, it is favorable for advection fog to form, which is dense and lasts a long time. On ice cap or vast floating ice, due to the strong radiation cooling effect, stable radiating fog is likely to form. In floating ice area there forms vapor fog with the appearance of masses of vapor from a boiling pot, which is different from short-lasting land fog. The study indicates that the reason why there are many kinds of sea fog form in the Arctic Ocean is because of the complicated cushion and the consequent sea-air interaction caused by the sea ice distribution and its unique physical characteristics. Sea fog is the atmospheric phenomenon of sea-air heat exchange. Especially, due to the high albedo of ice and snow surface, it is diffcult to absorb great amount of solar radiation during the polar days. Besides, ice is a poor conductor of heat; it blocks the sea-air heat exchange. The sea-air exchange is active in floating ice area where the ice is broken. The sea sends heat to the atmosphere in form of latent heat; vapor fog is a way of sea-air heat exchange influencing the climate and an indicator of the extent of the exchange. The study also indicates that the sea also transports heat to the atmosophere in form of sensible heat when vapor fog occurs.

关键词： Arctic sea fog vapor fog radiation fog advection fog mechanism of the creation of sea fog

Band gap anomaly and topological properties in lead chalcogenides

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chinese physics B 2016年第3期25卷 27-34页

作者：聂思敏许霄琰徐刚方忠 beijing National Laboratory for condensed {2. physics and Institute of Physics Chinese Academy of Sciences Beijing 1O0190 China Collaborative Innovation center of Quantum matter Beijing 100084 China

Band gap anomaly is a well-known issue in lead chalcogenides PbX （X = S, Se, Te, Po）. Combining ab initio calculations and tight-binding （TB） method, we have studied the band evolution in PbX, and found that the band gap anomaly in PbTe is mainly related to the high on-site energy of Te 5s orbital and the large s-p hopping originated from the irregular extended distribution of Te 5s electrons. Furthermore, our calculations show that PbPo is an indirect band gap （6.5 meV） semiconductor with band inversion at L point, which clearly indicates that PbPo is a topological crystalline insulator （TCI）. The calculated mirror Chern number and surface states double confirm this conclusion.

关键词： band gap anomaly lead chalcogenides indirect band gap semiconductor topological crystallineinsulator