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Magnetic properties of Jiaxian red clay sequences from northern chinese Loess Plateau and its paleoclimatic significance

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Science china Earth sciences 2005年第8期48卷 1234-1245页

作者： QIANG Xiaoke, AN Zhisheng, LI Huamei, CHANG Hong & SONG Yougui 1. SKLLQG, Institute of Earth Environment, chinese academy of sciences, Xi’an 710075, china 2. {2. Institute of Geochemistry, chinese academy of sciences, guangzhou 51064., china 1. chinese academy of sciences SKLLQG Institute of Earth Environment 710075 Xi’an China 2. chinese academy of sciences Guangzhou Institute of Geochemistry 510640 Guangzhou China

Detailed rock magnetism investigation of the Jiaxian red clay sequences indicated that there are common magnetic mineralogy properties in red clay and loess-paleosol sequences from the chinese Loess Plateau as well as the marked properties of themselves, magnetic min-erals mainly with magnetite, maghemite, hematite, and possibly limonite/goethite contributing to the magnetic behavior. Meanwhile, it is found that the strong paleosol in red clay sequences has a lower coercivity and higher content of ultra-fine ferrimagnetic grains than that of the weak pa-leosol, which is similar to loess and paleosol in upper Wucheng Loess sequences, and indicates that humid conditions and relatively strong pedogenesis play a significant role in the increase of ultra-fine magnetic minerals and transformation of the magnetic minerals. This suggests that, like Quaternary loess-paleosols, the change of characteristics of paleoclimatic conditions of the late Tertiary red clay deposits is fluctuant. In addition, the results of magnetic hysteresis properties show that the applied saturated field for samples from the Jiaxian red clay sequences is higher than that of the samples from eastern and southern chinese Loess Plateau. It is obviously shown that there exist more hard magnetic minerals and relatively weak biochemical processes in the Jiaxian red clay sequences on northern chinese Loess Plateau. We conclude that the paleocli-matic environment is different between northern and eastern/southern chinese Loess Plateau, and it should be more arid in northern chinese Loess Plateau.

关键词： northern chinese Loess Plateau, red clay, magnetic property, paleoclimatic significance.

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SHRIMP zircon U-Pb geochronology of early Mesozoic felsic igneous rocks from the southern Lancangjiang and its tectonic implications

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Science china Earth sciences 2006年第10期49卷 1032-1042页

作者： PENG Touping1,2. WANG Yuejun1, FAN Weiming1, LIU Dunyi3, SHI Yuruo3 & MIAO Laicheng4.1. Key Laboratory of Isotope Geochronology and Geochemistry, guangzhou Institute of Geochemistry, chinese academy of sciences,{2.,{4. 2. Graduate University of chinese academy of sciences, Beijing 100039,{4. 3. SHRIMP isotope Laboratory, chinese academy of Geological sciences, Beijing 100037,{4. 4. Institute of Geology and Geophysics, chinese academy of sciences, Beijing 10002.,{4. Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Graduate University of chinese academy of sciences Beijing China SHRIMP isotope Laboratory Chinese Academy of Geological Sciences Beijing China Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

The SHRIMP zircon U-Pb geochronology of three typical samples, including two monzo nitic granites from the Lincang batholith and a rhyolite from the Manghuai Formation are presented in the southern Lancangjiang, western Yunnan Province. The analyses of zircons for the biotite monzonitic granites from the northern (02.X-137) and southern (2.JH-10) Lincang batholith show the single and tight clusters on the concordia, and yield the weighted mean 2.6Pb/2.8U ages of 2.9.4.± 3.0 Ma and 2.0.4.± 3.6 Ma, respectively, representing the crystallized ages of these granites. The zircons for the rhyolitic sample (02.X-95) from the Manghuai Formation give a weighted mean 2.6Pb/2.8U age of 2.1.0 ± 5.0 Ma. These data suggest that the igneous rocks from the Lincang granitic batholith and Manghuai Formation have a similar crystallized age. In combination with other data, it is inferred that both were generated at a narrow age span (~2.0 Ma) and were originated from the postcollisional tectonic regime. An early Proterozoic 2.6Pb/2.8U apparent age of 1977±4. Ma is additionally obtained from one zircon from the biotite monzonitic granite (southern Lincang batholith), indicative of devel- opment of the early Proterozoic Yangtze basement in the region. These precisely geochronological data provide important constraints on better understanding the Paleozoic tectonic evolution of the Tethys, western Yunnan Province.

关键词： SHRIMP zircon U-Pb dating, Middle Triassic, Lincang granitic batholith, Manghuai Formation rhyolite, southern Lancangjiang.

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Experimental study of ore gabbro liquid immiscibility

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Science china Earth sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2. XIA Bin1, ZHOU Yongsheng3 & JIN Zhenmin4.1. guangzhou Institute of Geochemistry, chinese academy of sciences,{2.,{4. 2. Wuhan University, Wuhan 4.0072.{4. 3. Institute of Geology,{4. Seismological Bureau, Beijing 10002.,{4. 4. Faculty of Earth sciences,{4. University of Geosciences, Wuhan 4.0074.{4. 1. guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. Wuhan University 430072 Wuhan China 3. Institute of Geology China Seismological Bureau 100029 Beijing China 4. Faculty of Earth sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, china. Experiments were conducted under (confining) pressure ranging from 4.0 to 500 MPa and temperature of 900— 12.0℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

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The biomarkers of 2.6,10,15, 19-pentamethylicosenes and their carbon isotopic composition in the sediments from the Gulf of Mexico

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chinese Science Bulletin 2006年第14期51卷 1736-1740页

作者： SONG Zhiguang1,2.& WANG Cuiping1,31. State Key Laboratory of Organic Geochemistry, guangzhou Institute of Geochemistry, chinese academy of sciences,{2.,{4. 2. guangzhou Research Center of Gas Hydrate, chinese academy of sciences,{2.,{4. 3. Graduate School of chinese academy of sciences, Beijing 100039,{4. State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China guangzhou Research Center of Gas Hydrate Chinese Academy of Sciences Guangzhou 510640 China Graduate School of chinese academy of sciences Beijing 100039 China

A group of 2.6,10,15,19-pentamethyli- cosenes (PMIΔ) containing 1―5 unsaturated double bonds has been identified in the sea floor sediments from the Gulf of Mexico at the Green Canyon 2.8 *** PMIΔ compounds are distributed between nC2. and nC2. on the mass chromatogram of aliphatic fraction. Their δ 13C values are very much depleted in 13C and in the range of ?86.7‰ to ?115.5‰, whereas the δ 13C values of companion n-alkanes range from ?2..4. to ?34.6‰. These unsaturated PMIΔ com-pounds are typical biomarkers derived from the an-aerobic oxidation of methane mediated by meth-ane-oxidizing archaeal bacteria and indicative of the gas seeps or even the occurrence of gas hydrates in the deep sea sediments.

关键词：生物标志墨西哥湾沉积物 PMIA 天然气水化物

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PREPARATION AND PROPERTIES OF ETHYL-CYANOETHYL CELLULOSE/POLYACRYLIC ACID COMPOSITE FILMS WITH REFLECTION COLORS

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chinese Journal of Polymer Science 2001年第3期19卷 277-282页

作者： Yong Huang Institute of Chemistry, chinese academy of sciences, Beijing 100080 china Laboratory of Cellulose and Lignocellulosics Chemistry {2. Institute of Chemistry chinese academy of sciences, {2. 510650, china 中科院化学所北京

Ethyl-cyanoethyl cellulose [(E-CE)C]/acrylic acid (AA) becomes a cholesteric liquid crystalline solution withvivid colors when the (E-CE)C concentration is 4.0}wt%～52.wt%. (E-CE)C/polyacrylic acid (PAA) composites withcholesteric structure were prepared by polymerzing AA in (E-CE)C/AA liquid crystalline solutions. The layers of orderedpolymer chains in the cholesteric phase were inclined during polymerization and the degree of the inclination depended onthe polymerization temperature and the concentration of the solution before polymerization. The cholesteric structure in thecomposites could not be changed when temperature was lower than 100℃. Cross-linking of the PAA in compositesimproved their water-resistance. The cholesteric order of the composites without cross-linking was destroyed when theywhere immersed in water. The color derived from the selective reflection of the cholesteric phase of the cross-linkedcomposites turned from blue to red after the composites absorbed water. The color of the composites could be returned to theoriginal one when the absorbed water was removed from the swollen composites.

关键词： Cholesteric structure Composites Selective reflection Liquid crystalline solutions

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Research on the method for retrieving soil moisture using thermal inertia model

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Science china Earth sciences 2006年第5期49卷 539-545页

作者： LIU Zhenhua1 & ZHAO Yingshi2.1. Information College, South china Agricultural University, guangzhou 51064., china 2. Graduate University of chinese academy of sciences, Beijing 10004., china 1. Information College South China Agricultural University Guangzhou 510642 China 2. Graduate University of chinese academy of sciences Beijing 100049 China

In order to improve accuracy of soil moisture inversion using remote sensing, a new thermal inertia model is proposed in this paper. The improved model needs only surface maximum temperature as the temperature parameter input instead of input of the surface temperature difference, as well as the surface sensible and latent fluxes are introduced into boundary conditions of thermal conductivity equation. Furthermore, surface soil conductive heat transfer equation of two-layer model is used to solve the soil thermal inertia so that the remote sensing thermal inertia method can be ap- plied to regions with better-covered vegetation, but usually only for the bare areas or worse vegetation covered areas. The model has been tested at several locations in the area of west Inner Mongolia. Comparing the simulation of the new model with the measurements obtained by apparent thermal inertia and by field test, the result shows that the inertia thermal model can be used to estimate soil moisture in more reasonable accuracy.

关键词： thermal model, thermal conductivity equation, soil initial, sensible flux, latent flux, two-layer model.

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Research on the dynamics of the South china Sea opening:Evidence from analogue modeling

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Science china Earth sciences 2006年第10期49卷 1053-1069页

作者： SUN Zhen1,2. ZHOU Di1, ZHONG Zhihong3, XIA Bin2. QIU Xuelin1, ZENG Zuoxun4.& JIANG Jianqun5 1. CAS Key Laboratory of Marginal Sea Geology, South china Sea Institute of Oceanology, chinese academy of sciences, {2. 510301, china 2. CAS Key Laboratory of Marginal Sea Geology, {2. Institute of Geochemistry, chinese academy of sciences, guangzhou 51064., china 3. Department of Technology, Shenzhen Branch of CNOOC, {2. 5102.0, china 4. Faculty of Earth {14., china University of Geo{14., Wuhan 4.0074. china 5. Hainan Oil & Gas Exploration Company, Liaohe Oilfield Petrochina, Panjin 12.010, china 1. CAS Key Laboratory of Marginal Sea Geology South China Sea Institute of Oceanology Chinese Academy of Sciences Guangzhou 510301 China 2. CAS Key Laboratory of Marginal Sea Geology Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 3. Department of Technology Shenzhen Branch of CNOOC Guangzhou 510240 China 4. Faculty of Earth sciences China University of Geosciences Wuhan 430074 China 5. Hainan Oil & Gas Exploration Company Liaohe Oilfield PetroChina Panjin 124010 China

Independent of Indochina extrusion, the South china Sea experienced a process from passive continental rifting to marginal sea drifting. According to the fault patterns in the Beibu Gulf basin and the Pearl River Mouth basin, the continental rifting and early spreading stage from 32.to 2. Ma were controlled by extensional stress field, which shifted clockwise from southeastward to south southeastward. From 2. Ma on, the sea spread in NW-SE direction and ceased spreading at around 15.5 Ma. Integrated geological information with the assumption that the South china Sea developed along a pre-Cenozoic weakness zone, we did analogue experiments on the South china Sea evolu- tion. Experiments revealed that the pre-existing weakness zone goes roughly along the uplift zone between the present Zhu-1 and Zhu-2.depression. The pre-existing weakness zone is composed of three segments trending NNE, roughly EW and NEE, respectively. The early opening of the South china Sea is accompanied with roughly 15° clockwise rotation, while the SE sub-sea basin opened with SE extension. Tinjar fault was the western boundary of the Nansha block (Dangerous Ground), while Lupar fault was the eastern boundary of the Indochina, NW-trending rift belt known as Zengmu basin developed between above two faults due to block divergent of Indochina from Nansha. In the experiment, transtensional flower structures along NW-trending faults are seen, and slight inversion occurs along some NE-dipping faults. The existence of rigid massifs changed the orientations of some faults and rift belt, and also led to deformation concentrate around the massifs. The rifting and drifting of the South china Sea might be caused by slab pull from the proto South china Sea subducting toward Borneo and/or mantle flow caused by India-Asia collision.

关键词： South china Sea, rifting and drifting, clockwise rotation, analogue modeling, rigid massifs.

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Quasirational dynamic system

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chinese Science Bulletin 2000年第14期45卷 1277-1279页

作者： SUN Daochun & YANG Lo1. Department of Mathematics, South china Normal University, guangzhou 510631, china 2. Institute of Mathematics, {4. of Mathematics and System sciences, chinese academy of sciences, Beijing 100080, china Department of Mathematics South China Normal University Guangzhou China Institute of Mathematics Academy of Mathematics and System Sciences Chinese Academy of Sciences Beijing China

Using the iterations of quasirational mappings, the theorems on dynamic system are generalized to the quasirational dynamic system. Some different results are also obtained.

关键词： quasirational mapping dynamic system covering surface.

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Trace element characteristics and origin of intergranular components in mantle peridotites

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chinese Science Bulletin 2000年第7期45卷 643-649页

作者： XU Yigangguangzhou Institute of Geochemistry, chinese academy of sciences,{2., china guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China

Leaching experiment has been carried out on mantle xenoliths with different petrographic features in order to directly characterize the nature of intergranular components. ICP-MS analyses of leachates show that they are characterized by high LREE concentrations with strong depletion of Ta. The total REE contents and whether the negative Rb, Ba and Nb anomalies are present or not in intergranular components are largely dependent upon the nature of mantle metasomatism experienced by its host rock. It is proposed that intergranular components may represent residues of small volume metasomatic melts.

关键词： peridotite xenoliths intergranular components trace elements upper mantle.

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Trace element geochemical characteristics of plants and their influence on the remote-sensing spectral properties in the North Jiangsu oil field

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chinese Science Bulletin 2000年第S1期45卷 26-34页

作者： WANG Yunpengguangzhou Institute of Geochemistry, chinese academy of sciences,{2., china chinese Acad Sci Guangzhou Inst Geochem Guangzhou 510640 Peoples R China

This paper presents the contents of 17 kinds of trace elements in plant leaf samples collected from 4.sections in the North Jiangsu oil field, and the dada on their visible-near infrared spectra. By comparing the results of the inner and outer oil-gas remote-sensing anomaly areas, the plant trace element composition, and the enrichment characteristics and their influence on the plant spectral properties are described. The results indicated that the plant leaves had very strong enrichment ability toward some elements such as Mg, Ca, K, Na, Fe, Al, Mn, V, Zn and Cr. The plant leaves from the oil-gas abnormal areas were enriched in trace elements of the Fe-series, but depleted in alkali and alkali-earth metal elements. The plant trace elements had a strong influence on the 'blue-shift' strength and the reflectance of visible bands. And the ratios between Fe, Co and K, Na, Cd, Cu, Ba are the effective remote-sensing oil-indicating factors of plant trace elements. plant trace element, geochemistry, remote

关键词： plant trace element geochemistry remote sensing spectra North Jiangsu oil fleld.

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