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Electron microscopy study of the sakhaite from endogenous borate deposit in Hunan, china

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Science china earth Sciences 2004年第3期47卷 232-238页

作者： LIU Xiangwen1,2. YANG Guangming2. ZOU Huamin3, QU Jing1 & ZHAO Wenxia4.1. Graduate School, china university of geosciences, wuhan {2., china 2. Test Center, china university of geosciences, wuhan {2., china 3. Physics and Technology College, wuhan university, wuhan 4.0072. china 4. Test Center, Zhongshan university, Guangzhou 5102.5, china china Univ Geosci Grad Sch Wuhan 430074 Peoples R China china Univ Geosci Test Ctr Wuhan 430074 Peoples R China wuhan Univ Phys & Technol Coll Wuhan 430072 Peoples R China Zhongshan Univ Test Ctr Guangzhou 510275 Peoples R China

Sakhaite specimens from an endogenous borate deposit in Hunan Province, china have been studied in detail by means of transmission electron microscopy (TEM). The selected area electron diffraction (SAED) patterns obtained with different crystal zone axes show that the crystal system is cubic, with a = 1.4.3 nm. The convergent beam electron diffraction (CBED) patterns indicate that the point group and space group of sakhaite is m3m and Fd3m, respec-tively. The space group of synthetic sakhaite determined by Chichagov (1974. is F4.32. The possible reasons why the space groups of the natural and the synthetic sakhaites are different are discussed.

关键词： sakhaite, space group, convergent beam electron diffraction (CBED).

Experimental study of ore gabbro liquid immiscibility

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Science china earth Sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2. XIA Bin1, ZHOU Yongsheng3 & JIN Zhenmin4.1. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 51064., china 2. wuhan {2., wuhan 4.0072. china 3. Institute of Geology, china Seismological Bureau, Beijing 10002., china 4. Faculty of earth Sciences, china university of geosciences, wuhan {14., china 1. Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. wuhan university 430072 Wuhan China 3. Institute of Geology China Seismological Bureau 100029 Beijing China 4. Faculty of earth Sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, china. Experiments were conducted under (confining) pressure ranging from 4.0 to 500 MPa and temperature of 900— 12.0℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

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Science china earth Sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of geosciences, Ministry of Education of china, Beijing 100083, china 2. School of earth Sciences and Mineral Resources, china university of geosciences, Beijing 100083, china 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. School of earth Sciences and Mineral Resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174.a and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

Transport network and flow mechanism of shallow ore-bearing magma in Tongling ore cluster area

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Science china earth Sciences 2006年第4期49卷 397-407页

作者： DENG Jun1,2. WANG Qingfei1,2., HUANG Dinghua3 , WAN Li4. YANG Liqiang1,2.& GAO Bangfei1,2.1. State Key Laboratory of Geological Processes and Mineral Resources, {4., Beijing 100083, china 2. Key Laboratory of Lithosphere Tectonics and Lithoprobing Technology of Ministry of Education, china university of Geo- sciences, Beijing 100083, china 3. Faculty of earth Sciences, {4., wuhan 4.0074, china 4. School of Mathematics and Information Science, Guangzhou university, Guangzhou 5104.5, china 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China 2. Key Laboratory of Lithosphere Tectonics and Lithoprobing Technology of Ministry of Education China University of Geosciences Beijing 100083 China 3. Faculty of earth Sciences China University of Geosciences Wuhan 430074 China 4. School of Mathematics and Information Science Guangzhou University Guangzhou 510405 China

Abundant studies revealed that shallow intrusions of the Yanshanian epoch resulted in the mass mineralization of the Tongling region. Various evidences showed there existed a concealed magma chamber at ?10 km depth in the middle part of this region during Yanshanian epoch, from which the ore-forming magma was generated and then transported to the superficial layer. Yet the transport network and flow mechanism of the shallow ore-bearing magma, the key problem associ- ated with ore-forming process, was relatively little focused on. Integrate analysis of structural me- chanics, statistical fractal and geological facts suggested that NE trending high-angle fold-related thrust faults and the tessellated basement ones served as the main pathways for the shallow magma’s transporting, moreover, the saddle void spaces among adjacent strata in the folds upon this fault system provided the place for magma’s emplacement. So the folds in the upper part and faults in the lower part of the upper crust constituted the fluid’s transport and emplacement network. During the deformation of geologic body with multi-layer structure, the layers in the upper part tended to fold when received the jacking stress from the lower part, while the lower one inclined to fault undergoing loads of the upper part. And the producing probability of this structure assemblage was highly in- creased in the condition, such as in the Tongling area, that the mechanic rigidity of the lower layers was stronger than that of the upper ones. For the pre-existence of fluid-conducting network, the top magma with high volatile in the magma chamber transported rapidly to the superficial layer in dyking pattern, located in the void spaces of folds, filled and reconstructed them. The sudden drop of pres- sure caused the fluid unmixing from the magma and mass ore-forming elements concentration. Pulse activity of the dyking may be the principal reason why magmatic bodies in the Tongling area were spatially-temporally con

关键词： Tongling, structural network, magma intrusion, fractal, dyke.

Permian carbonates of Baoshan block, Western Yunnan and their paleoclimatic implications

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Science china earth Sciences 2004年第5期47卷 385-392页

作者： YAN Jiaxin1, LIANG Dingyi1 & WU Ming2.1. Faculty of earth Sciences, china university of geosciences, {2. {4., china 2. College of Chemistry and Life Sciences, South-Central university for Nationalities, {2. {4., china china Univ Geosci Fac Earth Sci Wuhan 430074 Peoples R China S Cent Univ National Coll Chem & Life Sci Wuhan 430074 Peoples R China

Recently, much attention has been paid to the climatic significance of carbonates originating in shallow water. Permian carbonates of shallow shelf origin are present in the upper part of the Dingjiazhai Formation, the upper part of the Yongde Formation, and the Shazipo Formation on the Baoshan block of Western Yunnan. Their skeleton and non-skeleton grain as-sociations have been investigated in this study. The carbonates of the Dingjiazhai Formation indicate a Bryonoderm (bryozoans-echinoderm) association without non-skeleton grains. The carbonates of Yongde and Shazipo formations show Chloroforam (green algae-foraminifers) association with peloids. Oolites develop in the Shazipo Formation. Based on the comparisons of grain association with coeval carbonates formed in different paleolatitudes (i.e. various paleo-climatic zones), the carbonates of the Dingjiazhai Formation were thought to have been accu-mulated in shelf environments of warm-temperate zone, and those of the Yongde and Shazipo formations in shelf environments of warm-water.

关键词： Early Permian, carbonate, paleoclimate, Western Yunnan.

Geochemical and isotopic imprints of hydrodynamic environments of fissure waters in crystalline rocks

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Chinese Science Bulletin 1997年第9期42卷 756-761页

作者： WANG Yanxin and Khaustov Alexander P.1. china university of geosciences, wuhan {2., china 2. Russian university of People’s Friendship, Moscow, Russia china university of geosciences Wuhan 430074 China

IN recent years,world-wide researches in relation to geologic disposal of nuclear wastes,ore-forming process modelling and ultradeep geologic drilling have been carried out in areas of crys-talline rocks,and,as a resu... 详细信息

关键词： crystalline rocks hydraulic continuity hydrochemistry isotopes.

Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china earth Sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2. ZHAO Zhidan1,2. ZHANG Hongfei3, ZHANG Benren3 & CHEN Yuelong2.1. State Key Laboratory of Geological Processes and Mineral Resources, china university of geosciences, Beijing 100083, {4. 2. School of {2. Science and Mineral Resources, china university of geosciences, Beijing 100083, {4. 3. Faculty of {2. Sciences, china university of geosciences, wuhan 4.0074, {4. 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China 2. School of earth Science and Mineral Resources China University of Geosciences Beijing 100083 China 3. Faculty of earth Sciences China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.2.). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2.b-Zr/4.Y and Ti/100-Zr-YX3 tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(14.)Nd/^(14.)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(2.6)Pb/^(2.4.Pb (18.054.2..562., ^(2.7)Pb/^(2.4.Pb (15.537-15.74.) and ^(2.8)Pb/^(2.4.Pb(38.068-38.530). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

Experimental remolding on the caprock's 3D strain field of the Indosinian-Yanshanian epoch in Tongling deposit concentrating area

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Science china earth Sciences 2005年第7期48卷 863-874页

作者： DENG Jun1,HUANG Dinghua2.WANG Qingfei1,WAN Li1,SUN Zhongshi3,YANG Liqiang1 & GAO Bangfei1 1. State Key Laboratory of Geological Processes and Mineral Resources,china university of geosciences,Beijing 100083,china 2. Faculty of {2. Sciences,china university of geosciences,wuhan 4.0074.china 3. Department of {2. Sciences,Jilin university,Changchun 130061,china State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China Faculty of earth Sciences China University of Geosciences Wuhan 430074 China Department of earth Sciences Jilin University Changchun 130061 China

Based on field observations and rheology analysis, we perform one analogue experiment and remold the 3D structural frame of Tongling deposit concentrating area firstly. Then we disassemble and dialyze the 3D structures of the model using the methods of "slicing" and "stripping". A series of sliced planes vertical to the fold hinges show similar landscapes of that in the drill hole profiles. Meanwhile, layer stripping analysis indicates that the deformation features of each layer in the model are qualitatively analogical to those obtained from field observations. Through contrasting the 3D structure between the experimental model and the field phenomena, we verify the following 3D deformation features of the caprock in this area: (1) the Tongling area mainly consists of three series of NE S-typed fold groups; (2. in the uniform stress field, the incoherent folds universally develop in different positions, along different axes as well as in different strata; (3) the faults propagate upward which are mostly inter-bedded detachment faults, while the fold amplitudes decrease while going deeper; and (4. the folds and cleavages are highly developed in the Silurian System indicating that the deformation effect of the Indosin-ian-Yanshanian structural layer terminates at this layer, which suggests that the Silurian System is the crucial layer for the inversion between brittle and plastic deformation domains and the underlying strata are subject to the control of another deformation system with distinct properties.

关键词： Tongling deposit concentrating area Indosinian-Yanshanian epoch 3D structural frame of the caprock analogue experiment slicing and stripping analysis structural model.

Geothermal and fluid flowing simulation of ore-forming antimony deposits in Xikuangshan

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Science china earth Sciences 2006年第8期49卷 862-871页

作者： YANG Ruiyan1,2. MA Dongsheng2. BAO Zhengyu3, PAN Jiayong2. CAO Shuanglin2.& XIA Fei2.1. School of Mathematics and Physics, china university of geosciences, wuhan {2., china 2. State Key Laboratory for Research of Mineral Deposits, Nanjing university, Nanjing 2.0093, china 3. Faculty of earth Sciences, china university of geosciences, wuhan {2., china 1. School of Mathematics and Physics China University of Geosciences Wuhan 430074 China 2. State Key Laboratory for Research of Mineral Deposits Nanjing University Nanjing 210093 China 3. Faculty of earth Sciences China University of Geosciences Wuhan 430074 China

The Xikuangshan Antimony Deposit located in the Mid-Hunan Basin, china, is the larg- est antimony deposit in the world. Based on the hydrogeological and geochemical data collected from four sections, Xikuangshan-Dajienao (AO), Xikuangshan-Dashengshan (BO), Xikuang- shan-Longshan (CO) and Dafengshan (DO) in the Basin, an advanced metallogenic model related to deep-cyclic meteoric water of Xikuangshan Antimony Deposit is put forward in this paper using a model of heat-gravity-driving fluid flow transportation. The simulation results show that the ore-forming fluid of the deposit mainly comes from the Dashengshan and Longshan areas where BO and CO sections are located if the overall basin keeps a constant atmospheric precipitation and infiltration rate during mineralization, and that the average transportation speed of the ore-forming fluids is about 0.2.0.4.m/a.

关键词： ore-forming fluid, numerical simulation, geothermal field, geofluid transport, Xikuangshan, antimony deposits.