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CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of science and technology {2.,{2. 100083,china

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Acta Metallurgica Sinica(English Letters) 1992年第9期5卷 178-182页

作者： QIAO Lijie LIU Rui XIAO Jimei University of science and technology {2.,{2.,china

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词： stress corrosion cracking stress compoonent brass ammonia solution

Photogeneration of the free radicals and singlet oxygen by chrysophanol from rheum

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science china Chemistry 2004年第5期47卷 381-387页

作者： RAO Jing1,2. XIE Jie1, ZHAO Jingquan1 & ZHU Teng2.1. Key Laboratory of Photochemistry, Center for Molecular science, Institute of Chemistry, The Chinese Academy of sciences, {2. 100080, china 2. University of science and technology {2., beijing 10083, china 1. Key Laboratory of Photochemistry Center for Molecular Science Institute of Chemistry The Chinese Academy of Sciences 100080 Beijing China 2. University of science and technology {2. 10083 Beijing China

In the current work, chryosphanol (MHAQ) was isolated and purified from rheum, and the photosensitization activities were studied. In nitrogen-saturated DMSO solution, irradia- tion of chryosphanol (MHAQ) with visible light (>430 nm) produced the semiquinone radical anions (MHAQ??), which was intensified significantly by an electron donor NADH, suggesting electron transfer between the excited and ground state photosensitizer molecules. In an air-saturated DMSO solution, superoxide radical anions (O2.), trapped by DMPO, were detected. ?? It was proved that O2.was not originated from the singlet oxygen (1O2. but dependent on DMPO, ?? chrysophanol, oxygen and the irradiation time. The singlet oxygen and OH could also be pro- ? duced by the photosensitization of the photosensitizer. These suggest that chrysophanol pos- sesses the photosensitization activity via Type I mechanism and Type II mechanism. To evaluate the photosensitization activities of MHAQ, emodin and mixed anthraquinone derivatives ex- tracted from rheum, the relative productivities of O2.were estimated to be 1.8, 1.1 and 1.0 re- ?? spectively and the quantum yields for singlet oxygen to be 0.36, 0.53 and 0.14 respectively. Therefore, these low-cost pigments may be potentially used as phototherapeutic medicine for some kind of vascular diseases or photo-activated pesticides.

关键词： chrysophanol, ESR, semiquinone radical anions, superoxide radical anions, hydroxyl radical, singlet oxygen.

Research progress in synthesis and catalysis of polyoxometalates

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Progress in Natural science:Materials International 2005年第5期15卷 385-394页

作者： GONG Yun1, HU Changwen1* and LIANG Hong2.1. Department of Chemistry, School of science, the Institute for Chemical Physics, beijing Institute of {2., beijing 100081, china 2. Chemical Industry Press, beijing 10002., china) Department of Chemistry School of Science the Institute for Chemical Physics Beijing Institute of Technology Beijing 100081 China Chemical Industry Press Beijing 100029 China

Recent progress in the synthetic chemistry and catalysis of polyoxometalates (POMs) is reviewed. The novel POMs and their derivatives emerging in nearly three years (2.02.2.04) are introduced, including POMs with novel structure, POMs-organic hybrid compounds and host-guest complexes. Our review is focused on the elaboration of POMs' supramolecular chemistry.

关键词： polyoxometalates hybrid host-guest structure supramolecule catalysis.

On three-dimensional geological modeling and visualization

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science china Earth sciences 2004年第8期47卷 739-748页

作者： WU Qiang1 & XU Hua2.1. Department of Resource Exploitation Engineering, china University of Mining and technology, {2. 100083, china 2. {2. Institute of Petrochemical technology, {2. 102.17, china 1. Department of Resource Exploitation Engineering China University of Mining and Technology 100083 Beijing China 2. beijing Institute of Petrochemical technology 102617 Beijing China

The technology of 3D geological modeling will bring about great changes in the methods of geological data acquiring, storing, processing and displaying. However, no perfect or convenient software systems have been developed up to now since the geologic data which re-flect geological entities bear the feature of diversity, uncertainty and complexity. Some supervoxel models, mathematical models of fault and geometrical models of fold have been contrived so as to show the space geometric configuration of the complicated geologic structures. The application-oriented system architecture for 3D geological modeling is established; and a novel design concept based on spatial data processing is also proposed with the technology of solid modeling as its core and the application of models as its objective. Theories and methods for 3D geological modeling will hopefully be enriched and developed. In the light of these theories and methods, a feature-based navigation visualization technique is also put forward in the paper. By integrating geo-database, graphics libraries and KBS with 3D dynamic simulation systems, geologists will be able to capture the partial characteristics and whole structure embodied in the geological data in a direct-viewing, figurative and accurate manner.

关键词： 3D geological modeling,geometrical model,system architecture,visualization

Flotation Separating Rutile from Calcium and Silicon Gangue Minerals

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Rare Metals 2001年第4期20卷 205-208页

作者： Hao Ding1, HaiLin 2.1) beijing Academy of Building Materials, beijing 100041,{2. 2. University of science and technology beijing, beijing 100083,{2. beijing Acad Bldg Mat Beijing 100041 Peoples R China Univ Sci & Technol beijing Beijing 100083 Peoples R China

Rutile separation from calcite, apatite and quartz by flotation was investigated. The results show that the rutile separation from calcium and silicon gangue minerals can be realized with alkyl-imino-bismethylene phos... 详细信息

关键词： rutile calcium and silicon gangue minerals flotation separate alkyl-imino-bismethylene phosphoric acid sodium hexametaphosphate

The mathematical model of wetting angle of heterogeneous nucleation

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science china(Technological sciences) 2004年第4期47卷 391-397页

作者： HUANG Cheng1, SONG Bo1, MAO Jinghong2.& ZHAO Pei3 1. School of Metallurgical and Ecological Engineering, University of science and technology {2., {2. 100083, china 2. School of Material science, University of science and technology {2., {2. 100083, china 3. Central Iron and Steel Research Institute, {2. 100081, china 1. School of Metallurgical and Ecological Engineering University of Science and Technology Beijing 100083 Beijing China 2. School of Material science University of Science and Technology Beijing 100083 Beijing China 3. Central Iron and Steel Research Institute 100081 Beijing China

The heterogeneous nucleation has been analyzed in terms of the thermodynamic theory, and the mathematical model of wetting angle of heterogeneous nucleation has been developed based on the dynamic requirements of hetero- and homogeneous nucleation. With the wetting angel model, the wetting angles of different catalysts in liquid iron have been calculated. The result shows that the wetting angle of most catalysts is smaller than 40, and the value of f() is far less than 1. The wetting angles of TiN, TiC and RE2.3 are smaller, while the wetting angle of MnO is bigger among the ordinary nucleation catalysts. The wetting angles calculated by this model are in agreement with the results of other research work.

关键词： heterogeneous nucleation, mathematical model, wetting angle, undercooling.

Research progress in the inner surface modification of metal tubes by plasma processing

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Progress in Natural science:Materials International 2006年第11期16卷 1119-1126页

作者： ZHANG Guling~ 1,2.**, WU Xingfang~1, GU Weichao~2. CHEN Guangliang~2. FENG Wenran~2. NIU Erwu~2. LI Li~2. L Guohua~2. CHEN Huan~2. FAN Songhua~2. LIU Chizi~2.and YANG Size~2.1. School of Material science and Engineering, University of science and {2. beijing, beijing 100083, china 2. beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of sciences, beijing 100080, china) School of Material science and Engineering University of Science and Technology Beijing Beijing 100083 China beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100080 China

The recent progress in inner surface hardening of tubes by plasma processing is summerized. Several techniques of inner surface plasma source ion implantation and deposition are introduced, and their advantages and disadvantages are discussed. The basic principles, technical features and new progress of inner surface plasma source ion implantation methods for metal tubes, which were developed in our laboratory, are described in detail. And perspectives of the future technical development for inner surface ion implantation of tubes are presented.

关键词： PSII metal tubes inner surface surface modification.

A new DNA algorithm to solve graph coloring problem

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Progress in Natural science:Materials International 2007年第6期17卷 733-738页

作者： Jiang Xingpeng1, Li Yin2. Meng Ya3 and Meng Dazhi2.1. National Laboratory of Pattern Recognition,Institute of Automation, Chinese Academy of sciences, beijing 100080,{2. 2. College of Applied sciences, beijing University of technology, beijing 10002.,{2. 3. School of science, beijing Institute of technology, beijing 100081,{2.) National Laboratory of Pattern Recognition Institute of Automation Chinese Academy of Sciences Beijing 100080 China College of Applied sciences Beijing University of Technology Beijing 100022 China School of science Beijing Institute of Technology Beijing 100081 China

Using a small quantity of DNA molecules and little experimental time to solve complex problems successfully is a goal of DNA computing. Some NP-hard problems have been solved by DNA computing with lower time complexity than conventional computing. However, this advantage often brings higher space complexity and needs a large number of DNA encoding molecules. One example is graph coloring problem. Current DNA algorithms need exponentially increasing DNA encoding strands with the growing of problem size. Here we propose a new DNA algorithm of graph coloring problem based on the proof of four-color theorem. This algorithm has good properties of needing a relatively small number of operations in polynomial time and needing a small number of DNA encoding molecules (we need only 6R DNA encoding molecules if the number of regions in a graph is R).

关键词： DNA computing NP-hard problem graph coloring problem.

Structure and kinematic analysis of a novel 2.DOF translational parallel robot

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Progress in Natural science:Materials International 2007年第10期17卷 1213-1219页

作者： Chen Tao1, Wu Chao2.and Liu Xinjun2.1. School of Application science and technology, Harbin University of science and technology, Harbin 150080, china 2. Department of Precision Instruments, Tsinghua University, beijing 100084, china) School of Application science and technology Harbin University of Science and Technology Harbin 150080 China Department of Precision Instruments Tsinghua University Beijing 100084 China

This paper addresses the analysis of a novel parallel robot with 2.translational degrees of freedom (DOFs). The robot can position a rigid body in a plane with constant orientation. The kinematic structure of the robot is first described in detail. Some kinematic problems, such as the inverse and forward kinematics, velocity, and singularity are then analyzed. The working and assembly modes are discussed. Since it is the most important index to design a robot, the workspace of the robot is studied systematically in this paper. Based on the analysis of reachable workspace and singularity, a kind of workspace concept characterizing the region that the end-effector of the robot can reach in practice is defined. The results of this paper will be very useful for the design and application of the robot.

关键词： parallel robot degree of freedom kinematics workspace.