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Carbon isotopic characteristics and their genetic relationships for individual lipids in plants and sediments from a marsh sedimentary environment

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science China earth {2. 2005年第8期48卷 1203-1210页

作者： DUAN Yi1, ZHANG Hui1, ZHENG Chaoyang1, WU Baoxiang1 & ZHENG Guodong2.1. Lanzhou Institute of Geology, Chinese Academy of sciences, Lanzhou 730000, China 2. Department of earth & {2. System science, graduate school of science, Hiroshima university, Higashi-Hiroshima 739-85japan 1. Lanzhou Institute of Geology Chinese Academy of Sciences 730000 Lanzhou China 2. Department of earth & planetary System {2. Graduate School of Science Hiroshima University 739-8526 Higashi-Hiroshima Japan

The carbon isotopes of individual lipids in herbaceous plants and tree leaves in Ruoergai marsh were measured by the GC-IRMS analytical technique in order to understand the inherent relationships of carbon isotopes between sedimentary and plant lipids from typical marsh environment. The analytical results show that the carbon isotopic compositions of n-alkanes in different kinds of plants differ significantly. Mean δ 13C values of n-alkanes in her-baceous plants (?32.2.―?36.9‰) are 3.3‰ lower than those in woody plant (?2..2.― ?35.0‰). The carbon isotopic compositions of fatty acids in organisms (?30.3‰― ?36.2.) are very similar to those of n-alkanes and the δ 13C values for unsaturated fatty acids are within the range of those for saturated fatty acids. The differences in δ 13C values between plant lipids are obvious and range from 2.4‰ to 7.8‰. It is observed that the carbon isotopic compositions of sedimentary lipids are closely related to those of plant lipids. The carbon isotopic compositions (?2..0‰―?36.9‰) of n-alkanes, ≥C16 fatty acids, n-alkanols, sterols and n-alkanones in the sediments are similar to those of plant lipids and the carbon isotopic compositions of short-chain sedimentary lipids are similar to those of long-chain sedimentary homologues. These indicate that the sedimentary lipids are derived from high plants. However, the δ 13C values of C14:0 and C15:0 fatty acids in the sediments are lighter than those of the same carbon number saturated homologues in plants, reflecting the genetic features partially derived from bacteria. These data provide scientific evidence for carbon isotope-applied research of individual lipids.

关键词： marsh environment, plants, sediments, individual lipids, carbon isotopic compositions, genetic relationships.

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science China earth {2. 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, China university of Geosciences, Ministry of Education of China, Beijing 100083, China 2. {2. of earth sciences and Mineral Resources, China university of Geosciences, Beijing 100083, China 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. school of earth {2. and Mineral Resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

Paleoceanographic evolution recorded in the northern South China Sea since 4 Ma

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science China earth {2. 2005年第12期48卷 2166-2173页

作者： HUANG Baoqi1,2. JIAN Zhimin2.& WANG Pinxian2.1. school of earth and Space {2., Peking university, Beijing 100871, China 2. Laboratory of Marine Geology, Tongji university, Shanghai 2.0092. China 1. school of earth and Space {2. Peking University 100871 Beijing China 2. Laboratory of Marine Geology Tongji University 200092 Shanghai China

Upper water structure over the last 4 million years in the northern South China Sea (SCS) was reconstructed by sea surface temperature (SST) and primary productivity estimated by changes in the abundance of planktonic foraminifer, planktonic foraminifer transfer function, and the accumulation rate of benthic foraminifera. Results of SST and primary productivity show that SST gradually decreased since 4 Ma, but differential seasonal temperature and primary productivity increased in steps mainly at about 3.1, 2.7, 2.1, 1.6, 0.9 and 0.5 Ma. Comparison with tectonics and orbital variations indicates that phased rising of the Tibet since 3.6 Ma, closing of Panama and Indonesian seaways, and orbital changes were responsible for the changes of upper water structure in the SCS, respectively.

关键词： northern South China Sea, upper water structure, Late Pliocene, planktonic foraminifer, ODP 1146.

Pioneer organisms after F-F mass extinction in Dushan region,Guizhou Province,and their significance in establishing new ecosystem

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science China earth {2. 2006年第5期49卷 449-460页

作者： WANG Yue1, 2. WANG Xunlian1 & SHI Xiaoying1 1. school of earth {2. and Resources, China university of Geo{2., Beijing 100083, China 2. school of Resources and Environment, Guizhou university, Guiyang 550003, China 1. school of earth {2. and Resources China University of Geosciences Beijing 100083 China 2. school of Resources and Environment Guizhou University Guiyang 550003 China

After mass extinctions, most areas became “ecologically barren areas” lacking or even without ecosystem over an extensive region. Studying the pioneer organisms and the reconstruction process of a new ecosystem in the “ecologically barren area” is very important for revealing the evo- lution after bio-mass extinctions. In the Dushan region, Guizhou Province, China, the trace fossils appeared and flourished evidently earlier than body fossils after Frasnian-Famennian (F-F) mass extinction. The pioneer organisms and pathfinders in the “ecologically barren areas” are the trace-makers that are deposit-feeders with relatively simple structure and conformation on or near the deposit surface. The trace-makers have undergone an evolutionary process that their trace structures changed from simple to complex, and their living and moving areas and spaces enlarged from linear to planar and then to three-dimension spaces. Those characters show that the ability of the trace-makers to deposits and their efficiency of looking for food have been enhanced gradually and that those trace-makers constructed gradually a base for the new ecosystem. This process is similar to that of the trace fossils near the Precambrian-Cambrian boundary. In the Dushan area, only the recovery intervals have been identified for the Famennian body fossils, with no eminent radiation interval recognizable due to the Devonian-Carboniferous (C-D) mass ex- tinction. However, both the recovery and radiation intervals may be clearly recognized in the Famen- nian trace fossils based on their conformation and diversity. The evolution and diversification of the trace fossils in the “ecologically barren area” is considered to have played a role of necessary foun- dation for the recovery of body fossils in the ecological chain. With the gradual disappearance of the unfavourable environment factors resulting in the F-F mass extinction, a new ecosystem was reconstructed in the “ecologically barren area” through a three-

关键词： pioneer organisms, reconstruction of ecosystem, trace fossils, F-F mass extinction, Later Devonian, Dushan region, Guizhou Province, China.

Numerical simulations of the bi-level and branched structure of intracloud lightning flashes

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science China earth {2. 2006年第6期49卷 661-672页

作者： TAN Yongbo1, TAO Shanchang1, ZHU Baoyou1, MA Ming2.& LU Weitao2.1. school of earth and Space {2., university of science and Technology of China, Hefei 2.002., China 2. Chinese Academy of Meteorological {2., Beijing 100081, China 1. school of earth and Space {2. University of Science and Technology of China Hefei 230026 China 2. Chinese Academy of Meteorological sciences Beijing 100081 China

Intracloud (IC) lightning flashes have been simulated in fine resolution (12.5 m) by using a bidirectional stochastic lightning parameterization scheme within 2.dimensional domain. The simu-lated results show that the IC flashes have a bilevel channel structure and the altitudes of the hori-zontal channels are at the same heights of potential wells, which are supported by the previous VHF source observations and balloon soundings of electric field profile in the thundercloud. Further con-clusions are: (1) After an IC flash is initiated near the boundary between positve and nagetive charge zone, the negative (or positive) leader tends to propagate into the positive (or negative) charge zone. Both types of positive and negative IC flashes have been reproduced and their polarity depends on the up and down disposition of the positive and negative charge regions. (2. The extension range of leaders is correlative with the cloud charge distribution. The leader is possible to extend through the inverted charge region all over where it is extending, but keeps away from the isolated charge area of the same polarity. (3) The channel structures also depend on the electric potential distributions in the thundercloud. Before propagating into the central area of potential wells, the leader tends to extend along the direction with the maximum of potential gradient. Once extending away from the center of potential wells, the leader tends to extend along the direction with the slowest potential change. (4) The IC flash channels have the fractal feature with fractal dimension 1.45 before leaders pass through the central area of charge regions. The exponent decreases rapidly once leaders extend into the low-density charge regions. (5) The induced charges of opposite polarity are deposited in the leader channels within preexisting positive and negative charge regions during IC flash discharges. This causes a new and complicated charge distribution in the thundercloud, and the potential

关键词： IC, lightning parameterization, branched bilevel structure, fractal feature, propagation tendency.

Almandine megacrysts from Yingfengling Cenozoic basalt in Leizhou Peninsula and their parental magma origin

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Chinese science Bulletin 2001年第14期46卷 1215-1219页

作者： YU Jinhai & S. Y. O’Reilly1. National Key Laboratory of Metallogenic Mechanism of Endogenetic Deposits, Department of earth sciences, Nanjing {2., Nanjing 2.0093, China 2. National Key Center of GEMOC, Department of earth and planetary sciences, Macquarie {2., North Ryde, NSW 2.09, Australia National Key Laboratory of Metallogenic Mechanism of Endogenetic Deposits Department of Earth Sciences Nanjing University Nanjing China National Key Center of GEMOC Department of Earth and Planetary Sciences Macquarie University North Ryde Australia

The garnet megacrysts from Yingfengling basalts are characterlzed by high FeO (>2.%), CaO (7.02. -8.16%) and low MgO (5.88%-10.87%). Significant composition variations are observed in these megacrysts, of which Ni, V, Sc, Co, and HREE are positively correlated with their Mg# and Zr, Hf, Ga, Y, Sr, Nb, Zn and LREE-MREE are negatively correlated with Mg#. Megacryst parent magma is a highly evolved residual melt with strongl depletion in Ti, Sr, Hf, Nb and HREE. This parental magma was generated by more than 60% of crystallization fractionation of clinopyroxene, garnet, plagioclase and ilmenite from quartz tholeiitic magma. It has not erupted to the surface, but stayed at the upper mantle and formed the megacrystic cumulate. Megacrysts and their host basalt are in disequilibrium.

关键词： almandine megacryst geochemistry LAM-ICPMS Lei-zhou Peninsula.

Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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science China earth {2. 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2. JIN Zhenmin1,3, QU Jing2.& WANG Lu2.1. State Key Laboratory of Geological Processes and Mineral Resources, China university of Geosciences, Wuhan 430074, China 2. {2. school of China university of Geosciences, Wuhan 430074, China 3. Faculty of earth sciences, China university of Geosciences, Wuhan 430074, China 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences 430074 Wuhan China 2. graduate school of China {2. of Geosciences 430074 Wuhan China 3. Faculty of earth sciences China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 300 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

Tectonic evolution of the Dabieshan orogen: In the view from polyphase deformation of the Beihuaiyang metamorphic zone

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science China earth {2. 2005年第7期48卷 886-899页

作者： LIN Wei1, 2. Faure Michel3, WANG Qingchen1 & Arnaud Nicolas4 1. LTE, Institute of Geology and Geophysics, Chinese Academy of sciences, Beijing 10002., China 2. Department of earth and {2. sciences, graduate school of science, nagoya university, japan 3. ISTO, UMR CNRS 6113, Batiment Géosciences, Orléans Université d’Orléans, 45067 Orléans Cedex 2. France 4. UMR 652. "Magmas et Volcans", 5 Rue Kessler, 63000 Clermont-Ferrand, France LTE Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China Department of earth and planetary {2. Graduate School of Science Nagoya University Japan ISTO UMR CNRS 6113 Orléans Université d'Orléans 45067 Orléans Cedex 2 France UMR 652. Magmas et Volcans 63000 Clermont-Ferrand 5 Rue Kessler France

The Beihuaiyang metamorphic zone was formed by the Early Mesozoic collision of the North and South China Blocks. It consisted of the Foziling and Luzhenguan complexes and was thought to have never afforded a deep subduction. A similar feature of the deformation in the Dabieshan UHP metamorphic rocks implies that these different tectonic units share the same geodynamic background. The early stage of deformation can be preserved on account of their relatively shallower subduction than that for UHP rocks. On the basis of an analysis of the geo- logical structure and geochronological results, five deformational stages have been recognized: a D1-Early compressional deformation which represents the continental subduction; a D2.Early exhumation deformation producing a syn-convergence exhumation; a D3-Main deformation, represented by an exhumation deformation with Late Triassic age; a D4-Doming and its margin extensional gravity collapse deformation and finally a D5-regional extensional deformation of Cretaceous that was mostly introduced by the migmatization and plutonism.

关键词： Beihuaiyang metamorphic zone geometry kinematic polyphase deformation tectonic evolution.

earthquake-controlled event deposits and its tectonic significance from the Middle Permian Wandrawandian Siltstone in the Sydney Basin, Australia

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science China earth {2. 2005年第9期48卷 1337-1346页

作者： DU Yuansheng1, G. R. Shi1,2.& GONG Yiming1 1. Faculty of earth sciences, China {2. of Geosciences, Wuhan 430074, China 2. school of Ecology and Environment, Deakin {2., Victoria 312., Australia 1. Faculty of earth sciences China University of Geosciences 430074 Wuhan China 2. school of Ecology and Environment Deakin University 3125 Victoria Australia

The Sydney-Bowen basin in eastern Australia is an elongate back arc-converted foreland basin system situated between the Lachlan Fold Belt in the west and the New England Fold Belt in the east. The Middle Permian Wandrawandian Siltstone at Warden Head near Ulla- dulla in the southern Sydney Basin is dominated by fossiliferous siltstone and mudstone, with a large amount of dropstones and minor pebbly sandstone beds. Two general types of deposits are recognized from the siltstone unit in view of the timing and mechanism of formation. One is rep- resented by the primary deposits from offshore to subtidal environments with abundant drop- stones of glacial marine origin. The second type is distinguished by secondary, soft-sediment deformational deposits and structures, and comprises three layers of mudstone dykes of seismic origin. In the latter type, metre scale, laterally extensive syn-depositional slump deformation structures occur in the middle part of the Wandrawandian Siltstone. The deformation structures vary in morphology and pattern, including large-scale complex-type folds, flexural stratification, concave-up structures, faulting of small displacements accompanied by folding and brecciation. The slumps and associated syn-sedimentary structures are attributed to penecontemporaneous deformations of soft sediments (mostly silty mud) formed as a result of mass movement of un- consolidated and/or semi-consolidated substrate following an earthquake event. The occurrence of the earthquake event deposits supports the current view that the Sydney Basin was located in a back-arc setting near the New England magmatic arc on an active continental margin during the Middle Permian.

关键词： Permian, seismites, earthquake, tectonics, Sydney Basin, Australia.