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Synthesis,characterization,and thermostability of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(Ⅱ)

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Rare Metals 2012年第4期31卷 343-349页

作者： ZHANG Teng,GU Hongwei,DING Fazhu,QU Fei,and DAI Shaotao key laboratory of Applied Superconductivity,institute of Electrical Engineering,chinese academy of sciences,beijing 100190,china key laboratory of Applied Superconductivity Institute of Electrical Engineering Chinese Academy of Sciences Beijing China

Owing to the adaptability to large scale processing,excellent composition control and film uniformity,the metal-organic chemical vapor deposition（MOCVD） technique is a promising process for high-temperature superconductor YBa;Cu;O;（YBCO） *** this technique,the evaporation characteristics and thermostability of adopted precursors in whole process will decide the quality and reproducible results of YBCO *** the present report,bis（2,2,6,6-tetramethyl-3,5-heptanedionato）copper（II）(Cu（TMHD）;) was synthesized by the interaction of copper acetate hydrate with TMHD in methanol solution,and its structure was identified by FTIR,1 H NMR,and EI-MS ***,thermal property and the kinetics of decomposition were systematically investigated by nonisothermal thermogravimetric analysis methods（TGA） at different heating rates in streams of N;,and the average apparent activation energy of evaporation process was evaluated by the Ozawa,Kissinger,and Friedman *** possible conversion function was estimated through the Coats-Redfern method to characterize the evaporation patterns and followed a phase boundary reaction mechanism by the contracting area equation with average activation energy of 85.1 kJ·mol;.

关键词： Cu(TMHD)_2 metal-organic chemical vapor deposition(MOCVD) synthesis thermostability

VISCOELASTIC BEHAVIOR OF THE NON-HOOKE DEFORMATION BEFORE YIELDING IN UNIAXIAL DRAWING OF AMORPHOUS POLY(ETHYLENE TEREPHTHALATE)

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chinese Journal of Polymer Science 2001年第4期19卷 399-405页

作者： Zhen-hua Yuan De-yan Shen Ren-yuan Qian Polymer physics laboratory Center for Molecular Science, institute of Chemistry chinese academy of sciences, beijing 100080 china chinese Acad Sci Inst Chem Ctr Mol Sci Polymer Phys Lab Beijing 100080 Peoples R China

Viscoelastic behavior of the non-Hooke deformation of amorphous PET film before yield was investigated in the temperature region 74-80.5 degreesC around the glass transition temperature. The film specimen was drawn to yield point followed by unloading to zero stress, then the residual deformation was held constant; while the subsequent evolution of the stress was recorded. An induction period was found in the course of stress evolution followed by a stress step-increase. The induction period decreases with increasing drawing temperature with an activation energy of 1.10 MJ/mol.K, which is attributed to the time needed for the relaxation of rubbery deformation through cooperative internal rotations. At temperatures lower than 74 degreesC, there is no stress increase or the induction period becomes too long to be observed. Thus the nature of anelasticity in the non-Hooke region before yielding is attributed to stress induced rubbery deformation. The experimental results are interpreted in terms of Perez' theological model of a series connected Hooks spring and a Voigt element consisting of a parallel connected elastic spring and a dashpot.

关键词： pre-yield deformation PET uniaxial drawing non-Hooke deformation viscoelasticity stress induced rubbery deformation

Evolution of desertification in a two-dimensional energy balance model coupled with thermodynamics and dynamics

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Science china Earth sciences 2010年第11期53卷 1726-1733页

作者： CHAO JiPing1,2 & LI YaoKun3,4 1National Marine Environmental Forecasting Center, beijing 100081, china 2First institute of Oceanography, State Oceanic Administration, Qingdao 266061, china 3State key laboratory of Numerical Modeling for Atmospheric sciences and Geophysical Fluid Dynamics, institute of Atmospheric physics, chinese academy of sciences, beijing 100029, china 4Graduate University of chinese academy of sciences, beijing 10004., china 1. National Marine Environmental Forecasting Center Beijing 100081 China2. First Institute of Oceanography State Oceanic Administration Qingdao 266061 China3. State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China4. Graduate University of Chinese Academy of Sciences Beijing 100049 China

The relationship between desert evolution and change in albedo has been investigated quasi-analytically using a zonal mean two-dimensional energy balance model which considers the radiation transmission process due to thermodynamics and bound- ary layer movement caused by kinetics. A climate state including temperature, zonal wind, meridional wind and vertical wind can be simulated according to the current zonal distribution of albedo. Given desert distribution, characterized by the value and distribution of albedo, the response of climate on albedo has been studied to analyze the evolution of desert climate. One significant result is that the simple model can reproduce mean meridional circulation. Another result indicates that climate corresponds to two equilibria. This happens when the junction temperature between vegetation and desert is higher than a certain critical value. As for the first equilibrium, the desert belt is predicted to move southward in the northern hemisphere with the increasing values of albedo, which corresponds to the current trend of climate change. For the second equilibrium, vegetation will expand northward with increasing values of albedo, which would indicate a narrowing of the desert belt. In order to determine if the two equilibria exist, new physical models are needed.

关键词： two-dimensional energy balance model desertification two equilibria

EI NIO PHENOMENON AND EXTENDED ASSOCIATE PATTERN ANALYSIS

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Journal of Hydrodynamics 2004年第1期16卷 90-100页

作者： CUIMao-chang MOJun QIAOFang-li instituteofOceanology ChineseAcademyofSciences.Qingdao266071China／KeyLaboratoryofMarineScienceandNumericalmodelingTheFirstInstituteofOceanographyStateOceanicAdministrationQingdao266061China. instituteofOceanology ChineseAcademyofSciences.Qingdao266071China keylaboratoryofMarineScienceandNumericalmodeling TheFirstInstituteofOceanographyStateOceanicAdministrationQingdao266061China

To study the causes of El Nino Phenomenon the Extended Associate PatternAnalysis (EAPA) is set up with monthly sea surface wind stress and precipitation besides Sea LevelPressure (SLP) and Sea Surface Temperature (SST) in or over the Pacific and related seas since 1979in present paper. The results show that El Nino Phenomenon means a SST redistribution, coveringalmost the whole Pacific that needs a huge amount of energy provided by air-sea interaction in themost Pacific regions; It is the wester burst and wind convergence, coming from meddle latitudesdirectly, instead of Kelvin waves that produce the strong SST warm signal in Nino regions; Twonegative SLP anomalies in middle of the North and South Pacific, most likely produced by the averageair pressure decreasing effect of explosive cyclones through precipitation, and the positive SLPanomaly o-ver the Asia-Australia land bridge, coming mainly from the south hemisphere with a littleinfluence from the Asian continent, are the three major causes for El Nino onset, they work togetherto produce anomalous wind convergence in Nino regions and wester burst in middle of the North andSouth Pacific that result in a warm tongue and cold pincers gearing together; Basically, during itsearly stage the ocean is forced by the atmosphere, while during its late stage the atmosphere isforced by the ocean.

关键词： extended associate pattern analysis (EAPA) El nino phenomenon

A template of rat brain based on fMRI T2* imaging

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Progress in Natural Science:Materials International 2005年第6期15卷 502-506页

作者： HU Zhenghui1, WU Yigen2, WANG Xiaochuan3, WANG Jianzhi3, CHEN Feiyan1 and TANG Xiaowei1*(1. Department of physics and Bio-X laboratory, Zhejiang University, Hangzhou 310027, china 2. institute of high energy physics and key laboratory of Nuclear Analysis Techniques, chinese academy of sciences,beijing 100039, china 3. Department of Pathophysiology, Tongji Medical College, Huazhong University of Science and Technology, Wuhan 430030, china) Department of physics and Bio-X laboratory Zhejiang University Hangzhou 310027 China institute of high energy physics and key laboratory of Nuclear Analysis Techniques Chinese Academy of Sciences Beijing 100039 China Department of Pathophysiology Tongji Medical College Huazhong University of Science and Technology Wuhan 430030 China

The development of functional magnetic resonance imaging (fMRI) technology has made it possible to carry out functional brain imaging experiments in small animals. Usually, group data is required to form the assessment of population, which can not only increase the sensitivity of the overall experiment, but also allow the generalization of the conclusion to the whole population. In order to average the signals of functional brain images from different subjects, it is necessary to put all the mapping images into the same standard space (template image). However, up to now, most animal brain templates remain unavailable and it must be done by ourselves. In this study, a template image based on the brains of eight male Wistar rats is obtained, and it is successfully used in our present Alzheimer disease (AD)-like rat model studies as template for spatially normalizing images to the same stereotaxical space. The fMRI results processed with statistical parametric mapping (SPM99) software are in agreement with the results from immunohistochemical experiment, which proves that this method is universally applicable to the pathologic models of other small animals and to human brain lesion studies.

关键词： fMRI animal model atlas template normalization T*2.

Preparation and Characterization of Palladium Colloidal Nanoparticles by Thermal Decomposition of Palladium Acetate with Microwave Irradiation

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Journal of Materials Science & Technology 2005年第2期21卷 187-190页

作者： Yixian CHEN, Baolin HE and Hanfan LIU Hubei key laboratory for Catalysis and Material Science, University of South-Central for Nationalities, Wuhan 430074, china PCLCC, State key laboratory of Polymer physics and Chemistry, institute of Chemistry, chinese academy of sciences, beijing 100080, china Lab. for Catalysis and Mat. Sci. Univ. of South-Central for Natl. Wuhan 430074 China Lab. of Polymer Phys. and Chem. Inst. of Chem. Chinese Acad. of Sci. Beijing 100080 China

A series of solvent-stabilized palladium colloidal nanoparticles were prepared via thermal decomposition of palladium acetate methylisobutylketone (MIBK) solution in the presence of alkali and alcohol with microwave irradiation. The colloidal nanoparticles were characterized with TEM, XPS and XRD. The average diameters of nanoparticles increase from 30 to 40 nm with the increase in concentration of palladium acetate. TEM and XRD observation demonstrated that the palladium colloidal nanoparticles were clusters agglomerated from hundreds of smaller palladium crystallines with size of 3-4 nm. The influence of the concentrations of alkali and alcohol to the particle size was also discussed.

关键词： Thermal decomposition Microwave Palladium acetate Methylisobutylketone

energy Transfer among Chlorophylls in Trimeric Light-harvesting Complex Ⅱ of Bryopsis corticulans

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Acta Biochimica et Biophysica Sinica 2006年第5期38卷 310-317页

作者： Su-Juan ZHANG~(1,2*)Shui-Cai WANG~2 Jun-Fang HE~2 Hui CHEN~3 1 institute of Photonics and Photo-Technology,Northwest University,Xi'an 710069,china 2 State key laboratory of Transient Optics and Photonics,Xi 'an institute of Optics and Precision Mechanics,chinese academy of sciences,Xi'an 710068.china 3 Laboratoty of Photosynthesis Basic Research,institute of Botany,chinese academy of sciences,beijing 100093,china institute of Photonics and Photo-Technology Northwest UniversityXi'an 710069 China State key laboratory of Transient Optics and Photonics Xi'an Institute of Optics and Precision Mechanics Chinese Academy of SciencesXi'an 710068 China laboratory of Photosynthesis Basic Research Institute of Botany Chinese Academy of SciencesBeijing 100093 China

A study on energy transfer among chlorophylls（Chls）in the trimeric unit of the major light-harvesting complex Ⅱ（LHC Ⅱ）from Bryopsis corriculan,was carried out using time-correlated singlephoton *** the chlorophyll Q region of LHC Ⅱ,six molecules characterized as Chlb628,Chlb646,Chlb652654,657,Chla664666,Chla674677.680and Chla682683were discriminated according to their absorption spectrumand fluorescence emission ***,excited by pulsed light of 628 nm,fluorescence kinetics spectrain the chlorophyll Q region were *** accordance with the principles of fluorescence kinetics,thesekinetics data were analyzed with a multi-exponential *** constants on energy transfer were *** overwhelming percentage of energy transfer among chlorophylls undergoes a process longer than 97picoseconds（ps）,which shows that,before transferring energy to another Chl,the excited Chl might convertenergy to vibrations of a lower state with different multiplicity（intersystem crossing）.energy transfer at thelevel of approximately 10 ps was also obtained,which was interpreted as the excited Chls may go throughinternal conversion before transferring energy to another *** with a higher standard deviation,timeconstants at the femtosecond level can not be entirely excluded,which can be attributed to the ultrafastprocess of direct energy *** to the arrangement and direction of the dipole moment of Chls inLHC Ⅱ,the probability of these processes is *** fluorescence lifetimes of Chlb652654,657,Chla664666,Chla674677.680and Chla682683were determined to be 1.44ns,1.43 ns,636 ps and 713 ps,*** of energy dissipation in the pathway of fluorescence emission were no more than 40% in thetrimeric unit of LHC Ⅱ.These results are important for a better understanding of the relationship between thestructure and function of LHC Ⅱ.

关键词： energy transfer LHC Ⅱ transient spectrum fluorescence kinetics

Current distribution and stability of LTS/HTS hybrid superconducting conductors

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Science china(Technological sciences) 2010年第7期53卷 2000-2007页

作者： GUAN XiaoJin1,2, WANG YinShun1 & ZHOU WeiWei3 1 key laboratory of HV and EMC beijing, North china Electric Power University, beijing 102206, china 2 Department of physics, Baoding University, Baoding 071000, china 3 institute of Electrical Engineering, chinese academy of sciences, beijing 100190, china 1. key laboratory of HV and EMC beijing North China Electric Power University Beijing 102206 China2. Department of Physics Baoding University Baoding 071000 China3. Institute of Electrical Engineering Chinese Academy of Sciences Beijing 100190 China

Current distribution and stability of a hybrid LTS/HTS superconductor, consisting of multifilamentary NbTi/Cu and Bi2223/Ag tapes, were numerically analyzed according to power-law models. The results showed that most of current passed through the LTS and the current increased in the HTS with temperature rise when the transport current was below the critical current of the hybrid conductor. The quench propagation velocity of the hybrid conductor was smaller but its minimum quench energy was larger than those of LTS conductors, indicating that the stability of the hybrid superconducting conductor was effectively improved and a high engineering current density was simultaneously achieved. Finally, a hybrid sample, made by soldering Bi2223/Ag tape onto NbTi/Cu conductor, was prepared and tested successfully at helium temperature. The experimental results qualitatively agreed with the simulated ones.

关键词： distribution hybrid conductor minimum quench energy quench propagation velocity n value stability

Analysis of leakage current in GaAs micro-solar cell arrays

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Science china(Technological sciences) 2010年第5期53卷 1240-1246页

作者： WANG YanShuo1,CHEN NuoFu1,2,3,ZHANG XingWang1,BAI YiMing1,WANG Yu1,HUANG TianMao1,ZHANG Han1 & SHI HuiWei1 1 key laboratory of Semiconductor Materials Science,institute of Semiconductors,chinese academy of sciences,PO Box 912,beijing 100083,china 2 School of Renewable energy Engineering,North china Electric Power University,beijing 102206,china 3 National laboratory of Micro-Gravity,institute of Mechanics,chinese academy of sciences,beijing 100080,china 1. key laboratory of Semiconductor Materials Science Institute of Semiconductors Chinese Academy of Sciences PO Box 912 Beijing 100083 China2. School of Renewable Energy Engineering North China Electric Power University Beijing 102206 China3. National Laboratory of Micro-Gravity Institute of Mechanics Chinese Academy of Sciences Beijing 100080 China

The output characteristics of micro-solar cell arrays are analyzed on the basis of a modified model in which the shunt resistance between cell lines results in current *** modification mainly consists of adding a shunt resistor network to the traditional *** obtained results agree well with the reported experimental *** calculation results demonstrate that leakage current in substrate affects seriously the performance of GaAs micro-solar cell *** performance of arrays can be improved by reducing the number of cells per *** addition,at a certain level of integration,an appropriate space occupancy rate of the single cell is recommended for ensuring high open circuit voltages,and it is more appropriate to set the rates at 80%-90% through the calculation.

关键词： micro-solar cell MEMS(micro-electromechanical systems) leakage current