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Theoretical analysis of alloy multiplying factor by the empirical electron theory of solids and molecules

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science china(Technological sciences) 2007年第6期50卷 807-814页

作者： SONG YuePeng1,2, LIU GuoQuan2, LI ZhiLin3, FENG ChengMing1 1 Mechanical and Electronic engineering college, Shandong Agricultural university, Tai’an 271018, china 2 college of materials science and engineering, university of science and technology, beijing 100083. china 3 college of Material science and engineering, beijing university of Chemical technology, beijing 100029, china Mechanical and Electronic engineering college Shandong Agricultural University Tai’an China college of materials science and engineering University of Science and Technology Beijing China college of Material science and engineering Beijing University of Chemical Technology Beijing China

By introducing the distribution probability of structural units in austenite contain- ing alloying elements and considering its effects on phase transformation, this paper establishes a calculation model of distribution probability of structural units. A new valence electron structure (VES) parameter-transformation effect coefficient of alloying elements (HL), is defined and then studied both theoretically and ex- perimentally. The relationship between the parameter HL and the multiplying factor (the quenching capability factor) of alloying elements is studied. The results indi- cate that the two parameters (HL and the quenching capability factor) have the same variation characteristic and substance feature. Therefore, the multiplying factor virtually expresses the relative quantity of structural units in the alloying elements-containing austenite.

关键词： multiplying factor (the quenching capability factor), empirical electron theory of solids and molecules, transformation effect coefficient of alloying elements, structural units in austenite containing alloying elements

Dislocation Densites of Deformed Steel Sheets Based on Positron Annihilation

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International Journal of Minerals,Metallurgy and materials 1998年第1期12卷 47-50页

作者： Yonglin Kang Xianjin Wang (materials science and engineering School, university of science and technology beijing, beijing 100083. china) materials science and engineering School University of Science and Technology Beijing Beijing 100083 China

The variation regularity of dislocation densites of some deformed steel sheets under three kinds of strainpaths as uniaxial tension, plane strain and equal biaxial stretching was investigated by means of positron lifetimespectrum and Doppler-broadening techniques. The results show that the increasing rate of dislocation densites isrelated to the plastic strain path. A relationship between the increasing rate of micro-defects, macro-instability andforming limits during the process of steel sheet forming was got based on analyzing the mechanism of dislocationdensity increasing under different stress-strain condihons.

关键词： positron annihilation dislocation steel sheet strain path

Sol-gel Preparation and Infrared Radiation Property of Boron-substituted Cordierite Glass-ceramics

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Journal of materials science & technology 2010年第5期26卷 445-448页

作者： Shuming Wang and Fenghua Kuang School of materials science and engineering,university of science & technology beijing,beijing 100083.china School of materials science and engineering University of Science & Technology Beijing Beijing 100083 China

Boron for aluminum substitution in the cordierite structure has been examined by sol-gel preparation of different samples along the compositional junction Mg2Al4-xBxSi5O18 with x=0,0.5,1,*** increasing the x value from 0 to 1.5 the crystallization behavior changed *** amount B2O3 doping can promote the sintering of amorphous cordierite gel,effectively restrain the precipitation of μ-cordierite and enhance the crystallization of α-*** substitution of B3＋ for Al3＋ in cordierite crystal structure can effectively improve the near-infrared spectral emissivity of this cordierite based glass-ceramics.

关键词： Sol-gel Glass-ceramics Infrared radiation B3+ substitution Solid solution

Microstructural Features During Strain Induced Ferrite Transformation in 08 and 20Mn Steels

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Journal of university of science and technology beijing 2001年第2期8卷 105-110页

作者： Ping Yang, Feng-e Cui, Fuming Wang (materials science and engineering School, university of science and technology beijing, beijing 100083. china) (Metallurgy School, university of science and technology beijing, beijing 100083. china) materials Sci. and Eng. School University of Science and Technology Beijing 100083 China

The microstructure evolution during strain induced ferrite transformation was followed in thermal-simulation tests of clean 08 and 20Mn steels. The influences of carbon equivalence and initial austenite grain size on ferrite grain refinement and the volume fraction of ferrite during straining were inspected. The results revealed that the accelerating effect of ferrite transformation by strain was increased as the carbon equivalence decreased. However, finer ferrite grains were obtained at higher carbon content. At strain of similar to1.5 ferrite grains less than 3 mum and 2 mum can be obtained in 08 and 20Mn steels respectively. Whereas the ferrite grain refinement in 08 steel was due to both effects of strain induced transformation and ferrite dynamic recrystallization, that in 20Mn was mainly due to strain induced transformation. Heavy strain can produce fine ferrite grains in coarse austenite grained 08 steel, but it would lead to band microstructure in coarse austenite grained 20Mn.

关键词： clean carbon steel strain induced transformation grain refinement ferrite dynamic recrystallization

Effects of silver powder particle size on the microstructure and properties of Ag-Yb_2O_3 electrical contact materials prepared by spark plasma sintering

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Rare Metals 2010年第4期29卷 366-370页

作者： CHEN Xiaohua,JIA Chengchang,and LIU Xiangbing School of materials science and engineering,university of science and technology beijing,beijing 100083.china School of materials science and engineering University of Science and Technology Beijing Beijing China

mg-Yb203 electrical contact materials were fabricated by spark plasma sintefing （SPS）. The effects of silver powder particle size on the microstructure and properties of the samples were investigated. The surface morphologies of the sintered samples were examined by optical microscope （OM）, and the fracture morphologies were observed by scanning electron microscopy （SEM）. The physical and mechanical properties such as density, electrical resistivity, microhardness, and tensile strength were also tested. The results show that the silver powder particle size has evident effects on the sintered materials. Comparing with coarse silver powder （5 ktm）, homogeneous and fme microstmcture was obtained by fine silver powder （_〈0.5-1am）. At the same time, the electrical conductivity, microhardness, and tensile strength of the sin- tered samples with fine silver powder were higher than those of the samples with coarse silver powder. However, silver powder particle size has little influence on the relative densities, which of all samples （both by free and coarse silver powders） is more than 95%. The fracture characteristics are ductile.

关键词： composites electrical contact materials spark plasma sintering particle size microstructure physical properties mechanical properties

Analysis on Microstructure and Misorientation of Ultrathin Hot Strip of Low Carbon Steel Produced by Compact Strip Production

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Journal of materials science & technology 2002年第6期18卷 501-503页

作者： Hao YU, Yonglin KANG and Jie FUSchool of materials science and engineering, university of science and technology beijing, beijing 100083. china Sch. of Mat. Sci. and Eng. Univ. of Sci. and Technol. Beijing Beijing 100083 China

The microstructure and misorientation of ultrathin hot strip were analyzed by CSP technology using electron back scattered diffraction (EBSD) method and Autoforge finite element program. The experimental results showed that the finishing hot rolling microstructures were the mixture of recrystallized and deformed austenite. After phase transformation, ferrite grains embody substructures and dislocations, leading to the high strength and relatively low elongation rate of the ultrathin hot strip. The FEM simulation of strain mode and distribution in deformation area has been fulfilled. The simulation results are in good agreement with the theoretical analysis and experimental results.

关键词： CSP Electron back scattered diffraction, Texture, Finite element method

Effect of powder mixing process on the microstructure and thermal conductivity of Al/diamond composites fabricated by spark plasma sintering

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Rare Metals 2010年第1期29卷 86-91页

作者： CHU Ke, JIA Chengchang, LIANG Xuebing, and CHEN Hui School of materials science and engineering, university of science and technology beijing, beijing 100083. china School of materials science and engineering University of Science and Technology Beijing Beijing China

Two powder mixing processes, mechanical mixing （MM） and mechanical alloying （MA）, were used to prepare mixed Al/diamond powders, which were subsequently consolidated using spark plasma sintering （SPS） to produce bulk Al/diamond composites. The effects of the powder mixing process on the morphologies of the mixed powders, the microstructure and the thermal conductivity of the composites were investigated. The results show that the powder mixing process can significantly affect the microstructure and the thermal conductivity of the composites. Agglomerations of the particles occurred in mixed powders using MM for 30 min, which led to high pore content and weak interfacial bonding in the composites and resulted in low relative density and low thermal conductivity for the composites. Mixed powders of homogeneous distribution of diamond particles could be obtained using MA for 10 min and MM for 2 h. The composite prepared through MA indicated a high relative density but low thermal conductivity due to its defects, such as damaged particles, Fe impurity, and local interfacial debonding, which were mainly introduced in the MA process. In contrast, the composite made by MM for 2 h demonstrated high relative density and an excellent thermal conductivity of 325 W.m^-1.K^-1, owing to its having few defects and strong inter-facial bonding.

关键词： metal matrix composites thermal properties sintering powder mixing

Predicting Equation for Adjusting Glass Temperature of Binder Used for P/M Warm Compaction Processing

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International Journal of Minerals,Metallurgy and materials 1998年第1期12卷 39-40页

作者： Shiju Guo Tao Lin Mingyi Li (materials science and engineering School, university of science and technology beijing, beijing 100083. china) materials science and engineering School University of Science and Technology Beijing Beijing 100083 China

Based on considering both negative effect of compacting pressure on glass temperature (Tg) and positiveeffect of plasticizer added into organic binder, a mathematical equation for adjusting Tg of binder used for warmcompaction processing is given. The equation shows that mass fraction of plasticizer need for lowering Tg is function of compacting plessure. The rationality of the equation for warm compaction processing is also discussed.

关键词： warm compaction binder glass temperature

Fabrication of pure copper rods containing continuous columnar crystals by continuous unidirectional solidification technology

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Journal of university of science and technology beijing 2004年第3期11卷 240-244页

作者： Hong zhang Jianxin Xie Zidong Wang materials science and engineering School, university of science and technology beijing, beijing 100083. china Mat. Sci. and Eng. Sch. Univ. of Sci. and Technol. Beijing Beijing 100083 China

Pure copper rods containing continuous columnar crystals were fabricatedusing the downward CUS (Continuous Unidirectional Solidification) equipment. When the technologicalparameters were set as the ranges of mould temperature 1100-1300℃, cooling distance (the distancefrom the exit of the cast mould to the start point of cooling) 10-20 mm, casting speed 0.2-2.5 mm/s,cooling water (20-25℃) volume 1000-1320 L/h, and when these parameters matched reasonably, the CUSprocess was performed stably, and pure copper rods containing continuous columnar crystals withbright and smooth surface were produced. The dendritic arm spacing of the crystals in copper rodsdecreased with increasing the casting speed. The results of the texture by X-ray diffractionanalysis showed that the rods has strong fiber texture.

关键词： copper continuous unidirectional solidification mould temperature castingspeed microstructure texture