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Total alkyl dibenzothiophenes content tracing the filling pathway of condensate reservoir in the Fushan Depression,South china Sea

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Science china Earth Sciences 2008年第S2期51卷 138-145页

作者： LI MeiJun1,WANG TieGuan1,LIU Ju2,ZHANG MeiZhu2,LU Hong3,MA QinLin2 & GAO LiHui2 1 State Key Laboratory of Petroleum Resources and Prospecting,Earth Sciences and Geoinformatics School,china University of Petroleum,Beijing 102249,china 2 southern oil exploration and development company,petrochina,guangzhou 510640,china 3 guangzhou Institute of Geochemistry,Chinese Academy of Sciences,guangzhou 510240,china State Key Laboratory of Petroleum Resources and Prospecting Earth Sciences and Geoinformatics School China University of Petroleum Beijing China southern oil exploration and development company PetroChina Guangzhou China guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China

The condensates are generally characterized by high maturity,low concentration of steranes and ter-panes biomarkers and low content of non-hydrocarbon fraction. In this case commonly used steranes,terpanes and carbazoles parameters cannot be effectively applied in the reservoir-filling tracing. The hydrogen bond formed by sulfur atom in the dibenzothiophenes (DBTs) results in molecule adsorption and fractionation during oil migration in reservoir. Like carbazoles,total DBTs content decreases with the increasing of oil migration distance. Therefore,a new parameter——total DBTs content is proposed to be used to trace the oil migration orientation and filling pathway. In present study,total DBTs con-tents of condensates and light oils are obtained by adding internal standard——eight deuterium atoms substituted DBT during Gas Chromatography-Mass Spectrometry analysis of aromatic fraction. Except for a few samples with much lower content of non-hydrocarbon fraction,the total DBTs content shows a fine positive correlation with that of carbazoles. Large errors can be caused in the process of pyrrolic nitrogen compounds separation. The application of this new parameter in the Fushan Depression of Beibu Gulf Basin,South china Sea indicates that this parameter is a reliable one to trace filling pathway in condensate reservoirs. Combined with other DBTs-related parameters,such as 4-/1-methydibenzo-thiophene and 2,4-/1,4-dimethyldibenzothiophene,oil migration orientation and filling pathway of the Fushan Depression was determined. The accumulations of Huachang oil field in the Fushan Depres-sion are mainly migrated and charged from northeast to southeast along the Huachang uplift. It can be predicated that the light oil and condensates in the Huachang oil field should be sourced from the source kitchen at the Bailian Sag. It shows that total DBTs content is an effective parameter to tracing oil migration orientation and filling pathway.

关键词： dibenzothiophene alkyl dibenzothiophene condensate reservoir filling pathway molecular markers the Fushan Depression

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Present geotemperature and its suggestion to natural gas generation in Xujiaweizi fault-depression of the northern Songliao Basin

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Science china Earth Sciences 2008年第S1期51卷 207-220页

作者： ZHOU QingHua 1,2 ,FENG ZiHui 3 &MEN GuangTian 3 1 Research Institute of Petroleum exploration and development,petrochina,Beijing 100083,china 2 Geological Logging Subcompany of Daqing oil Field company Ltd.,Daqing 163411,china 3 Research Institute of Petroleum exploration and development of Daqing oil field company Ltd.,Daqing 163732,china Research Institute of Petroleum exploration and development PetroChina Beijing China Geological Logging Subcompany of Daqing oil Field company Ltd. Daqing China Research Institute of Petroleum exploration and development of Daqing oil field company Ltd. Daqing China

According to stastistic of present geotemperatures at the depths of 1000,2000,3000 and 4000 m,respectively in the Xujiaweizi fault-depression of the north Songliao Basin,the result indicates that Xujiaweizi fault-depression falls in the high geotemperature area,with the higher geothermal gradient in the depression layer than that in the fault-depression *** geothermal gradient decreases with the increasing of the *** thermal conductivity of rock greatly controls the geothermal *** main factors constraining the current geotemperature include thermal configuration of the earth's crust, deep faults,distribution and abundance of *** high geotemperature is in favour of generation of deep gas.

关键词： Xujiaweizi fault-depression geotemperature geothermal gradient thermal conductivity of rock deep layer natural gas

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Abnormal high pressure in Kuqa foreland thrust belt of Tarim basin: Origin and impacts on hydrocarbon accumulation

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Progress in Natural Science:Materials International 2006年第12期16卷 1307-1314页

作者： ZENG Lianbo~1** and LIU Benming~ 1,2 (1. Key Laboratory of Hydrocarbon Accumulation in china Petroleum University, Ministry of Education, Beijing 102249, china 2. The Institute of oil and Gas exploration and development, Tarim oilfield company, petrochina company Limited, Korla 841000, china) Key Laboratory of Hydrocarbon Accumulation in china Petroleum University Ministry of Education Beijing 102249 China The Institute of oil and Gas exploration and development Tarim Oilfield Company PetroChina Company Limited Korla 841000 China

Following analyses of the abnormal high pressure distribution characteristics, based on the geological characteristics, tectonic stress field and physical simulation, we investigated the formation mechanisms of abnormal high pressure and its impacts on hydrocarbon accumulation in the Kuqa foreland thrust belt. The abnormal high pressure appears at the bottom of the Paleogene and obviously exists in the Triassic and Jurassic. However, the pressure coefficient in the Triassic and Jurassic is lower than that in the Cretaceous and at the bottom of the Paleogene. Horizontally, the abnormal high pressure distribution is characterized by E-W orientation zoning. The maximum pressure coefficient lies in the Kelasu-Dongqiu-Dina tectonic zones in the center of the Kuqa foreland thrust belt and decreases away from the tectonic zones. The formation of abnormal high pressure was mainly related with the intense tectonic compression in the Early Pleistocene time, and tectonic uplifting, undercompaction and hydrocarbon generation were secondary factors contributing to abnormal high pressure. Under the rapid and intense tectonic compression in the Early Pleistocene, the rock framework firstly undertook 1/4 of the compression stress and the other was borne by the pore fluids. Due to the presence of great seal of gypsum-salt or gypsum-mudstone beds in the Paleogene, the pressure of pore fluids increased rapidly and led to the abnormal high pressure in the Kuqa foreland thrust belt. The abnormal high pressure has important impacts on hydrocarbon accumulation. It is one of the necessary conditions for formation of large oil and gas fields in the Kuqa foreland thrust belt.

关键词： abnormal high pressure formation mechanism oil and gas reservoir Kuqa foreland thrust belt Tarim basin.

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Kinetics of hydrocarbon generation for Well Yingnan 2 gas reservoir,Tarim Basin,china

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Science china Earth Sciences 2008年第S1期51卷 107-114页

作者： XIAO ZhongYao 1,2 ,XIAO XianMing 3 ,MA DeMing 4 ,LU YuHong 2 &YANG ChaoShi 2 1 china University of Mining&Technology,Beijing 100083,china 2 Research Institutes of exploration and development,Tarim oilfield company,petrochina,Korla 841000,china 3 guangzhou Institutes of Geochemistry,Chinese Academy of Sciences,guangzhou 510640,china 4 Department of Synthetic Physical-Chemical Prospecting,BGP,Zhuozhou 072656,china china University of Mining & Technology Beijing China Research Institutes of exploration and development Tarim Oilfield Company PetroChina Korla China guangzhou Institutes of Geochemistry Chinese Academy of Sciences Guangzhou China Department of Synthetic Physical-Chemical Prospecting BGP Zhuozhou China

Well Yingnan 2,an important exploratory well in the east of Tarim Basin,yields high commercial oil and gas flow in *** gas components and carbon isotopic composition indicate that it belongs to sapropel type *** this region presents many suits of hydrocarbon source rocks,there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at *** using the kinetics of hydrocarbon generation and carbon isotope,natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas,about 72%,it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil *** main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2,so the gas reservoir belongs to late accumulation and continuous filling type.

关键词： kinetic migration and accumulation process crude oil cracking gas Well Yingnan 2 Tarim Basin

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Structural characteristics and petroliferous features of Tarim Basin

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Chinese Science Bulletin 2002年第S1期47卷 1-11页

作者： JIA Chengzao~1 & WEI Guoqi~2 1. petrochina company Limited, Beijing 100011, china 2. Langfang Branch of Research Institute of Petroleum exploration & development, petrochina, Langfang 065007, china petrochina company Limited Beijing China Langfang Branch of Research Institute of Petroleum exploration & development PetroChina Langfang China

Using the modern tectonic geology theories andmethods such as the plate tectonic analysis, the paleo-struc-ture analysis, the structural-Iithofacies analysis, and the faultrelated fold and petroleum system, and combining with theseismic data, well drilling data and the circumferential fieldgeology, study on the structural characteristics and petro-leum prospect in the Tarim Basin has been carried out. Re-sults show that the Tarim Basin is a large superimpositionand combination basin with continental crustal basement,composed of a Paleozoic craton and Meso-Cenozoic forelandbasins. The characteristics of the basin are: the kernel partof the basin is the marine facies Paleozoic craton, superim-posed 4 continental facies foreland basins. Though the scaleof the paleozoic craton of the Tarim Basin is relatively small,the structure is steady. The petroleum prospect of the Paleo-zoic craton is: multiphase pool-generation and accumulationcontrolled by ancient uplift. The Meso-Cenozoic forelandbasins in the Tarim Basin, which are distributed on the era-tonic circumference and are a long-term subsidence, turnedinto rejuvenated foreland basins after the Meso-Cenozoicperiod. The petroleum prospects are: coal-bed generatinghydrocarbon, abundant natural gas, pool-generation in laterand recent periods, the oil and gas distribution controlled bythe foreland thrust belt. The structural characteristics ofTarim provide it with a superimposition and combinationpetroleum system of multiple resources, multiple reservoirsand multiphase pool-generation. The oil and gas explorationprospect covers two large fields: the Paleozoic craton and theMeso-Cenozoic foreland thrust belt.

关键词： Tarim superimposition and combination basin craton foreland basin superimposition and combination petroleum system.

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Complex petroleum accumulating process and accumulation series in the buried-hill trend in the rift basin:An example of Xinglongtai structure trend,Liaohe subbasin

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Science china Earth Sciences 2008年第S2期51卷 108-116页

作者： GAO XianZhi1,PANG XiongQi1,LI XiaoGuang2,CHEN ZhenYan2,SHAN JunFeng2,LIU Feng1,ZOU ZhiWen1 & Li WeiLian1 1 Faculty of Resources and Information Technology,china University of Petroleum,Beijing 102249,china 2 exploration and development Institute of Liaohe oilfield,petrochina Liaohe oil company,Panjin 124010,china Faculty of Resources and Information Technology China University of Petroleum Beijing China exploration and development Institute of Liaohe oilfield Petrochina Liaohe Oil Company Panjin China

The buried-hill trend is a typical style of the petroliferous structure in the faulted basin of eastern china. The Xinglongtai structure trend in the Liaohe subbasin,Bohai Bay Basin is a buried faulted-hill trend resulting from the periodic faulting of the Tai’an-Dawa faults. The structure was cut by various faults,which are interlinked and constitute the conduits for petroleum migration. Petroleum accumulated in the Tertiary sandstones and pre-Tertiary basement of metamorphosed rocks through the migration pathways of the fault system. Petroleum in the structure was derived from different hydrocarbon kitchens to form a hybrid field complex. Petroleum charged the structure from different directions and accumulated in various reservoirs through different pathways in different times. The accumulations in the buried hill trend of Xingongtai are composed of two types of traps in the two stratigraphic systems: traps in the Tertiary sandstones were formed by the fault blocks and by the pinchout of the sandstone,and traps in the pre-Tertiary basement of metamorphosed rocks were formed by fissures in the inner part of the buried hills and by the unconformity near the surface of the buried hills.

关键词： faulted basin petroleum migration and accumulation petroleum occurrence buried hills Achaean basement Liaohe subbasin Bohai Bay basin

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Geochemical characteristics and origin of gases from the Upper,Lower Paleozoic and the Mesozoic reservoirs in the Ordos Basin,china

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Science china Earth Sciences 2008年第S1期51卷 183-194页

作者： HU AnPing 1 ,Li Jian 2 ,ZHANG WenZheng 3 ,LI ZhiSheng 2 ,HOU Lu 4 &LIU QuanYou 5 1 Department of Earth Sciences,Zhejiang University,Hangzhou 310027,china 2 Langfang Branch,Reasearch Institute of Petroleum exploration and development,petrochina,Langfang 065007,china 3 Institute of exploration and development,petrochina Changqing oilfield company,Xi’an 710021,china 4 University of Petroleum,Beijing102249,china 5 petrochina Research Institute of Petroleum exploration and development,Beijing 100083,china Department of Earth Sciences Zhejiang University Hangzhou China Langfang Branch Reasearch Institute of Petroleum Exploration and Development PetroChina Langfang China Institute of exploration and development PetroChina Changqing Oilfield Company Xi’an China University of Petroleum Beijing China petrochina Research Institute of Petroleum exploration and development Beijing China

The Ordos Basin,the second largest sedimentary basin in china,contains the broad distribution of natural gas *** far,several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin,each having over 1000×10 8 m 3 of proven gas reserves,and several gas pools have also been discovered in the *** paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs,and then discussed their *** hydrocarbons preserved in the Upper Paleozoic,the elevatedδ13C values of methane,ethane and propane indicate that the gases would be mainly coal-formed gases;the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different *** the Lower Paleozoic,theδ13C 1 values are mostly similar with those in the Upper Paleozoic,but theδ13C 2 andδ13C 3 values are slightly lighter,suggesting that the gases would be mixing of coal-type gases as a main member and oil-type *** are multiple reversals in carbon isotopes for gaseous alkanes,especially abnormal reversal for methane and ethane(i.e.δ13C 1 >δ13C 2 ),inferring that gases would be mixed between high-mature coal-formed gases and oil-type *** the Mesozoic,the δ13Cvalues for gaseous alkanes are enriched in 12C,indicating that the gases are mainly derived from sapropelic sources;the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different *** contrast to the Upper Paleozoic gases,the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane,which may be caused by gases generated from different kerogen types. Finally,according toδ13C 1 -Ro relationship and extremely low total organic carbon contents,the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source,bycontrast, the Upper Pale

关键词： Ordos Basin natural gas chemical composition carbon isotope genesis

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Mn content of reservoir calcite cement: A novel inorganic geotracer of secondary petroleum migration in the tectonically complex Junggar Basin (NW china)

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Science china Earth Sciences 2007年第12期50卷 1796-1809页

作者： CAO Jian1,HU WenXuan1,YAO SuPing1,ZHANG YiJie2,WANG XuLong3,ZHANG YueQian3,TANG Yong3 & SHI XinPu3 1 State Key Laboratory for Mineral Deposit Research,Department of Earth Sciences,Nanjing University,Nanjing 210093,china 2 Research Institute of exploration and development,petrochina,Beijing 100083,china 3 Research Institute of exploration and development,petrochina Xinjiang oilfield company,Karamay 834000,china State Key Laboratory for Mineral Deposit Research Department of Earth Sciences Nanjing University Nanjing China Research Institute of exploration and development PetroChina Beijing China Research Institute of exploration and development PetroChina Xinjiang Oilfield Company Karamay China

Electronic probe microanalysis(EPMA) results of reservoir calcite cement from fourteen core samples in the Junggar Basin show that Mn-content varies largely between different samples from below the detect limitation to 4.14%,while it displays a generally good correlation with oil-gas ***,therefore,likely indicates that concentration of the Mn-content of the calcite cement has a close rela-tion to the intensity of petroleum fluid charging during hydrocarbon secondary *** order to assess this hypothesis,oxygen and strontium isotopic measurements on sixteen calcite veins host in source sequences were carried out to investigate the feature of the oil-source petroleum *** results imply that during hydrocarbon generation and migration,deep hot fluid has dissolved volcanic minerals interlined between mudstone source *** Mn is a kind of typical trace element enriched in volcanic rocks,it is reasonable to conclude that the petroleum fluid formed in the source sequences would be ***,calcite cements precipitated from such Mn-rich petroleum fluid would be Mn-rich *** to the geologic chromatographic effect during migration along reservoir rocks,the decreasing of the Mn-content of the reservoir calcite cements indicates the migration ***,this novel geotracer was further successfully applied in the study of hydrocarbon migration in the Junggar Basin in combination with organic geochemical analyses during the hydrocarbon *** Mn content of the reservoir calcite cement appears promising as a novel inorganic geotracer for the petroleum *** paper represents a search for novel indicators of secondary petroleum migration in tectonically complex basins based on fundamentals of the reservoir fluid-rock interactions.

关键词： Petroleum migration, inorganic geochemistry, water-rock interaction, reservoir calcite cement, the Junggar Basin

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Geochemical characteristics and accumulation of marine oil and gas around Halahatang depression,Tarim Basin,china

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Science china Earth Sciences 2008年第S1期51卷 195-206页

作者： LU YuHong,XIAO ZhongYao,GU QiaoYuan&ZHANG QiuCha Research Institute of exploration and development,Tarim oilfield company,petrochina,Korla 841000,china Research Institute of exploration and development Tarim Oilfield Company PetroChina Korla China

There exists a petroleum system rich of oil and gas around Halahatang depression,where the oil and gas possess obvious local distinctions of properties in different *** research proved that the discovered crude oil and natural gas in the region derived mainly from O2+3 source rock,and the differences of its properties were controlled by the oil and gas filling *** comprehensive study result shows the oil and gas reservoirs of the region mainly underwent three important accumulation phases:late Caledonian-Early Hercynian epoch,late Hercynian epoch,and Yanshan-Himalayan epoch. In the first phase,the oil and gas derived mostly from Cambrian source rock,which formed the primary ancient oil reservoirs,then suffered strong degradation and remained a great quantity of pyrobitumen in the high position of Tabei uplift in the *** the second phase,the O2+3 source rock of Manjia'er depression started its generation of hydrocarbon,which accumulated in the high position of Tabei uplift afterwards,and then biodegradated to heavy oil in the late Hercynian *** the last phase,the O2+3 source rock of southern Halahatang depression and margin of Manjia'er depression started its peak of generating liquid hydrocarbon,which mostly accumulated in the trap formed before the Indo-china and Yanshan epoch,and in somewhere the heavy oil suffered dilutions in various degrees or serious gas invading,to lead to obvious crude oil divergence.

关键词： marine facies Mid-Upper Ordovician source rock oil and gas source accumulation stage Halahatang depression Tarim Basin

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Characteristics,genesis and accumulation history of natural gas in Hetianhe gasfield,Tarim Basin,china

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Science china Earth Sciences 2008年第S1期51卷 84-95页

作者： WANG ZhaoMing 1 ,WANG QingHua 1 ,ZHAO MengJun 2 ,LI Yong 1 &XU ZhiMing 3 1 Tarim oilfield company,petrochina,Kuerle 841000,china 2 Research Institute of Petroleum exploration&development,petrochina,Beijing 100083,china 3 Southwest Petroleum Institute,Nanchong 637001,china Tarim oilfield company PetroChina Kuerle China Research Institute of Petroleum exploration & development PetroChina Beijing China Southwest Petroleum Institute Nanchong China

Hetianhe gasfield in Bachu region of the Tarim Basin is mainly composed of three reservoir-caprock assembly,namely regional caprock of upper mudstone,middle mudstone and lower mudstone of the Carboniferous and reservoir of Bachu bioclastic limestone,glutenite and the Ordovician carbonate buried *** gas in Hetianhe gasfield sourced from the Cambrian source *** is thought that gases in Ma4 well block in the east of Hetianhe gasfield are mainly crude-oil cracked gases,while those in Ma3 and Ma8 well blocks in the west are the mixture gases of kerogen cracked gases and crude-oil cracked *** gas is rich in H2S and accumulated in multiply stages as the result of *** accumulation history is divided into three stages,namely accumulation and breakage in the late Caledonian-early Hercynian,migration and dissipation in the late Hercynian and accumulation in Himalayan. The main accumulation of reformed gas reservoir is in Himalayan.

关键词： gas characteristics gas genesis accumulation history Hetianhe gasfield Tarim Basin

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