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Chronological record of the Early Mesozoic underplating in the northern margin of North China—U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

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Progress in Natural Science:Materials International 2007年第8期17卷 943-947页

作者： Shao ji'an~(1,2**) Zhang Hongfu~2 Liu Xiaoming~3 Li Zhitong~4 (1.school of earth and Space sciences,Peking University,Beijing 100871,China 2.institute of Geology and Geophysics and Key Laboratory of Mineral Resources,Chinese Academy of sciences,Beijing 100029,China 3.Key Laboratory of Continental Dynamics,Northwestern University,Xi'an 710069,China 4.institute of Geology and Mineral Resources of Shenyang,Shenyang 110032,China) school of earth and Space sciences Peking University Beijing 100871 China institute of Geology and Geophysics and Key Laboratory of Mineral Resources Chinese Academy of Sciences Beijing 100029 China Key Laboratory of Continental Dynamics Northwestern University Xi'' an 710069 China institute of Geology and Mineral Resources of Shenyang Shenyang 110032 China

Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Forma- tion in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma,which is consistent with the age of the Early Mesozoic underplating granulites,and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma,which is highly consistent with the Ar-Ar dating of the host volcanic *** of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites,indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.

关键词： northern margin of North China Mesozoic volcanic rock U-Pb chronometry of zircon underplating granulite

Progress in studies of the climate of humid period and the impacts of changing precession in early-mid Holocene

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Progress in Natural Science:Materials International 2008年第12期18卷 1459-1464页

作者： Jianbin Huang~a Shaowu Wang~a Xinyu Wen~a Bao Yang~b a Department of atmospheric sciences,school of Physics,Peking University,Beijing 100871,China b Laboratory for Desert and Desertification,Cold and Arid Regions Environmental and Engineering Research institute,Chinese Academy of sciences,Lanzhou 730000,China Department of atmospheric sciences School of Physics Peking University Beijing 100871 China Laboratory for Desert and Desertification Cold and Arid Regions Environmental and Engineering Research Institute Chinese Academy of Sciences Lanzhou 730000 China

Studies on the climate of humid period and the impacts of changing precession in the early-mid Holocene are reviewed in this paper. High-resolution proxy data indicated that the African Humid Period,strong summer monsoon from the Arabian Sea to South Asia, northward migration of ITCZ (lntertropical Convergence Zone) over the northern South America,and the humid period of China appeared in 10.5-5.5 kaBP,10.0-6.0 kaBP,10.5 5.4 kaBP,and 11.0-8.0 kaBP,*** studies proved that summer inso- lation over the Northern Hemisphere increased following the changes of precession in the early Holocene,which increased the land-sea temperature contrasts,intensified the summer monsoon circulation in the Northern Hemisphere,and finally induced a humid climate over the area under the influence of summer ***,modeling results underestimated the increase of precipitation and the degree of northward extension of monsoon rain belt compared with palaeo-environmental *** discrepancies between the modeling results and the palaeo-environmental data may be associated with the changes of North Atlantic circulation,sea ice and veg- etation ***,climate of the humid period was not stable,in which several droughts were inlaid on centennial *** this review,perspectives for further studies of the climate change of the humid period in the early-mid Holocene are also proposed.

关键词： Holocene Humid period Precession Summer monsoon

Effects of abnormally high heat stress on petroleum in reservoir——An example from the Tazhong 18 Well in the Tarim Basin

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Science China earth sciences 2008年第4期51卷 515-527页

作者： ZHU DongYa1, JIN ZhiJun1, HU WenXuan2 & ZHANG XueFeng3 1 Petroleum Exploration and Production institute, China Petroleum & Chemical Corporation, Beijing 100083, China 2 Department of earth sciences, Nanjing University, Nanjing 210093, China 3 school of Resource and Information, China University of Petroleum, Beijing 102249, China Petroleum Exploration and Production institute China Petroleum & Chemical Corporation Department of earth sciences Nanjing University

An igneous intrusion of 94m thick was discovered intruding into the Silurian sandstone from Tazhong 18 Well. The petroleum previously preserved in the Silurian sandstone reservoir was altered into black carbonaceous bitumen by abnormally high heat stress induced by the igneous intrusion. The reflec-tance of the carbonaceous bitumen reaches as high as 3.54%, indicating that the bitumen had evolved into a high thermal evolution level. Similar to the Silurian samples from the neighboring Tazhong 11, Tazhong 12, Tazhong 45 and Tazhong 47 wells, the distribution of C27, C28 and C29 steranes of the car-bonaceous bitumen is still "V" -shaped and can still be employed as an efficient parameter in oil source correlation. The "V" -shaped distribution indicates that the hydrocarbons from the Tazhong 18 and the neighboring wells were all generated from the Middle-Upper Ordovician hydrocarbon source rocks. However, the oil source correlation parameters associated with and terpanes had been changed greatly by the high heat stress and can no longer be used in oil source correlation. The δ 13C values of the pe-troleum from the neighboring wells are between -32.53‰ and -33.37‰, coincident with those of the Paleozoic marine petroleum in the Tarim Basin. However, the δ 13C values of the carbonaceous bitumen from the Tazhong 18 Well are between -27.18‰ and -29.26‰, isotopically much heavier than the pe-troleum from the neighboring wells. The content of light hydrocarbons (nC14-nC20) of the saturated hydrocarbon fraction in the carbonaceous bitumen is extremely higher than the content of heavy hy-drocarbons. The light/heavy hydrocarbon ratios (ΣnC21-/ΣnC22+) are between 4.56 and 39.17. In the saturated fraction, the even numbered hydrocarbons are predominant to the odd numbered, and the OEP (Odd to Even Predominance) values are between 0.22 and 0.49. However, the content of light hy-drocarbons in the petroleum from the neighboring wells is relatively low and the content of the even numb

关键词： Tarim Basin igneous intrusive abnormally high heat stress bitumen carbon isotope PAH

Environmental archaeology of the Dachang region in the Daning Valley,the Three Gorges reservoir region of the Yangtze River,China

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Chinese Science Bulletin 2008年第S1期53卷 140-152页

作者： ZHANG Yun 1 &ZHU Cheng 2 1 State Key Laboratory of Vegetation and Environmental Change,institute of Botany,Chinese Academy of sciences,Beijing 100093, China 2 school of Geographic and Oceanographic sciences,Nanjing University,Nanjing 210093,China State Key Laboratory of Vegetation and Environmental Change Institute of Botany Chinese Academy of Sciences Beijing 100093 China school of Geographic and Oceanographic sciences Nanjing University Nanjing 210093 China

Environmental archaeology of archaeological sites on both sides of the Dachang section in the Daning River,the Three Gorges of the Yangtze River,shows that riverbed evolution has a great influence on the distribution of archaeological sites during the prehistorical and historical period,and it restricts human activity and the development of ancient *** investigation,dating data,paleocurrent analysis of 100 gravels on the riverbed and archaeological excavation reveal that the riverbed of the Dachang section developed in the Shuangyantang region during the early stage,after about 30 kaBP it shifted westward gradually and reached the present *** with the westward shift,the focus of ancient culture changed for several *** the Western Zhou Dynasty's period,the east riverbank of the Daning River was the main residential *** the Han Dynasty,along with the westward shift,the living space of ancient people was no longer confined to the east riverbank and the focus of culture moved *** the Zhangjiawan site became the main dwelling *** the late Han Dynasty, the villages were flooded and the ancients had to immigrate to a high *** of the Han and the Jin Dynasties outcropped on the flood plain of the east bank because their surface sediments were eroded by several flood events and the westward shift of the riverbed.

关键词： the Daning River environmental archaeology the Shuangyantang site the Zhangjiawan site tombs of the Han and the Jin Dynasties

A semi-implicit semi-Lagrangian global nonhydrostatic model and the polar discretization scheme

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Science China earth sciences 2007年第12期50卷 1885-1891页

作者： YANG XueSheng1,CHEN JiaBin2,HU JiangLin1,CHEN DeHui1,SHEN XueShun1,ZHANG HongLiang1 1 State Key Laboratory of Severe Weather,Chinese Academy of Meteorological sciences,Beijing 100081,China 2 State Key Laboratory of Numerical Modeling for atmospheric sciences and Geophysical Fluid Dynamics,institute of atmospheric Physics,Beijing 100029,China State Key Laboratory of Severe Weather Chinese Academy of Meteorological Sciences Beijing China State Key Laboratory of Numerical Modeling for atmospheric sciences and Geophysical Fluid Dynamics Institute of Atmospheric Physics Beijing China

The Global/Regional Assimilation and PrEdiction System(GRAPES) is a newly developed global non-hydrostatic numerical prediction model,which will become the next generation medium-range opera-tional model at China Meteorological Administration(CMA).The dynamic framework of GRAPES is featuring with fully compressible equations,nonhydrostatic or hydrostatic optionally,two-level time semi-Lagrangian and semi-implicit time integration,Charney-Phillips vertical staggering,and complex three-dimensional pre-conditioned Helmholtz solver,*** the singularity of horizontal momentum equations at the poles,the polar discretization schemes are described,which include adoption of Arakawa C horizontal grid with ν at poles,incorporation of polar filtering to maintain the computational stability,the correction to Helmholtz equation near the poles,as well as the treatment of semi-Lagrangian interpolation to improve the departure point accuracy,*** balanced flow tests validate the rationality of the treatment of semi-Lagrangian departure point calculation and the polar discretization during long time *** and Suarez tests show that the conservation proper-ties of GRAPES model are quite good.

关键词： nonhydrostatic, global model, semi-implicit, semi-Lagrangian, polar discretization, conservation

Some characteristics of the atmosphere during an adiabatic process

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Progress in Natural Science:Materials International 2006年第6期16卷 644-648页

作者： gaO Li, LI Jianping and REN Hongli (LASG, institute of atmospheric Physics, Chinese Academy of sciences, Beijing 100029, China Graduate school of Chinese Academy of sciences, Beijing 100049, China National Climate Center, Laboratory of Climate Studies, China Meteorological Administration, Beijing 100081, China) LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China Graduate school of Chinese Academy of sciences Beijing 100049 China National Climate Center Laboratory of Climate Studies China Meteorological Administration Beijing 100081 China

Some important characteristics of the atmosphere during an adiabatic process are investigated, which include the invariability of atmospheric entropy range and local surface potential temperature, the conservation of the atmospheric mass intervened between any isentropic surface and the ground, and the isentropic surface intersecting with the ground. The analysis shows that the atmospheric reference state (ARS) for investigation on available potential energy (APE) should be defined objectively as the state which could be approached from the existing atmosphere by adiabatic adjustment, and be related to initial atmospheric state before adjustment. For the initial atmosphere state at any time, its corresponding ARS is different from the one at another time. Based on the above-mentioned conclusions, the reference state proposed by Lorenz cannot be obtained physically, so a new conception, the conditional minimum total potential energy, is put forward in order to objectively investigate atmospheric APE.

关键词： available potential energy adiabatic isentropic surface atmospheric reference state conditional minimum total potential energy.

Origin of the Red earth sequence on the northeastern Tibetan Plateau and its implications for regional aridity since the middle Miocene

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Science China earth sciences 2006年第5期49卷 505-517页

作者： WANG Xianyan1,7, LU Huayu1,2, JI Junfeg3, WANG Xiaoyong1,7, ZHAO Jingbo4, HUANG Baochun5 & LI Zhen6 1. SKLLQG, institute of earth Environment, Chinese Academy of sciences, Xi’an 710075, China 2. Department of Urban and Resources sciences, Nanjing University, Nanjing 210093, China 3. Department of earth sciences, Nanjing University, Nanjing 210093, China 4. Department of Geography, Shaanxi Normal University, Xi’an 710062, China 5. institute of Geology and Geophysics, Chinese Academy of sciences, Beijing 100029, China 6 Department of Geography, Qinghai Normal University, Xining 810008, China 7. Graduate school of the Chinese Academy of sciences, Beijing 100039, China SKLLQG Institute of Earth Environment Chinese Academy of Sciences Xi’an China Graduate school of the Chinese Academy of sciences Beijing China Department of Urban and Resources sciences Nanjing University Nanjing China Department of earth sciences Nanjing University Nanjing China Department of Geography Shaanxi Normal University Xi’an China institute of Geology and Geophysics Chinese Academy of Sciences Beijing China Department of Geography Qinghai Normal University Xining China

The Red earth deposit around Xining, northeastern Tibetan Plateau, has beenstudied in terms of soil micro-structure, grain-size distribution, major- and trace-elementchemistry and magne-tostratigraphy. Field investigations indicate that the Red earth sequenceconsists of 25 visually definable yellow-brown and weakly-developed soils interbedded with reddishstrongly-developed soils, and has a similar structure to the aeolian Red Clay deposit on the ChineseLoess Plateau. Grain-size analysis shows that the Red earth deposit is very fine-grained with anegligible sand fraction ( > 63 μm). Thin-section observations under light microscopy show that thedeposit has a clayey texture and the coarse fraction ( > 10 μm) mainly consists of quartz,feldspar and micas. Pyroxene and hornblende were also observed. This mineralogical composition ofthe coarse fraction is similar to that of the Quaternary loess. In addition, all of the mineralgrains are semi angular semi-angular and are generally finer than 63 μm. There is a good agreementbetween the major and minor trace element chemistry of loess-soil units and the Red earth *** REE distributions of the loess-soil and the Red earth deposit are similar in shape, withenriched LREE and fairly flat HREE profiles and a clear negative Eu anomaly. The geochemicalcharacteristics of the Red earth deposit are also identical to those of upper continental crust,thus indicating a wind-blown origin. Magnetostratigraphic investigation shows that onset of the Redearth deposition predates 11.4 Ma BP (13.6 Ma at a nearby site). The distribution of the reportedMiocene aeolian loess at Qin''an of the Loess Plateau is still unknown. Our results indicate thatthis aeolian deposit had extended to the northeastern Tibetan Plateau by at least the middleMiocene. The similarity of the element geochemistry between the Red earth deposit and the overlyingloess shows that they may have similar sources and dynamic transport system, and may indicate thatthe

关键词： Red earth deposit, Northeastern Tibetan Plateau, aeolian deposit, aridity of Asia, the middle Miocene.

Elemental and isotopic compositions of the hydrothermal sulfide on the East Pacific Rise near 13°N

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Science China earth sciences 2010年第2期53卷 253-266页

作者： ZENG Zhigang1,CHEN DaiGeng1,2,YIN XueBo1,WANG XiaoYuan1,ZHANG GuoLiang1,2 & WANG XiaoMei1,2 1 Seafloor Hydrothermal Activity Laboratory of the Key Laboratory of Marine Geology and Environment,institute of Oceanology,Chinese Academy of sciences,Qingdao 266071,China 2 Graduate school of Chinese Academy of sciences,Beijing 100049,China Seafloor Hydrothermal Activity Laboratory of the Key Laboratory of Marine Geology and Environment Institute of Oceanology Chinese Academy of Sciences Qingdao China Graduate school of Chinese Academy of sciences Beijing China

The mineralogical,elemental,and isotopic characteristics of a hydrothermal sulfide sample from one dredge station (12°42.30’N,103°54.48’W,water depth 2655 m) on the East Pacific Rise near 13°N were *** hydrothermal sulfide was composed mainly of sphalerite,chalcopyrite,and pyrite and was a Zn-rich sulfide;in layer ep-s-1,goethite formed by secondary oxidation was *** concentrations of rare elements,such as Li (0.15×10-6-0.30×10-6),Be (0.01×10-6-0.05×10-6),Zr (73.8×10-9-1344×10-9),Nb (8.14×10-9-64.7×10-9),Hf (2.54×10-9-28.0×10-9),and Ta (0.203×10-9-1.21×10-9),were far lower in the hydrothermal sulfide than in the ocean crust,whereas the content of Au was higher and the contents of Co,Ni,Sr,Cs,Ba,Bi,and U were *** correlations between Zn and Cr,Cd and ga,Cu and P,P and In (R2 > 0.8) were positive,whereas those between Zn and Fe,Cu,and Ba (R2 > 0.8) were distinctly *** low-temperature mineral assemblages to high-temperature mineral assemblages,the spatial distributions of dispersive and rare elements (***,Li,Cs) in the hydrothermal sulfide displayed corresponding *** variations observed in some elements (e.g.,Cd,Cs,P) are controlled by Zn,Fe,and Cu sulfides,*** weathering accounts for the enrichment of V,Mn,and rare earth elements (REE) in the henna sulfide-oxidation layer that bears the secondary oxide mineral,leading to identical REE patterns for this layer (ep-s-1) and *** weathering also distinctly affects the correlations between the element ratios of the hydrothermal *** high-temperature mineral assemblages to low-temperature mineral assemblages,Fe content and δ 34S value of the hydrothermal sulfide increase gradually,and Zn content and lead isotopic ratios decrease gradually on the contrary,which indicate the influences of seawater on elements and the sulfur and lead isotopic compositions enhance gradually during the formation of hydrothermal sulfides.

关键词： variation element isotopic composition hydrothermal sulfide East Pacific Rise 13oN

Total alkyl dibenzothiophenes content tracing the filling pathway of condensate reservoir in the Fushan Depression,South China Sea

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Science China earth sciences 2008年第S2期51卷 138-145页

作者： LI MeiJun1,WANG TieGuan1,LIU Ju2,ZHANG MeiZhu2,LU Hong3,MA QinLin2 & gaO LiHui2 1 State Key Laboratory of Petroleum Resources and Prospecting,earth sciences and Geoinformatics school,China University of Petroleum,Beijing 102249,China 2 Southern Oil Exploration and Development Company,PetroChina,Guangzhou 510640,China 3 Guangzhou institute of Geochemistry,Chinese Academy of sciences,Guangzhou 510240,China State Key Laboratory of Petroleum Resources and Prospecting Earth Sciences and Geoinformatics School China University of Petroleum Beijing China Southern Oil Exploration and Development Company PetroChina Guangzhou China Guangzhou institute of Geochemistry Chinese Academy of Sciences Guangzhou China

The condensates are generally characterized by high maturity,low concentration of steranes and ter-panes biomarkers and low content of non-hydrocarbon fraction. In this case commonly used steranes,terpanes and carbazoles parameters cannot be effectively applied in the reservoir-filling tracing. The hydrogen bond formed by sulfur atom in the dibenzothiophenes (DBTs) results in molecule adsorption and fractionation during oil migration in reservoir. Like carbazoles,total DBTs content decreases with the increasing of oil migration distance. Therefore,a new parameter——total DBTs content is proposed to be used to trace the oil migration orientation and filling pathway. In present study,total DBTs con-tents of condensates and light oils are obtained by adding internal standard——eight deuterium atoms substituted DBT during gas Chromatography-Mass Spectrometry analysis of aromatic fraction. Except for a few samples with much lower content of non-hydrocarbon fraction,the total DBTs content shows a fine positive correlation with that of carbazoles. Large errors can be caused in the process of pyrrolic nitrogen compounds separation. The application of this new parameter in the Fushan Depression of Beibu Gulf Basin,South China Sea indicates that this parameter is a reliable one to trace filling pathway in condensate reservoirs. Combined with other DBTs-related parameters,such as 4-/1-methydibenzo-thiophene and 2,4-/1,4-dimethyldibenzothiophene,oil migration orientation and filling pathway of the Fushan Depression was determined. The accumulations of Huachang oil field in the Fushan Depres-sion are mainly migrated and charged from northeast to southeast along the Huachang uplift. It can be predicated that the light oil and condensates in the Huachang oil field should be sourced from the source kitchen at the Bailian Sag. It shows that total DBTs content is an effective parameter to tracing oil migration orientation and filling pathway.

关键词： dibenzothiophene alkyl dibenzothiophene condensate reservoir filling pathway molecular markers the Fushan Depression