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Models of Spatial Structures of Regional Multi-element Geochemical Anomalies over Copper-Polymetallic Orefields

Acta Geologica Sinica(English Edition) 2003年第1期77卷 72-80页

作者： SHI Changyi and ZHANG Jinhua china University of Geosciences, Beijing 100083.institute of Geophysical and Geochemical exploration, {3. Hebei 065000 china University of Geosciences Beijing 100083

Regional stream sediment surveys at a 1:200,000 scale reveal positive andnegative regional multi-element geochemical anomalies over medium to large copper-polymetallicorefields of different genetic types in china. Regional geochemical anomalies of orefield refer tothose geochemical anomalies that are related to metallogenesis of an orefield in a certain area. Theanomaly area is typically 10 to 100 km^2. The regional multi-element anomalies related tomineralization can be divided into three groups, that is, the ore-element anomaly association,indicator element anomaly association, and metallogenic environmental element anomaly *** common spatial distributions over ore deposits or orefields possess unique structures. Themodel of spatial structure of regional multi-element geochemical anomalies (RAGSS) of an orefielddelineates structural feature possessed by orderly spatial distributions of different groups ofmulti-element anomaly associations related to orefield metallogenesis. It is used to outline thecommon metallogenetic anomaly visage that is composed of the orderly spatial distribution ofdifferent groups of multi-element anomaly associations. The orderly spatial distribution ofmulti-element anomalies over an orefield reflects element distributions as they are changed from adispersed 'out-of-order' state into a concentrated 'orderly' state during the mineralization of anorefield. Three different patterns of the spatial anomaly structure related to mineralization in anorefield can be concluded: (1) nested pattern; (2) eccentric pattern and; (3. peripheral *** are marked differences between multi-element anomaly patterns related and not related tomineralization. RAGSS models of orefields can be used to better understand and evaluate regionalmulti-element anomalies and identify ore types.

关键词： orefield regional geochemical anomaly model anomaly structure RAGSSmodel

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Application of backflush and micro-flow techniques to the analysis of C5—C13.hydrocarbons in crude oils and its geochemical significance

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Progress in Natural Science:Materials International 2007年第11期17卷 1382-1387页

作者： Wang Peirong1,2, Zhao Hong2,3. Xu Guanjun1,4, Zhu Cuishan2,3. Xiao Tingrong4, Zhang Min2,3.and Zhang Bin1,4(1. Key Laboratory of petroleum Geochemistry, china National petroleum Corporation, Beijing 100083. china 2. Geochemistry Department of Yangtze University, Jingzhou 43.023. china 3. Key Laboratory of exploration Technologies for Oil and Gas Resources, Ministry of Education, Yangtze University, Jingzhou 43.023. china 4. petroleum Geology Central Laboratory, Research institute of petroleum exploration and Development, petrochina, Beijing 100083. china) Key Laboratory of petroleum Geochemistry China National Petroleum Corporation Beijing 100083 China Geochemistry Department of Yangtze University Jingzhou 434023 China Key Laboratory of exploration Technologies for Oil and Gas Resources Ministry of Education Yangtze University Jingzhou 434023 China petroleum Geology Central Laboratory Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083 China

An Agilent 6890N GC equipped with both FID and Agilent 5975 MSD analyzer has been employed to analyze C5—C13.hydrocarbon fractions of crude oils. A technical combination of program temperature volatilizer injection, backflush and micro-flow controller afforded a fine separation of C5—C13.compounds on a PONA column with the heavy part of crude oils being cut off before entering the analytical column. Both GC-FID chromatogram and GC-MS mass chromatograms (MID and full scan) could be obtained at the same time. The retension time differences of nC6—nC13.alkanes between GC and TIC were in the range of 0.02—0.58 minutes. Totally 286 peaks have been assigned group compositions. Results on 8 typical oil samples from CNPC Key Laboratory Crude Oil Library showed that the characteristics of C6—C13.hydrocarbon group composition could be used in oil-oil correlation studies.

关键词： GC analysis GC/MS analysis backflush micro-flow controller light fraction in crude oil

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Propagation characteristics of converted refracted wave and its application in static correction of converted wave

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Science china Earth Sciences 2008年第S2期51卷 226-232页

作者： LIU Yang1,2 & WEI XiuCheng3.1 State Key Laboratory of petroleum Resource and Prospecting,china University of petroleum,Beijing 102249,china 2 CNPC Geophysical exploration Key Laboratory,china University of petroleum,Beijing 102249,china 3.exploration and Production Research institute,SINOPEC,Beijing 100083.china china Univ Petr State Key Lab Petr Resource & Prospecting Beijing 102249 Peoples R China china Univ Petr CNPC Geophys Explorat Key Lab Beijing 102249 Peoples R China SINOPEC Explorat & Prod Res Inst Beijing 100083 Peoples R China

Three-component seismic exploration through P-wave source and three-component geophone is an effective technique used in complicated reservoir exploration. In three-component seismic exploration data processing,one of the difficulties is static correction of converted wave. This paper analyzes propagation characteristics of non-converted and converted refracted waves,and discovers a favor-able condition for the formation of converted refracted wave,i.e. the velocity of overlaying medium S wave is much lower than that of underlying medium S wave. In addition,the paper proposes the static correction method of converted wave based on PPS converted refracted wave,and processes the real three-component seismic data with better results of static correction of converted wave.

关键词： PPS converted refracted wave converted wave static correction

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The generation and its sealing condition of natural gas in the Tadong area

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Science china Earth Sciences 2009年第S1期52卷 96-105页

作者： HU GuoYi1,2,3.LI Jin3.CUI HuiYing3.RAN QiGui3.ZHANG Li3.WANG XiaoBo3.& WANG YiFeng3.1 Research institute of petroleum exploration and Development,{3.,Beijing,100083.china 2 College of Resources and Environment,china University of petroleum,Beijing 102249,china 3.Research institute of petroleum exploration and Development-langfang branch,{3.,langfang 065007,china 1. Research institute of petroleum exploration and Development PetroChina Beijing 100083 China 2. College of Resources and Environment China University of Petroleum Beijing 102249 China 3. Research institute of petroleum exploration and Development-{3. branch PetroChina Langfang 065007 China

Focusing on the two natural gas exploration geological problems with abundant source of oil cracking gas in the late stage and the sealing condition of the oil cracking gas reservoir,the kinetics of oil cracking gas and the evaluation parameters of gas cap rock are adopted to the study on the natural gas accumulation conditions in the Tadong area. Both the study on the kinetics of oil cracking gas and the statistical results of reservoir bitumen reveal that the geological formation of oil cracking gas in the Tadong area is located in the top of Cambrian. Two kinds of oil cracking gas geological models at least,namely well Mandong-1's early rapid generation model(Middle Ordovician-end Silurian) and peak cracking model(with the natural gas conversion rate >90%) ,namely well Yingnan-2's two-stage generation model of oil cracking gas,have been set up. The oil cracking gas of Yingnan-2 in the late stage is very significant in the evaluation of natural gas exploration in the Tadong area. The evaluation results of the cap rock show that the microscopic parameters of cap rock from the lower assemblage of Cambrian-Ordovician are better than those from the upper assemblage. The former has strong capillary sealing ability and higher cap rock breakthrough pressure than the upper assemblage,with strong sealing ability,so that natural gas dissipates mainly by diffusion. According to the above investigations,the lower assemblage Cambrian-Ordovician natural gas of Kongquehe slope,Tadong low uplift and Yingjisu depression in the Tadong area prospects well.

关键词： Tadong area oil cracking gas gas generation geological model sealing condition evaluation

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Mn content of reservoir calcite cement: A novel inorganic geotracer of secondary petroleum migration in the tectonically complex Junggar Basin (NW china)

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Science china Earth Sciences 2007年第12期50卷 1796-1809页

作者： CAO Jian1,HU WenXuan1,YAO SuPing1,ZHANG YiJie2,WANG XuLong3.ZHANG YueQian3.TANG Yong3.& SHI XinPu3.1 State Key Laboratory for Mineral Deposit Research,Department of Earth Sciences,Nanjing University,Nanjing 210093.china 2 Research institute of exploration and Development,{3.,Beijing 100083.china 3.Research institute of exploration and Development,{3. Xinjiang Oilfield Company,Karamay 83.000,china 1. State Key Laboratory for Mineral Deposit Research Department of Earth Sciences Nanjing University Nanjing 210093 China 2. Research institute of exploration and Development PetroChina Beijing 100083 China 3. Research institute of exploration and Development PetroChina Xinjiang Oilfield Company Karamay 834000 China

Electronic probe microanalysis(EPMA) results of reservoir calcite cement from fourteen core samples in the Junggar Basin show that Mn-content varies largely between different samples from below the detect limitation to 4.14%,while it displays a generally good correlation with oil-gas ***,therefore,likely indicates that concentration of the Mn-content of the calcite cement has a close rela-tion to the intensity of petroleum fluid charging during hydrocarbon secondary *** order to assess this hypothesis,oxygen and strontium isotopic measurements on sixteen calcite veins host in source sequences were carried out to investigate the feature of the oil-source petroleum *** results imply that during hydrocarbon generation and migration,deep hot fluid has dissolved volcanic minerals interlined between mudstone source *** Mn is a kind of typical trace element enriched in volcanic rocks,it is reasonable to conclude that the petroleum fluid formed in the source sequences would be ***,calcite cements precipitated from such Mn-rich petroleum fluid would be Mn-rich *** to the geologic chromatographic effect during migration along reservoir rocks,the decreasing of the Mn-content of the reservoir calcite cements indicates the migration ***,this novel geotracer was further successfully applied in the study of hydrocarbon migration in the Junggar Basin in combination with organic geochemical analyses during the hydrocarbon *** Mn content of the reservoir calcite cement appears promising as a novel inorganic geotracer for the petroleum *** paper represents a search for novel indicators of secondary petroleum migration in tectonically complex basins based on fundamentals of the reservoir fluid-rock interactions.

关键词： petroleum migration, inorganic geochemistry, water-rock interaction, reservoir calcite cement, the Junggar Basin

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Neutron and density logging responses to gas reservoir for well-balanced and under-balanced logging:Gas reservoirs of sandstone in a western china field

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Science china Earth Sciences 2008年第S2期51卷 201-206页

作者： WU WenSheng1,XIAO LiZhi1 & ZHANG LongHai2 1 Resource & Information Department,china University of petroleum,Beijing 102249,china 2 Research {3. of petroleum exploration and Development,petrochina,Beijing 100083.china china Univ Petr Resource & Informat Dept Beijing 102249 Peoples R China petrochina Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China

Studying the response differences between neutron and density logging of gas reservoir for well-balanced and under-balanced logging will be of significance in evaluation of gas reservoir under the under-balanced condition and application of logging data. With Monte Carlo simulation technique,the paper obtains the relationship between neutron and density logging measurement and borehole di-ameter,porosity or gas saturation for well-balanced and under-balanced logging. The conclusions show that the response trend of under-balanced logging to gas reservoirs agrees with that of well-balanced logging with small borehole,and under-balanced logging data can be used usually as well-balanced logging data. When borehole diameter is large,under-balanced logging data should be corrected for the influences of borehole.

关键词： under-balanced logging density logging neutron logging gas reservoir response

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Geochemical characteristics and applications of 18α(H)-neohopanes and 17α(H)-diahopanes

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Chinese Science Bulletin 2000年第19期45卷 1742-1748页

作者： WANG Chunjiang, FU Jiamo, SHENG Guoying, XIAO Qianhua, LI Jinyou, ZHANG Yali & PIAO Mingzhi1. Slate Key Laboratory of Organic Geochemistry, Guangzhou institute of Geochemistry, Chinese Academy of Sciences. Guang/hou 510640, china 2. Department of Geosciences, petroleum University, Beijing 102200, china 3. institute of petroleum exploration and Exploitation, Liaohe Bureau of petroleum exploration, Panjin 240000, china State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Department of Geosciences Petroleum University Beijing China institute of petroleum exploration and Exploitation Liaohe Bureau of Petroleum Exploration Panjin China

Distributions and geochemical significances of 18α(H)-neohopanes and of 17α(H)-diahopanes in oils from west Xialiaohe depression of the Bohai Bay Basin have been studied. Relative abundance of 18α(H)-neohopanes and of 17α(H)-diahopanes can be effectively used as maturity parameters, in a range of medium-high mature stage, based on consideration on sedimentary-organic facies of source rocks. With a dual geochemical significance of maturity and sedimentary-organic facies, neohopane and diahopane parameters can be well used in oil-source correlation and in petroleum population division. Formation, primary concentration and preservation of precursors of rearranged hopanes are closely related to depositional conditions such as Eh-pH and clays content. A series of probable diahopanes (series D) was detected in the oils, which exhibits a similar distribution pattern and geochemical behavior as that of 17α(H)-diahopanes (series B).

关键词： 18α(H)-neohopane 17α(H)-diahopane maturity sedimentary-organic facies.

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中国陆上天然气资源的特征及发展策略

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石油学报 2004年第5期25卷 1-5页

作者：赵贤正赵政璋李景明李东旭石油大学北京102249 中国石油勘探与生产公司北京100011 中国石油勘探开发研究院廊坊分院河北廊坊065007

对中国陆上天然气资源的基本特征作了全面分析 ,其特征主要表现为 :①天然气勘探程度不高 ,资源相对丰富 ,主要集中分布于四个气区 ;②天然气成藏特点明显 ,类型差别较大 ;③目前天然气勘探进入大发现时期 ,天然气产量大幅度增长 ,储采... 详细信息

对中国陆上天然气资源的基本特征作了全面分析 ,其特征主要表现为 :①天然气勘探程度不高 ,资源相对丰富 ,主要集中分布于四个气区 ;②天然气成藏特点明显 ,类型差别较大 ;③目前天然气勘探进入大发现时期 ,天然气产量大幅度增长 ,储采比暂时较高。根据目前勘探开发状况 ,今后加快天然气发展的策略应是 :①突出重点 ,继续加强天然气勘探 ;②加强提高单井产能的工程技术攻关 ,降低开发成本 ;③转变开发理念 ,提高管理水平 ;④通过体制创新 ,提高开发效益。

关键词：天然气工业发展策略中国天然气资源储量复合圈闭岩性

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Hydrocarbon test in lower-layer atmosphere to predict deep-sea petroleum or hydrate in the Okinawa Trough: an example

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Acta Oceanologica Sinica 2003年第4期22卷 569-576页

作者： Gong Jianming1, Chen Jianwen 1, 2, Li Gang1, Zhang Xunhua1, Li Jipeng3. Huang Fulin1 1. Qingdao institute of Marine Geology, Qingdao 266071, china. 2. Ocean University of china, Qingdao 266003. china 3. Hefei institute of petroleum Chemical exploration, china petroleum exploration and Development Research institute, Hefei 23.022,china Qingdao Inst Marine Geol Qingdao 266071 Peoples R China Ocean Univ china Qingdao 266003 Peoples R China china Petr Explorat & Dev Res Inst Hefei Inst Petr Chem Explorat Hefei 230022 Peoples R China

Light hydrocarbon (methane, ethane, propane, butane and CO2) test and C isotopic analysis of CO are conducted for over 100 lower-layer atmospheric samples from the East china Sea slope and the Okinawa Trough. The results show that the lower-layer atmosphere mainly consists of CO2 and then of CH4, and the CO2 concentrations are calculated to have a high average value of 0.87 omega/10(-2) about three times that of the regional background (0-3.omega/10(-2)). The result also shows that the average value of C isotope - 20.8 x 10(-3. is given to the CO2, inferring that it is inorganic gas. Thus, for the future 's work in the Okinawa Trough, special attention should be paid to CO2 hydrate, which is very possibly an important hydrate type.

关键词： lower-layer atmosphere hydrocarbon test C isotopic analysis deep-sea petroleum gas hydrate

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Discovery of a Late Permian Angara-Cathaysia mixed flora from Acheng of Heilongjiang,china,with discussions on the closure of the Paleoasian Ocean

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Science china Earth Sciences 2009年第12期52卷 1746-1755页

作者： DENG ShengHui1,2, WAN ChuanBiao3.& YANG JianGuo3.1 Research institute of petroleum exploration and Development, {3., Beijing 100083. china 2 State Key Laboratory of Enhanced Oil Recovery, Beijing 100083.china 3.Daqing institute of petroleum exploration and Development, {3., Daqing 164712, china Research institute of petroleum exploration and Development PetroChina Beijing 100083 China State Key Laboratory of Enhanced Oil Recovery Beijing 100083 China Daqing institute of petroleum exploration and Development PetroChina Daqing 164712 China

This work documents a new flora from the Upper Permian Hongshan Formation of Acheng County, Heilongjiang Province, Northwest china. The flora consists of 20 species: Paracalamites sp., Pecopteris tangwangheensis Huang, Callipteris obese Huang, Callipteris shenshuensis Huang, C. tangwangheensis Huang, C. heilongjiangensis Huang, C. zeilleri Zalessky, C. sp., Comia yichunensis Huang, C. tenueaxis Huang, Iniopteris sibirica Zalessky, Supaia teiliensis Huang, Compsopteris tchirkovae Zalessky, C. cf. adzvensis Zalessky, Nilssonia sp. 1, Nil. sp. 2, Taeniopteris cf. densissima Halle, T. cf. nystraemii Halle, T. sp. and Noeggerathiopsis derzavinii Neub. It is dominated by Angara species but mixed with some typical Cathaysian elements. The age of the flora is assigned to late of the Late Permian according to the stratigraphic ranges of the known species and the comparisons of it with the similar floras. The new discovery indicates that the final collision between the North china Plate and Siberian Plate occurred in Late Permian along the Xar Moron River-Changchun-Yanji sutured zone, and the Paleoasian Ocean was finally closed at the end of the Permian.

关键词： Late Permian mixed Angara-Cathaysia flora Paleoasian Ocean plate collision Heilongjiang Province of china

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