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Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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Science china Earth Sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2. JIN Zhenmin1,3, QU Jing2.& WANG Lu2.1. State key laboratory of Geological Processes and Mineral {2., china university of geosciences, wuhan 430074, china 2. Graduate School of china university of geosciences, wuhan 430074, china 3. Faculty of Earth Sciences, china university of geosciences, wuhan 430074, china State key laboratory of Geological Processes and Mineral {2. China University of Geosciences Wuhan China Graduate School of china university of geosciences Wuhan China Faculty of Earth Sciences China University of Geosciences Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental Sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 300 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

Fault System,Deformation Style and Development Mechanism of the Bachu Uplift,Tarim Basin

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Journal of Earth Science 2012年第4期23卷 529-541页

作者：佟殿君张俊霞阳怀忠胡德胜任建业 key laboratory of {2. and Petroleum resources of ministry of education China University of Geosciences School of Economics and Management China University of Geosciences Beijing Research Institute CNOOC Zhanjiang Branch CNOOC Structral Research Center of Oil&Gas Bearing Basin Ministry of EducationChina University of Geosciences

The Bachu （巴楚） uplift is one of the most active tectonic regions nowadays in the Tarim basin, which is also a faulted block uplift that was intensively active during the Cenozoic. This study was based primarily on the geological structure interpretation of seismic profiles, applying the theories and methods of basin dynamics, structural analysis and tectono-stratigraphic analysis, the geometry and kinematics features of the fault systems in the Bachn uplift were analyzed in detail. Our study shows that each fault belt is mainly characterized by compression and overthrusting, most of the faults initiated and activated during the Mid-Late Himalayan period, and that the general structural styles of the Bachu uplift were basement-involved pop-up thrust faulted block uplift, of which the southern margin was covered by the large-scale decollement fault system. The basement-involved structures widely developed in the higher position of the basement uplift, while decollement fault system developed mainly at the position with gypsum mudstone. The evolution process of Bachu uplift included back-bulge slope of the peripheral foreland basin in Mid-Late Caledonian, forebulge in HercynianYanshanian and the latest compressional faulted block uplift in Mid-Late Himalayan. Meanwhile,the study also suggests that the formation, reconstruction and stabilization of the uplift were controlled by the development and evolution of fault systems clearly. In the early forebulge stage, it was mainly presented as flexural deformation without the developing of thrust faults in the Bachu area; to the late stage, under the influence of violent lateral compression deformation, the faulted block uplift formed finally.

关键词： fault system structural style structural evolution Bachu uplift Tarim basin.

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Science china Earth Sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. key laboratory of Lithospheric {2. and Lithoprobing Technology, china university of geosciences, ministry of education of china, Beijing 100083, china 2. School of Earth Sciences and Mineral resources, china university of geosciences, Beijing 100083, china key laboratory of Lithospheric {2. and Lithoprobing Technology China University of Geosciences Ministry of Education of China Beijing China School of Earth Sciences and Mineral resources China University of Geosciences Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

Seismic Image Prediction of Cenozoic Reef-Banks in the Northwestern South china Sea

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Journal of Earth Science 2012年第4期23卷 597-611页

作者：陈平陆永潮王振峰陈雷 key laboratory of {2. and Petroleum resources of ministry of education China University of Geosciences Zhanjiang Branch Company of CNOOC Limited

The Cenozoic reef-banks reservoir in Qiongdongnan （琼东南） basin is one of the most profitable targets worthy of prospecting in the deep water area of the northwestern South china Sea. In this study, the characteristics of organic reef-like reflectors in southern uplift area of Qiongdongnan basin are analyzed based on the latest 2. and 3D seismic data. It is found that reef-like reflectors in Qiongdongnan basin show high-amplitude moundy continuous reflection at the top and the bottom, chaotic reflection inside the reef-like reflector and there is obviously speed difference between reef-like reflector body and surrounding rock. Combining the geological setting of reef and comparative analysis, the reef-like reflectors are considered to be the reef-banks. Furthermore, the results show that there are three kinds of reef structures in the southern uplift area of Qiongdongnan basin： the fault controlling structure, the fault flexure structure and the carbonate ramp structure. Each structure has its own grow-units that can reveal the growth process of the reef in order. The distribution of reef-like reflec- tors in space shows an arc belt pattern. According to this, four reef arc belts are identified, and their spatial trends are thought to have a good relationship with the buried fault. The internal structure con- stitution and the growth state of reef-like reflectors are mainly controlled by the geomorphology and monsoon-ocean current. The result has an instructive significance to oil-gas exploration of organic reef not only in Qiongdongnan basin, but also even in deep water areas of the South china Sea.

关键词： northwestern South china Sea reef-like reflector structure constitute control factor.

Transport network and flow mechanism of shallow ore-bearing magma in Tongling ore cluster area

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Science china Earth Sciences 2006年第4期49卷 397-407页

作者： DENG Jun1,2. WANG Qingfei1,2., HUANG Dinghua3 , WAN Li4, YANG Liqiang1,2.& GAO Bangfei1,2.1. State key laboratory of Geological Processes and Mineral {2., china university of geosciences, Beijing 100083, china 2. key laboratory of Lithosphere tectonics and Lithoprobing Technology of ministry of education, china university of Geo- sciences, Beijing 100083, china 3. Faculty of Earth Sciences, china university of geosciences, wuhan 430074, china 4. School of Mathematics and Information Science, Guangzhou university, Guangzhou 510405, china State key laboratory of Geological Processes and Mineral {2. China University of Geosciences Beijing China key laboratory of Lithosphere {2. and Lithoprobing Technology of ministry of education China University of Geosciences Beijing China Faculty of Earth Sciences China University of Geosciences Wuhan China School of Mathematics and Information Science Guangzhou University Guangzhou China

Abundant studies revealed that shallow intrusions of the Yanshanian epoch resulted in the mass mineralization of the Tongling region. Various evidences showed there existed a concealed magma chamber at ?10 km depth in the middle part of this region during Yanshanian epoch, from which the ore-forming magma was generated and then transported to the superficial layer. Yet the transport network and flow mechanism of the shallow ore-bearing magma, the key problem associ- ated with ore-forming process, was relatively little focused on. Integrate analysis of structural me- chanics, statistical fractal and geological facts suggested that NE trending high-angle fold-related thrust faults and the tessellated basement ones served as the main pathways for the shallow magma’s transporting, moreover, the saddle void spaces among adjacent strata in the folds upon this fault system provided the place for magma’s emplacement. So the folds in the upper part and faults in the lower part of the upper crust constituted the fluid’s transport and emplacement network. During the deformation of geologic body with multi-layer structure, the layers in the upper part tended to fold when received the jacking stress from the lower part, while the lower one inclined to fault undergoing loads of the upper part. And the producing probability of this structure assemblage was highly in- creased in the condition, such as in the Tongling area, that the mechanic rigidity of the lower layers was stronger than that of the upper ones. For the pre-existence of fluid-conducting network, the top magma with high volatile in the magma chamber transported rapidly to the superficial layer in dyking pattern, located in the void spaces of folds, filled and reconstructed them. The sudden drop of pres- sure caused the fluid unmixing from the magma and mass ore-forming elements concentration. Pulse activity of the dyking may be the principal reason why magmatic bodies in the Tongling area were spatially-temporally con

关键词： Tongling, structural network, magma intrusion, fractal, dyke.

Characteristics of the Bottom Boundary(T11) of Late Cretaceous Yaojia Formation in Songliao Basin and Its Dynamic Background

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地学前缘 2009年第S1期16卷 141-142页

作者： Ying Song~(1,2.,Jianye Ren~3,Huaizhong Yang~2.1.key laboratory of {2. and Petroleum resources(china university of geosciences),ministry of education,wuhan 430074,china. 2.Faculty of Earth resources,china university of geosciences(wuhan),wuhan 430074,china 3.Structural Research Center of Oil&Gas Bearing Basin,ministry of education,Branch Center in china university of geosciences,wuhan 430074,china

Well-preserved Cretaceous lacustrine deposits in Songliao Basin NE china provide a unique oppor- tunity both for building the terrestrial type stage of Cretaceous in china and for studying the response of Cretaceous major global geological *** basin had undergone three stages of tectonic evolution during the Late Jurassic and Cretaceous:syn-rifting phase,post-rifting thermal subsidence phase and basin inversion *** shallow strata of Yaojia Formation contain excellent Putaohua and Sartu reservoir rocks,which contribute great to the giant

关键词： Songliao Basin tectonic inversion responding surface tectonic revolution

Analytical method of Cr stable isotope and its application to water pollution survey

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Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2.3,MA Teng 4,5,LING WenLi 1,2.LIU CunFu 4,5 & LI Li 4,5 1Faculty of Earth Science,china university of geosciences,wuhan 430074,{2. 2.tate key laboratory of Geological Processes and Mineral resources,china university of geosciences,wuhan 430074,{2. 3 Graduate School,china university of geosciences,wuhan 430074,{2. 4 Biogeological and Environmental Geology laboratory of ministry of education(china university of geosciences) ,wuhan 430074,{2. 5 Sino-Hungary Joint laboratory of Environmental Sciences and Health,china university of geosciences,wuhan 430074,{2. Faculty of Earth Science China University of Geosciences Wuhan China State key laboratory of Geological Processes and Mineral {2. China University of Geosciences Wuhan China Graduate School China University of Geosciences Wuhan China Biogeological and Environmental Geology laboratory of ministry of {2. (china university of geosciences) Wuhan China Sino-Hungary Joint laboratory of Environmental Sciences and Health China University of Geosciences Wuhan China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

The integration of methanogenesis with denitrification and anaerobic ammonium oxidation in an expanded granular sludge bed reactor

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Journal of Environmental Sciences 2003年第3期15卷 423-432页

作者： ZHANG Dai-jun 1,2.(1. Department of Environmental Science, Chongqing university, Campus A, Chongqing 400044, china 2. {2. laboratory for the Southwest china resources Exploitation and Environmental Disaster Control Engineering, ministry of education, china.) Department of Environmental Science Chongqing University Campus A 重庆 400044

The integration of methanogenesis with denitrification and anaerobic ammonium oxidation(ANAMMOX) was studied in an expanded granular sludge bed(EGSB) reactor in this work. Experimental results from the continuous treatment of wastewater with nitrite and ammonium, which lasted for 107 days, demonstrated that wastewater with high nitrite and ammonium could be anaerobically treated in an expanded granular sludge bed reactor. More than 91% to 97% of COD were removed at up to about 3.9 g COD/(L·d) of COD volumetric loading rate. More than 97% to 100% of nitrite was denitrified at up to about 0.8 g NO -_2.N/(L·d), which is 16 times higher than that in a conventional activated sludge system with nitrification/denitrification(0.05 gN/(L·d)). No dissimilatory reduction of nitrite to ammonium occurred in the process. However, maximum of about 40% ammonium was found to be lost. Batch tests of 15 days with sludge from the reactor showed that 100% of nitrite was denitrified completely, and about 3% of ammonium was removed when only ammonium (34.3 mg/L) and nitrite(34.3 mg/L) were added into the sludge suspension medium. Furthermore, about 15% of ammonium amounts were lost with organic COD addition. It suggested that the methanogenesis in the system could enhance ANAMMOX because of intermediate hydrogen produced during methanogenesis.

关键词： methanogenesis denitrification ANAMMOX EGSB reactor

Sedimentary geochemistry of the Cambrian-Ordovician cherts: Implication on archipelagic ocean of North Qilian orogenic belt

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Science china Earth Sciences 2007年第11期50卷 1628-1644页

作者： DU YuanSheng1,2. ZHU Jie1, GU SongZhu1, 2. XU YaJun1 & YANG JiangHai1 1 Faculty of Earth Sciences, china university of geosciences, wuhan 430074, {2. 2.key laboratory of Biogeology and Environment Geology of education ministry, wuhan 430074, {2. Faculty of Earth Sciences China University of Geosciences Wuhan China key laboratory of Biogeology and Environment Geology of {2. ministry Wuhan China

The Caledonian North Qilian orogenic belt lies between the North china plate and the Qaidam mi-croplates, and resulted from the collision among the Qaidam microplate, mid-Qilian block and the North china plate. The orogen initiated from the rifting of the Late Proterozoic Rodinia, and then it experi-enced stages of Cambrian rift basin and Ordovician archipelagic oceanic basin, and foreland basin during Silurian to Early-Middle Devonian. The average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn and Lan/Cen from cherts of Cambrian Heicigou Formation are 0.797, 0.62., 1.114, 0.994 and 1.034 re-spectively. In the NAS standardized REE distribution pattern, the cherts from Xiangqianshan is slightly HREE enriched, and the cherts from Ganluci and Shiqingdong are plane. All of these features indicated that Cambrian cherts of the Heicigou Formation originated from a continental margin rift background. On the contrary, the average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn, Lan/Cen of the Ordovician chert from Dakecha, Cuijiadun, Shihuigou, Laohushan, Heicigou, Maomaoshan, Bianmagou, Da-chadaban, Baiquanmen, Jiugequan and Angzanggou, are respectively 0.72. 0.58, 0.99, 1.09 and 0.96 respectively. Their NAS standardized REE distribution patterns of most Ordovician cherts are plane mode or slightly HREE enriched. The REE distribution pattern of few samples of cherts are slightly LREE enriched. Characteristics of sedimentary geochemistry and tectonic evolution demonstrated that the Cambrian-Ordovician cherts, associated with rift, oceanic, island arc and back-arc volcanic rocks, was not formed in a typical abyssal oceanic basin or mid-oceanic ridge. On the contrary, they formed in a deepwater basin of continental margin or a archipelagic ocean tectonic setting. Several Early Paleo-zoic ophiolite belts in North Qilian and adjacent periphery Qaidam microplate imply that an archipelagic ocean during Ordovician existed in the east of Pro-Tethys.

关键词： North Qilian orogenic belt,Cambrian-Ordovician,cherts sedimentary geochemistry,archipelagic ocean