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Study on the atmospheric photochemical reaction of CF_3 radicals using ultraviolet photoelectron and photoionization mass spectrometer

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Science china Chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2, DU Lin1,2, YIN Shi1,2 & GE MaoFa1 1 beijing National Laboratory for Molecular sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, chinese academy of sciences, beijing 100080, china 2 graduate university of chinese academy of sciences, beijing 100080, china beijing National Laboratory for Molecular sciences (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing China graduate university of chinese academy of sciences Beijing China

A study of the atmospheric photochemical reaction of CF3 radical with CO and O2 was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3OC(O)OOC(O)- OCF3 were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3OC(O)OOC(O)OCF3 are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3 group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.21 and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3OCO+ and CF3+. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species

The deep thermal characteristic of continental margin of the northern South china Sea

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chinese Science Bulletin 2000年第18期45卷 1717-1722页

作者： ZHANG Jian & WANG Jiyang1. graduate School, university of Science and Technology of china, chinese academy of sciences, beijing 100039, china 2. Institute of Geology, chinese academy of sciences, beijing 100029, china graduate School University of Science and Technology of China Chinese Academy of Sciences Beijing China Institute of Geology Chinese Academy of Sciences Beijing China

Heat flow plays an important role in the study ot thermal structure and thermal evolutionof continental margin of the northern South china Sea. The analysis of heat flow value shows that margin heat flow in the northern South china Sea is relatively high setting, but the percentage of crustal heat flow is lower than 35% in terrestrial heat flow. The terrestrial heat flow exhibited a current of rise from the Northern Continental Margin to the Southern Central Basin. However, the proportion of crustal heat flow in terrestrial heat flow slowly dropped down in the same direction. It is suggested that the main factor causing high heat flow setting is the moving up of hot material from asthenosphere.

关键词： margin of northern South china Sea terrestrial heat flow thermal structures.

A novel operation mode for spaceborne polarimetric SAR

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Science china(Information sciences) 2011年第4期54卷 884-897页

作者： QI WeiKong 1,2 & YU WeiDong 1 1 Institute of Electronics,chinese academy of sciences,beijing 100190,china 2 graduate School of chinese academy of sciences,beijing 100039,china Institute of Electronics Chinese Academy of Sciences Beijing China graduate School of chinese academy of sciences Beijing China

A novel operation mode for spaceborne polarimetric SAR,named polarization space-division adding polarization code-division (PSD-PCD) operation mode,is proposed in this paper through combining polarimetric SAR with elevation digital beam-forming (DBF) on *** a pulse repetition interval the up-chirp LFM sub-pulse is transmitted with horizontal polarization antenna,and with some delay the down-chip LFM subpulse is transmitted with vertical polarization antenna to realize code *** every sub-aperture receives returns from ground,SAR system uses range DBF to separate echoes relative to different sub-pulses in order to realize space *** system PRF is equal to that of single-polarization SAR,and elevation DBF help reduce range ambiguity ***,the main system parameters,including PRF,delay between two sub-pulses,radar equation and ambiguity are analyzed and compared with those of single-polarization *** results demonstrate the feasibility and validity of PSD-PCD operation mode.

关键词： spaceborne synthetic aperture radar (SAR) polarimetry digital beamforming (DBF) operation mode ambiguity ratio polarization space-division polarization code-division

Thermal analysis of the baffle structure of the Solar Space Telescope

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Science china(Physics,Mechanics & Astronomy) 2010年第9期53卷 1755-1764页

作者： LI Rong1,2,3 & WANG Sen1,3 1 National Astronomical Observatories,chinese academy of sciences,beijing 100012,china 2 graduate university of chinese academy of sciences,beijing 1.0049,china 3 Key Laboratory of Solar Activity,National Astronomical Observatories of chinese academy of sciences,beijing 100012,china National Astronomical Observatories Chinese Academy of Sciences Beijing China graduate university of chinese academy of sciences Beijing China Key Laboratory of Solar Activity National Astronomical Observatories of Chinese Academy of Sciences Beijing China

The SST(Space Solar Telescope) is an astronomical telescope with a primary mirror of 1 m in *** observes the sun with a small view field to ensure that its high spatial resolution imaging has 0.1″-0.15″ and high SNR(signal to noise ratio).Surrounding the small view field is still the sun,which is an intense source of both heat and stray *** baffles(the main baffle,the aperture,and the outer baffle),which are used to eliminate the stray light,will change the thermal flux in the SST and will weaken the effect of the thermal control *** this study,the compatibility analysis of the thermal effect of baffle structures in SST is *** GCF(Geometry Composing Function) and BRDF(Bidirectional Reflectance Distribution Function),which are two inherent related parameters in the compatibility analysis,are *** objective and method of the compatibility analysis are *** the thermal analysis software,the temperature fields are calculated for different lengths of the main baffle,different radii of apertures,different lengths of the outer baffle with a 3' tilt angle and 16' tilt angle,and different tilt angles of the outer baffle with a 200 mm length.A series of configurations and sizes of the baffles are studied with the goals of both thermal control and elimination of stray *** design of the baffle structure of SST is achieved:the main baffle of length 4100 mm,the internal shield of radius 494 mm,the outer baffle of length 200 mm,and the outer baffle of tilt angle 3' are successfully *** paper presents the relationship between the thermal control design and stray light elimination plan in the *** aims of the optimal design of the baffle structure of SST are *** thoughts and methods of the optimal analysis are also useful for similar optical telescopes designed for solar observation.

关键词： baffle the main baffle the outer baffle GCF BRDF

The solid lubricating material experiment device for Shenzhou-7 Spaceship

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Science china(Technological sciences) 2010年第9期53卷 2521-2527页

作者： WANG Ke1,2,REN WeiJia1,WANG ShiDa1 & WENG LiJun3 1 academy of Opto-Electronics,chinese academy of sciences,beijing 100190,china 2 graduate university of chinese academy of sciences,beijing 1.0049,china 3 Lanzhou Institute of Chemical Physics,chinese academy of sciences,Lanzhou 730000,china academy of Opto-Electronics Chinese Academy of Sciences Beijing China graduate university of chinese academy of sciences Beijing China Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou China

A solid lubricating material exposure experiment in space is one of the missions during the seventh manned spaceflight of china,and the key is to develop a device which can be fixed reliably outside of the orbital module and can be fetched conveniently by an astronaut during space *** solid lubricating material experiment device needs to be locked reliably in a vibrating and impacting environment during the launch phase,and should meet the requirement that it can be unlocked and fetched reliably by the astronaut wearing an extravehicular spacesuit via simple operations in orbit in an environment of high and low *** for the device we developed,the environmental characteristic of the mission was analyzed,the mechanical analysis and thermal analysis were carried out,and then a mechanism with functions of mechanical locking,structural self-locking and manual unlocking was *** device was verified by a sequence of experiments and was fetched by the astronaut during the flight of the Shenzhou-7 Spaceship.

关键词： manned spaceflight exposure experiment mechanism unlock

Testing local realism in P → VV decays

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Science china(Physics,Mechanics & Astronomy) 2010年第5期53卷 870-875页

作者： LI JunLi1 & QIAO CongFeng1,2 1Department of Physics,graduate university of chinese academy of sciences,beijing 1.0049,china 2Theoretical Physics Center for Science Facilities(TPCSF),chinese academy of sciences,beijing 1.0049,china Department of Physics Graduate University of Chinese Academy of Sciences Beijing China Theoretical Physics Center for Science Facilities (TPCSF) Chinese Academy of Sciences Beijing China

It was found that the vector meson pair from the pseudoscalar decays can form an entangled *** this work we give out detailed explanations on the polarization correlation of the two entangled vector *** is demonstrated that an experimental test of the Clauser-Horne inequality can be carried out through measuring the azimuthal distribution of four pseudoscalars in the cascade decay ηc→ VV →(PP)(PP),and the measurement of this process is feasible with the current running experiments in tau-charm ***,a brief discussion on the polarization correlation of the two vector mesons from B → VV decays is also presented.

关键词： nonlocality test high energy experiment meson decays

The establishment of crystal position look-up table for positron emission tomography with block detectors

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Science china(Technological sciences) 2009年第8期52卷 2418-2423页

作者： CHAI Pei1,2 & SHAN BaoCi1 1 Key Laboratory of Nuclear Analytical Techniques, Institute of High Energy Physics, chinese academy of sciences, beijing 1.0049, china 2 graduate university of chinese academy of sciences, beijing 1.0049, china Key Laboratory of Nuclear Analytical Techniques Institute of High Energy Physics Chinese Academy of Sciences Beijing China graduate university of chinese academy of sciences Beijing China

A method has been developed to establish the crystal position look-up table for positron emission tomography with block detectors. It is based on the principle that the counts in crystal position histogram obey the Gaussian mixture model (GMM). This method has taken full consideration of the characteristics of the GMM and the detector itself. The experimental results have proved that it is simple, reliable, and universal.

关键词： positron emission tomography position look-up table 2-D position histogram

Research on applying physical chaos generator to spacecraft information security

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Science china(Technological sciences) 2009年第5期52卷 1463-1470页

作者： ZHAO HePing State Key Laboratory of Information Security,graduate university of chinese academy of sciences,beijing 1.0049,china china academy of Space Technology,beijing 100094,china State Key Laboratory of Information Security Graduate University of Chinese Academy of Sciences Beijing China china academy of Space Technology Beijing China

The effectiveness of a short-length message extension method based on physical chaos generator was analyzed and the entropy of the extended message was calculated in this *** analysis demon-strated that with the mentioned method the entropy of short-length messages,which are repeatedly used in spacecraft data systems,is obviously increased,and the security of transmission is enhanced as *** paper also presented an improvement of the protocol for secret key agreement presented by *** and *** of depending on characteristics of communication channel,this method takes advantage of the random data produced by physical chaos generator to preset the initial parameters of the procedure on both sides of communication,so that the procedure and quantity of cipher key can be precisely *** method can be used to cipher key management of se-cure communication between long life-span spacecraft and ground system.

关键词： physical chaos generator spacecraft information security message extension cipher key management

A two-round honest-verifier zero-knowledge protocol

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Science china(Information sciences) 2010年第5期53卷 954-963页

作者： LIU HanWu 1,2 & LIN DongDai 1 1 The State Key Laboratory of Information Security, Institute of Software, chinese academy of sciences, beijing 100190, china 2 graduate university of the chinese academy of sciences, beijing 1.0049, china The State Key Laboratory of Information Security Institute of Software Chinese Academy of Sciences Beijing China graduate university of the chinese academy of sciences Beijing China

Since the concept of zero-knowledge protocols was introduced, it has attracted a lot of attention and in turn showed significant effect on the development of cryptography, complexity theory and other areas. The round complexity of a zero-knowledge protocol is a very important efficiency consideration, and it is required to be as small as possible. Generally, it is desirable to have zero-knowledge protocols with constant numbers of rounds. Goldreich and Oren proved that only languages in BPP have one-round and two-round zero-knowledge protocols. Moreover, they also showed that only languages in BPP have one-round honest-verifier zero-knowledge protocols. The notion of honest-verifier zero-knowledge protocols is highly non-trivial and fascinating itself, and has many other uses. Thus, the problem as to whether there exist two-round honest-verifier zero-knowledge protocols becomes an important open problem. In this paper, we introduce a new simulation technique and present a two-round honest-verifier zero-knowledge protocol for any language in N P under a standard complexity assumption based on this technique.

关键词： proof system argument system zero-knowledge witness indistinguishability black-box one-way permutation commitment scheme zap