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Progress and review of the studies on the end-Triassic mass extinction event

Science china Earth Sciences 2005年第12期48卷 2049-2060页

作者： DENG Shenghui1,2, LU Yuanzheng1,2,3 & XU Daoyi4.1. Research Institute of Petroleum Exploration and Development, Beijing 100083, china 2. Key Laboratory of Oil and Gas Reservoir of Petrochina, Beijing 100083, china 3. china university of geosciences, Beijing 100083, china 4. Institute of geology, china Earthquake Administration, Beijing 100029, china Research Institute of Petroleum Exploration and Development Beijing China Key Laboratory of Oil and Gas Reservoir of Petrochina Beijing China china university of geosciences Beijing China Institute of geology China Earthquake Administration Beijing China

The mass extinction at the end-Triassic is one of the five biggest in the Phanerozoic. However,it is the least well understood among these five events, and only till last decade it became a great academic interesting subject to geologists. The evidences for this event come obviously from bivalves, brachiopods, ammonites, corals, radiolaria, ostracods and foraminifera of marine habitats, and plants and tetrapods of terrestrial realm. By contrast, for some of other groups, such as marine gastropods and marine vertebrates, no mass extinction has been recog-nized yet. The extinction event is strongly marked at specific level but shown a complicated situa-tion at generic and family levels. Dramatic changing of the environment, such as the temperature raise due to the greenhouse effect, the marine anoxic habitats caused by a sudden transgression after the regression at the end of Triassic, has been claimed to be the main cause of the extinction. Many hypotheses have been suggested to demonstrate the mechanisms of the environment changing, among which two popular ones are the bolide impact and volcanic eruption. The Triassic-Jurassic (Tr-J) boundary mass extinction event is still poorly understood because no enough data have been obtained from the Tr-J boundary successional sections of both marine and terrestrial sediments, and most of these studies were regionally restricted. The basic aspects of the event and its associated environmental conditions remain poorly characterized and the causal mechanism or mechanisms are equivocal. Some authors even doubt its occurrence. china has many successionally developed terrestrial and marine Tr-J sections. Detailed studies of these sections may be important and significant for well understanding of the event.

关键词： progress, review, end-Triassic, mass extinction, mechanism, Tr-J boundary.

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Discovery of potassic spilite (or poenite) in Langshan Group of Tanyaokou District,Inner Mongolia,china

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Chinese Science Bulletin 1999年第6期44卷 563-567页

作者： PENG Runmindepartment of geology and Mineral Resources , china university of geosciences, Beijing 100083,{4. department of geology and Mineral Resources China University of Geosciences Beijing China

It is believed that the albite-potash-feldspar-greenschists in the middle Proterozoic Langshan Group in Tanyaokou District are synsedimentary potassic spilite （or poenite） based on the following facts and features: （ ⅰ ） they occur in beds and look blackish （or apple） green and compact; （ ⅱ ） they bear blasto-glomeroporphyritic and blastocrystalloclastic crystals which consist of （altered） albite laths with hollow skeleton crystal texture in which there are slender dark strips and minor pyroxene, and blasto-amygdaloid filled with pyrite, chlorite, magnetite, etc.; （ ⅲ ） the results of the petrochemical diagrams show that they are orthometamorphites; （ Ⅳ ） Sm-Nd isotopic age of them is 1 824.Ma (model age (tDM) is 2 006—2 132 Ma).

关键词： potassic spilite (or poenite) middle Proterozoic Tanyaokou Deposit Inner Mongolia.

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Electrical Properties of Expanded Graphite Intercalation Compounds

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Journal of Materials Science & Technology 2001年第3期17卷 371-374页

作者： Xiuyun CHUAN department of geology, Peking university, Beijing 100871, china Daizhang CHEN and Xunruo ZHOU department of Materials Science, china university of geosciences, Beijing 100083, china E-mail: cxyljhcj@*** Dept. of Geol. Beijing Univ. Beijing 100871 China

The intercalation compounds of CuCl2 were synthesized with expanded graphite, whose magnitude of the electrical conductivity is about 10(3)S(.)cm(-1). Their electrical conductivity is 3 similar to6 times as high as that of the expanded graphite, and about 10 times as high as that of GIC made of the non-expanded graphite. The microanalysis results of chemical compounds by X-ray energy spectrum scanning of TEM testified that the atomic ratio of chloride and cupric is nonstoichoimetric. The multivalence and exchange of electrovalence of the cupric ion was confirmed by the XPS-ESCA. Vacancy of chlorine anion increases the concentration of charge carrier. The special stage structure, made of graphite and chloride, produces a weak chemical bond belt and provides a carrier space in the direction of GIC layer. These factors develop the electrical properties.

关键词： In Ph Electrical Properties of Expanded Graphite Intercalation Compounds Graphite ESCA

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Dehydration melting of solid amphibolite at 2.0 GPa: Effects of time and temperature

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Science china Earth Sciences 2005年第8期48卷 1120-1133页

作者： ZHOU Wenge1, XIE Hongsen1, LIU Yonggang1, ZHENG Xiaogang1, ZHAO Zhidan2 & ZHOU Hui3 1. Laboratory of Material in the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, china 2. department of geology, china university of geosciences, Beijing {4., china 3. department of geology, Peking university, Beijing 100871, china Laboratory of Material in the Earth’s Interior Institute of Geochemistry Chinese Academy of Sciences Guiyang China department of geology China University of Geosciences Beijing China department of geology Peking University Beijing China

Two sets of dehydration-melting with a natural solid amphibolite, collected from North Himalayan structure zone, Tibet, have been carried out in multi-anvil apparatus at 2.0 GPa and 800―1000℃, for 12―200 h. One is keeping the pressure at 2.0 GPa and the annealing time of 12 h, changing the temperature (800―1000℃). The other is keeping the pressure at 2.0 GPa and temperature at 850℃, varying the annealing time (12―200 h). The products are inspected with microscope and electron probe. The results indicate that at 2.0 GPa, annealing time of 12 h, garnets, melts and clinopyroxenes occur in amphibolite gradually with increasing temperature and the chemical compositions of melt vary from tonalite to granodiorite, and then to tonalite. However, at 2.0 GPa and 850℃, with the annealing time increasing, the garnets, melts and cli-nopyroxenes also occur in amphibolite gradually and the chemical compositions of melt vary from tonalite to granodiorite. In both cases, melts interconnect with each other when the contents of melt are over the 5 vol.%. the viscosities of the melt produced in amphibolite at temperature higher than 850℃ are on a level with 104.Pa·s. The interconnected melt with such a viscosity may segregate from the source rock and form the magma over reasonable geological time. Therefore, it is believed that at the lower part of the overthickened crust, the tonlitic and grano-dioritic magma may be generated through the dehydration melting of amphibolite.

关键词： solid amphibolite, high pressure, high temperature, time, partial melting.

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Mechanism for calcite dissolution and its contribution to development of reservoir porosity and permeability in the Kela 2 gas field,Tarim Basin,china

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Science china Earth Sciences 2008年第4期51卷 567-578页

作者： YU BingSong1,3, DONG HailLiang2,3 & RUAN Zhuang1,3 1 State Key Laboratory of Geological Processes and Mineral Resources, china university of geosciences, Beijing 100083, china 2 department of {4., Miami university,Oxford, OH 4.056, USA 3 Geomicrobiology Laboratory, china university of geosciences, Beijing, 100083, china State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing China Geomicrobiology Laboratory China University of Geosciences Beijing China department of geology Miami University Oxford USA

This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern china. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4.00 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4.type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2+ concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2+]). In the Na2SO4.water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and

关键词： calcite dissolution porosity thermodynamic Tarim Basin

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Mineralogy and crystal structure determination of Mg-fillowite

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Science china Earth Sciences 2005年第5期48卷 635-646页

作者： MA Zhesheng 1 , SHI Nicheng 1 & YE Danian 2 1. china university of geosciences, Beijing 100083, china 2. Institute of geology, Chinese Academy of Sciences, Beijing 100029, china china university of geosciences Beijing China Institute of geology Chinese Academy of Sciences Beijing China

Accurate crystal structure determination of complex phosphate Mg-fillowite ? Na2Ca(Mn4.g2Fe)7[PO4.6 has been finished. Mg-fillowite occurs in muscovite-pegmatite in the Altay area, Xinjiang, china. It is of the trigonal lattice, with space group R-3, unit cell a=1.514.(3) nm, c=4.3191(2) nm, V=8.5736 nm3, Z = 18. The R-factor of the determination accuracy is R (I > 2σ ( I )) = 0.0776. The cationic polyhedra consist of two kinds of structural units: compound col- umn and screw column. In three-dimensional space, they are linked with each other through corner sharing or edge sharing to build the entire structure. There are 4. atoms in an asymmetric unit and 720 atoms in a unit cell. In terms of types and connection manners of the coordination polyhedra, the degree of complicity is rarely seen in all mineral crystal structures. Study of such a structure is significant for the classification of phosphate and the building rule of coordination polyhedra in a complex crystal structure.

关键词： Mg-fillowite, complex phosphate, crystal structure, coordination polyhedron.

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Petrogenesis of Songshugou dunite body in the Qinling orogenic belt, Central china: Constraints from geochemistry and melt inclusions

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Science china Earth Sciences 2005年第8期48卷 1146-1157页

作者： SU Li1,2, SONG Shuguang3 & ZHOU Dingwu1 1. Key Laboratory of Continental Dynamics of the Ministry of Education, department of geology, Northwestern university, Xi’an 710069, china 2. The Geological Lab Center,{4. (Beijing), Beijing 100083, china 3. Key Laboratory of Orogenic Belts of the Ministry of Education, department of geology, Peking university, Beijing 100871, china Key Laboratory of Continental Dynamics of the Ministry of Education Department of Geology Northwestern University Xi’an China The Geological Lab Center China University of Geosciences (Beijing)Beijing China Key Laboratory of Orogenic Belts of the Ministry of Education Department of Geology Peking University Beijing China

The Songshugou dunite body, which occupies an area of about 20 km2, is the largest ultramafic massif in the eastern Qinling orogenic belt, Central china. The major compo-nent of this body is dunitic rocks including mylonitic dunite and coarse-grained dunite; they oc-cupy about 95 vol% of the total body. Petrography, mineral composition, major and trace ele-ments and primitive melt inclusions have been investigated in this paper; all revealed that this dunite body is the product of melt-rock interaction by porous percolation flow. In comparison with dunite sills or veins in harzburgite from the basal part of Oman ophiolite, this dunite body is characterized by lower contents of Al2O3, CaO and HREE but higher content of highly incom-patible elements and Zr and Hf. The LREE enriched patterns and primitive mantle normalized spidergrams of trace elements are also different from the Oman dunite. Combining with melt in-clusions observed in olivines, we conclude that this dunite body is the product of large- scale porous percolation flow of high-MgO melts within depleted mantle peridotites. The high-MgO magma, in essence, was most probably produced at the hot head of an upwelling mantle plume. The occurrence of the Songshugou dunite body is closely associated with the activity of mantle super-plume in Neo-Proterozoic era in the Yangtze Craton.

关键词： Songshugou dunite body, geochemistry, melt inclusion, mantle plume, Qinling orogenic belt.

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The crustal structure under Sanjiang and its dynamic implications:Revealed by seismic reflection/refraction profile between Zhefang and Binchuan,Yunnan

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Science china Earth Sciences 2005年第9期48卷 1329-1336页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2, TENG Jiwen1, Lü Qingtian3, LI Jiliang1, LIU Yifeng1 & LIU Zhenkuan4.1. Institute of geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, china 2. Institute of Geophysics, china Seismological Bureau, Beijing 100085, china 3. Institute of Deposition Resource, Chinese Academy of {4., Beijing 100037, china 4. School of Exploration and Information, china university of geosciences, Beijing 100083, china Institute of geology and Geophysics Chinese Academy of Sciences Beijing China Institute of Geophysics China Seismological Bureau Beijing China Institute of Deposition Resource Chinese Academy of Geosciences Beijing China School of Exploration and Information China University of Geosciences Beijing China

The fault belts in Sanjiang mainly include Jinshajiang-Honghe fault, Lancangjiang fault and Nujiang fault (called Sanjiang faults) in western Yunnan Province, china. By interpreting the wide-angle seismic reflection/refraction profile between Zhefang and Binchuan, which crosses Tengchong and Baoshan blocks in Dianxi (western Yunnan) tectonic zone, we recon- struct the crustal structure with seismic traveltime tomography for crustal P-wave velocity and the seismic scattering image for crustal seismic reflection structure. In this paper, we firstly present the crustal structure images of P-wave velocity and seismic reflection under the wide-angle seismic profile. These results demonstrate that, the crustal velocity structure and seismic reflec- tion structure along the profile can be divided into 3 segments, and there is an obvious difference of crustal structure among the eastern, the western and the middle segment. Generally, crustal P-wave velocities in the Baoshan segment are 0.1―0.2 km/s slower and seismic reflection am- plitudes from Moho discontinuity are stronger than the other 2 segments. In the studied area, crustal thickness is about 4. km, and shows the thickening tendency from west to east along the profile. Additionally, it can be seen that there is one strong-amplitude seismic reflection event as bright points at the depths of 8―10 km, along the segment of 80―115 km of the profile (south- ward of Tengchong); and seismic reflection wave-field from Moho discontinuity varies obviously along the lateral direction. Finally, we make some discussions on the crustal thickening pattern in the Sanjiang fault belt, structural environment of earthquake development and the contact rela- tionship between the Tengchong block, Banshan block and Luxi trough.

关键词： Sanjiang area wide-angle seismic profile crustal structure.

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Modeling of 3-D terrain effect on MT field using BEM

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Chinese Science Bulletin 1997年第9期42卷 764-767页

作者： XU Shizhe, RUAN Baiyao, ZHOU Hui and CHEN Leshou1.Institute of geology and Geophysics, Ocean university of Qingdao, Qingdao 266003, china 2. china university of geosciences, Beijing {4., china Institute of geology and Geophysics Ocean University of Qingdao Qingdao China Chi university of geosciences Beijing China

THE modeling of 2-D terrain effect on magnetotelluric(MT)has been solved using finite ele-ment method(FEM)and boundary element method(BEM).This note uses BEM tosolve the *** solution of H_x- and E_x-polarization wave ... 详细信息

关键词： MT 3-D terrain boundary element method.

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Changes of infrared absorption wave number of aromatic-ring C=C bond of vitrinite and their significance

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Chinese Science Bulletin 1998年第12期43卷 1048-1050页

作者： XIAO Jianxin 1 and CHEN Shanqing 2 1. china university of geosciences, Beijing 100083, china 2. Yichang Institute of geology and Mineral Resources, Yichang 4.3003, china china university of geosciences Beijing China Yichang Institute of geology and Mineral Resources Yichang China

The humilith series of lignite, longflame coal, gas coal, fat coal, coking coal, lean coal, meagre coal and anthracite are measured by FIR1600 infrared spectrophotometer. The variation curve between the infrared absorption wave number of aromaticring C--C bond of vitrinite and its reflectance values are gained, which shows the shift of infrared absorption wave number of aromaticring C--C bond of humic coals towards lower wave number with the increase of coalification. It is believed that the coal rank of humilith series can be determined and more evolutional information about coal composition and structure can be obtained by the infrared spectroscopic method.

关键词： aromatic_nucleus C--C bond infrared absorption wave number vitrinite humic coal.

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