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Science china chemistry 2007年第6期50卷 770-775页

作者： LIU LiLi1, MA WanHong1, SONG WenJing1, CHEN ChunCheng1, LIN Jun2, ZHAO JinCai1, QIAN XinHua3 & ZHANG ShiBo3 1 Institute of chemistry, Chinese Academy of Sciences, beijing 100080, china 2 department of chemistry, renmin university of china, beijing 100872, china 3 Fushun Petrochemical Company, Petrochina Company Limited, Fushun 113008, china Institute of chemistry Chinese Academy of Sciences Beijing China department of chemistry Renmin University of China Beijing China Fushun Petrochemical Company PetroChina Company Limited Fushun China

This study investigated the visible-light catalysis mediated by zeolite NaY on the oxidation of dyes with H2O2. The results demonstrated that zeolite NaY acts as a sink for the electron from the photo-excited dye in the heterogeneous catalysis. Furthermore, the electron can effectively activate H2O2 to produce ?OH radical that is a powerful oxidant for the oxidation of dye at room temperature. The effects of the framework topology, Si/Al ratio, and exchangeable cation of the zeolite on the oxidation of various dyes were also shown.

关键词： photooxidation, zeolite NaY, dye, hydrogen peroxide, visible light

Hierarchical linear regression models for conditional quantiles

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Science china Mathematics 2006年第12期49卷 1800-1815页

作者： TIAN Maozai & CHEN Gemai School of Statistics, renmin university of china, beijing 100872, china and Center for Applied Statistics, renmin university of china, beijing 100872, china department of Mathematics and Statistics, university of Calgary, Canada School of Statistics Renmin University of China Beijing China Center for Applied Statistics Renmin University of China Beijing China department of Mathematics and Statistics University of Calgary Canada

The quantile regression has several useful features and therefore is gradually developing into a comprehensive approach to the statistical analysis of linear and nonlinear response models,but it cannot deal effectively with the data with a hierarchical *** practice,the existence of such data hierarchies is neither accidental nor ignorable,it is a common *** ignore this hierarchical data structure risks overlooking the importance of group effects,and may also render many of the traditional statistical analysis techniques used for studying data relationships *** the other hand,the hierarchical models take a hierarchical data structure into account and have also many applications in statistics,ranging from overdispersion to constructing min-max ***,the hierarchical models are virtually the mean regression,therefore,they cannot be used to characterize the entire conditional distribution of a dependent variable given high-dimensional ***,the estimated coefficient vector (marginal effects)is sensitive to an outlier observation on the dependent *** this article,a new approach,which is based on the Gauss-Seidel iteration and taking a full advantage of the quantile regression and hierarchical models,is *** the theoretical front,we also consider the asymptotic properties of the new method,obtaining the simple conditions for an n1/2-convergence and an asymptotic *** also illustrate the use of the technique with the real educational data which is hierarchical and how the results can be explained.

关键词： hierarchical quantile regression models,EQ algorithm,fixed effects,random effects,regression quantile.

The genus distributions for a certain type of permutation graphs in orientable surfaces

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Science china Mathematics 2007年第12期50卷 1748-1754页

作者： Rong-xia HAO~(1+) Wei-li HE~1 Yan-pei LIU~1 Er-ling WEI~2 ~1 department of Mathematics,beijing Jiaotong university,beijing 100044,china ~2 School of Information,renmin university of china,beijing 100872,china department of Mathematics Beijing Jiaotong University Beijing China School of Information Renmin University of China Beijing China

A circuit is a connected nontrivial 2-regular graph. A graph G is a permutation graph over a circuit C, if G can be obtained from two copies of C by joining these two copies with a perfect matching. In this paper, based on the joint tree method introduced by Liu, the genus polynomials for a certain type of permutation graphs in orientable surfaces are given.

关键词： graph, genus distribution, genus, surfaces

Progress in the study of molecular organized assemblies by dielectric relaxation spectroscopy

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Progress in Natural Science:Materials International 2006年第3期16卷 221-230页

作者： ZHAO Kongshuang, HE Kejuan and WEI Suxiang (department of chemistry, beijing Normal university, beijing 100875, china department of chemistry, South china Normal university, Guangzhou 510631, china) department of chemistry Beijing Normal University Beijing 100875 China department of chemistry South China Normal University Guangzhou 510631 China

Because dielectric spectroscopy covers a great many problems in physical and chemical systems occurring in an extremely wide frequency range, the study of this method plays an important role in physical chemistry. As an effective tool to detect inner properties of substance systems, the dielectric spectroscopy method is widely used in chemical systems and has been dramatically developed in recent decade. This review paper describes the applications of the dielectric spectroscopy in the chemical field, and main concentrations are focused on the micelle, microemulsion and other so-called molecular organized assemblies. Some dielectric principles and models proposed for these systems are introduced. In addition, recent technical developments in dielectric spectroscopy and developing trend of this method in other chemical systems are reviewed.

关键词： dielectric relaxation micelle microemulsion vesicle relaxation time.

Electron-phonon coupling in cuprate and iron-based superconductors revealed by Raman scattering

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Chinese Physics B 2013年第8期22卷 51-62页

作者：张安民张清明 department of Physics Renmin University of China

Electron-phonon coupling （EPC） in cuprate and iron-based superconducting systems, as revealed by Raman scat- tering, is briefly reviewed. We introduce how to extract the coupling information through phonon lineshape. Then we discuss the strength of EPC in different high-temperature superconductor （HTSC） systems and possible factors affecting the strength. A comparative study between Raman phonon theories and experiments allows us to gain insight into some crucial electronic properties, especially superconductivity. Finally, we summarize and compare EPC in the two existing HTSC systems, and discuss what role it may play in the HTSC.

关键词： electron-phonon coupling cuprate and iron-based superconducting systems Raman scattering,high-temperature superconductor

Study on the two and three-parameter working stability regions of 3Y-TZP suspension

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Science china(Technological Sciences) 2006年第5期49卷 547-568页

作者： CHEN Youqiang1, 2, ZHANG Xinni3, CHEN Sha’ou3 & QI Ping3 1. department of chemistry, Qingdao university, Qingdao 266071, china 2. department of chemistry, Tsinghua university, beijing 100084, china 3. department of Physics, Qingdao university, Qingdao 266071, china department of chemistry Qingdao University Qingdao China department of chemistry Tsinghua University Beijing China department of Physics Qingdao University Qingdao China

We determined the variation tendency of viscosity (η) at various solids load- ing (α) for 3Y-TZP suspension as a function of dispersant concentration (Cw) using vis- cosity measurement, measured the diameter of particles as a function of Cw in very dilute suspension using light scattering method, and obtained the surface features of the sedi- ment of suspension with different Cw using SEM. We also discussed the influence of the microstructure of adsorbed polymer layers on particles and their interactions in the dis- persing medium on the stability of suspension. Then two different stable states and two different unstable states for 3Y-TZP suspension were given. Accordingly, the (Cw, η), (Cw, α), and (α, η) two-parameter, and (Cw, α, η) three-parameter stability maps were con- structed. Based on the DLVO theory calculations, the dispersant concentration, particle distance (r), and interparticle potential energy (VT) maps with various solids loading for 3Y-TZP aqueous suspension were also constructed. In (Cw, r) two-parameter coordinate system, the stable motion region map for particles was established. The Cw, α, and VT,max (the highest potential energy) surface of the potential barrier map was obtained through calculation and simulation on the basis of the surfaces of Cw, r, VT maps introduced above. The (Cw, α) two-parameter stability map was then obtained from the Cw, α, VT,max map. The results showed that this theoretical map can qualitatively prove the experimentally obtained results—the existence of different dispersed states of particles in suspension system and the variation tendency of suspension stability with changing each parame- ter—were reasonable.

关键词： 3Y-TZP, suspension, stability, DLVO theory, interparticle potential energy.

THE PHYSICAL ENTROPY OF SINGLE CONSERVATION LAWS

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Journal of Computational Mathematics 1998年第5期16卷 437-444页

作者： (department of Mathematics, Peking university, beijing 100871, china) 北京大学数学系北京

By means of the comparisons with the formulas in statistical mechanics and thermodynamics, in this paper it is demonstrated that for the single conservation law partial derivative(t)u + partial derivative(x)f(u) = 0, if the flux function f(u) is convex (or concave), then, the physical entropy is S = -f(u); Furthermore, if we assume this result can be generalized to any f(u) with two order continuous derivative, from the thermodynamical principle that the local entropy production must be non-negative, one entropy inequality is derived, by which the O.A. Olejnik's famous E- condition can be explained successfully in physics.

关键词： conservation laws entropy entropy production

SYNTHESIS OF NOVEL SOLUBLE AROMATIC POLYPYROMELLITIMIDE CONTAINING ORDERED 1,2,4-TRIAZINE IN THE MAIN CHAIN

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Chinese Journal of Polymer Science 2002年第3期20卷 219-224页

作者： Xiao-bing Yi Guo-shi Wu Feng-cai Lu department of chemistry Tsinghua university, beijing 100084 china Institute of chemistry Chinese Academy of Sciences, beijing 100080, china department of chemistry Tsinghua University 北京 100084 Institute of chemistry Chinese Academy of Sciences 北京 100080

A new heat-resistant, soluble polymer, poly(phenyl-1,2,4-triazine imide), has been prepared via a two-step method of polycondensation of N,N'-bis(4-benzil)pyromellitimide and terephthalamidrazone in cresol, followed by curing at higher temperature. The rigid 1,2,4-triazine group increases the solubility of the polyimide so that the polymer is soluble in cresol, N-methyl-2-pyrrolidone (NMP), trifluoroacetic acid and concentrated sulfuric acid, etc. Thermogravimetric analysis (TGA) indicates that this novel polyimide has good thermal stability with a high decomposition temperature of 447degreesC in air and of 423 degreesC in N-2, It has a tensile strength of 107.4 MI'a with an elongation at break of around 7.6%.

关键词： polyimides N,N '-bis(4-benzil)pyromellitimide rigid-rod group 1,2,4-triazine

L~∞ CONVERGENCE OF TRUNC ELEMENT FOR THE BIHARMONIC EQUATION

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Journal of Computational Mathematics 1997年第1期15卷 14-22页

作者： M. Wang(department of Mathematics, beijing university, beijing, china) 北京大学数学系北京

The paper considers the L∞ convergence for TRUNC finite elements solving the boundary value problems of the biharmonic equation. The nearly optimal L∞ estimates for the error of first order derivatives are *** TRUNC plate element is proposed and developed by Argyris et al.. The numerical experiences show that the element has very good .***,[1l2]. The mathematicalproof of convergence of the TRUNC element is given by Shi Zong-ci in paper [3]. Thispaper will consider the L~∞ convergence for the TRUNC plate element.

关键词：双谐波方程边值问题收敛性有限元法

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,department of Materials Physics,university of Science and Technology beijing,beijing 100083,china

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Acta Metallurgica Sinica(English Letters) 1992年第9期5卷 178-182页

作者： QIAO Lijie LIU Rui XIAO Jimei university of Science and Technology beijing,beijing,china

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词： stress corrosion cracking stress compoonent brass ammonia solution