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Stress relaxation properties of calcium silicate hydrate:a molecular dynamics study

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第2期25卷 97-115页

作者： Zhicheng GENG Shengwen TANG yang WANG Hubao A Zhen HE Kai WU lei WANG State Key Laboratory of Water Resources Engineering and management Wuhan UniversityWuhan430072China Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education School of Materials Science and EngineeringTongji UniversityShanghai200092China college of Materials Science and Engineering Xi’an University of Architecture and TechnologyXi’an710055China

The time-dependent viscoelastic response of cement-based materials to applied deformation is far from fully understood at the atomic *** silicate hydrate(C-S-H),the main hydration product of Portland cement,is responsible for the viscoelastic mechanism of cement-based *** this study,a molecular model of C-S-H was developed to explain the stress relaxation characteristics of C-S-H at different initial deformation states,Ca/Si ratios,temperatures,and water contents,which cannot be accessed *** stress relaxation of C-S-H occurs regardless of whether it is subjected to initial shear,tensile,or compressive deformation,and shows a heterogeneous *** plays a crucial role in the stress relaxation process.A large Ca/Si ratio and high temperature reduce the cohesion between the calcium-silicate layer and the interlayer region,and the viscosity of the interlayer region,thereby accelerating the stress relaxation of *** effect of the hydrogen bond network and the morphology of C-S-H on the evolution of the stress relaxation characteristics of C-S-H at different water contents was elucidated by nonaffine mean squared *** results shed light on the stress relaxation characteristics of C-S-H from a microscopic perspective,bridging the gap between the microscopic phenomena and the underlying atomic-level mechanisms.

关键词： Calcium silicate hydrate(C-S-H) Stress relaxation Ca/Si ratio Temperature Water content Atomic simulation

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Comparative Experimental Study on Heat Transfer Characteristics of Building Exterior Surface at High and Low Altitudes

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Journal of Thermal Science 2024年第3期33卷 1119-1131页

作者： JIA Yonghong GUO Shurui LI Jin GUO lei CHENG Zhu ZHANG Yin yang Hanyu LONG Enshen Institute for Disaster management and Reconstruction Sichuan UniversityChengdu610065China MOE Key Laboratory of Deep Earth Science and Engineering College of Architecture and EnvironmentSichuan UniversityChengdu610065China

The external surface heat transfer coefficient of building envelope is one of the important parameters necessary for building energy saving design,but the basic data in high-altitude area are ***,the authors propose a modified measurement method based on the heat balance of a model building,and use the same model building to measure its external surface heat transfer coefficient under outdoor conditions in Chengdu city,China at an altitude of 520 m and Daocheng city at an altitude of 3750 m *** results show that the total heat transfer coefficient(h_(t))of building surface in high-altitude area is reduced by 34.48%.The influence of outdoor wind speed on the convective heat transfer coefficient(h_(c))in high-altitude area is not as significant as that in low-altitude *** fitting relation between convection heat transfer coefficient and outdoor wind speed is also *** the same heating power,the average temperature rise of indoor and outdoor air at highaltitude is 41.9%higher than that at low altitude,and the average temperature rise of inner wall is 25.8%higher than that at low *** shows that high-altitude area can create a more comfortable indoor thermal environment than low-altitude area under the same energy consumption *** is not appropriate to use the heat transfer characteristics of the exterior surface of buildings in low-altitude area for building energy saving design and related heating equipment selection and system terminal matching design in high-altitude area.

关键词： altitude heat transfer characteristics convective heat transfer coefficient(h_(c)) radiative heat transfer coefficient(h_(r)) external building envelope

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Weed biology andmanagement in the multi-omics era:Progress and perspectives

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Plant Communications 2024年第4期5卷 16-35页

作者： Ke Chen Haona yang Di Wu Yajun Peng lei Lian Lianyang Bai Lifeng Wang Key Laboratory of Indica Rice Genetics and Breeding in the Middle and Lower Reaches of yangtze River Valley Ministry of Agriculture and Rural AffairsHunan Rice Research InstituteHunan Academy of Agricultural SciencesChangsha 410125China State Key Laboratory of Hybrid Rice Hunan Academy of Agricultural SciencesChangsha 410125China Longping Branch College of BiologyHunan UniversityChangsha 410125China Huangpu Research Institute of Longping Agricultural Science and Technology Guangzhou 510715China Hunan Weed Science Key Laboratory Hunan Agricultural Biotechnology Research InstituteHunan Academy of Agricultural SciencesChangsha 410125China Qingdao Kingagroot Compounds Co.Ltd Qingdao 266000China

Weeds pose a significant threat to crop production,resulting in substantial yield *** addition,they possess robust weedy traits that enable them to survive in extreme environments and evade human *** recent years,the application of multi-omics biotechnologies has helped to reveal the molecular mechanisms underlying these weedy *** this review,we systematically describe diverse applications of multi-omics platforms for characterizing key aspects of weed biology,including the origins of weed spe-cies,weed classification,and the underlying genetic and molecular bases of important weedy traits such as crop–weed interactions,adaptability to different environments,photoperiodicflowering responses,and herbicide *** addition,we discuss limitations to the application of multi-omics techniques in weed science,particularly compared with their extensive use in model plants and *** this regard,we provide a forward-looking perspective on the future application of multi-omics technologies to weed science *** powerful tools hold great promise for comprehensively and efficiently unraveling the intricate molecular genetic mechanisms that underlie weedy *** resulting advances will facilitate the development of sustainable and highly effective weed management strategies,promoting greener practices in agriculture.

关键词： weeds multi-omics weed management genomics RNA-seq

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Prediction of soil organic carbon stock combining Sentinel-1 and Sentinel-2 images in the Zoige Plateau, the northeastern Qinghai-Tibet Plateau

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Ecological Processes 2024年第2期13卷 165-176页

作者： Junjie lei Changli Zeng Lv Zhang Xiaogang Wang Chanhua Ma Tao Zhou Benjamin Laffitte Ke Luo Zhihan yang Xiaolu Tang State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Chengdu University of Technology Sichuan Academy of Geological Survey Sichuan Institute of Nuclear Geological Survey college of Earth Sciences Chengdu University of Technology Tianfu Yongxing Laboratory

Background Soil organic carbon（SOC） is a critical component of the global carbon cycle, and an accurate estimate of regional SOC stock（SOCS） would significantly improve our understanding of SOC sequestration and cycles. Zoige Plateau, locating in the northeastern Qinghai-Tibet Plateau, has the largest alpine marsh wetland worldwide and exhibits a high sensitivity to climate fluctuations. Despite an increasing use of optical remote sensing in predicting regional SOCS, optical remote sensing has obvious limitations in the Zoige Plateau due to highly cloudy weather, and knowledge of on the spatial patterns of SOCS is limited. Therefore, in the current study, the spatial distributions of SOCS within 100 cm were predicted using an XGBoost model—a machine learning approach, by integrating Sentinel-1, Sentinel-2 and field observations in the Zoige *** The results showed that SOC content exhibited vertical distribution patterns within 100 cm, with the highest SOC content in topsoil. The tenfold cross-validation approach showed that XGBoost model satisfactorily predicted the spatial patterns of SOCS with a model efficiency of 0.59 and a root mean standard error of 95.2 Mg ha-1. Predicted SOCS showed a distinct spatial heterogeneity in the Zoige Plateau, with an average of 355.7 ± 123.1 Mg ha-1within 100 cm and totaled 0.27 × 10～9 Mg *** High SOC content in topsoil highlights the high risks of significant carbon loss from topsoil due to human activities in the Zoige Plateau. Combining Sentinel-1 and Sentinel-2 satisfactorily predicted SOCS using the XGBoost model, which demonstrates the importance of selecting modeling approaches and satellite images to improve efficiency in predicting SOCS distribution at a fine spatial resolution of 10 m. Furthermore, the study emphasizes the potential of radar（Sentinel-1） in developing SOCS mapping, with the newly developed fine-resolution mapping having important applications in land management, ecological resto

关键词： SOC Vegetation index Texture XGBoost Sentinel-1 Sentinel-2

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Medium distribution, source characteristics and ecological risk of bisphenol compounds in agricultural environment

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Emerging Contaminants 2024年第2期10卷 65-75页

作者： Yihao Qin Jianchao Liu lei Han Jinghua Ren Chenyang Jing Guanghua Lu Xinming yang Key Laboratory of Integrated Regulation and Resource Development of Shallow Lakes of Ministry of Education Hohai UniversityNanjing210098China college of Environment Hohai UniversityNanjing210098China Jinan Environmental Research Institute(Jinan Yellow River Basin Ecological Protection Promotion Center) JinanChina Technology Innovation Center for Ecological Monitoring&Restoration Project on Land(arable) Ministry of Natural Resources Geological Survey of Jiangsu ProvinceNanjing210018China

Bisphenol compounds(BPs)are commonly used in industry and ***,BPs pollution has already raised global concerns due to their ecological *** study investigated nine types of BPs in agricultural soil and irrigation rivers,and evaluated the occurrence,source apportionment,and ecological risks for BPs in soils of agricultural environment by using principal component analysis-multivariate linear regression(PCA-MLR)and risk quotients(RQ).The average concentration of BPs in soil,irrigation water and sediments were 29.19 ng/g,30.21 ng/L and 610.09 ng/g dw,*** was the most highly detected contaminant in all *** soil,the primary BPA substitutes were bisphenol S(BPS)and bisphenol F(BPF),contributing about 50%to the pollution in ***-MLR analysis indicated that the release of solid waste was the primary cause of BPs pollution in the agricultural soils,following by waste water *** evaluation of RQ revealed that BPs presented a low to medium risk to algae,daphnia,and fish in irrigation rivers,while more than 90% of soil sampling sites faced medium or high risk,with BPA and BPS as the main contributors to the *** research findings offer evidence to support the assessment of contaminants concentration,source pathways,and risk management strategies pertaining to BPs in the agricultural *** ongoing BPA substitute occurrence,addressing risks to agricultural soil ecosystems remains crucial.

关键词： Bisphenol compounds Soil Irrigation rivers Ecological risks

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Ways to Cultivate and Develop Human Resources in the New Situation

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Journal of Sustainable Business and economics 2024年第2期7卷 38-43页

作者： lei Wang Gengliang yang Hebei Children’s Hospital ShijiazhuangHebei050000China

In the trend of globalization,digitization,and economic integration,human resources are the core competitiveness of enterprises,and cultivating and developing them is crucial for enhancing competitive *** article delves into how human resource development drives enterprise innovation,promotes team collaboration,and optimizes performance ***,although many enterprises are beginning to attach importance to human resource development,they still face problems such as insufficient investment,weak targeted training,and insufficient exploration of employee ***,it is proposed that in the new situation,enterprises need to strengthen diversified training strategies,use digital tools to improve training efficiency,build a fair performance evaluation system,stimulate employee potential,and promote internal talent *** implementation of these strategies will effectively enhance the efficiency of enterprise human resource management and consolidate market position.

关键词： Human Resources Cultivation development New situation Channel

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Arbuscular mycorrhizal fungi reduce ammonia emissions under different land-use types in agro-pastoral areas

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Pedosphere 2024年第2期34卷 497-507页

作者： Huaisong WANG Rui GUO Yibo TIAN Nan CUI Xinxin WANG lei WANG Zhongbao yang Shuying LI Jixun GUO Lianxuan SHI Tao ZHANG Institute of Grassland Science Northeast Normal UniversityKey Laboratory of Vegetation EcologyMinistry of EducationJilin Songnen Grassland Ecosystem National Observation and Research StationChangchun 130024China Institute of Environment and Sustainable Development in Agriculture Chinese Academy of Agricultural SciencesKey Laboratory of Dryland AgricultureMinistry of AgricultureBeijing 100081China Mountainous Area Research Institute of Hebei Province Hebei Agricultural UniversityBaoding 071001China college of Agronomy Liaocheng UniversityLiaocheng 252059China The Key Laboratory of Plant Development and Environmental Adaptation Biology Ministry of EducationSchool of Life ScienceShandong UniversityQingdao 266237China Forestry and Grassland Bureau of Aohan Banner Chifeng 024005China

Ammonia(NH3)emissions,the most important nitrogen(N)loss form,always induce a series of environmental problems such as increased frequency of regional haze pollution,accelerated N deposition,and N *** mycorrhizal(AM)fungi play key roles in N ***,it is still unclear whether AM fungi can alleviate N losses by reducing *** potential mechanisms by which AM fungi reduce NH_(3)emissions in five land-use types(grazed grassland,mowed grassland,fenced grassland,artificial alfalfa grassland,and cropland)were explored in this *** showed that AM fungal inoculation significantly reduced NH3emissions,and the mycorrhizal responses of NH3emissions were determined by land-use *** equation modeling(SEM)showed that AM fungi and land-use type directly affected NH_(3)*** addition,the reduction in NH_(3)emissions was largely driven by the decline in soil NH_(4)^(+)-N and pH and the increases in abundances of ammonia-oxidizing archaea(AOA)amoA and bacteria(AOB)amoB genes,urease activity,and plant N uptake induced by AM fungal inoculation and land-use *** present results highlight that reducing the negative influence of agricultural intensification caused by land-use type changes on AM fungi should be considered to reduce N losses in agriculture and grassland ecosystems.

关键词： agricultural intensification grassland management functional genes plant N uptake N leaching N loss

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Characterization of Flame Retardancy and Oil-Water Separation Capacity of Superhydrophobic Silylated Melamine Sponges

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Fluid Dynamics & Materials Processing 2024年第2期20卷 383-400页

作者： Yongchun Liu Ni Qiao Yanli yang Yanchun Li Chunxiao He Siyang Wang Chengcheng Liu Ruixia lei Wang Li Wenwen Gao college of Chemistry and Chemical Engineering FLUOBON Pilot Base of Chemical EngineeringLongdong UniversityQingyang745000China Qingyang Solid and Hazardous Waste Pollution Prevention and Control management Center Qingyang745000China Gansu Qingluyuan Environmental Monitoring Co. Ltd.Qingyang745000China School of Chemistry and Chemical Engineering Shanxi Key Laboratory of Low Metamorphic Coal Clean UtilizationYulin UniversityYulin719000China

A silylated melamine sponge(SMS)was prepared by two simple steps,namely,immersion and dehydration of a melamine sponge coated with *** silylated structure of SMS was characterized by FT-IR(Fourier-transform infrared)spectroscopy,SEM(Scanning electron microscopy)and in terms of water contact *** oil-water absorption and separation capacities were measured by FT-IR and UV-visible *** experimental results have shown that oligomeric silanol covalently bonds by Si-N onto the surface of melamine sponge *** has shown superhydrophobicity with a water contact angle exceeding 150°±1°,a better separation efﬁciency with regard to diesel oil(by 99.31%(wt/wt%)in oil-water mixture and even up to 99.99%(wt/wt%)for diesel oil in its saturated aqueous ***,SMS inherited the intrinsicﬂame retardancy of the melamine *** general,SMS has shown superhydrophobicity,high porosity,excellent selectivity,remarkable recyclability,and better absorption capacity for various oils and organic solvents,and a high separation efﬁciency for oil in saturated aqueous solutions.

关键词： Methyltrichlorosilane silylated melamine sponge(SMS) superhydrophobicity absorption capacity oil-water separable efﬁciency ﬂame retardancy

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Revolution in thermoelectric cooling using PbSe thermoelectrics by grid plainification

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Science China Materials 2024年第5期67卷 1672-1673页

作者： Xiao-lei Shi Qingfeng Liu Zhi-Gang Chen School of Chemistry and Physics ARC Research Hub in Zero-emission Power Generation for Carbon Neutralityand Centre for Materials ScienceQueensland University of TechnologyBrisbaneQueensland4000Australia State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing211816China

Thermoelectric materials and devices enable direct conversion between heat and electricity,holding potential applications in thermoelectric power generation,localized cooling,and electronic thermal management[1].Howev... 详细信息

关键词： enable thermoelectric constrained

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Evaluation of physicochemical and functional properties of protein isolates from 5 edible mushroom species

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Food Science and Human Wellness 2024年

作者： Zheng Qian Mengdie yang Xiao Chen Qiping Zhan lei Zhong Qiuhui Hu Liyan Zhao Key Laboratory of Edible Mushroom Processing， Ministry of Agriculture and Rural Affairs， college of Food Science and Technology， Nanjing Agricultural University college of Food Science and Engineering， Nanjing University of Finance and economics

Edible mushroom proteins are the promising ones with the advantages of complete essential amino acid profile and multiple functional activities. To reinforce their applications in functional food development， this study comprehensively evaluated the physicochemical and functional properties of protein isolates from 5 mushroom species， i.e.， Pleurotus eryngii (PEP)， Pleurotus ostreatus (POP)， Lentinula edodes (LEP)， Flammulina velutipes (FVP) and Hypsizygus marmoreus (HMP). Results showed that PEP， LEP， FVP， POP and HMP exhibited better protein solubility (PS)， water holding capacity (WHC)， emulsifying capacity (EAI)， and foaming capacity (FC) than those of soybean protein and pea protein isolates. PEP (51.95%) and POP (49.15%) had a higher amount of β-sheet structure. Principal component analysis and correlation analysis showed that the seven proteins could be divided into 3 clusters， and WHC， EAI and FC were significantly positively correlated with PS and β-sheet. The least gelation concentration of PEP (16%) and FVP (16%) at pH 6.0 and 7.0 was similar to PPI， and PEP showed better hardness， springiness and rheological properties than other proteins gels. Overall， our study showed that 5 edible mushroom proteins possessed excellent functionalities (except for gelling capacity)， which provided novel insights on unexploited sources of mushroom proteins used as protein-based foods in the food industry.

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