Surface modified PbS nanocrystals were fabricated by a novel method and their ultrafast optical nonlinearity was studied by the femtosecond time-resolved optical Kerr effect.A large nonlinear effect(χ^((3))~5×10^(-1...
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Surface modified PbS nanocrystals were fabricated by a novel method and their ultrafast optical nonlinearity was studied by the femtosecond time-resolved optical Kerr effect.A large nonlinear effect(χ^((3))~5×10^(-12) esu)with a laser pulse limited response was *** may be attributed to the reduction of surface trapped electrons due to the surface modification.
Four novel 2-methoxyimino phenylacetate derivatives containing 1,3,4-oxadiazole ring were designed and synthesized from the key intermediate of Trifloxystrobin or Azoxystrobin via intermediate derivatization and activ...
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Four novel 2-methoxyimino phenylacetate derivatives containing 1,3,4-oxadiazole ring were designed and synthesized from the key intermediate of Trifloxystrobin or Azoxystrobin via intermediate derivatization and active structure *** chemical structures of the target compounds were confirmed by]H NMR,13C NMR and elemental *** crystal structure of methyl(E)-2-(methoxyimino)-2-(2-(((5-((4-methoxyphenoxy)methyl)-1,3,4-oxadiazol-2-yl)thio)methyl)phenyl)acetate(Al)was determined by single-crystal X-ray *** A1 belongs to triclinic system,space group Pi with two molecules in each unit *** benzene ring plane C(2)-C(3)-C(4)-C(5)-C(6)-C(7)and oxazole ring plane are nearly parallel with the dihedral angle of 6.4°.The benzene ring plane C(12)-C(13)-C(14)-C(15)-C(16)-C(17)and oxazole ring plane are not perpendicular with the dihedral angle of 49.4°.The crystal of compound Al is stabilized by π-π stacking *** fungicidal activities of the target compounds against four plant pathogenic fungi in vitro were tested,and some of them had good *** DFT calculation was carried out to study the structure-activity relationship of the title derivatives using Gasian 09 and Multiwfii 3.6.
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