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Chinese Journal of Structural Chemistry 1991年第3期10卷 227-230页

作者：陈学太翁林红等 FuzhouLaboratoryofStructuralChemistry FujianInstit FuzhouLaboratoryofStructuralC

Compound (Ph3PCH2Ph)[Ni (OSNC5H3)2] . DMF was obtained from the *** NiCl2,Na2(OSNC5H3)and Ph3PCH2PhCl. Mr = 735. 53,monoclinic,P21/ c,a=9. 857(6),b=17. 594(9),c=21. 369(10) A,β=102. 85(4)°,V=3613. 1A3,Z = 4,Dc=1. 35g/cm3,λ(Mo-Ka) = 0.71073A.μ=7. 3cm-1,F(000) = 1532,The nickel (Ⅲ) ion is coordinated by two 2-mercapto-3-pyridinolate ligands to give an approximate square-plannar configuration with cis-geometry.

关键词：制备晶体结构二甲基甲酰胺镍配合物 2-巯基-3-吡啶酚配位体

SYNTHESIS AND STRUCTURE OF A COBALT DIMER COMPLEX (Bt_4N)_2 [Co(SOC_6H_4 )(HOSC_6H_4)]_2

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Chinese Journal of Structural Chemistry 1989年第2期8卷 136-139页

作者：翁林红黄梁仁乖

The title compound was obtained by reaction of CoCl2.6H2O and mp2- (σ-C6H4SO2-) in MeCN,crystallized as Et4N+ salt in monoclinic system with space group P21/c, Mr=877.040. The cell parameters are:a =16.606(2), b=15.575(1),c=17.725(2)A,β=111.07(1)°,V=4277.8A3,Z=4,Dx= 1.36g/*** is a dimer of [Co(mp)(Hmp)]- connected by two strong hydrogen bonds with a twist angle of about 36.94 .

关键词：合成二聚物钴配合物四乙基铵配位体邻羟基苯硫酚晶体结构

Synthesis and Structure of the First Protonated Zincoborophosphate: (H_3O)Zn(H_2O)_2BP_2O_8·H_2O

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Chinese Journal of Chemistry 2003年第9期21卷 1170-1173页

作者：石恒真单永奎何鸣元刘煜炎翁林红 Department of Chemistry East China Normal University Shanghai 200062 ChinaLaboratory for Quantum Optics of National Education Ministry East China Normal University Shanghai 200062 China Department of Chemistry East China Normal University Shanghai 200062 China Laboratory for Quantum Optics of National Education Ministry East China Normal University Shanghai 200062 China Department of Chemistry Fudan University Shanghai 200433 China

The solid acid of the first protonated zincoborophosphate, (H 3O)Zn(H 2O) 2BP 2O 8·H 2O (1), was soventothermally synthesized by the reaction of Zn(NO 3) 2·6H 2O and H 3BO 3 with H 3PO 4 in a mixed solvent, and structurally characterized by single-crystal X-ray diffraction analysis. It crystallizes in the hexagonal P6 122, a=0.9604(4) nm, c=1.5297(6) nm, V=1.2218(8) nm 3, D c=2.921 g/cm 3, Z=6, F(000)=1080, μ=3.495 mm -1. The structure features that the tetrahedra-tetrahedra helices interconnected by octahedra and strong hydrogen bond interactions form a three-dimensional framework. The protonated water molecules are located at unique positions. Other characterizations by IR and thermal analysis are also described.

关键词： soventothermal synthesis zincoborophosphate protonation helical ribbon structure

新型配位聚合物Zn2.5(OH)2(O3PC6H4C6H4COO)的合成与结构

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新型配位聚合物Zn2.5(OH)2(O3PC6H4C6H4COO)的合成与结构

SYNTHESIS AND STRUCTURE OF (Ph_4P)_2[Ni_3(μ-SC_3H_6S)_4]·2CH_3CN

中国晶体学会第四届全国会员代表大会暨学术会议

作者：冯璐陈珍霞翁林红周亚明复旦大学化学系

近年来,配位聚合物因其比表面大、孔径大小分布均匀、空隙率高等特点及其潜在的应用价值而引起科学家的广泛关注。本文采用4’-膦酸-联苯4-羧酸(PBPDC)为配体,溶剂热法与乙酸锌合成了一种新颖的三维配位聚合物Zn(OH)(OPCHCHCOO),并通过X...

近年来,配位聚合物因其比表面大、孔径大小分布均匀、空隙率高等特点及其潜在的应用价值而引起科学家的广泛关注。本文采用4’-膦酸-联苯4-羧酸(PBPDC)为配体,溶剂热法与乙酸锌合成了一种新颖的三维配位聚合物Zn(OH)(OPCHCHCOO),并通过X-射线单晶衍射,X射线多晶衍射,元素分析等对其结构进行表征。该配位聚合物属单斜晶系,C2空间群,晶胞参数为a=32.854(17)A,b=5.367(3)A,C=7.928(4)A,β=103.875(7)。,Z=4,V=1357.1(12)A,Dc=2.313 g/cm,R=0.0465,wR=0.1032。Zn原子分别采用四配位,五配位,六配位三种配位方式形成一个致密的无机层,层与层之间通过配体的有机部分连接,形成典型的柱层状结构。

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Chinese Journal of Structural Chemistry 1989年第3期8卷 202-204页

作者：陈学太翁林红等

(Ph4P)2[Ni3(u-SC3H6S)4].2CH3CN was obtained from the reaction of NiCl2.6H2O,Na2(1,2-pdt)(pdtH2=CH3CH(SH)CH2SH) and ***=1361. 80, P21/c,a=10.802(2),b=30.111 (7),c=9. 907(3) A ,B=93. 60(3) ;V= 3216. 0 A3;Z=2,Dc=1. 41g/cm3. The three Ni atoms of the anion are linearly arranged and bridged by four sulfur atoms from the four 1 ,2-propyldithiolato ligands.

关键词： CN Ni3 SC3H6S Ph4P SYNTHESIS AND STRUCTURE OF CH

Synthesis, Crystal Structure of [(MeC_5H_4)_2Ln(μ-OCH_2CH_2NMe_2)]_2 (Ln=Sm, Y, Nd) and Their Catalytic Activity for Ring-Opening Polymerization of ε-Caprolactone

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Journal of Rare Earths 2003年第5期21卷 505-509页

作者：邓明宇周玉芳姚英明沈琪翁林红 Department of Chemistry and Chemical Engineering Suzhou University Department of Chemistry Fudan University

Reaction of (MeC 5H 4) 3Ln with HOCH 2CH 2NMe 2 in tetrahydrofuran(THF) gives the new complexes [(MeC 5H 4) 2Ln(μ OCH 2CH 2NMe 2)] 2 (Ln=Sm, Y, Nd) with nitrogen functionalized μ alkoxide ligand. The complexes were characterized by elemental analysis and IR, and [(MeC 5H 4) 2Sm(μ OCH 2CH 2NMe 2)] 2 was structurally characterized by the X ray diffraction to be a dimer formed by two unsymmetric oxygen bridges. The complex has a tricyclic skeleton with the additional two Sm-N bonds via intramolecular coordination of OCH 2CH 2NMe 2. The coordination number of the central metal Sm is nine. The title complexes show good catalytic activity for ring opening polymerization of ε caprolactone.

关键词： inorganic chemistry nitrogen functionalized alkoxide complex crystal structure ring opening polymerization ε caprolactone rare earths

含硫邻苯二酚配体的钴化合物1H-NMR研究

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含硫邻苯二酚配体的钴化合物1H-NMR研究

Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol (H_2bdt)——Synthesis and Structure of Fe_3(bdt)_3(PBu_3~n)_3

第六届全国波谱学学术会议

作者：吴达旭翁林红彭金海康北笙刘汉钦中国科学院福建物质结构研究所

邻苯二硫酚(Ebdt)、三苯基和二氯化钴作用得到化合物[1]Bu P-H(Co(bdt)]BuP]和(Ⅱ)BuP.H(Co(bdt)):邻硫基苯酚二钠盐

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Science China Chemistry 1993年第8期36卷 912-919页

作者：康北笙徐勇进吴达旭彭金海洪茂椿翁林红陈学太刘汉钦 State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter Academia Sinica Fuzhou 350002 PRC

Complex Fe_3(bdt)_3(PBu_3~n)_3 was synthesized in the presence of PBu_3~n and the structural regularities in a series of transition metal complexes containing bdtH_2 ligand were summarized. The title complex crystallizes in the triclinic space group P-, Mr=1195.19, cell parameters: a=13.283(3), b=20.115(5), c=13.156(3), (?)=90.33(2), β= 116.47 (1), γ=92.19(2)°, V=3143.5(2.7)~3, Z=2, d_c=1.26g/cm^3. The structure was solved by direct methods from 4122 unique reflections with I>4σ(I) and reached the final convergence factor of R(Rw) = 0.053 (0.060). The complex exhibits strong paramagnetism.

关键词： o-benzenedithiol ligand thiolate and phosphine-mixed coordinated complex structural regularity trinuclear iron cluster compound.

Synthesis and structure of neutral double helicate

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Chinese Journal of Chemistry 2000年第5期18卷 773-776页

作者：苏循成周志芬朱守荣林华宽翁林红冷雪冰陈荣悌 Department of Chemistry Nankai University Tianjin 300071 China

A new approach to generating supramolecular architectures, based on easy-to-prepare schiff base ligands, is described together with its application to the self-assembly of supramolecular neutral double helicates.

关键词： Self-assembly Schiff base helical complex