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Understanding Bonding nature ofα-Keggin Polyoxometalates[XW_(12)O_(40)]^(n−)(X=Al,Si,P,S):A Generalized Superatomic Perspective

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Energy & Environmental Materials 2024年第6期7卷 176-183页

作者： Rui Li yulei Shi Famin yu Rui wang Haitao Yan Boon K.Teo Zhigang wang Department of Physics Capital Normal UniversityBeijing 100048China Key Laboratory of Material Simulation Methods&Software of Ministry of Education College of PhysicsJilin UniversityChangchun 130012China Institute of Atomic and Molecular Physics Jilin UniversityChangchun 130012China State Key Laboratory for Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Institute of Theoretical Chemistry College of ChemistryJilin UniversityChangchun 130012China

α-Keggin polyoxometalates(POMs)[XW_(12)O_(40)]^(n−)(X=Al,Si,P,S)are widely used in batteries owing to their remarkable redox ***,the mechanism underlying the applications appears inconsistent with the widely accepted covalent bonding ***,first-principles calculations show that XW_(12)are core–shell structures composed of a shell and an XO_(4)^(n−)core,both are stabilized by covalent ***,owing to the presence of a substantial number of electrons in W_(12)O_(36)shell,the frontier molecular orbitals of XW_(12)are not only strongly delocalized but also exhibit superatomic properties with high-angular momentum electrons that do not conform to the Jellium *** analysis indicates that energetically high lying filled molecular orbitals(MOs)have reached unusually high-angular momentum characterized by quantum number K or higher,allowing for the accommodation of numerous *** attribute confers strong electron acceptor ability and redox activity to XW_(12).Moreover,electrons added to XW_(12)still occupy the K orbitals and will not cause rearrangement of the MOs,thereby maintaining the stability of these *** findings highlight the structure–activity relationship and provide a direction for tailor-made POMs with specific properties at atomic level.

关键词： first principles molecular orbital polyoxometalate redox activity superatom

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Slip rate and interseismic coupling along the Moxi-Shimian segment of the Xianshuihe fault, Eastern Qinghai-Xizang Plateau

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Geodesy and Geodynamics 2024年第4期15卷 338-351页

作者： Xinyu Zhao Gang Liu Zhaosheng nie Wei Xiong Wei Chen Mu Lin Dijin wang Qi Li Jiansheng yu Dongzhen wang Pengfei yu Institute of Seismology China Earthquake AdministrationWuhan 430071China Key Laboratory of Earthquake Geodesy.China Earthquake Administration Wuhan 430071China State Key Laboratory of Geodesy and Earth's Dynamics Innovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan 430077China

On September 5,2022,the Luding M6.8 earthquake occurred in the Moxi-Shimian segment of the Xianshuihe fault,coinciding with the historical ruptured zone of the 1786 Moxi *** seis-mogenic environment provides a foundation for comprehending the mechanism of the earthquake and its future *** the Moxi-Shimian segment,we establish a series of near-field Global navigation Satellite Systems(GnsS)stations to enhance the spatial resolution of observational data for the inversion of the interseismic kinematic *** this study,with an elastic screw dislocation model con-strained by GnsS observations,the slip rate of the Moxi-Shimian segment is estimated to be 10.9±1.0 mm/yr,while the locking depth is 15.7±6.2 ***,we utilize a block-dislocation model to invert the interseismic fault coupling along the Kangding-Moxi-Shimian *** result indicates a gradual deepening of the locking depth along the section from Kangding to *** coseismic rupture of the 2022 event occurred within the high coupling regions in the Kangding-Moxi-Shimian segment,which indicates that the rupture kinematics in this event might be controlled by the interseismic *** seismic moment accumulated within the ruptured zone of the Luding earthquake since 1786 ranges in[1.42-3.40]×10^(19) n-m,which is significantly greater than the seismic moment released during the 2022 *** a result,we infer that the Luding earthquake released only a portion of the accumulated energy within the original rupture zone since 1786,indicating that the 2022 event has not caused a complete rupture in the Moxi-Shimian ***,there remains a substantial seismic hazard in this area.

关键词： Moxi-Shimian segment of Xianshuihe fault Luding earthquake Global positioning system Interseismic kinematic parameters

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Morphological and molecular analyses of a Philine kinglipini outbreak in summer of 2022 in Jiaozhou Bay,China

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Journal of Oceanology and Limnology 2024年第3期42卷 831-848页

作者： Zelin DUAn Yanan yu Jing wang Junlong ZHAnG nansheng CHEn CAS Key Laboratory of Marine Ecology and Environmental Sciences Institute of OceanologyChinese Academy of SciencesQingdao 266071China Laboratory of Marine Ecology and Environmental Science Laoshan LaboratoryQingdao 266237China Center for Ocean Mega-Science Chinese Academy of SciencesQingdao 266071China Laboratory of Marine Organism Taxonomy and Phylogeny Qingdao Key Laboratory of Marine Biodiversity and ConservationInstitute of OceanologyChinese Academy of SciencesQingdao 266071China Marine Biological Museum Chinese Academy of SciencesQingdao 266071China Department of Molecular Biology and Biochemistry Simon Fraser UniversityBurnabyBritish ColumbiaV5A 1S6Canada

A sudden and unprecedented outbreak of molluscan Philine kinglipini occurred in summer 2022 in Jiaozhou Bay,Shandong,China,causing substantial damage to local mariculture industry of the Manila clam Ruditapes *** *** has been found in many coastal regions of China,the molecular research of *** has not been extensively studied,making it difficult to accurately identify and track *** samples in field using molecular *** were collected during the outbreak and their morphological features and molecular sequences were *** show that the causative species of the outbreak was *** mitochondrial genome(mt DnA)of *** was constructed for the first time,based on which phylogenetic analysis of the mt DnAs of *** and related species in the order Cephalaspidea was carried *** revealed by metabarcoding analysis of 18S rDnA V4,the seasonal change of *** and closely related Philine species was striking with peaks between April and ***,metabarcoding analysis is applicable tool for monitoring the bloom development of *** and related *** study generated for the first time essential molecular marker sequences and mtDnA of ***,which provided a reference for future characterization and monitoring of its outbreaks and for phylogenetic analysis of Philine species.

关键词： marine species outbreaks metabarcoding analysis mitochondrial genome Philine kinglipini phylogenetics spatial-temporal dynamics

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Effect of nourishing Yin and purging fire Chinese herbal mixture on delaying light-induced premature puberty in rats

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Journal of Traditional Chinese Medicine 2024年第1期44卷 95-102页

作者： SUn Yanyan XUE yuanyuan SUn Wen wang Yonghong yu Jian Department of Traditional Chinese Medicine Children's Hospital of Fudan UniversityShanghai 201102China Department of Pediatrics Zibo Central HospitalZibo 255000China

OBJECTIVE:To elucidate the mechanism of the nourishing Yin and purging fire Chinese herbal mixture(nYPF)in delaying light-induced premature puberty in ***:Twenty-one days old female SpragueDawley rats were randomly assigned to normal group(n),long light exposure group(L),nYPF and normal saline group(nS).Rats in the L,nYPF and nS groups were exposed to 16 h:350 lux light/8 h:dark,while rats in the n group were exposed to 12 h:50 lux light/12 h:*** and normal saline was administered to the rats in the nYPF group or nS group,respectively,from day *** rats in every group were sacrificed at 9 *** day 28(P28),on the day when rat's vulva opened in the L group(L-VO),on the day when the first estrous interphase occurred in rats of L group(L-E1),and on the day when the second estrous interphase occurred in rats of L group(L-E2),***:On day 34,all rats in the L group,80%of rats in the nS group,40%of rats in the n group,and 20%of rats in the nYPF group showed complete opening of the *** P28,m RnA level of hypothalamic kisspeptin(Kiss-1)in the L group was significantly higher than that in the n group(Pn the L and nS groups had significantly lower hypothalamic argininephenylalanine-amide(RFamide)-related peptide 3(RFRP-3)m RnA levels than those in the n group(P3 m RnA level was significantly higher in the nYPF group than that in the L group(Pn index of the L and nS groups was significantly higher than that of the n group(Pnd estradiol(E2)level of the nYPF group was significantly lower than that of the n and nS groups(PnA level in the L and nS groups was significantly higher than that in the n and nYPF groups(P3 m RnA level in the L,nYPF,and nS groups was significantly lower than that in the n group(Pnd nS groups was significantly higher than that of the n group(P<0.01),wher

关键词： light puberty precocious kisspeptins RFRP-3 melatonin nourishing Yin and Purging Fire

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Recent Developments of Photodeformable Polymers:From Materials to Applications

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Research 2024年第2期2023卷 729-752页

作者： Shuting Kong Hailan wang Eethamukkala Ubba yuxin Xiao Tao yu Wei Huang Frontiers Science Center for Flexible Electronics(FSCFE) Shaanxi Institute of Flexible Electronics(SIFE)Northwestern Polytechnical University127 West Youyi RoadXian 710072China OMC Research Laboratory.Department of Chemistry School of Advanced SciencesVITVelloreTamilnaduIndia Key Laboratory of Flexible Electronics(KLOFE)&Institute of Advanced Materials(IAM) Nanjing Tech University(NanjingTech)30 South Puzhu RoadNanjing 211816China State Key Laboratory of Organic Electronics and Information Displays&Institute of Advanced Materials(IAM) Nanjing University of Posts and Telecommunications9 Wenyuan RoadNanjing 210023China

Photodeformable polymer materials have a far influence in the fields of flexibility and *** stimulation energy is converted into mechanical energy through molecular *** kinds of photodeformable polymer materials,liquid crystalline polymer(LCP)photodeformable materials have been a hot topic in recent *** such as azobenzene,a-cyanostilbene,and 9,10-dithiopheneanthracene have been widely used in LCP,which are helpful for designing functional molecules to increase the penetration depth of light to change physical *** to the various applications of photodeformable polymer materials,there are many excellent reports in intelligent *** this review,we have systematized LCP containing azobenzene into 3 categories depending on the degree of crosslinking liquid crystalline elastomers,liquid crystalline networks,and linear *** structural,typical polymer materials and their applications are *** issues faced and future directions to be developed for photodeformable polymer materials are also summarized.

关键词： properties. field. crystalline

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Coordination-environment regulation of atomic Co-Mn dual-sites for efficient oxygen reduction reaction

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nano Research 2024年第8期17卷 6841-6848页

作者： Caiting Sun Yarong Liu Zunhang Lv Rui Liu Changli wang Liuhua Li Jinming wang yu Zhang Wenxiu Yang Bo wang Key Laboratory of Cluster Science(Ministry of Education) Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion MaterialsAdvanced Technology Research Institute(Jinan)Advanced Research Institute of Multidisciplinary ScienceSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Library Beijing Institute of TechnologyBeijing 100081China

Precisely designing atomic metal-nitrogen-carbon(M-n-C)catalysts with asymmetric diatomic configurations and studying their structure–activity relationships for oxygen reduction reaction(ORR)are important for zinc-air batteries(ZABs).Herein,a dualatomic-site catalyst(DASC)with Con_(3)S-Mnn_(2)S_(2) configuration was prepared for the cathodes of *** with Co-n-C(Mn-free)and CoMn-n-C(S-free doping),CoMn-n/S-C exhibits excellent half-wave potential(0.883 V)and turnover frequency(1.54 e·s^(−1)·site^(−1)),surpassing most of the reported state-of-the-art Pt-free ORR *** CoMn-n/S-C-based ZABs achieve extremely high specific capacity(959 mAh·g^(−1))and good stability(350 h@5 mA·cm^(−2)).Density functional theory(DFT)calculation shows that the introduction of Mn and S can break the electron configuration symmetry of the original Co 3d orbital,lower the dband center of the Co site,and optimize the desorption behavior of*OH intermediate,thereby increasing the ORR activity.

关键词： metal organic frameworks oxygen reduction reaction dual-atom catalyst coordination-environment regulation zinc-air batteries

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Engineering the axial coordination of cobalt single atom catalysts for efficient photocatalytic hydrogen evolution

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nano Research 2024年第6期17卷 5114-5121页

作者： ning Kang Lingwen Liao Xue Zhang Zhen He Binlu yu Jiahong wang Yongquan Qu Paul KChu Seeram Ramakrishna Xue-Feng yu Xin wang Licheng Bai Materials Interfaces Center Shenzhen Institute of Advanced TechnologyChinese Academy of Sciences(CAS)Shenzhen 518055China Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and NanotechnologyCAS Center for Excellence in NanoscienceInstitute of Solid State PhysicsChinese Academy of SciencesHefei 230031China Department of Chemistry City University of Hong KongKowloonHong Kong 999077China Hong Kong Branch of national Precious Metals Material Engineering Research Center(nPMM) City University of Hong KongKowloonHong Kong 999077China Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Department of Physics and Department of Materials Science and Engineering City University of Hong KongKowloonHong Kong 999077China national University of Singapore(nUS)Centre for nanofibers and nanotechnology Department of Mechanical EngineeringNational University of SingaporeSingapore 117542Singapore

Improving the catalytic activity of non-noble metal single atom catalysts(SACs)has attracted considerable attention in materials *** optimizing the local electronic structure of single atom can greatly improve their catalytic activity,it often involves in-plane modulation and requires high ***,we report a novel strategy to manipulate the local electronic structure of SACs via the modulation of axial Co-S bond anchored onto graphitic carbon nitride(C_(3.n_(4))at room temperature(RT).Each Co atom is bonded to four n atoms and one S atom(Co-(n,S)/C_(3.n_(4)).Owing to the greater electronegativity of S in the Co-S bond,the local electronic structure of the Co atoms is available to be controlled at a relatively moderate ***,when employed for the photocatalytic hydrogen evolution reaction,the adsorption energy of intermediate hydrogen(H*)on the Co atoms is remarkably *** the presence of the Co-(n,S)/C_(3.n_(4)SACs,the hydrogen evolution rates reach up to 10 mmol/(g·h),which is nearly 10 and 2.5 times greater than the rates in the presence of previously reported transition metal/C_(3.n_(4)and noble platinum nanoparticles(PtnPs)/C_(3.n_(4)catalysts,*** to the tailorable axial Co-S bond in the SAC,the local electronic structure of the Co atoms can be further optimized for other photocatalytic *** axial coordination engineering strategy is universal in catalyst designing and can be used for a variety of photocatalytic applications.

关键词： transition metal single-atom local electronic structure photocatalytic hydrogen evolution graphitic carbon nitride axial coordination environment

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Channel-bias-controlled reconfigurable silicon nanowire transistors via an asymmetric electrode contact strategy

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Chip 2024年第3期3卷 8-14页

作者： Wentao Qian Junzhuan wang Jun Xu Linwei yu School of Electronic Science and Engineering/national Laboratory of Solid-State Microstructures Nanjing UniversityNanjing 210093China

Reconfigurable field-effect transistors(R-FETs)that can dynamically reconfigure the transistor polarity,from n-type to p-type channel or vice versa,represent a promising new approach to reduce the logic complexity and granularity of programmable *** R-FETs have been successfully demonstrated upon silicon nanowire(SinW)channels,a pair of extra program gates is still needed to control the source/drain(S/D)*** this work,we propose a rather simple single gate R-FET structure with an asymmetric S/D electrode contact,where the FET channel polarity can be altered by changing the sign of channel bias V_(ds).These R-FETs were fabricated upon an orderly array of planar SinW channels,grown via in-plane solid-liquid-solid mechanism,and contacted by Ti/Al and Pt/Au at the S/D electrodes,***,this channel-bias-controlled R-FET strategy has been successfully testified and implemented upon both p-typedoped(with indium dopants)or n-type-doped(phosphorus)SinW channels,whereas the R-FET prototypes demonstrate an impressive high I_(on/off) ratio of>10^(6) and a steep subthreshold swing of 79 mV/*** results indicate a rather simple,compact and generic enough R-FET strategy for the construction of a new generation of SinW-based programmable and low-power electronics.

关键词： Catalytic Si nanowires Asymmetric electrodes Reconfigure transistor

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Aspartoacylase suppresses prostate cancer progression by blocking LYn activation

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Military Medical Research 2024年第2期11卷 180-205页

作者： Hong Weng Kang-Ping Xiong wang wang Kai-yu Qian Shuai yuan Gang wang Fang yu Jun Luo Meng‑Xin Lu Zhong‑Hua Yang Tao Liu Xing Huang Hang Zheng Xing-Huan wang Department of Urology Zhongnan Hospital of Wuhan UniversityWuhan 430071China Center for Evidence‑Based and Translational Medicine Zhongnan Hospital of Wuhan UniversityWuhan 430071China Department of Biological Repositories Zhongnan Hospital of Wuhan UniversityWuhan 430071China Hubei Key Laboratory of Tumor Biological Behaviors Wuhan 430071China Department of Pathology Zhongnan Hospital of Wuhan UniversityWuhan 430071China Center for Pathology and Molecular Diagnostics Wuhan UniversityWuhan 430071China Wuhan Research Center for Infectious Diseases and Cancer Chinese Academy of Medical SciencesWuhan 430071China

Background:Globally,despite prostate cancer(PCa)representing second most prevalent malignancy in male,the precise molecular mechanisms implicated in its pathogenesis remain ***,elucidating the key molecular regulators that govern disease progression could substantially contribute to the establishment of novel therapeutic strategies,ultimately advancing the management of ***:A total of 49 PCa tissues and 43 adjacent normal tissues were collected from January 2017 to December 2021 at Zhongnan Hospital of Wuhan *** advanced transcriptomic methodologies were employed to identify differentially expressed mRnAs in *** expression of aspartoacylase(ASPA)in PCa was thoroughly evaluated using quantitative real-time PCR and Western blotting *** elucidate the inhibitory role of ASPA in PCa cell proliferation and metastasis,a comprehensive set of in vitro and in vivo assays were conducted,including orthotopic and tumor-bearing mouse models(n=8 for each group).A combination of experimental approaches,such as Western blotting,luciferase assays,immunoprecipitation assays,mass spectrometry,glutathione S-transferase pulldown experiments,and rescue studies,were employed to investigate the underlying molecular mechanisms of ASPA's action in *** Student‘s t-test was employed to assess the statistical significance between two distinct groups,while one-way analysis of variance was utilized for comparisons involving more than two groups.A two-sided Pndicate statistical ***:ASPA was identified as a novel inhibitor of PCa *** expression of ASPA was found to be significantly down-regulated in PCa tissue samples,and its decreased expression was independently associated with patients’prognosis(HR=0.60,95%CI 0.40–0.92,P=0.018).Our experiments demonstrated that modulation of ASPA activity,either through gain-or loss-of-function,led to the suppression or enhancement of PCa cell proliferation,mig

关键词： Prostate cancer Aspartoacylase LYn JnK AP-1 C-Jun Phosphorylation

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Experimental and theoretical investigation of sulfur-doped g-C_(3.n_(4)nanosheets/FeCo_(2)O_(4)nanorods S-scheme heterojunction for photocatalytic H_(2)evolution

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nano Research 2024年第9期17卷 8007-8016页

作者： Haitao wang Lianglang yu Jiahe Peng Jing Zou Weiping Gong Jizhou Jiang School of Chemistry and Environmental Engineering School of Environmental Ecology and Biological EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices Huizhou UniversityHuizhou 516007China

g-C_(3.n_(4)emerges as a promising metal-free semiconductor photocatalyst due to its cost-effectiveness,facile synthesis,suitable visible light response,and robust thermal ***,its practical application in photocatalytic hydrogen evolution reaction(HER)is impeded by rapid carrier recombination and limited light absorption *** this study,we successfully develop a novel g-C_(3.n_(4)-based step-scheme(S-scheme)heterojunction comprising two-dimensional(2D)sulfur-doped g-C_(3.n_(4)nanosheets(SCn)and one-dimensional(1D)FeCo_(2)O_(4)nanorods(FeCo_(2)O_(4)),demonstrating enhanced photocatalytic HER *** engineered SCn/FeCo_(2)O_(4)S-scheme heterojunction features a well-defined 2D/1D heterogeneous interface facilitating directed interfacial electron transfer from FeCo_(2)O_(4)to SCn,driven by the lower Fermi level of SCn compared to FeCo_(2)O_(4).This establishment of electron-interacting 2D/1D S-scheme heterojunction not only facilitates the separation and migration of photogenerated carriers,but also enhances visible-light absorption and mitigates electron-hole pair *** structure analysis and density functional theory calculations corroborate that the carrier migration in the SCn/FeCo_(2)O_(4)photocatalyst adheres to a typical S-scheme heterojunction mechanism,effectively retaining highly reactive photogenerated ***,the optimized SCn/FeCo_(2)O_(4)heterojunction exhibits a substantially high hydrogen production rate of 6303.5μmol·g^(-1)·h^(-1)under visible light excitation,which is 2.4 times higher than that of the ***,the conjecture of the S-scheme mechanism is confirmed by in situ XPS *** 2D/1D S-scheme heterojunction established in this study provides valuable insights into the development of high-efficiency carbon-based catalysts for diverse energy conversion and storage applications.

关键词： g-C_(3.n_(4) FeCo_(2)O_(4) S-scheme heterojunction photocatalytic hydrogen evolution reaction(HER)

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