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Experimental and computational analysis of the structure-activity relationship of ionic gel electrolytes based on bistrifluoromethanesulfonimide salts for supercapacitors

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Journal of Materiomics 2024年第6期10卷 1222-1233页

作者： Wei chen Ying Wei Xiuling Dong Zhong-Xia Wang Zheng xing Qingguo Zhang Xiang Liu College of Chemistry and Materials Engineering Bohai UniversityJinzhou121013LiaoningChina College of Chemistry and Chemical Engineering Gannan Normal UniversityGanzhou341000JiangxiChina Institute of Medicine&Chemical Engineering Zhenjiang CollegeZhenjiang212028JiangsuChina

Ionic gel(IG)electrolytes are emerging as promising components for the development of next-generation supercapacitors(SCs),offering benefits in terms of safety,cost-effectiveness,and *** ionic conductivity,stability,and mechanical properties of the gel electrolyte are relevant factors to be considered and the key to improving the performance of the ***,the structure–activity relationship between the internal structure of IGs and their SC properties is not fully *** the current study,the intuitive and regular structure–activity relationship between the structure and properties of IGs was revealed via combining computational simulation and *** terms of conductivity,the ionic liquid(IL)([EMIM][TFSI])in the IG has a high self-diffusion coefficient calculated by molecular dynamics simulation(MDS),which is conductive to transfer and then improves the *** radial distribution function of the MDS shows that the larger the g(r)between the particles in the polymer network,the stronger the *** stability,IGs based on[EMIM][TFSI]and[EOMIM][TFSI]ILs have higher density functional theory calculated binding energy,which is reflected in the excellent thermal stability and excellent capacitor cycle *** on the internal pore size distribution and stress-strain characterization of the gel network([ME3MePy][TFSI]and[BMIM][TFSI]as additives),the highly crosslinked aggregate network significantly reduces the internal mesoporous distribution and plays a leading role in improving the mechanical properties of the *** using this strategy,it will be possible to design the ideal structure of the IG and achieve excellent performance.

关键词： Ionic gel electrolytes Density functional theory Molecular dynamics simulation Self-diffusion coefficient Mean square displacement

Efficient recovery of tungsten from scheelite concentrates using a sulfur-phosphorus mixed acid leaching system

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Tungsten 2024年第4期6卷 821-832页

作者： Jiang-Tao Li Li-Li Gao Zhong-Wei Zhao Xu-Heng Liu xing-Yu chen School of Metallurgy and Environment Central South University Key Laboratory of Hunan Province for Metallurgy and Material Processing of Rare Metals

In recent years,a new process for leaching scheelite concentrates with sulfur-phosphorus mixed acid has been successfully *** process suffers from the elimination of the retarding effect of calcium sulfate,the selective extraction of tungsten from the H3PW12O40-H2SO4-H3PO4mixture solution,and the removal of introduced ***,in this paper,we investigated the inhibition measures of a calcium sulfate-blocking membrane,the selective extraction of tungsten by ion exchange,and the removal of phosphorus by the magnesium ammonium salt *** results showed that the addition of calcium sulfate whisker seeds and a higher H3PO4concentration inhibited spontaneous diffuse nucleation,promoted crystal growth,and avoided the formation of a dense blocking *** 98 wt.% of the scheelite concentrate was digested by *** selective adsorption of PW12O403-was realized using D301 resin,and the extraction efficiency of tungsten exceeded 99.9%.After desorption with ammonia water,PW12O403-was depolymerized into WO42.and PO43-.99.9 wt.% of phosphorus was removed in the form of MgNH4PO4by the magnesium ammonium salt method,and the residual phosphorus concentration in the solution was lower than 10 mg·*** purification,the highest-grade ammonium paratungstate product was prepared by evaporative crystallization.

关键词： Calcium sulfate Ion exchange Scheelite concentrates Sulfur-phosphorus mixed acid Tungsten

In-situ interfacial passivation and self-adaptability synergistically stabilizing all-solid-state lithium metal batteries

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Journal of Energy Chemistry 2024年第1期88卷 282-292,I0007页

作者： Huanhui chen xing Cao Moujie Huang Xiangzhong Ren Yubin Zhao Liang Yu Ya Liu Liubiao Zhong Yejun Qiu Shenzhen Engineering Lab of Flexible Transparent Conductive Films School of Materials Science and EngineeringHarbin Institute of TechnologyShenzhen 518055GuangdongChina Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems School of Materials Science and EngineeringHarbin Institute of TechnologyShenzhen 518055GuangdongChina College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060GuangdongChina School of Resource and Environmental Sciences Wuhan UniversityWuhan 430072HubeiChina

The function of solid electrolytes and the composition of solid electrolyte interphase(SEI)are highly significant for inhibiting the growth of Li ***,we report an in-situ interfacial passivation combined with self-adaptability strategy to reinforce Li_(0.33)La_(0.557)TiO_(3)(LLTO)-based solid-state ***,a functional SEI enriched with LiF/Li_(3)PO_(4) is formed by in-situ electrochemical conversion,which is greatly beneficial to improving interface compatibility and enhancing ion *** the polarized dielectric BaTiO_(3)-polyamic acid(BTO-PAA,BP)film greatly improves the Li-ion transport kinetics and homogenizes the Li *** expected,the resulting electrolyte offers considerable ionic conductivity at room temperature(4.3 x 10~(-4)S cm^(-1))and appreciable electrochemical decomposition voltage(5.23 V)after electrochemical *** Li-LiFePO_(4) batteries,it shows a high specific capacity of 153 mA h g^(-1)at 0.2C after 100 cycles and a long-term durability of 115 mA h g^(-1)at 1.0 C after 800 ***,a stable Li plating/stripping can be achieved for more than 900 h at 0.5 mA cm^(-2).The stabilization mechanisms are elucidated by ex-situ XRD,ex-situ XPS,and ex-situ FTIR techniques,and the corresponding results reveal that the interfacial passivation combined with polarization effect is an effective strategy for improving the electrochemical *** present study provides a deeper insight into the dynamic adjustment of electrode-electrolyte interfacial for solid-state lithium batteries.

关键词： Solid-state lithium batteries Composite solid electrolyte In-situ polymerization Interfacial passivation layer Self-adaptability

Graphene-anchored sodium single atoms:A highly active and stable catalyst for transesterification reaction

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Nano Research 2024年第6期17卷 4979-4985页

作者： Song-Song Peng Yao Nian xing-Ru Song Xiang-Bin Shao chen Gu Zhi-Wei xing Shi-Chao Qi Peng Tan You Han Xiao-Qin Liu Lin-Bing Sun State Key Laboratory of Materials-Oriented Chemical Engineering Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)College of Chemical EngineeringNanjing Tech University30 South Puzhu RoadNanjing 211816China School of Chemical Engineering and Technology Tianjin UniversityTianjin 300072China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

Solid strong base catalysts have received considerable attention in various organic reactions due to their facile separation,neglectable corrosion,and environmental *** great progress has been made in the preparation of solid strong base catalysts,it is still challenging to avoid basic sites aggregation on support and active sites loss in reaction ***,we report a tandem redox strategy to prepare Na single atoms on graphene,producing a new kind of solid strong base catalyst(Na1/G).The base precursor NaNO_(3)was first reduced to Na2O by graphene(400℃)and successively to single atoms Na anchored on the graphene vacancies(800℃).Owing to the atomically dispersed of basicity,the resultant catalyst presents high activity toward the transesterification of methanol and ethylene carbonate to synthesize dimethyl carbonate(turnover frequency(TOF)value:125.7 h^(−1)),which is much better than the conventional counterpart Na2O/G and various reported solid strong bases(TOF:1.0-90.1 h^(−1)).Furthermore,thanks to the basicity anchored on graphene,the Na1/G catalyst shows excellent durability during *** work may provide a new direction for the development of solid strong base catalysts.

关键词： solid strong base catalyst basic sites redox graphene single Na atoms

Biological factors driving colorectal cancer metastasis

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World Journal of Gastrointestinal Oncology 2024年第2期16卷 259-272页

作者： Shuai-xing An Zhao-Jin Yu chen Fu Min-Jie Wei Long-Hai Shen Department of Pharmacology School of PharmacyChina Medical UniversityShenyang 110122Liaoning ProvinceChina Liaoning Key Laboratory of Molecular Targeted Antitumor Drug Development and Evaluation Liaoning Cancer Immune Peptide Drug Engineering Technology Research CenterKey Laboratory of Precision Diagnosis and Treatment of Gastrointestinal Tumors(China Medical University)Ministry of EducationShenyang 110122Liaoning ProvinceChina BD Department Greenpine Pharma Group Co.LtdTianjin 300020China Center of Oncology Genertec Liaoyou Gem Flower HospitalPanJin 124010Liaoning ProvinceChina

Approximately 20%of colorectal cancer(CRC)patients present with metastasis at *** Stage I-III CRC patients who undergo surgical resection,18%typically suffer from distal metastasis within the first three years following initial *** median survival duration after the diagnosis of metastatic CRC(mCRC)is only 9 *** is traditionally considered to be an advanced stage malignancy or is thought to be caused by incomplete resection of tumor tissue,allowing cancer cells to spread from primary to distant organs;however,increa-sing evidence suggests that the mCRC process can begin early in tumor *** patients present with high heterogeneity and diverse cancer phenotypes that are classified on the basis of molecular and morphological *** genomic and nongenomic events can induce subclone diversity,which leads to cancer and *** the course of mCRC,metastatic cascades are associated with invasive cancer cell migration through the circulatory system,extravasation,distal seeding,dormancy,and reactivation,with each step requiring specific molecular ***,cancer cells presenting neoantigens can be recognized and eliminated by the immune *** this review,we explain the biological factors that drive CRC metastasis,namely,genomic instability,epigenetic instability,the metastatic cascade,the cancer-immunity cycle,and external lifestyle *** remarkable progress in CRC research,the role of molecular classification in therapeutic intervention remains *** review shows the driving factors of mCRC which may help in identifying potential candidate biomarkers that can improve the diagnosis and early detection of mCRC cases.

关键词： cancer Metastasis cascade Cancer immunity Genomic variation Epigenetic instability Lifestyle factor

Boost VS_(2) electrochemical reactive kinetics by regulating crystallographic planes and coupling carbon matrix for high performance sodium-ion storage

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Rare Metals 2024年第1期43卷 98-112页

作者： Min Zeng Ming-Shan Wang Lin chen En-Zhi Li Zhen-Liang Yang Dan Zhou Hai-Jiao Xie Jun-chen chen Zhi-Yuan Ma Bing-Shu Guo Bo Yu xing Li School of New Energy and Materials Southwest Petroleum UniversityChengdu 610500China Energy Storage Research Institute Southwest Petroleum UniversityChengdu 610500China Institute of Materials China Academy of Engineering PhysicsMianyang 621908China Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and TechnologyBeijingBeijing 100083China Hangzhou Yanqu Information Technology Co. Ltd.Hangzhou 310003China

Vanadium disulfide(VS_(2)) as a typical two-dimensional transition metal chalcogenide has excellent competitiveness for sodium-ion storage due to its wide layer spacing(0.575 nm),high theoretical capacity of 932.ah·g^(-1) originating from multi-electron electrochemical ***,continuous sodiation process accompanied by crystal structural evolution and collapse cause rapid capacity ***,novel few-layer VS_(2)nanosheets with open(001) crystal planes are in-situ constructed on reduced graphene oxide to solve these issues mentioned *** indicates that few-layer VS_(2)provides more Na^(+) storage activity due to the low Na^(+)surface migration energy barrier on exposed crystal(001)*** flexible and high electronic conductivity of carbon matrix also effectively builds multi-level buffer structure and electron transport kinetics to boost the Na^(+)insertion/conversion reactive activity on VS_(2) as well as Na^(+) pseudocapacitance storage kinetics on edges and defects of nano *** coupling effects result in high rate capability and long cycling stability as a battery/capacitor *** delivers conspicuous high energy density of 81 and 40 Wh·kg^(-1) at power density of 118 and 10,286W·kg^(-1),as well as 80% energy retention rate after 5000cycles,confirming its great application potential in sodiumbased storage devices.

关键词： Vanadium disulfide Reduced graphene oxide Anode Sodium-ion battery Sodium-ion capacitor

Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication

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Chinese Chemical Letters 2024年第9期35卷 432-436页

作者： Xiaxia xing Xiaoyu chen Zhenxu Li Xinhua Zhao Yingying Tian Xiaoyan Lang Dachi Yang Tianjin Key Laboratory of Optoelectronic Sensor and Sensing Network Technology Engineering Research Center of Thin Film Optoelectronics TechnologyMinistry of Education and Department of ElectronicsCollege of Electronic Information and Optical EngineeringNankai UniversityTianjin 300350China

Highly selective and remotely communicable nitrogen dioxide(NO_(2))sensing may contribute to future Internet of Things in environmental ***,room-temperature NO_(2)sensing materials such as carbon materials is still less than satisfactory due to their insensitive interaction with target ***,polyethylene imine functionalized three-dimensional(3D)carbon framework(PEI/C framework)has been developed for enhanced selective NO_(2)sensing,via combined template synthesis and subsequent ***,the 3D PEI/C framework is observed porous shape with irregular ***,the response of C framework to NO_(2)increases while those of interfering gases decrease after being functionalized with ***,the sensor prototypes show a 100 ppb-concentration detection limit at room ***,such excellent NO_(2)sensing is attributed to the large specific surface ratio of porous 3D PEI/C framework,in which PEI serves as an active layer for target NO_(2),while a passivated one for interfering ***,such PEI/C framework sensor prototype is simulated for NO_(2)sensing device and communicated with a smartphone,showing great potential in future intelligent environmental monitoring.

关键词： PEI/C framework Nitrogen dioxide sensing Enhanced selectivity Smartphone communication Practical monitoring simulation

Light-stabilized GIL1 suppresses PIN3 activity to inhibit hypocotyl gravitropism

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Journal of Integrative Plant Biology 2024年第9期66卷 1886-1897页

作者： Xiaolian Wang Yanfang Yuan Laurence Charrier Zhaoguo Deng Markus Geisler xing Wang Deng Haodong chen Center for Plant Biology School of Life SciencesTsinghua UniversityBeijing 100084China Tsinghua‐Peking Center for Life Sciences Beijing 100084China School of Advanced Agricultural Sciences and School of Life Sciences Peking‐Tsinghua Center for Life SciencesPeking UniversityBeijing 100871China Department of Biology University of FribourgFribourg 1700Switzerland

Light and gravity coordinately regulate the directional growth of *** Gravitropic in the Light 1(GIL1)inhibits the negative gravitropism of hypocotyls in red and far-red light,but the underlying molecular mechanisms remain *** study found that GIL1 is a plasma membrane-localized *** endodermal cells of the upper part of hypocotyls,GIL1 controls the negative gravitropism of ***1 directly interacts with PIN3 and inhibits the auxin transport activity of *** of PIN3 suppresses the abnormal gravitropic response of gil1 *** GIL1 protein is unstable in darkness but it is stabilized by red and far-red ***,our data suggest that light-stabilized GIL1 inhibits the negative gravitropism of hypocotyls by suppressing the activity of the auxin transporter PIN3,thereby enhancing the emergence of young seedlings from the soil.

关键词： GIL1 gravitropism hypocotyls light PIN3

Cost-Efficient Edge Caching for NOMA-Enabled IoT Services

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China Communications 2024年第8期21卷 182-191页

作者： chen Ying xing Hua Ma Zhuo chen Xin Huang Jiwei School of Computer Science Beijing Information Science and Technology UniversityBeijing 100101China Beijing Key Laboratory of Petroleum Data Mining China University of PetroleumBeijing 102249China

Mobile edge computing(MEC)is a promising paradigm by deploying edge servers(nodes)with computation and storage capacity close to IoT *** Providers can cache data in edge servers and provide services for IoT devices,which effectively reduces the delay for acquiring *** the increasing number of IoT devices requesting for services,the spectrum resources are generally *** order to effectively meet the challenge of limited spectrum resources,the Non-Orthogonal Multiple Access(NOMA)is proposed to improve the transmission *** this paper,we consider the caching scenario in a NOMA-enabled MEC *** the devices compete for the limited resources and tend to minimize their own *** formulate the caching problem,and the goal is to minimize the delay cost for each individual device subject to resource *** reformulate the optimization as a non-cooperative game *** prove the existence of Nash equilibrium(NE)solution in the game ***,we design the Game-based Cost-Efficient Edge Caching Algorithm(GCECA)to solve the *** effectiveness of our GCECA algorithm is validated by both parameter analysis and comparison experiments.

关键词： caching cost Internet of Things mobile edge computing non-orthogonal multiple access