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吉林师范大学学报（自然科学版） 2009年第1期30卷 21-22,33页

作者：车广波刘春波刘长宝王庆伟孙军王艰吉林师范大学化学学院吉林四平136000 吉林师范大学应用化学研究所吉林四平136000 医药中间体吉林省高等学校工程研究中心吉林四平136000

研究了由双环戊二烯热分解制备环戊二烯的工艺方法,优化了环戊二烯和丙烯醛Diels-Alder反应的条件,所得产品双环[2,2,1]-5-庚烯-2-醛的纯度高达98%,收率达到96%.

关键词：环戊二烯丙烯醛 Diels-Alder反应

H-TiO_(2)/MoS_(2)的调控制备及其光催化活性研究

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吉林师范大学学报（自然科学版） 2021年第3期42卷 34-41页

作者：王丹丹李寓函邓旭闻晏于博刘春波车广波吉林师范大学环境科学与工程学院吉林四平136000 吉林师范大学环境友好材料制备与应用教育部重点实验室吉林长春130103 吉林师范大学吉林省高校环境材料与污染控制重点实验室吉林四平136000 吉林师范大学化学学院吉林四平136000

通过煅烧P25合成系列氢化二氧化钛(H-TiO_(2)-20、H-TiO_(2)-40、H-TiO_(2)-60),利用水热法制备出H-TiO_(2)-40/MoS_(2)复合光催化剂,并通过XRD、XPS、SEM、PL等对合成样品的形貌、组成以及光学性质进行了分析表征.在可见光辐照下,以四... 详细信息

通过煅烧P25合成系列氢化二氧化钛(H-TiO_(2)-20、H-TiO_(2)-40、H-TiO_(2)-60),利用水热法制备出H-TiO_(2)-40/MoS_(2)复合光催化剂,并通过XRD、XPS、SEM、PL等对合成样品的形貌、组成以及光学性质进行了分析表征.在可见光辐照下,以四环素(TC)、亚甲基蓝(MB)为目标污染物的光催化降解实验表明,H-TiO_(2)-40样品的催化性能明显优于P25,而且H-TiO_(2)-40/MoS_(2)对MB的降解效率在4 h内达到92%,是纯H-TiO_(2)-40的1.32倍.另外,在4次循环光催化实验中,H-TiO_(2)-40/MoS_(2)对MB的降解率仍达到88%.

关键词：氢化二氧化钛光催化四环素亚甲基蓝可见光

二吡啶[3,2-a:2’,3’-c]并吩嗪构建的Co(Ⅱ)配合物的合成及结构表征

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吉林师范大学学报（自然科学版） 2016年第4期37卷 101-105页

作者：李秀颖吴秀贺李丽娜郭如霞杨艺乔宇车广波吉林师范大学环境友好材料制备与应用教育部重点实验室吉林四平136000 吉林师范大学化学学院吉林四平136000

利用水热合成法合成了一种新的配合物[Co(1,4-bdoa)(DPPZ)_2]_n·2n H)_2O(1),其中DPPZ为二吡啶[3,2-a:2’,3’-c]并吩嗪,1,4-H)_2bdoa为1,4-苯氧基二乙酸.同时,利用元素分析、红外光谱(IR)、粉末X-射线衍射(XRD)、热重分析(TGA)和X-射线单晶衍射等多种检测手段对配合物的晶体结构进行了表征.配合物(1)为三斜晶系,空间群为P_ī,a=0.820 36(11)nm,b=0.994 55(13)nm,c=1.237 63(17)nm,α=110.946(2)°,β=96.507(2)°,γ=95.045(2)°,V=0.927 9(2)nm^3,Z=1.配合物(1)为一维的链状结构,又通过π-π堆积以及氢键作用形成稳定的二维超分子层结构.

关键词： 1,10-邻菲罗啉衍生物 1,4-苯氧基二乙酸 Co(Ⅱ)配合物

磁响应型SERS印迹探针的制备并用于选择性检测水体中的2,6-二氯苯酚

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吉林师范大学学报（自然科学版） 2020年第3期41卷 86-92页

作者：李洪吉张金月任楚奇任桐高炎车广波王庆伟吉林师范大学环境科学与工程学院吉林四平136000 吉林师范大学环境友好材料制备与应用教育部重点实验室吉林长春130103 吉林师范大学吉林省高校环境材料与污染控制重点实验室吉林四平136000

将表面增强拉曼散射技术(SERS)与分子印迹技术(MIT)相结合,合成了一种新型印迹传感器.本实验以Fe3O4@SiO2为支撑材料,利用磁性分离技术代替传统离心分离技术,以降低样品损失.随后,将银纳米颗粒固定在Fe3O4@SiO2表面作为SERS基底,通过沉... 详细信息

将表面增强拉曼散射技术(SERS)与分子印迹技术(MIT)相结合,合成了一种新型印迹传感器.本实验以Fe3O4@SiO2为支撑材料,利用磁性分离技术代替传统离心分离技术,以降低样品损失.随后,将银纳米颗粒固定在Fe3O4@SiO2表面作为SERS基底,通过沉淀聚合技术合成Fe3O4@Ag@MIPs,并用于选择性检测水溶液中2,6-DCP.实验结果表明,Fe3O4@Ag@MIPs具有良好的磁分离性能、灵敏的检测性能以及选择性.该研究证实Fe3O4@Ag@MIPs展现出较高的灵敏度和选择性,能够有效地选择性检测水体中残留的2,6-DCP.同时,也为环境水中残留的其他氯酚类污染物的检测提供了一种新的方法.

关键词：表面增强拉曼散射技术分子印迹聚合物磁性分离选择性检测 2,6-二氯苯酚

A Fe(Ⅱ) Coordination Polymer Based on 1,10-Phenanthroline Derivative and Oxalic Acid:Synthesis,Structure,and Properties

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Chinese Journal of Structural Chemistry 2021年第3期40卷 317-323,272页

作者： LI Xiu-Ying GAO Lin CHE Guang-Bo YAN Yong-Sheng LI Chun-Xiang School of Chemistry and Chemical Engineering Jiangsu UniversityZhenjiang 212013China College of Chemistry Jilin Normal UniversitySiping 136000China College of Environmental Engineering Jilin Normal UniversitySiping 136000China

A Fe-based coordination polymer,[Fe(C_(2)O_4)_(0.5)(4-NCP)]_(n)·2nH_(2)O (1,4-HNCP=2-(4-carboxyphenyl)-1H-imidazo(4,5-f)-(1,10)phenanthroline,H_(2)C_(2)O_(4)=oxalic acid),was hydrothermally synthesized and characterized by infrared spectrum,elemental analysis,single-crystal X-ray diffraction,power X-ray diffraction,and UV-vis absorption *** analyses reveal that polymer 1 possesses a (4,4)-connected 2D *** addition,1 shows photocatalytic activity toward the degradation of rhodamine B (RhB) in the presence of H_(2)O_(2) under visible light illumination.

关键词： Fe-based coordination polymer hydrothermal synthesis crystal structure photocatalytic activity

A novel Cu(I) complex based organic ultraviolet optical sensor

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Optoelectronics Letters 2009年第1期5卷 14-17页

作者：车广波刘春波徐占林李文连孔治国王庆伟 Department of Chemistry Jilin Normal University Stata Key Laboratory of the Excited States Process Changchun Institute of OpticsFine Mechanics and PhysicsChinese Academy of Sciences Institute of Applied Chemistry Jilin Normal University

A novel Cu(I) complex with the formula of [Cu(DPEphos)(Dicnq)]BF4(CuDD) was synthesized and characterized by X-ray single crystal diffraction method,in which DPEphos and Dicnq denote bis[2-(diphenylphosphino)phenyl]ether and 6,7-Dicyanodipyrido[2,2-d:2 ,3 -f] quinoxaline,*** ultraviolet optical sensor based on photovoltaic diode is fabricated by using CuDD as an electron acceptor and 4,4′,4″-tris-(2-methylphenyl phenylamino) triphenylamine(m-MTDATA) as an electron *** sensor is sensit...

关键词： Conversion efficiency Ethers Light Open circuit voltage Optical sensors Single crystals

基于芘功能化核壳型磁性二氧化硅纳米微球的荧光传感器及其对水溶液中汞离子的检测和去除

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Syntheses, Crystal Structures and Photoluminescence of Three Complexes Based on 3,5-(3-Carboxybenzyloxy)benzoic Acid

发光学报 2018年第12期

作者：王岩岩唐美瑶申赫车广波苏斌

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Chinese Journal of Structural Chemistry 2019年第6期38卷 947-955页

作者： LIU Li-Hui WANG Xuan-Bo LIU Bo QIAO Yu JIANG Wei CHE Guang-Bo LIU Chun-Bo Institute of Green Chemistry and Chemical Technology Jiangsu UniversityZhenjiang 212013China Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University) Ministry of EducationChangchun 130103China College of Environmental Science and Engineering Jilin Normal UniversitySiping 136000China

Three stable coordination polymers(CPs) assembled by 3,5-(carboxybenzyloxy)-benzoic acid(H3 L) and 1,10-phenanthroline(phen), namely, [Zn(HL)(phen)]n(1), [Cd(HL)(phen)]_n(2) and [Co(HL)(phen)]_n(3), have been synthesized under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, infrared(IR) spectroscopy and powder X-ray diffraction(PXRD). Investigation on crystal structure indicates that complexes 1 ～ 3 exhibit similar architecture. In these complexes, metal ions coordinate with H3 L and phen ligands, forming infinite 1 D chains. Then the adjacent chains combine together through intramolecular hydrogen-bonding interactions, generating 2 D supramolecular architectures. In addition, complexes 1～3 present excellent thermal stabilities and 1 and 2 exhibit strong luminescent emission bands at room temperature.

关键词： coordination polymer crystal structure photoluminescence,3,5-(carboxybenzyloxy)benzoic acid

Synthesis, Crystal Structure and Theoretical Calculation of a Novel 2D Network of Manganese(Ⅱ) Complex

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Chinese Journal of Structural Chemistry 2019年第12期38卷 2113-2120页

作者： LI Xiu-Ying YIN Tian-Qi WANG Chun-Yue ZHANG Jing WANG Yue GAO Lin HU Bo LIU Bo JIANG Wei CHE Guang-Bo Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University) Ministry of EducationChangchun 130103China College of Chemistry Jilin Normal UniversitySiping 136000China College of Environmental Engineering Jilin Normal UniversitySiping 136000China

A novel complex, [Mn（2-NCP）（H2BTC）（H2O）]n（1, 1,3,5-H3BTC = 1,3,5-benzenetricarboxylic acid, 2-HNCP = 2-（2-carboxyphenyl）-1 H-imidazo（4,5-f）-（1,10）phenanthroline）, was hydrothermally synthesized and structurally characterized by elemental analysis, IR, XRD and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 exhibits a（6, 6）-connected topology network with a Schl?fli symbol of（63）. The adjacent 2 D layers are further stacked via strong hydrogen-bonding interactions, giving a 3 D supramolecular framework. In addition, the structure of complex 1 was calculated by the B3LYP/LANL2 DZ method by Gaussian program. The results from natural bond orbital（NBO） analysis shows obvious covalent interaction between the coordinated atoms and Mn（Ⅱ） ion.

关键词： manganese(Ⅱ)complex hydrothermal synthesis crystal structure theoretical calculation