Iridium(iii) complexes based fluorescent supramolecular metallohydrogel
作者单位:Bioinspired Soft Mater UnitOkinawa Institute of Science and Technology Graduate University
会议名称:《第十一届全国化学生物学学术会议》
会议日期:2019年
学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
关 键 词:iridium complex self-assembling
摘 要:Metal complexes,besides being able to impart rich optical,electronic,redox,or magnetic properties to supramolecular hydrogels,also offer a unique geometrical control to prearrange the self-assembly motif prior to ***,we design and synthesize a cationic iridium(iii) – peptide complexes to investigate its capability of gelation in different solvent system and varied *** hydrolysis,assembled nanostructures can gradually transit to different *** work facilitates the development related metallohydrogel and attempt to extend the iridium(iii) metallohydrogel molecules,in order to link the optical property changes to the different self-assembly state.