Application of Zhu's Equation in Lewis Base-Acid Reactions——Limitations of Mayr's Equation and sN(N+E)
作者单位:The State Key Laboratory of Elemento-Organic ChemistryNankai UniversityDepartment of Chemistry
会议名称:《中国化学会第十二届全国物理有机化学学术会议》
会议日期:2017年
学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
摘 要:It is well known that the reactions of Lewis bases (X) with Lewis acids (Y) to form adducts (eq 1)are one type of very important chemical reactions in chemistry,it has been a chemist’s dream to reliably predict the reaction rate constants using physical parameters of *** order to realize this dream,