Synthesis and characterization of conjugated perylene bisimide copolymers tuned by series of oligo(phenyleneethynylene)s

作     者：Huibiao Liu Xiaorong He Yuliang Li~* Daoben Zhu Beijing National Laboratory for Molecular Science,CAS Key Laboratory of organic solid,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,P.R.China 

会议名称：《The 9th China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena》

会议日期：2007年

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

摘      要：We designed and synthesized three conjugated copolymers based on perylene bisimide and oligo(phenyleneethynylene)(OPE)*** electronic absorption,fluorescence and redox potentials of the copolymers were studied,which exhibited regular changes with the number of OPE chromophores increasing *** measurements were also performed and quantum efficiencies were *** result demonstrated that an increase in the number of OPEs in the polymers could improve the photocurrent generation efficiency.