To Photoredox or Not in Neutral Aqueous Solutions for Selected Benzophenone and Anthraquinone Derivatives
作者单位：Department of ChemistryThe University of Hong Kong Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of EducationCollege of Chemistry and Materials ScienceNorthwest University
会议名称：《第十五届全国化学动力学会议》
会议日期：2017年
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要：正The experimental and theoretical results in neutral aqueous solutions reported here indicate that a proton-coupled electron transfer（PCET）from an alcohol C-H bond to the para-carbonyl is the initial and crucial process for the photoredox reaction of 2-（1-hydroxyethyl）-anthraquinone（HEAQ）to occur while the counterpart3-（hydroxymethyl）-benzophenone（3-BPOH）compound displays a different PCET from an alcohol O-H bond to