Modulation of single-molecule magnet behavior via photochemical [2+2] cycloaddition
作者单位：Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional Universitat de Barcelona School of Chemistry & Chemical Engineering Sun Yat-Sen University
会议名称：《中国化学会第七届全国结构化学学术会议》
会议日期：2016年
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
摘 要：The first example of phototunable SMM has been *** on the potential[2+2]photodimerization reaction of bpe(bpe=1,2-bis(4-pyridyl)ethene)ligands,we successfully synthesized a mononuclear Dy(Ⅲ)-based complex,[Dy(bpe)(HO)(NO)]NO·2bpe(1),in which the coordinated bpe underwent[2+2]transformations upon UV irradiation,leading to an